| HS Code | 777072 |
| Melt Flow Rate | 33 g/10 min (190°C/2.16 kg) |
| Density | 0.924 g/cm³ |
| Comonomer | Butene-1 |
| Melting Point | 122 °C |
| Vicat Softening Temperature | 94 °C |
| Tensile Strength At Yield | 10 MPa |
| Tensile Strength At Break | 12 MPa |
| Elongation At Break | 800% |
| Flexural Modulus | 240 MPa |
| Shore D Hardness | 50 |
| Notched Izod Impact At 23 C | 80 J/m |
| Notched Izod Impact At 20 C | 40 J/m |
| Environmental Stress Crack Resistance | >1000 h (10% Igepal, 50°C) |
| Mold Shrinkage | 1.5-2.0% |
| Thermal Expansion Coefficient | 1.5E-4 /°C |
As an accredited Braskem IF33 LLDPE Injection Molding Polyethylene Copolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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Thin-wall injection moulding of IF33 for dairy spread cups, delicatessen packs, freezer-tray inserts, and snap-on lids places the resin’s flow-length-to-wall-thickness behaviour at the centre of tooling decisions. In high-cavitation tooling, IF33 is processed as 100% natural pellets or as a dry blend of 85–95 wt% IF33 with 5–15 wt% LDPE where improved pin-hole tear and hinge flexibility are required. Colour masterbatch is dosed at 2–4 wt%, and slip/antiblock masterbatch at 1.0–2.0 wt%, depending on denesting force and lid-to-tub release behaviour. Melt temperature is held at 220–235 °C, mould temperature at 15–30 °C, injection velocity at 180–260 mm/s, and cavity pressure during pack at 35–55 MPa; screw decompression before recovery is kept below 5 mm to avoid nozzle drool in hot-runner valve-gated tools. A general-purpose polyolefin screw with L/D 20:1–24:1 and compression ratio 2.5:1–3.0:1 is sufficient for homogenization. The primary process conflict is shear heating in the hot runner and valve gate: excessive melt temperature at the gate produces odour and organoleptic drift in dairy applications, while insufficient temperature causes flow marks and cavity-to-cavity weight variation. Food-contact compliance is assessed under FDA 21 CFR 177.1520 and EU Regulation 10/2011, with overall migration testing according to EN 1186 parts 1 and 14. Terminal converted articles include heat-sealed dairy cups, deli packs, freezer-tray inserts, and snap-on lids; seal-peel performance is not controlled by the resin alone but by the interface between the moulded edge and the lid film, and tool maintenance controls gate vestige below 0.10 mm.
Where the finished article is sold into retail food service, the following compliance matrix applies:
| Compliance domain | Standard / clause | Parameter / limit | Test condition |
|---|---|---|---|
| US FDA food contact | FDA 21 CFR 177.1520 | Olefin polymer specification | Food-type extraction end tests |
| EU food contact | EU Regulation 10/2011 | OML 10 mg/dm² | EN 1186 migration series |
| REACH | EC 1907/2006 Annex XVII | SVHC communication 0.1% w/w | Article-level declaration |
| RoHS | 2011/65/EU Annex II | Pb 1000 ppm, Cd 100 ppm | XRF and wet chemistry |
Closure injection tooling running IF33 in the 20–40 wt% blend band for HDPE-based tamper-evident caps demonstrates a measurable improvement in environmental stress crack resistance under ASTM D1693, but only when the melt is not overheated. The addition ratio is reversed in flexible dispensing closures, where IF33 can be used at 70–100 wt% with HDPE or LDPE at 0–30 wt% to tune hinge memory and squeeze recovery. Melt temperature for closure moulding is normally set between 190 °C and 220 °C; exceeding 230 °C for prolonged residence above 6 min accelerates thermo-oxidative chain scission, causing cap skirts to fail under applied torque and reducing environmental stress crack resistance. Multi-cavity closure tools operate with valve-gated hot runners, nozzle shut-off, and screw decompression below 3 mm; injection speed is aligned to fill the cap tether before gate freeze, typically 120–180 mm/s, with pack pressure 40–60 MPa and mould temperature 10–25 °C. For food-contact closures, the finished article must meet FDA 21 CFR 177.1520 and EU Regulation 10/2011, including organoleptic evaluation on the converted article. Terminal articles include tamper-evident dairy caps, condiment orifice caps, sports caps, and flush-cut dispensing closures for personal-care tubes. The primary production failure mode is hinge whitening in flip-top designs when the hinge is packed too long or the mould is too cold; the second is skirt ovality due to uneven cooling in non-concentric gates.
