Celanese Uhmw Pe 402m13

Celanese UHMW-PE 402M13

    • Product Name: Celanese UHMW-PE 402M13
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 639718
    Chemical Family Ultra-high molecular weight polyethylene (UHMW-PE)
    Molecular Weight 4.0 million g/mol
    Density 0.930 g/cm³
    Bulk Density 0.43 g/cm³
    Particle Size 130 µm
    Melting Point 135 °C
    Crystallinity 45%
    Tensile Modulus 700 MPa
    Tensile Strength At Yield 20 MPa
    Elongation At Break 300%
    Charpy Notched Impact Strength 100 kJ/m²
    Shore D Hardness 62
    Water Absorption <0.01%
    Thermal Conductivity 0.4 W/mK
    Coefficient Of Linear Thermal Expansion 200 µm/m°C
    Dielectric Constant 2.3
    Volume Resistivity >10^15 ohm·cm
    Flammability UL 94 HB

    As an accredited Celanese UHMW-PE 402M13 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Celanese UHMW-PE 402M13 is typically packaged in 25 kg multiwall paper bags, palletized, or 1,000 kg bulk bags for shipment.
    Container Loading (20′ FCL) Celanese UHMW-PE 402M13, 20′ FCL loading: palletized bags, securely stowed in a dry container for safe ocean transport.
    Shipping Celanese UHMW-PE 402M13 is a non-hazardous ultra-high molecular weight polyethylene powder. It is typically shipped in sealed, moisture-resistant 20–25 kg bags or drums, palletized and shrink-wrapped. Transport is not regulated as dangerous goods under DOT, IMDG, IATA, or ADR/RID; keep dry and away from heat and oxidizers.
    Storage Store Celanese UHMW-PE 402M13 in a cool, dry, well-ventilated area, away from heat, sparks, flames, and strong oxidizers. Keep containers tightly closed when not in use. Protect from moisture, direct sunlight, and contamination. Use original packaging, minimize dust generation, and maintain good housekeeping. Avoid excessive stacking or physical damage to containers. Store at ambient temperature. Follow local regulations.
    Shelf Life Celanese UHMW-PE 402M13 shelf life: two years if stored unopened in a cool, dry, ventilated area away from direct sunlight and heat.
    Application of Celanese UHMW-PE 402M13

    Direct conversion of 402M13 into orthopaedic bearing stock begins with incoming-lot verification against ISO 5834-2 and ASTM F648 before any compression-moulding cycle is released. The powder is consolidated in a compression mould rather than by conventional screw extrusion because the high melt viscosity of UHMWPE does not produce a measurable melt flow index under ISO 1133-1. Typical moulding envelopes for this molecular-weight class use platen temperatures of 190–220°C, consolidation pressure of 10–15 MPa, and hold time scaled to 10–15 min per 10 mm of final slab thickness. The mould cavity is blanketed with nitrogen or vacuum; oxygen concentration is held below 0.5 vol% during heating and consolidation to limit oxidation index development measured later by ASTM F2102. The consolidated slab is cooled under pressure at a controlled rate, usually below 10 K/min through the crystallisation plateau, to reduce density gradients and trapped volatile pockets. After demoulding, slabs are stress-relieved and machined into acetabular liners, tibial inserts, and patellar components on CNC lathes with carbide or polycrystalline diamond tooling; machining feeds and speeds are kept low because the low thermal conductivity of UHMWPE can produce melt streaks and surface oxidation on the cut face. Gamma sterilization at 25–40 kGy in vacuum or inert-gas packaging remains the standard terminal sterilization route for this polymer class, but the radiation dose generates residual free radicals that accelerate oxidative embrittlement over implant shelf life unless packaging oxygen levels are controlled and post-irradiation annealing or vitamin E blending is specified. Because 402M13 is supplied as a virgin UHMWPE powder grade, any alpha-tocopherol-stabilised formulation must be produced through validated secondary blending under ISO 5834-2 qualification unless the supplier certificate indicates otherwise. Published data for the specific 402M13 configuration with vitamin E is limited and must be generated for the intended implant design.

