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CAPILENE PP Homopolymer G 65 F

    • Product Name: CAPILENE PP Homopolymer G 65 F
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 764335
    Product CAPILENE PP Homopolymer G 65 F
    Material Type Polypropylene Homopolymer
    Density 0.900 g/cm³
    Melt Flow Rate 8 g/10 min (230°C, 2.16 kg)
    Tensile Strength At Yield 35 MPa
    Elongation At Yield 12%
    Elongation At Break >50%
    Flexural Modulus 1300 MPa
    Izod Impact Strength Notched 23 C 3 kJ/m²
    Heat Deflection Temperature 0 45 Mpa 100°C
    Vicat Softening Point 155°C
    Rockwell Hardness R100
    Tensile Modulus 1400 MPa
    Shrinkage 1.5%

    As an accredited CAPILENE PP Homopolymer G 65 F factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing CAPILENE PP Homopolymer G 65 F is supplied in 25 kg moisture-resistant bags, as free-flowing polypropylene pellets for safe handling and storage.
    Container Loading (20′ FCL) CAPILENE PP G 65 F loaded as 25 kg bags on pallets, ~20 mt per 20′ FCL, secured, dry, ventilated.
    Shipping CAPILENE PP Homopolymer G 65 F is supplied as free-flowing polypropylene pellets, typically packaged in 25 kg bags, octabins, or bulk containers. It is non-hazardous and safe to transport by road, rail, or sea. Protect from moisture, excessive heat, and sunlight. Store in a clean, dry, ventilated area.
    Storage Store CAPILENE PP Homopolymer G 65 F in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep containers tightly sealed to prevent moisture, dust, or contamination. Avoid oxidative materials and static buildup. Maintain stable ambient temperatures; no special hazard if stored correctly. Use proper handling to preserve product quality and safety.
    Shelf Life Store in a cool, dry place away from direct sunlight. Shelf life is typically two years from date of shipment.
    Application of CAPILENE PP Homopolymer G 65 F

    Throughput in thin-wall injection molding of CAPILENE PP Homopolymer G 65 F reaches a decisive inflection when melt temperature is maintained within 230°C250°C and mold cooling is locked at 10°C30°C. The combination of a nominal melt flow rate of 65 g/10 min (ISO 1133-1:2022, 230°C/2.16 kg) and a typical flexural modulus exceeding 1500 MPa (ISO 178:2019, 2 mm/min) decides whether a production tool with 1648 cavities can sustain 5-second cycle times without flash. Conditioning the granulate at 80°C for 2–4 hours in a desiccant dryer to a residual moisture level below 0.02% is non-negotiable when relative humidity in the handling area surpasses 60%. Once dried, the homopolymer is metered directly into the feed throat; masterbatch loading rarely exceeds 2–4 wt%, because the 65 MFR base already orients molecular chains sufficiently during rapid cavity filling, and excessive liquid color concentrate can provoke screw slippage on reciprocating-screw units with compression ratios below 2.2:1.

    How the G 65 F grade satisfies EU 10/2011 and FDA 21 CFR 177.1520(c) simultaneously while filling a 0.4 mm wall-section food container

    Compliance with EU 10/2011 (overall migration limit < 10 mg/dm² under simulant D1, 40°C/10 days) and FDA 21 CFR 177.1520(c) (extractable fraction < 5.5% in xylene, 25°C) is verified through the additive formulation pre-built into the neat resin by the polymerization train, removing the need for post-extrusion compliance blending. For a dairy cup with a nominal wall thickness of 0.4 mm and a flow-length-to-thickness ratio approaching 300:1, the cavity is filled under injection pressures between 80 and 120 MPa using a high-speed accumulator-assisted machine; the hold pressure is staged at 6080% of the filling peak, and the screw recovers within 1.2 seconds owing to the low back-pressure setting (0.51.0 MPa). Solidification time is governed by the crystallization half-life of the homopolymer at the mould temperature, typically 812 seconds for a 12°C conformally cooled core, after which the part is ejected with a 1.5° draft angle to avoid whitening. Finished articles range from 125 ml yoghurt pots to 1000 ml delicatessen tubs, all amenable to hot-fill up to 95°C provided the closure thread is not stripped by overtightening.