In low-unit-cost houseware conversion, the controlling process variable is retained core heat rather than thin-wall frozen-layer formation. Storage crates, foldable baskets, drawer modules, and garment hangers are moulded from IF33 in conventional single-face tools with wall thicknesses of 2.5–4.0 mm; the copolymer is dosed at 100 wt% or blended with 15–25 wt% post-industrial LLDPE regrind where closed-loop scrap handling is available. Melt temperature is kept at 190–215 °C, mould temperature at 15–35 °C, injection pressure at 60–90 MPa, and hold time is set by gate-freeze rather than cosmetic finish. Compliance for this segment is commercial rather than food-contact: REACH Article 33 SVHC communication and RoHS Directive 2011/65/EU Annex II heavy-metal limits apply when the articles enter electrical or electronic equipment packaging. Terminal product types include injection-moulded crates, foldable storage boxes, drawer organisers, garment hangers, and refuse-bin bases. Published peel-strength or ESCR data for these specific geometries is limited; processors rely on in-house drop tests and visual stress-whitening checks, not on laboratory tensile values alone.
Five-litre to 25 L injection-moulded pails produced from IF33-modified HDPE or from 100% IF33 use the copolymer’s low-temperature impact retention where standard HDPE grades can show brittle failure below −20 °C. The blend ratio is typically 60–80 wt% IF33 with 20–40 wt% HDPE for open-head pails requiring stacking stiffness, or 100% IF33 for low-stiffness pails and collapsible buckets; colour masterbatch is kept at 1.5–2.5 wt% to limit modulus loss. Melt temperature is 200–230 °C, and the mould wall is maintained at 10–20 °C to extract heat from the 3.0–4.5 mm wall section; cooling time, not fill time, dominates the cycle. Pack pressure is ramped from 50 MPa to 30 MPa over 6–10 s to prevent core voids at the pail handle pinches. Transport packaging compliance for dangerous goods is assessed under the UN Model Regulations Chapter 6.1 drop and stack provisions, with drop testing carried out to ASTM D5276 on loaded containers at −18 °C or 23 °C. Terminal articles include open-head pails, tamper-evident paint pails, industrial waste bins, and stackable materials-handling tubs. The critical process boundary is the slab-like handle pinch: if pack pressure is released too early, frozen-layer separation at the core creates a void that later initiates brittle failure under drop load; if the melt temperature exceeds 240 °C, surface gloss improves but low-temperature impact falls due to molecular weight reduction.
Diagnostic packaging trays, transport-box lids, and non-fluid-path analyser components moulded from IF33 are produced in electric injection machines with cavity pressure monitoring where the cycle window is compressed to 15–18 s. The resin is used at 100% virgin; if closed-loop regrind is permitted in a quality-control plan, rework is capped at 20 wt% and segregated by lot. Melt temperature is set at 210–225 °C, mould temperature at 20–35 °C, and fill speed is limited to 140–180 mm/s to prevent jetting around mould inserts. Cleanroom production under ISO 14644-1 Class 8 is common, and packaging operations for terminally sterilized devices are controlled under ISO 11607-1:2019; the quality system is evaluated to ISO 13485:2016. No statement of biocompatibility is made for IF33 in primary blood-contact or implantable applications; if such use is evaluated, ISO 10993-1 biological risk assessment and USP Class VI testing would be required on the finished device, not on the resin alone. Terminal products include diagnostic analyser tray bases, specimen transport tube carriers, non-fluid-path lids, and laboratory benchtop organizers. The main rejection mode in this class is contamination from black specks and carbonized resin; screw and barrel wear, back pressure above 10 MPa, and long residence time are the dominant causes.
Under the EN 71 test regime, injection-moulded IF33 components for building blocks, playset figures, ball-pit shells, and push-along toys must satisfy mechanical and element-migration requirements before colour masterbatch is approved. The resin is processed at 100% or blended with 10–20 wt% LDPE where a softer hinge or lower gloss is required; colour masterbatch addition is 2–3 wt%, and only REACH-compliant pigments are allowed. Melt temperature is 190–220 °C, mould temperature 15–30 °C, injection speed 80–120 mm/s, and pack pressure 30–50 MPa; thick bosses and snap-fit features require gate sizes above 1.5 mm to prevent sink marks. The relevant regulatory set includes EN 71-3 for migration of elements, REACH Annex XVII entries 51 and 52 for phthalates, and ASTM F963 where North American distribution is intended. Terminal product types include construction blocks, figurine components, push-along toy bodies, ball-pit spheres, and indoor play modules. The operational boundary is not mechanical but chemical: switching to a non-approved phthalate-containing masterbatch can pass visible inspection and still fail total phthalate screening above 0.1 wt% per plasticized material. Because IF33 itself is an unplasticized polyolefin, the contamination risk is almost entirely introduced by pigment and slip masterbatches or by cross-contamination in shared silos.
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