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Braskem PP Homopolymer F006EC2

    • Product Name: Braskem PP Homopolymer F006EC2
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 354076
    Product Name Braskem PP F006EC2
    Polymer Type Polypropylene Homopolymer
    Melt Flow Rate 230 C 2 16 Kg 0.6 g/10 min
    Density 23 C 0.905 g/cm³
    Tensile Strength At Yield 33 MPa
    Elongation At Yield 11%
    Flexural Modulus 1500 MPa
    Izod Impact Strength Notched 23 C 42 J/m
    Heat Deflection Temperature 0 46 Mpa 100 °C
    Vicat Softening Temperature 155 °C
    Melting Point Dsc 160 °C
    Additive System Film-grade slip and antiblock package

    As an accredited Braskem PP Homopolymer F006EC2 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Packaged in 25 kg polyethylene-lined paper bags, palletized and stretch-wrapped for safe transport, moisture protection, and storage.
    Container Loading (20′ FCL) 20′ FCL container loaded with Braskem PP Homopolymer F006EC2 in 25 kg bags, palletized, heat-sealed, shipped at approximately 18–20 metric tons per container.
    Shipping Braskem PP Homopolymer F006EC2 ships as non-hazardous polypropylene resin in 25 kg bags, octabins, or bulk hopper trucks/railcars. Protect from moisture, direct sunlight, and damage. Store in clean, dry area. Avoid contact with strong oxidizers. Use proper lifting equipment for palletized loads.
    Storage Store Braskem PP Homopolymer F006EC2 in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed to prevent moisture uptake and contamination. Avoid creating dust clouds; static discharge should be controlled. No special temperature control is required under normal conditions, but storage should remain below 50°C.
    Shelf Life Shelf life is indefinite if stored properly in sealed, dry conditions, away from direct sunlight and heat.
    Application of Braskem PP Homopolymer F006EC2
    When Wall Thicknesses Drop Below **400 Microns**  Braskem PP homopolymer F006EC2 delivers a melt flow index of **6.0 g/10 min** (**ASTM D1238**, **230 °C**/**2.16 kg**) and a tensile yield strength of **34 MPa** (**ASTM D638**, **50 mm/min**). These values position the grade for thin-wall injection molding of food-contact containers with nominal wall stock from **0.35 mm** to **0.80 mm**. On toggle-clamp or hydraulic machines with clamping forces of **1,200–2,500 kN**, the recommended melt temperature window is **210–250 °C** and mold surface temperature is held at **20–50 °C**. Injection speeds above **200 mm/s** prevent premature freeze-off in pin-gated multi-cavity tools producing dairy tubs, margarine basins, and delicatessen trays. The European Food Contact Regulation **EU No. 10/2011** and **FDA 21 CFR 177.1520(c)** cover the neat homopolymer; converters must validate overall migration limits below **10 mg/dm²** for aqueous, acidic, and fatty simulants. Shrinkage anisotropy of **1.2–1.6 %** parallel to flow and **1.0–1.4 %** perpendicular (**ISO 294-4**) necessitates mold dimension compensation, especially for lids requiring lip-seal integrity after hot-fill exposure at **85–95 °C**. Process-stabilization packages supplied in the pellet eliminate the need for drying below **60 %** ambient relative humidity; only in saturated environments prior to molding is a **2-hour** desiccant drying cycle at **80 °C** advised.  Extruded tape yarn production from Braskem PP F006EC2 begins with melt pumping through a slit die into a water quench bath maintained at **30–40 °C**. Barrel zones are profiled from **190 °C** at the feed throat to **240 °C** at the die head, ensuring a homogeneous melt without gel inclusions that would cause fiber breakage during the stretching phase. The solidified tape, typically **1.5–3.0 mm** wide and **50–100 µm** thick, passes through a hot-air oven or over heated godet rolls at **110–140 °C** where a draw ratio of **1:5.5** to **1:8.0** is applied. The molecular orientation induced in this step lifts tensile strength at break to **250–350 MPa** in the machine direction and reduces elongation at break below **20 %**. Circular or box looms interlace the tapes into heavy-duty woven sacks for fertilizers, cement, resins, and pet-food granules; International Standard **ISO 21898:2004** governs sack-drop and seam-strength testing for such packaging. For UV-stabilized variants intended for outdoor storage, converters compound **0.15–0.30 wt%** hindered amine light stabilizer (HALS) masterbatch on-line, which extends the useful life of the fabric to approximately **6–12 months** under direct tropical sunlight, measured by tensile strength retention after accelerated weathering per **ASTM G154 Cycle 1**. A critical processing boundary appears when the quench-bath temperature drifts above **45 °C**: crystallinity drops too low, and the subsequent oven-stretching step produces frequent tape fibrillation and width variation exceeding **±8 %** of nominal.  What Controls Melt Curtain Stability in Monolayer Cast Film Extrusion?  