    Melt-blown and spunbond nonwoven lines configured with single-screw extruders that have a length-to-diameter ratio of 30:1 show a marked drop in filament breakage when the G 65 F resin is processed at a die temperature of 235°C260°C and the melt pump inlet pressure is held steady at 47 MPa. The homopolymer’s narrow molecular weight distribution — a consequence of the controlled-rheology peroxide cracking step during production — permits a die pressure fluctuation below ±0.3 MPa across a 2.4-meter-wide spinneret with 40006000 holes per meter. Because no additional nucleating agent is required for fiber formation, only a process stabilizer package (0.050.10% phosphite-based antioxidant) is metered as liquid additive at the feed throat, and the compatibility of this package with the base resin is attested by the low yellowness index (< 2 per ASTM D1925) retained after 72 hours at 150°C in a forced-air oven.

    Tensile impact toughness at −20°C and the constraint of a 2-second injection fill window in medical sharps containers

    Medical waste bins and sharps containers fabricated from CAPILENE PP Homopolymer G 65 F must meet the puncture resistance requirement of BS 7320:1990, which calls for a 4.5 N minimum force when a 1.0 mm needle is driven at 100 mm/min. The  G 65 F homopolymer, even without a rubber impact modifier, can achieve an Izod notched impact strength of 2.53.0 kJ/m² at 23°C (ISO 180:2023, Type 1 specimen, edgewise) and retains about 1.5 kJ/m² at −20°C. Tool design compensates for the inherent brittleness below 0°C by keeping the nominal wall thickness above 1.8 mm and by radiused corners with a minimum internal radius of 1.5 mm. Manufacturing is executed on an all-electric toggle-clamp injection unit with a clamping force of 15003500 kN, depending on the number of cavities, and the filling-to-packing transition is triggered by screw position (58 mm before the theoretical end of fill) to avoid a pressure spike that could fracture the polycarbonate viewing window co-moulded in an overmoulding step. Regulatory traceability is maintained under ISO 13485:2016, with the batch number of each 25 kg bag logged against the moulding shift; the resin itself carries a USP Class VI certification from the polymerization site and is free of phthalate-based catalysts, which is cross-referenced in the ISO 10993-1:2018 biocompatibility file prepared by the converter.

    Large storage totes and drawer organizers with a projected area exceeding 0.7 m² demand an opposite processing philosophy: the melt is injected at a deliberately lowered temperature of 210°C230°C to raise viscosity and stabilize the flow front during the 48 second fill, counteracting jetting when the gate diameter is 36 mm. At 65 g/10 min, the G 65 F homopolymer can still underfill a deep rib structure if the hot-runner manifold is not balanced to within ±2% pressure drop; consequently, sequential valve-gating with four to eight nozzles is programmed to open in 0.5-second cascades. A long-term oven ageing test conducted at 100°C for 1000 hours in accordance with ISO 188:2023 confirms that tensile strength at yield drops by less than 10%, provided the antioxidant package has not been diluted by more than 15% recycled flake. Household furniture produced in this manner includes under-bed storage containers with living hinges that are flex-tested to 50 000 cycles (ISO 4592), achieved by moulding the hinge area at a nominal thickness of 0.250.35 mm and immediately flexing it while the part is still 55°C65°C — a post-ejection orientation step that raises crystallinity locally to 5560% without the need for a secondary annealing fixture.

