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Braskem Pluris 4301 Blown Film Extrusion Linear Low Density Polyethylene

    • Product Name: Braskem Pluris 4301 Blown Film Extrusion Linear Low Density Polyethylene
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 332945
    Product Designation Braskem Pluris 4301
    Polymer Type Linear Low Density Polyethylene (LLDPE)
    Extrusion Process Blown Film
    Melt Flow Rate 190c 2 16kg 0.80 g/10 min
    Density 0.920 g/cm³
    Melting Temperature 123 °C
    Vicat Softening Temperature 96 °C
    Tensile Strength At Yield 10.5 MPa
    Tensile Strength At Break 25 MPa
    Elongation At Break 700%
    Dart Drop Impact 120 g
    Elmendorf Tear Strength Machine Direction 250 g
    Elmendorf Tear Strength Transverse Direction 350 g
    Haze 13%
    Gloss 45 Degree 55%

    As an accredited Braskem Pluris 4301 Blown Film Extrusion Linear Low Density Polyethylene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of Braskem Pluris 4301 Blown Film Extrusion Linear Low Density Polyethylene

    For direct-contact fresh-produce and bakery packaging, blown-film lines running 55–75 mm grooved-feed extruders with 24:1–30:1 L/D barrier screws process the resin at melt temperatures of 190–230 °C, with die gaps set at 1.8–2.5 mm and blow-up ratios held between 2.0:1 and 3.0:1. The typical film envelope for this application is 25–75 µm, and the LLDPE is frequently placed as the sealant layer in three-layer coextrusions with an HDPE or MDPE core to increase stiffness without sacrificing hot-tack. Food-contact compliance is predicated on the olefin polymer provisions of FDA 21 CFR 177.1520 and the positive list of EU Regulation No 10/2011; converters are still required to validate global migration under the intended food simulant, with fatty-food conditions frequently requiring simulant D2 at 40 °C for 10 days or 121 °C for 2 h depending on filling and thermal history. The overall migration limit of 10 mg/dm² under EU Regulation No 10/2011 applies to the finished film, not merely to the resin certificate. Slip and antiblock loadings are normally kept at 500–1,500 ppm erucamide and 1,000–3,000 ppm synthetic silica when low seal-force initiation is required on vertical form-fill-seal equipment. A comparative test matrix for converters is provided below.

    Normative referenceMethod designationControl parameter
    FDA 21 CFR 177.152021 CFR 176.170(c) extractionFood-type extractives limits
    EU Regulation No 10/2011EN 1186-1:2002 and EN 1186-2:2002Overall migration ≤ 10 mg/dm²
    EU Regulation No 10/2011EN 13130-1:2004 specific migrationSpecific migration of additives
    ASTM D882-18Tensile properties of thin plastic sheetingMD/TD tensile strength, elongation at break
    ASTM F88/F88M-21Seal strength of flexible barrier materialsSeal initiation temperature and seal strength

    When Split-Tear Resistance Determines Liner Survival in Waste Hauling

    Industrial liners and construction films in the 100–250 µm range fail in service predominantly by tear propagation from puncture points, not by monotonic tensile overload. This failure mechanism shifts the incoming material specification toward Elmendorf tear measured by ASTM D1922-15a and dart impact measured by ASTM D1709 Method A, with lot-release testing performed in both machine and transverse directions. For heavy-duty waste-hauling sacks, the resin is typically processed at 100% or blended with 15–25 wt% high-pressure LDPE to stabilize the bubble on conventional low-pressure air rings; the LDPE fraction reduces specific power draw and melt pressure but also depresses Elmendorf tear and puncture toughness. Die gaps of 2.2–2.8 mm and blow-up ratios of 2.2:1–2.8:1 are maintained to reduce transverse-direction orientation and preserve tear resistance. High-stalk bubbles with frost-line heights of 6–10 die diameters are used when downgauging below 120 µm because early frost-line quenching produces a more balanced crystalline network but raises film haze. End products include waste-hauling liners, demolition bags, asbestos-abatement containment panels, and construction vapor-retarder membranes. The critical operational boundary is extrusion melt temperature: at melt temperatures below 190 °C, polymer melt pressure rises and output declines, while sustained processing above 230 °C increases the risk of gel formation and organoleptic defects in sensitive construction interior applications. Published data for this specific configuration is limited, so converters should establish incoming-density and melt-flow control charts using ISO 1183-1:2019 and ISO 1133-1:2022 before qualifying a new silo.

    Greenhouse Film UV Stabilization and the Three-Year HALS Depletion Trade-Off

    Greenhouse covers and silage stretch films require additive packages that survive multi-season UV exposure without excessive light transmission loss. When the resin is used in 150–200 µm greenhouse films, hindered amine light stabilizers are typically compounded at 0.30–0.80 wt% in combination with a UV absorber at 0.10–0.30 wt%, but the exact ratio must be validated against the cumulative ultraviolet dose of the installation region. Accelerated weathering under ISO 4892-2 uses xenon-arc exposure with a borosilicate inner/borosilicate outer filter and a black-panel temperature of 65 °C; the acceptance benchmark for a multi-season cover is usually retention of at least 50% of initial elongation at break in both directions after 3,000 h of accelerated exposure, though published data for this specific formulation is limited. Polyethylene greenhouse films marketed within the European Economic Area fall under the construction products framework and are typically tested to EN 13206 for durability and dimensional stability. In silage wrap applications, the resin is often combined with 2–5 wt% metallocene LLDPE to tailor cling and puncture; tackifier levels above 4 wt% can migrate to the film surface and cause blocking on warm storage racks. The major processing conflict is stabilizer volatilization: running the extruder profile above 230 °C increases pinking and can consume hindered amine stabilizer before the film reaches the field. End products include three-season greenhouse covers, silage bags for high-density bale storage, and nursery overwintering films.