    What Restricts Ram Extrusion Throughput When 402M13 Is Formed into Wear Strips and Chain Guides?

    Ram extrusion of 402M13 into solid profiles is used for chain guides, wear strips, scraper blades, and spiral conveyor rails because the powder can be fed into a heated barrel without imposing screw shear. The process is thermally limited; UHMWPE exhibits a thermal conductivity of approximately 0.4 W/(m·K), so wall heat transfer controls the sintering front. Barrel temperatures are typically maintained at 200–230°C while the die is held 10–20 K lower to retain profile shape during cooling. The reciprocating ram compresses the powder into a solid plug that is sintered under pressure and advanced in discrete increments. Published production-rate data for 402M13 profiles is limited, but commercial ram extrusion of this molecular-weight class is substantially slower than single-screw extrusion of lower-molecular-weight HDPE, with output governed by cross-sectional area and cooling length rather than drive power. Operators monitor the die exit for surface defects associated with insufficient fusion or excessive die temperature; centreline porosity and transverse cracking indicate that the sintering front has not fully penetrated the profile before it enters the cooling zone. The process is incompatible with screw-based reclaim compounding unless the molecular weight is deliberately degraded, which defeats wear and abrasion resistance in the terminal part. Extruded profiles are cut and machined to final dimensions; because UHMWPE has high specific heat and low thermal diffusivity, dimensional inspection after 24 h at 23°C under ISO 291 is required. ASTM D4020 molecular-weight verification on the incoming powder and ISO 11542-2 tensile property checks on representative compression-moulded plaques are the usual release tests. This segment does not require food-contact or implant certification unless the profile is sold into food or pharmaceutical material-handling lines, in which case FDA 21 CFR 177.1520 and EU 10/2011 migration documentation must be added.

    In wet-process lithium-ion battery separator production, 402M13 powder is blended with high-density polyethylene and a high-boiling paraffin plasticizer before gel extrusion through a flat die. The UHMWPE fraction raises the viscosity of the polymer-plasticizer gel and modifies crystalline morphology after biaxial stretching; published literature on UHMWPE/HDPE separator compounds generally reports UHMWPE additions below 20 wt% because higher loadings reduce cast-film throughput and can destabilize the tentering stage. 402M13 enters the dry-blend or masterbatch feed as a powder with no measurable melt-flow index; adequate dispersion requires high-shear mixing upstream of the extruder because the UHMWPE domains do not molecularly dissolve into the HDPE melt at separator extrusion temperatures. After the gel film is quenched, solvent extraction removes the paraffin and biaxial orientation creates microporosity, followed by heat-setting to stabilise pore dimensions. The resulting membrane is evaluated for puncture resistance and tensile strength under the converter’s internal test methods; standardised published protocols vary, with ASTM D882 used for thin-film tensile and pore-size characterisation via gas-liquid porometry or mercury porosimetry. The functional contribution of 402M13 in this application is retention of melt integrity and formation of fine fibrils across the pore walls rather than a direct load-bearing role. Converters must verify foreign-body cleanliness and metal content because separator film thickness is typically below 20 µm and defects above 10 µm can trigger dielectric breakdown during cell formation. The powder should be stored below 50°C and kept dry; although UHMWPE has low moisture uptake, condensation on cold powder can create paper-like agglomerates that disturb gravimetric feeding. This application has no implant or food-contact compliance requirement, but REACH and RoHS documentation is commonly requested by cell manufacturers.

    Compression-Moulded Sheet Complies with FDA 21 CFR 177.1520 for Food-Contact Conveyor Liners