The cast film process relies on an air-knife system to pin a molten curtain exiting a T-slot die against a chill roll cooled to **18–30 °C**. For F006EC2 extruded at **220–260 °C** through a die gap of **0.5–0.8 mm**, the melt curtain must traverse an air gap of **100–180 mm** without neck-in exceeding **15 %** and without edge-bead build-up that disturbs winding tension. Chill-roll surface roughness of **Ra 0.2–0.4 µm** imparts a gloss level of **80–90 GU** at **60°** (**ASTM D2457**), suitable for bread bags, textile over-wrap, and photo-album lamination film. The film gauge normally ranges from **25 µm** to **60 µm**, controlled via gravimetric extruder output and line speeds of **80–200 m/min**. Polypropylene film in these thicknesses meets **EU Directive 94/62/EC** for packaging waste reduction and, when used in direct food contact, the specific migration limits of **EU No. 10/2011 Annex II**. Corona treatment applied on-line to a surface energy of **42–48 mN/m** (**ASTM D2578**) ensures adhesion of water-based flexographic inks and polyurethane laminating adhesives. A documented processing limit is the onset of surging at screw speeds above **120 rpm** in a **75 mm** single-screw extruder with an **L/D 30** when back-pressure exceeds **28 MPa**, leading to gauge bands visible at **±2 µm** amplitude every **5–8 m** of wound roll.  Thermoforming sheet gauges between **0.8 mm** and **2.0 mm** require a narrow melt temperature window to avoid sag in the clamping frame of a continuous roll-fed thermoformer. F006EC2 resin is extruded through a coat-hanger sheet die at **215–245 °C** onto a three-roll polishing stack with roll temperatures set to **30–55 °C**, producing amorphous or lightly crystalline sheet with a degree of crystallinity below **45 %**. The sheet is re-heated in a quartz or ceramic infrared oven to **155–170 °C** surface temperature before plug-assisted positive forming into dairy cups, drink tumblers, and portion packs. Forming pressures range from **0.4–0.7 MPa**, and aluminum temperature-controlled molds operating at **50–70 °C** shorten cycle times while preserving rim dimensional accuracy. Compliance with the U.S. Food and Drug Administration **21 CFR 177.1520** olefin polymer regulation is unconditional because no plasticizers or high levels of extractable catalyst residues are present; the grade carries a Braskem food-contact statement aligned with **FDA FCN 399** and **EU Regulation (EU) 10/2011**. The axial stretching during forming reduces the sheet thickness non-uniformly, necessitating a starting gauge **15–20 %** above the final base thickness. One documented failure mode is the appearance of translucent stress-whitening in container corners when the core sheet temperature at forming drops below **148 °C** — this brittle response can be eliminated by extending the oven dwell by **1.0–1.5 seconds** or raising the upper heater bank by **8–12 °C**.  When Spunbond Line Speeds Exceed **3,500 m/min**, Fiber Diameter Uniformity Depends on Melt Filtration  In spunbond nonwoven manufacturing, the polymer melt is extruded through a spinneret with capillaries of **0.3–0.6 mm** diameter at **230–260 °C**, and the filaments are drawn by high-velocity air streams at **3,000–5,000 m/min** onto a moving collection belt. Braskem F006EC2 with a narrow molecular weight distribution (**Mz/Mw ~ 3.5–4.2**, measured by high-temperature GPC) yields minimal oligomer fuming at the die face, which is critical for continuous production runs of **12–18 hours** between spinneret cleaning cycles. The as-spun filaments develop a degree of orientation that boosts tensile tenacity to **2.8–3.5 cN/dtex** without a separate drawing step. Fabric basis weights typically lie between **10 g/m²** and **50 g/m²** for hygiene top-sheet, medical gown, and furniture scrim applications. Medical-grade nonwovens must comply with **ISO 10993-5** (cytotoxicity) and **ISO 10993-10** (skin irritation) when the fabric is the body-contact layer; raw-material lot-to-lot traceability and a certificate of analysis showing heavy-metal content below **1 ppm** each are standard procurement specifications. Process data indicates that the critical shear rate at the spinneret hole entry must stay below **300,000 s⁻¹** to avoid melt fracture; for a typical hole diameter of **0.4 mm**, this imposes a maximum throughput per hole of **0.6 g/hole/min**. When throughput exceeds this ceiling, fiber diameter variability measured on-line by a laser micrometer rises above **±8 %CV**, compromising cover factor and hydrostatic head measured per **AATCC 127**. Additionally, the nonwoven fabric’s thermal bonding window is constrained: the bonding embossing roll must be maintained at **150–160 °C** to create discrete bond points without compacting the entire web, and the resulting tensile strength in machine direction reaches **20–35 N/5 cm** at a bonding area of **12–20 %**.  