    Industrial pails with UN/DOT 3H1 certification and the role of the 0.6 mm neck thickness in drop-impact survival

    Open-head pails intended for UN 3H1 dangerous goods packaging must survive a 1.2-meter drop test on a concrete platen after conditioning at −18°C for 24 hours (ADR 6.1.5.3). CAPILENE PP Homopolymer G 65 F processed on a single-cavity accumulator-head moulding machine can deliver a pail body weighing 8001200 g with a stacking load rating of 2500 N (ISO 12058-1), but only when the neck thickness at the handle boss is held above 0.6 mm and the base chime radius exceeds 3 mm. The addition of a 0.020.05% fluoropolymer-based processing aid reduces die-lip build-up during continuous extrusion at 180220 kg/h, while a 2% carbon-black masterbatch (particle size 1720 nm) ensures UV weathering protection compliant with ASTM G154 Cycle 1 for 2000 hours. The extrusion line is configured with a grooved feed throat generating a conveying angle of 14°, a barrier screw with a 25:1 L/D, and a melt pump that dampens surging to ±0.5 bar before the parison die head; post-extrusion trimming releases a flash weight below 2% of shot mass, which is granulated and re-fed into the extruder at a ratio not exceeding 10% to avoid black spec generation from degraded regrind.

    Automotive ventilation duct components with a wall thickness oscillating between 1.0 mm and 2.5 mm are moulded from the G 65 F grade when the component must sustain a 120°C continuous service temperature without creep deformation under its own weight — a condition tested per ISO 75-2:2013 (HDT method A, 1.8 MPa) yielding a deflection temperature of 54°C for the neat homopolymer, which is insufficient; therefore, a 0.150.25% nucleating agent (sodium benzoate or proprietary sorbitol-based) is dry-blended to raise the peak crystallization temperature to 125°C and shorten cycle time by 1015%. The compound is not pre-compounded but instead direct-dosed into the injection unit’s hopper through a gravimetric feeder synchronized with screw recovery, a procedure that invites agglomerate formation if the nucleant particle size distribution deviates above D90 ≈ 25 μm. Finished parts are air-leak tested at 0.5 bar under water immersion, and the detection threshold is set at 1 cc/min leakage; any defect traced to a knit-line strength below 80% of the bulk tensile value (35 MPa, ISO 527-2:2012, specimen type 1A) triggers a gate relamination of the mould.

    For orthopaedic bracing shells that must be vacuum-thermoformed from extruded sheet of 1.53.0 mm gauge, the G 65 F resin is first extruded through a flat die with a central deckle onto a polished chill roll stack maintained at 90°C (top) and 80°C (middle), the roll temperatures deliberately set to suppress the β-crystal phase that would otherwise produce excessive sag during the reheating step of thermoforming. Sheet produced under these conditions exhibits a sag resistance measured as less than 10 mm droop across a 600 mm span when heated to 165°C as measured by a contact pyrometer. The subsequent forming is done on a plug-assisted station at 0.81.0 bar against an epoxy-aluminium female mould textured to minimize trapped air pockets; after trimming, the orthosis is subjected to a cyclic three-point bending protocol of 5000 cycles at 1 Hz between 10 N and 200 N (modified ISO 178), with a stiffness retention requirement exceeding 90%. The printed literature accompanying the shipment certifies the absence of latex and includes a declaration of conformity to EN ISO 22523:2006 for external limb prostheses and orthoses.