    In food processing and packaging lines, compression-moulded sheet converted from 402M13 is used as chain-track wear strips, chute liners, guide rails, and conveyor bed components where repeated sliding contact and washdown exposure are present. The powder is consolidated into 2–100 mm sheet, then planed or skived to final thickness; because UHMWPE cannot be hot-air welded with structural reliability, assemblies rely on mechanical fastening, dovetail routing, or manufactured tongue-and-groove joints. Food-contact status is based on the olefin polymer provisions of FDA 21 CFR 177.1520, with condition-of-use limitations derived from the intended food type and temperature; EU conversion requires overall migration testing under Regulation (EU) No 10/2011 against the 10 mg/dm² limit. Continuous service temperature for UHMWPE sheet under load is generally below 80°C based on ASTM D648 heat deflection temperature and creep considerations; short-term contact with hot washdown above 80°C is not recommended where dimensional stability or load-bearing retention is critical. Wear performance in dry or wet sliding against steel or stainless-steel counterfaces is evaluated by thrust-washer or block-on-ring procedures such as ASTM D3702; published wear-rate data for 402M13 in specific food-contact configurations is limited and should be generated on the actual counterface and sanitizer exposure cycle. The sheet should not be sterilized by steam autoclave because the 121°C cycle exceeds the crystalline softening region and can induce distortion, surface whitening, and release locked-in stress. Terminals include poultry processing slats, bakery dough guides, bottling conveyor wear strips, and fish-filleting table liners; any use above 80°C or involving high load-bearing structural support requires a lower-modulus, higher-creep design review.

    Compliance and test matrix across 402M13 application segments
    SegmentStandard/CodeTest/ParameterNotes
    Orthopaedic bearing stockISO 5834-2, ASTM F648Oxidation index via ASTM F2102; tensile via ISO 527-2; density via ISO 1183-1Gamma dose 25–40 kGy; inert gas packaging required
    Ram-extruded wear profilesASTM D4020, ISO 11542-2Molecular weight; tensile on compression-moulded plaqueBarrel 200–230°C; die 10–20 K lower
    Battery separator compoundREACH, RoHSFilm tensile via ASTM D882; pore size via gas-liquid porometryFilm thickness below 20 µm; defects above 10 µm unacceptable
    Food-contact conveyor linerFDA 21 CFR 177.1520, EU 10/2011Overall migration limit 10 mg/dm²; HDT via ASTM D648Continuous use below 80°C
    Sintered porous filtrationASTM F316Bubble point; pore-size distributionSintering 180–220°C
    PA/POM wear compoundISO 527-2, ASTM D3702Tensile; wear factorAddition 5–20 wt%; L/D 40:1–52:1

    For porosity-controlled filtration plates, venting discs, and pneumatic silencers, 402M13 powder can be free-sintered in a closed mould without full densification. The particle boundaries fuse at contact points when the mould is held between 180°C and 220°C, producing a porous body whose void volume and throat size are set by powder particle-size distribution, filling density, and sintering time rather than by compaction pressure. Unlike compression-moulded solid sheet, the resulting porous stock is not intended for high-tensile or high-impact service; its function is controlled permeability, hydrophobicity, and chemical inertness. Bubble point and pore-size measurements are performed according to ASTM F316 or equivalent gas-liquid porometry, while air permeability is stated under the fabricator’s internal standard. Published data for 402M13 in specific sintered filter grades is limited because final pore diameter depends more on sieve cuts and mould fill than on the base resin itself. Cleanliness requirements are tight: loose powder fines must be removed after sintering because retained particles can detach in service and block downstream instrument orifices. The material is not suitable for sterilizing-grade filtration or pharmaceutical final filters unless validated in the fully assembled device under the applicable bacterial challenge standard. Terminal components are found in compressed-air exhaust silencers, gas sensor vents, water treatment diffusion plates, and laboratory filter supports. Chemical compatibility with acids and alkalis follows general UHMWPE resistance data, but organic solvents and strong oxidizers require specific immersion testing before production release.

    When 402M13 Powder Is Dispersed into Injection-Moulded PA and POM Compounds for Low-Speed Sliding Wear