Dimensional Fidelity in Appliance Components Molded to Tight Tolerances  Polypropylene homopolymer F006EC2 is specified for small appliance housings, structural brackets, and pump components where continuous service temperatures reach **90–105 °C** under zero mechanical load. Injection molding conditions in hot-runner tools with sequential valve gating employ a melt temperature of **220–240 °C** and mold temperature of **40–60 °C** to achieve a crystallinity level that balances impact resistance and shrinkage control. The heat deflection temperature under **0.455 MPa** (**ASTM D648**) is **105 °C**, and the Vicat softening point (**ISO 306, A50**) is **153 °C**, defining the upper working limit for parts near heating elements or in enclosed electronic enclosures. Compliance with flammability standard **UL 94 HB** at **1.5 mm** thickness is inherent for the unfilled homopolymer; thicker sections up to **3.0 mm** can also meet **IEC 60695-11-10** glow-wire ignition requirements for unattended appliance circuits. Long-term thermal aging data generated at **120 °C** in accordance with **UL 746B** indicates a Relative Thermal Index (RTI) of **110 °C** for mechanical impact and **115 °C** for electrical properties, placing it within the accepted range for coffee-machine frames, toaster side panels, and refrigerator door liners. When components are assembled with self-tapping screws, the resin’s flexural modulus of **1,450 MPa** (**ISO 178**) provides sufficient thread-holding strength, with pull-out forces of **120–180 N** in a **2.5 mm** boss diameter; however, insert molding with brass fittings requires a minimum boss diameter of **6 mm** to prevent hoop-stress cracking during thermal cycling between **-20 °C** and **80 °C**. Processors report that short-shot occurrences in multi-cavity molds decrease when the cushion distance is maintained at **4–6 mm** and the decompression after charge is limited to **2 mm**, preserving a uniform shot weight of **±0.15 %** across **32-cavity** arrangements. The absence of antistatic additives in the base grade should be noted for applications involving moving air streams, where surface resistivity above **10¹⁶ Ω/sq** (**IEC 62631-3-2**) promotes dust accumulation; inline addition of **0.5–1.5 %** ethoxylated amine concentrate during molding is permissible provided the final compound complies with **RoHS Directive 2011/65/EU** for electronic equipment. When hot-stamping or in-mold labeling is employed, the label adhesion must survive **85 °C** in a **95 %** relative humidity environment for **500 hours** without delamination, verified by cross-hatch peel testing according to **ISO 2409**.
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    Certification & Compliance
    More Introduction
    As a semicrystalline polypropylene homopolymer engineered for high-speed orientation processes, Braskem PP H F006EC2 is delivered in pellet form with a nominal density of 0.905 g/cm³ (ASTM D792). The material’s controlled isotactic index, specified by the manufacturer at a minimum of 96% (insoluble in boiling heptane, based on internal method analogous to ISO 9113), yields a crystallization temperature of approximately 118–122 °C (DSC, 10 °C/min cooling rate) on typical process equipment. Melt volume-flow rate, measured at 230 °C under a 2.16 kg load per ISO 1133-1:2022, is 2.8–3.2 g/10 min. This flow range is deliberately positioned to balance drawability against melt strength in oriented tape production; materials exhibiting MFR below 2.5 g/10 min often demand excessive extruder torque in the L/D 30:1 single-screw extruders common to woven sack lines, while grades above 3.5 g/10 min risk filament sag and gauge variability at draw ratios exceeding 1:7. Filament fracture during stretching presents a primary production-floor bottleneck with homopolymers in the F006EC2 viscosity class. The processing window between brittle tensile failure and excessive neck-in is constricted. When water-bath temperature deviates more than ±4 °C from the target setpoint, typically 35 °C for a quenching tank positioned 40 mm from the die face, surface quench inconsistencies induce internal voids that act as stress concentration sites during the subsequent hot-air oven draw. On a Starlinger StarEX 1500 tape line operating at a screw speed of 95–110 rpm and a die temperature of 230 °C, the fibrillated tapes exhibit an optimal tensile strength at break of 35–38 MPa (ASTM D638, 50 mm/min) only when the first godet roll temperature is maintained at 110–115 °C and the draw oven is set to 160 °C. The addition of recycled material from trimmed selvedge edges, even at 15% regrind, broadens the molecular weight distribution enough to shift the onset of melt fracture to higher take-off speeds, yet at the cost of a 5–8% reduction in tenacity as measured by the F/m² test method for tapes. Published data for the threshold at which gel count becomes visually unacceptable on a woven sack print surface when using this specific regrind fraction is limited; inline optical inspection systems on a Windmöller & Hölscher tape line usually trigger alarms at particle counts exceeding 5 defects per m² at a 50 µm gel detection threshold.