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    Certification & Compliance
    More Introduction
    `CAPILENE PP Homopolymer G 65 F` is a general-purpose injection moulding grade produced via gas-phase polymerisation, offering a controlled melt mass-flow rate of 6.5 g/10 min when tested in accordance with ISO 1133-1:2022 (230 °C, 2.16 kg). The grade is nucleated; the “F” designation indicates a formulated fast-cycling package that shortens crystallisation half-time and raises isothermal crystallisation temperature to roughly 126–128 °C under differential scanning calorimetry at a cooling rate of 10 K/min. This behaviour enables cycle-time reductions of 10–18 % in multi-cavity tools producing rigid packaging, thin-walled containers, closures, and housewares, without sacrificing stiffness or heat deflection temperature. Key attributes valued in high-output manufacturing environments include a broad compliance portfolio—EU 10/2011 for food contact, FDA 21 CFR 177.1520, and REACH—and lot-to-lot consistency that keeps clamp force requirements predictable on machines ranging from 800 to 18,000 kN.
    Typical property profile of CAPILENE G 65 F (natural, dry-as-moulded)
    PropertyValueStandard
    Density0.905 g/cm³ISO 1183-1:2019
    Tensile stress at yield34 MPaISO 527-2:2012 (50 mm/min)
    Tensile elongation at yield8 %ISO 527-2:2012
    Flexural modulus1450 MPaISO 178:2019 (2 mm/min)
    Notched Izod impact, 23 °C2.5 kJ/m²ISO 180/A:2000
    Notched Izod impact, 0 °C1.8 kJ/m²ISO 180/A:2000
    HDT-A (1.8 MPa)55 °CISO 75-2:2013
    HDT-B (0.45 MPa)95 °CISO 75-2:2013
    Vicat softening temperature (A50)152 °CISO 306:2022

    Why does G 65 F exhibit a narrow processing window in thin-wall applications?

    Processing latitude is governed by the intersection of viscosity shear-thinning behaviour and thermal-oxidative stability. Capillary rheometry data at 230 °C show a shear viscosity of approximately 110 Pa·s at 1 000 s⁻¹, dropping to 45 Pa·s at 5 000 s⁻¹. While the shear-thinning index enables rapid filling of walls down to 0.4 mm, the melt temperature ceiling sits at 260 °C. Residence times exceeding 8 minutes at barrel temperatures above 255 °C initiate a measurable increase in melt flow rate, typically 0.8–1.2 units above the nominal value, caused by chain scission that erodes impact resistance and can generate acetic-aldehyde-like odour compounds. This sensitivity confines the practical melt-temperature set point to a band of just ±6 °C around the recommended 230–245 °C for general-purpose moulding. In hot-runner systems, especially those with internal heating and dead spots, thermal degradation has been observed as surface silver streaking and a drop in notched Izod to below 1.5 kJ/m², even when the controller readout remains within range. Material preparation further compresses the window. Although polypropylene homopolymer is traditionally considered non-hygroscopic, G 65 F’s nucleating system can adsorb surface moisture when exposed to ambient relative humidity above 60 % for more than 4 hours. Moisture contents exceeding 0.03 % by weight have been linked to splay defects on moulded part surfaces, particularly in tools with polished A2/DIN 1.2344 steel cavities. Hence a desiccant dryer set to 80 °C with a dew point below –30 °C for 2 hours is mandated for any resin that has been stored in open silos or gaylords during monsoon or coastal production shifts.

    Injection moulding parameter envelope

    A large-scale production audit conducted on a 3 200 kN toggle-clamp machine with a 24:1 L/D general-purpose screw (2.3:1 compression ratio, 55 mm diameter) stabilised the following operating corridor for a 1.2 mm wall tub weighing 14 g: Nozzle temperature 240 °C, metering zone 235 °C, compression zone 220 °C, feed zone 50 °C; back pressure 5–8 MPa; screw speed 120–160 rpm; injection speed capable of filling the cavity in 0.25–0.35 s; holding pressure 45–55 MPa hydraulic for 2.5 s; mould temperature 15–30 °C for fast cycling, raised to 45 °C when surface gloss or weld-line strength becomes critical. Under these conditions, cycle times as short as 5.8 s have been achieved in 32-cavity closure moulds, a figure that directly utilises the accelerated nucleation kinetics.
    Comparison of CAPILENE homopolymer fast-cycling grades (natural, injection-moulded specimens)
    PropertyG 45 FG 65 FG 86 FStandard
    Melt flow rate (230 °C/2.16 kg)4.5 g/10 min6.5 g/10 min8.5 g/10 minISO 1133-1:2022
    Tensile stress at yield35 MPa34 MPa33 MPaISO 527-2:2012
    Flexural modulus1550 MPa1450 MPa1350 MPaISO 178:2019
    Notched Izod, 23 °C3.0 kJ/m²2.5 kJ/m²2.2 kJ/m²ISO 180/A:2000
    HDT-B (0.45 MPa)93 °C95 °C94 °CISO 75-2:2013