    Thermoplastic compounders add 402M13 to polyamide, polyoxymethylene, or polypropylene matrices to reduce coefficient of friction and improve wear resistance in injection-moulded sliding elements. The processing window is narrow: UHMWPE domains remain as discrete solid particles at the processing temperatures of PA and POM because the molecular weight of 402M13 prevents complete chain interdiffusion. Twin-screw extruders with L/D ratios of 40:1 to 52:1 and downstream side feeding are used to limit shear heating and prevent the UHMWPE particles from matting into agglomerates; barrel temperatures are set according to the carrier resin, not the UHMWPE melting range. Addition levels commonly range from 5 wt% to 20 wt%; above 15 wt% the weld-line strength and tensile modulus of the compound can decline because UHMWPE particles act as stress concentrators rather than reinforcing fillers. The compound is tested for tensile properties under ISO 527-2 and for wear factor by a thrust-washer method such as ASTM D3702, with counterface roughness and pressure-velocity conditions reported because UHMWPE-modified compounds are sensitive to frictional heat. Terminal parts include low-speed pulleys, gear blanks, bearing cages, and conveyor roller inserts where external lubrication is not desired. This application should not be confused with cross-linked or fiber-spun UHMWPE; 402M13 is an uncompounded powder and does not provide ballistic fiber tenacity unless it is processed through a dedicated gel-spinning line. Compounders must verify metal contamination and powder flowability because variance in particle-size distribution can alter feeding accuracy and produce batch-to-batch variation in the dispersion index. Published data for 402M13 in specific PA or POM matrices is limited; each carrier resin and additive package requires a designed experiment to map torque, melt temperature, and Izod impact retention.

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    Certification & Compliance
    More Introduction

    Celanese UHMW-PE 402M13 is an ultra-high-molecular-weight polyethylene homopolymer supplied as a white powder for compression moulding and subsequent machining of orthopaedic devices. The resin is specified with a viscosity-average molecular weight of 4.0 × 106 g/mol when determined by solution intrinsic viscosity per ISO 1628-3. Density is reported as 0.930 g/cm³ under ISO 1183-1, and the material is sold as a virgin powder without calcium stearate, titanium dioxide, or intentionally added crosslinking agents. Under ISO 527-2, tensile yield stress is typically reported at or above 21 MPa, with elongation at break above 300%. Notched impact testing to ISO 179-1 normally produces no break, which is a consequence of high molecular chain entanglement density rather than filler reinforcement. The powder is differentiated from general-purpose UHMW-PE by controlled particle fraction and by documentation aligned to ISO 5834-1 and ASTM F648.

    Compliance domainStandard or methodRelevance to 402M13
    Raw UHMW-PE powder for surgical implantsISO 5834-1Sets composition, density, and traceability requirements
    Moulded forms produced from surgical-grade powderISO 5834-2Defines test plaque preparation and mechanical acceptance
    Fabricated UHMW-PE formsASTM F648Specifies mechanical, physical, and oxidation limits
    Oxidation index of fabricated formsASTM F2102Used to detect oxidative chain scission after processing or sterilization

    How Does 402M13 Differ from Unfilled Ram-Extrusion UHMW-PE Grades?

    The primary distinction is process design. General-purpose UHMW-PE grades are frequently ram-extruded through heated dies at wall temperatures approaching 200 °C to 220 °C; 402M13 is optimized for compression moulding, where powder densification, air evacuation, and interparticle fusion control final sintered density. The medical-grade powder is manufactured with a controlled fraction below 150 µm, which improves packing density in deep compression cavities but may reduce free-flow characteristics compared with coarser extrusion powders. Industrial UHMW-PE can contain broader particle-size distributions and higher residual catalyst fractions; 402M13 is supplied with lower ash and volatile matter limits, commonly specified at ≤0.02 wt% and ≤0.05 wt% respectively on certificates of analysis. The absence of lubricants and stabilizers permits the material to meet the chemical requirements of ISO 5834-1, whereas general-purpose grades often lack the traceability and lot-release documentation required for implantable components. Compared with ram-extrusion grades that may use lower molecular weight for easier compacted flow, 402M13 retains the 4.0 × 106 g/mol population, which increases melt viscosity and eliminates injection-moulding viability.