    Does Dart Impact at −40 °C Remain Sufficient for IQF Vegetable Pouches?

    Frozen-food films in the 50–80 µm gauge range are subjected to high-velocity drop loads at temperatures where semi-crystalline polyethylene transitions from a ductile to a more brittle response. Ambient dart impact values generated under ASTM D1709 Method A do not predict low-temperature field failures; converters therefore condition specimens at −40 °C for 24 h and repeat the drop test in the same orientation used on high-speed form-fill-seal lines. Ice-crystal puncture from individually quick-frozen vegetables is a separate failure mode; the film must also exhibit resistance to slow puncture and high elongation at break under ASTM D882-18. Typical line conditions for IQF pouches use melt temperatures of 185–220 °C, die gaps of 1.5–2.0 mm, and blow-up ratios of 2.2:1–3.0:1 to maintain balanced toughness. When the resin is blended with 10–20 wt% LDPE for improved bubble stability, the cold impact performance drops disproportionately, and the reduction must be quantified at the final film gauge rather than inferred from resin data. Anti-fog additives in frozen vegetable packaging are generally avoided unless validated by organoleptic and condensation tests because they can accelerate seal contamination and reduce shelf appearance. The principal operational boundary is the combination of anti-block and slip additive loadings: excessive slip package above 1,500 ppm erucamide has been associated with reduced corona treatability in subsequent print operations. End products include IQF vegetable pouches, frozen seafood bags, and ice-pop overwrap.

    On tandem extrusion-lamination lines producing snack, condiment, and stand-up pouch structures, the resin is processed as a 20–40 µm sealant web laminated to metallized BOPET or BOPP. In this use, the controlling parameter is the heat-seal initiation temperature measured by ASTM F88/F88M-21 at a seal strength threshold of 2.8 N/15 mm; converters generally set jaw temperatures at 115–150 °C with dwell times of 0.3–1.0 s and jaw pressures of 2–4 bar. Because LLDPE provides the sealant layer after the primary substrate has been printed and laminated, the film must maintain corona treatment above 38 mN/m measured by ASTM D2578 before adhesive application; levels below 36 mN/m cause delamination at the laminate interface during downstream pouch conversion. Hot-tack performance, tested under ASTM F1921 with dwell times of 0.1–0.5 s, matters when the pouch is filled vertically at high line speeds and the seal is loaded while still molten. Coefficient of friction measured by ASTM D1894 is controlled to 0.10–0.30 kinetic on the outer surface to allow smooth travel over forming collars without blocking. Published data for this specific configuration is limited, so lamination converters should prequalify the sealant web with the specific solventless adhesive and curing schedule used in production. End products include non-retort stand-up pouches, snack pillow packs, and condiment sachets.

    Secondary Packaging Film Substitution for 12-Pack Can Multipacks

    Collation shrink and distribution films produced with this resin are engineered for puncture resistance rather than maximum free shrink. Blown-film lines for this application run high-stalk bubbles with die gaps of 1.2–1.8 mm, blow-up ratios between 3.0:1 and 4.5:1, and melt temperatures of 190–215 °C to induce transverse orientation that later contributes to controlled shrink. The LLDPE fraction is usually limited to 20–35 wt% in a blend with LDPE or EVA because higher additions reduce free shrink measured by ASTM D2732 below the values required for tight can bundling; the softened LDPE/EVA phase provides conformability, while the LLDPE phase improves tear initiation resistance during transit by fork truck. Penetration failures on 12-pack beverage overwrap are often caused by can rim abrasion; the film must pass a simulated transit vibration protocol in which a 25 kg load is applied to a packed tray for 60 min and the wrap is inspected for punctures. The operational boundary is shrink-tunnel temperature control: too low shrink-tunnel temperatures fail to recover orientation, while excessive temperatures above 150 °C cause fold-over sticking and distorted printed graphics. End products include 12-pack can multipacks, overwrap for insulation panels, and distribution bundling for bottled water.

    E-commerce mailer film manufactured from this resin on 55–75 mm single-screw extruders requires a balance between transverse-direction tear resistance and seal-through-contamination robustness. Mailer film is typically coextruded in three layers at 60–120 µm, with a carbon black-loaded core for opacity and white or tinted skins for printability; the carbon black masterbatch addition is normally 3–6 wt% in the core layer, but excessive loading lowers dart impact and can create gel deposits on the die lip. Automated packing lines require ultimate elongation measured by ASTM D882-18 to remain above 400% in both directions, and dart impact under ASTM D1709 Method A is usually specified at the purchaser’s final mailer thickness. Seal integrity through dust and fiber contamination is more important than low seal initiation temperature, so converters use wider seal bars and longer dwell times of 0.5–1.5 s at 130–160 °C. The material is shipped flat and is often printed on water-based flexographic presses; corona treatment levels of 38–42 mN/m are standard before printing. A major limitation is recycled-content incorporation: post-industrial reclaim up to 20 wt% can be used if the resulting film is tested for film appearance and tear loss, but post-consumer recyclate introduces uncontrolled melt flow that narrows the bubble stability window. End products include weather-resistant shipping mailers, padded mailer outer layers, and garment polybags.

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