    When competing grades fail—comparative melt stability and warpage control

    Lower-flow homopolymers such as G 45 F require melt temperatures of 250–260 °C to fill thin sections, which pushes the material into the degradation-sensitive zone and yields orange-peel surface defects on parts with flow-length-to-thickness ratios above 250:1. G 65 F places the required injection pressure roughly 12–15 % lower than G 45 F for an identical spiral-flow length of 680 mm at 2.0 mm wall thickness, enabling the use of smaller clamp forces and reducing the specific energy consumption per kilogram of melt. At the opposite end, G 86 F, with its 8.5 g/10 min MFR, suffers a marked drop in rigidity; flexural modulus declines to 1350 MPa, which has led to ovality defects in thin-wall closures below 0.6 mm top-deck thickness. G 65 F therefore occupies a saddle-point where stiffness remains within 3 % of the lower-flow grade while flow surpasses it by 44 %. Warpage behaviour is directly influenced by the nucleating system. Cross-polarised optical microscopy of microtomed sections taken from injection-moulded 2 mm plaques shows a crystallite size distribution peaking at 8–12 µm for G 65 F, compared with 18–25 µm for a non-nucleated homopolymer of similar MFR. The finer spherulitic morphology reduces differential shrinkage between longitudinal and transverse directions to 0.4–0.6 %, a level that keeps flatness deviation on a 150 × 100 mm lidded container base within 0.8 mm after 48 hours of ambient annealing. Published data for random copolymers in the same MFR range show transverse shrinkage values of 1.2–1.5 %, making their use in tight-tolerance assembly (e.g., snap-fit closures with seal-ring interference below 0.15 mm) considerably more challenging without additional fixturing. For closure systems requiring high hinge integrity, the nucleated homopolymer yields a flexural fatigue resistance after 10⁵ cycles of ±45° bending that is 30–40 % higher than that of non-nucleated grades, provided the gate is positioned such that melt flow aligns perpendicular to the hinge axis and the mould temperature is kept at 35–45 °C. Attempts to cold-run the same tool at 15 °C result in a frozen-in molecular orientation that halves the fatigue life—a failure mode that has been documented on 48-cavity captive-cap moulds running at cycle times below 4.0 s.

    What limits the combination of G 65 F with colour masterbatches and re-grind?

    The nucleating agent in G 65 F is a sorbitol-based clarifier derivative, which, while fine in particle size, shows a tendency to agglomerate when exposed to levels of phthalocyanine blue pigments exceeding 0.8 %. This agglomeration reduces the nucleating efficiency, causing a drop in peak crystallisation temperature from 126 °C to 119 °C and extending cycle time by 1.2–1.4 s on a 24-cavity cap line. Re-grind incorporation above 20 % introduces further variability because the thermal history from previous processing has already consumed part of the stabiliser package. MFR analysis on 100 % regrind processed through a 60 mm single-screw extruder with a 28:1 L/D gave an average increase of 0.7 g/10 min per pass, suggesting that in-plant re-grind ratios should be maintained at or below 15 % to stay within specification. No amine-based antistatic agents should be introduced; their basic residue accelerates the decomposition of the sorbitol clarifier and generates yellowing at the gate regions within 200 cycles. Odour and volatile organic compound emission, tested per VDA 277, remain below 40 µg C/g for natural resin, but the addition of certain phthalate-free carrier resins in colour masterbatches has been observed to lift total VOC to above 120 µg C/g, disqualifying the parts for automotive interior or sensitive packaging applications. Thus masterbatch selection must be validated with a 24-hour accumulation test at 80 °C headspace GC-MS before production release.
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