    Comparative property data for F006EC2 versus an impact copolymer grade at equivalent MFR
    PropertyF006EC2 (Homopolymer)Impact Copolymer (~MFR 3.0)Standard
    Flexural modulus (1% secant)1450–1550 MPa1050–1200 MPaASTM D790A
    Notched Izod impact (23 °C)25–35 J/m90–120 J/mASTM D256
    Tensile yield strength34–36 MPa26–28 MPaASTM D638
    Heat deflection temperature (0.455 MPa)100–105 °C85–90 °CASTM D648
    Differences in crystallinity kinetics become operationally relevant when processors attempt to substitute F006EC2 for a random copolymer on a tape extrusion line originally qualified with a 2.8 g/10 min random PP. The homopolymer’s faster nucleation rate produces a higher degree of frozen-in orientation in the as-quenched cast film, which manifests as a measurable increase in the force required to initiate fibrillation during the splitting process. On a pin-roller fibrillator, a 12–15% upward adjustment in the needle penetration depth and a reduction in the wrap angle on the grooved roll by approximately are often necessary to prevent filament breakage while maintaining uniform denier. Spunbond nonwoven trials with F006EC2, though less common due to the material’s narrow MWD, have been reported at pilot scale using a Reicofil-style line with a melt temperature of 245 °C and a throughput of 0.6 g/hole/min; the absence of ethylene comonomer eliminates the exudation of low-molecular-weight oligomers onto spinneret faces, reducing the frequency of manual die-face cleaning from once every 4–6 hours to once per shift.

    What Occurs When Draw Ratio Exceeds the Stable Necking Limit?

    Above a draw ratio of approximately 1:8.2 at a denier target of 850–900, the neck point destabilizes and oscillates between the second and third godet stands. This cyclical strain-rate variation imprints a periodic thickness defect along the filament length, commonly described on the floor as “barber pole” due to its helical visual appearance under polarized light. Attempts to suppress this by increasing godet separation do not resolve the root cause, which is the transition from homogeneous deformation to shear banding within the semicrystalline mesophase at true strain values exceeding 2.0. Substituting a nucleating agent masterbatch at a 0.5% letdown ratio can shift the threshold to a draw ratio of 1:8.8 by increasing the crystallization temperature to 128–130 °C, but the additional cost per kilogram of finished tape renders this approach economically unattractive for commodity woven sack applications where F006EC2 is typically deployed at the 1100–1300 USD/ton resin cost level.

    Colour Masterbatch Carrier Resin Compatibility

    F006EC2 exhibits a sensitivity to the carrier phase of polyolefin-based colour concentrates that is disproportionate to its molecular weight alone. When a masterbatch employs an ethylene-butene elastomer as its carrier to improve pigment dispersion, the resulting blend forms a two-phase morphology during melt drawing that scatters light and elevates haze from a baseline of 10–12% for unpigmented tape (ASTM D1003) to over 25% at a 3% masterbatch addition. For applications where print clarity on the woven bag is specified, the recommended carrier is a homopolymer PP with an MFR within ±0.5 g/10 min of the base resin. Titanium dioxide whites and carbon black grades formulated in a homopolymer base with an MFR of 2.5–3.5 g/10 min have been run on Barmag winders at speeds up to 240 m/min without measurable loss of elongation at break, provided the masterbatch is pre-blended via a gravimetric feeder mounted on the main hopper rather than introduced through a side-stuffer port, which introduces localized shear history variations.