    Powder densification during mould filling is the first critical variable. Because UHMW-PE exhibits no practical melt flow below degradation, 402M13 cannot be processed by screw plastication or injection moulding; the powder is consolidated by heated-platen compression at reported moulding temperatures of 190 °C to 220 °C and pressures of 5 MPa to 10 MPa. Heating rate and oxygen exclusion govern the final oxidation index. In production-scale presses with platens machined to ±3 °C uniformity, the powder bed reaches thermal equilibrium only after the core temperature remains above 180 °C for a time that scales with part cross-section. At wall thicknesses above 20 mm, the cycle must include a slow cooling ramp below 0.8 °C/min to minimize residual stress and density gradients. Nitrogen purge or vacuum during heat-up is used to keep oxidation index below 1.0 when tested by ASTM F2102; air-moulded plaques may exceed this threshold and fail the oxidation stability requirements of ASTM F648. Cold pressing prior to sintering at 10 MPa to 20 MPa removes trapped air and reduces the formation of internal voids. Pre-drying at 80 °C for 2 h is recommended when powder has been exposed to relative humidity above 60%; although moisture absorption is low, entrapped water can generate steam porosity during the 190 °C to 220 °C sintering plateau. The powder should not be dry-blended with metallic stearates or conventional HDPE processing aids unless the finished device specification explicitly permits such additions; these substances can invalidate ISO 5834-1 compliance and interfere with wear-test reproducibility.

    The as-received powder is characterized by a bulk density of 0.40 g/cm³ to 0.45 g/cm³ under ISO 60. Crystalline melting peak is typically observed between 133 °C and 138 °C by differential scanning calorimetry per ISO 11357-3, with crystalline fraction generally reported in the 50%–60% range before melt processing. Melt flow index is not measurable under conventional ISO 1133-1 conditions because the high molecular weight prevents flow through the die. This rheological boundary is central to the grade selection: 402M13 is not a melt-processable resin. Its consolidation depends on particle coalescence, chain diffusion across grain boundaries, and long reptation times. The resulting semicrystalline morphology contains residual particle boundaries that can act as weak points if sintering time or temperature is insufficient. Therefore, moulding trials must include cross-sectional density mapping and oxidation-index profiling because published data for specific 402M13 part configurations is limited.

    When 402M13 Is Selected for Orthopaedic Load-Bearing Implants

    Typical applications include tibial inserts, acetabular liners, and patellar components for total joint replacement. Components are either direct compression moulded near-net shape or machined from compression-moulded blocks. In both routes, the powder is batch-lot traceable and is supplied with certificates of conformance to ISO 5834-1. After moulding, sections are tested for density, tensile yield stress, ultimate tensile strength, elongation, and oxidation index; the acceptance criteria referenced in ASTM F648 apply to the fabricated form. For virgin UHMW-PE, ASTM F648 Type 1 requirements include tensile yield stress at or above 21 MPa, ultimate tensile strength at or above 27 MPa, elongation at break at or above 300%, and density in the range 0.930 g/cm³ to 0.940 g/cm³. Direct-compression-moulded components generally exhibit a uniform surface layer and low void content because the powder is sintered against the cavity wall; machined blocks can retain density gradients near the former block skin. If gamma irradiation sterilization is specified, irradiation in air promotes long-term oxidative chain scission; vacuum or inert-gas packaging is therefore used to reduce free-radical oxidation. Ethylene oxide and gas plasma are alternate terminal sterilization routes that do not generate the same oxidative load. The supplied powder is not crosslinked; if wear reduction is required, radiation crosslinking and subsequent remelting or annealing must be performed as separate manufacturing steps, which alter crystallinity and residual free-radical population. Published data for this specific configuration is limited, but cycle development typically includes testing of oxidation index to ASTM F2102 and tensile properties to ISO 527-2 on sections taken from the centre and near-surface of the part.

    In non-implant industrial applications, 402M13 is generally not cost-effective compared with extrusion-grade UHMW-PE. The absence of internal lubricants, the controlled particle distribution, and the regulatory documentation add cost without improving abrasive wear resistance in liners or guide rails beyond that of standard UHMW-PE. Where a wear tester or laboratory standard requires a virgin medical-grade powder with documented lot release, 402M13 can be selected as a control material. It is also used as a reference resin in studies of oxidation and crosslinking because its additive-free composition minimizes confounding variables. The material should not be specified for injection-moulded parts, thin-wall melt-spun fibres, or adhesive-bonded assemblies that require melt processability; these configurations exceed the processing envelope of 4.0 × 106 g/mol UHMW-PE.

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