    Regulatory compliance summary for F006EC2 in food-contact woven sacks
    Regulation / StandardApplicabilityLimiting Condition
    FDA 21 CFR §177.1520(c) Item 1.1aAll food types (no alcoholic content above 8%)Use temperature not exceeding 100 °C
    EU Regulation 10/2011 (as amended)Specific migration limit for overall migration10 mg/dm² per Annex I
    REACH (EC 1907/2006)Monomer and additive substances registeredNo SVHC content above 0.1% w/w
    CONEG (Model Toxics in Packaging)Sum of Pb, Cd, Hg, Cr(VI) below 100 ppmCompliance certified by supplier
    Geotextile stabilization applications subject to alkaline groundwater exposure require careful consideration of the oxidative induction time (OIT) of the finished filament. F006EC2 as supplied without additional antioxidant masterbatch exhibits an OIT of 15–18 minutes at 200 °C (ISO 11357-6). For a design lifetime exceeding 5 years in a pH 9.5 environment, the OIT must be raised to a minimum of 40 minutes through a post-consumer dry-blend of a hindered phenol/phosphite synergistic package at a 0.15% addition level. However, the phosphite stabilizer, at concentrations exceeding 0.2%, has been observed to plate out on the draw-oven rollers, causing a tacky deposit that alters friction coefficients enough to create tension control errors on multi-roll drawing stands. The use of calcium stearate as an acid scavenger, already present in F006EC2 at a standard 0.05–0.1%, mitigates this tendency but cannot eliminate it entirely when the water content of the as-received pellet exceeds 300 ppm; therefore, pre-drying at 80 °C for 2 hours in a desiccant hopper is mandated if the resin has been stored in an unheated warehouse where relative humidity has exceeded 75%. The injection molding of netting clips and buckles using F006EC2 regrind from edge trim illustrates the property cliff-edge associated with repeated heat histories. After three passes through a 90 mm extruder with a vented barrel and a melt temperature of 235 °C, the melt flow rate climbs to 4.8 g/10 min, and the flexural modulus drops below 1200 MPa, rendering the part unable to hold a 15 kg static load according to a customer-specific quality test. In contrast, the same component molded from F006EC2 processed with 30% glass fiber reinforcement (long-glass, pultrusion-compounded) retains a flexural modulus above 5500 MPa and is capable of withstanding a 65 kg load before creep deflection exceeds 2 mm over 100 hours at 60 °C. This stark divergence explains why composite-grade homopolymers with melt flow rates under 5 g/10 min are rarely cross-utilized in long-glass applications; F006EC2’s molecular structure is optimized for orientation-induced crystallization in the solid state, not for interfacial adhesion in a glass-fiber composite. The wax-like maleic anhydride grafted coupling agents that are effective at 1–2% addition in a 50 MFR homopolymer matrix have limited efficacy in the 3 MFR range due to diffusion limitations at the lower processing temperature needed to avoid thermal degradation of the peroxide initiator.

    Does the Anti-block Slip Agent Package Influence Heat-Seal Strength?

    Oriented tape woven into a tubular sack body and sealed with a hot-air or heated-jaw system frequently relies on a thin seal layer of a low-melting copolymer, not on the homopolymer tape itself. When F006EC2 tapes are sealed without a copolymer film interlayer, the minimum seal initiation temperature is approximately 160 °C, and the seal strength measured on a 15 mm-wide specimen (ASTM F88) rarely exceeds 2.5 N. Incorporating an anti-block agent, such as a synthetic silica masterbatch at a 2000 ppm net silica loading, introduces microscopic domains that act as cohesive failure initiators under peel stress, reducing seal strength by an additional 18–22%. If the sack is destined for a building material product that demands a hermetic closure with a seal strength above 4 N/15 mm, the specification must shift to a coextruded tape structure where the sealing layer is a 5 µm skin of a propylene-ethylene random copolymer with a melting point of 130–135 °C (DSC). The homopolymer core, comprising 90% of the tape thickness, remains F006EC2, thus preserving the stiffness and dimensional stability of the woven structure. Processing aids based on fluoroelastomer chemistry are occasionally introduced to combat die build-up when running F006EC2 on cast film lines with narrow die gaps of 0.8–1.0 mm. These additives, at concentrations as low as 200 ppm, coat the metal surface and reduce the shear stress at the die lip, but they also lower the critical shear rate for the onset of flow-induced crystallization in the melt. In practice, a 300 ppm dose of a PPA (polymer processing additive) shifts the melt fracture-free throughput from approximately 210 kg/h to over 260 kg/h on a 120 mm single-screw extruder with a 2.4 m wide coat-hanger die. Yet during the subsequent uniaxial stretching, the altered crystalline morphology formed under lower stress produces a tape with reduced fibrillation resistance; operators compensate by increasing the oven temperature by 5–10 °C, which erodes the energy savings associated with the lower extrusion pressure. The process economics, therefore, lie in a subtle trade-off between energy consumption, output rate, and the scrap rate from tape breakage, which at a break rate above 2 breaks per ton of finished product becomes the dominant cost penalty. On many lines producing F006EC2-based raffia for the construction bag market, the acceptance threshold for scrap from breaks is held below 1.5% of total throughput, a figure that demands rigorous control of both the PPA feed and the quenching bath turbulence.
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