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Braskem Idesa HDPE DHP0022

    • Product Name: Braskem Idesa HDPE DHP0022
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 575282
    Product Name Braskem Idesa HDPE DHP0022
    Manufacturer Braskem Idesa
    Material Type High Density Polyethylene (HDPE)
    Grade DHP0022
    Density 0.954 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.22 g/10 min
    Melt Flow Ratio I21 I2 90
    Tensile Strength At Yield 25 MPa
    Tensile Elongation At Break >600%
    Flexural Modulus 1200 MPa
    Izod Notched Impact Strength 200 J/m
    Vicat Softening Point 127°C
    Heat Deflection Temperature 0 45 Mpa 70°C
    Melting Point 131°C
    Environmental Stress Crack Resistance Escr >1000 h
    Hardness Shore D 65
    Water Absorption <0.01%
    Thermal Expansion Coefficient 1.2 × 10⁻⁴ /°C

    As an accredited Braskem Idesa HDPE DHP0022 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Braskem Idesa HDPE DHP0022 comes in 25 kg polyethylene bags, palletized and stretch-wrapped, or 1,000 kg jumbo bags.
    Container Loading (20′ FCL) 20′ FCL loading: 25 MT Braskem Idesa HDPE DHP0022 in 25 kg bags, palletized, stretch-wrapped, and secured for export.
    Shipping Braskem Idesa HDPE DHP0022 is shipped as non-hazardous high-density polyethylene pellets in 25 kg bags, jumbo bags, or octabins. It is not regulated for transport. Keep containers closed, dry, and away from heat, ignition sources, and strong oxidizers. Follow standard handling and local shipping regulations.
    Storage Store in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, and strong oxidizing agents. Keep original packaging sealed, palletized, and off the floor to prevent moisture and contamination. Avoid prolonged high temperatures and UV exposure. Use FIFO stock rotation. Maintain ambient storage conditions; protect from physical damage and moisture. Follow the manufacturer’s SDS and local regulations.
    Shelf Life Braskem Idesa HDPE DHP0022 shelf life: 24 months when stored unopened, dry, cool, away from direct sunlight and moisture.
    Application of Braskem Idesa HDPE DHP0022

    Braskem Idesa HDPE DHP0022 enters municipal potable water pressure pipe extrusion as a high-molecular-weight bimodal resin evaluated under ISO 9080:2022 and ISO 12162:2009 for PE100 compound classification. Municipal water pipe production lines equipped with gravimetric dosing hoppers and grooved-feed single-screw extruders operate at melt temperatures of 210–230°C, with feed-zone temperatures maintained at 190–210°C to avoid premature compaction and uncontrolled torque spikes. The potable water formulation for this resin class is typically maintained at 96.5–98.5 wt% base resin with a pre-compounded antioxidant/carrier resin masterbatch at 1.5–3.0 wt%; carbon black is omitted from buried potable water service lines, and blue or natural pigment masterbatches are preferred because they leave no carbon black surface bloom and allow visual inspection of the bore after hydraulic testing. Compliance is verified under ISO 4427:2007, EN 12201-2, and ASTM D3350-23, with PE100 pipe compound required to demonstrate a 10 MPa minimum hydrostatic design stress at 20°C for 50 years. Potable water contact is assessed under EU Regulation (EU) No 10/2011 and NSF/ANSI/CAN 61. The downstream extrusion process uses a grooved-feed single-screw extruder with L/D 30:1–36:1 and a barrier mixing section; vacuum calibration tanks are operated at -0.3 to -0.6 bar to fix outside diameter and wall thickness, and haul-off speed is set from 1.5 to 4.0 m/min depending on outside diameter. Terminal product forms include SDR 17 and SDR 11 PE100 pipes from 20 mm to 630 mm for potable water mains, service laterals, and insertion rehabilitation, supplied as coils up to 500 m for diameters ≤63 mm and as straight lengths for larger diameters.

    Production floor data from pipe extrusion lines indicate that wall-thickness variability above 0.5 mm on 450 mm SDR 17 pipe originates mainly from cooling-water temperature drift and vacuum fluctuation; closed-loop vacuum control is therefore maintained within ±0.03 bar and water temperature at 20–25°C to prevent ovality and residual stress. This operational boundary is critical because insufficient vacuum during calibration produces sag before solidification, while excessive vacuum increases haul-off load and can generate surface scoring on the pipe shell.

    Why Does Carbon Black Dispersion Determine the 50-Year Design Life of Buried Gas Pipe?

    For natural gas distribution, the same DHP0022 base resin is formulated with a carbon black masterbatch at 5.0–6.0 wt% to achieve a final carbon black content of 2.0–2.5 wt% in the pipe wall, as required by ISO 4437-2:2014 and ASTM D2513-22 for UV resistance and oxidative stabilisation. The masterbatch is usually a 40% carbon black concentrate in HDPE; dosing below 4.5 wt% produces inadequate carbon black in the finished wall, while dosing above 6.5 wt% raises melt viscosity and can promote pinholes during vacuum calibration. Dispersion is evaluated under ISO 18553:2002 on microtomed sections, with a maximum dispersion rating of ≤2 and no visible agglomerates larger than 100 µm in a 0.1 mm² section. The production line uses a grooved-feed single-screw extruder with L/D 30:1–36:1 and a Maddock or barrier mixing section, with melt temperature at the die held at 220–235°C; vacuum calibration at -0.4 to -0.7 bar is followed by online ultrasonic wall-thickness scanning to maintain SDR 11 and SDR 17 tolerances. Terminal products are black PE100 gas mains and service lines from 20 mm to 630 mm, certified for operating pressures up to 10 bar, supplied either in straight 12 m lengths or coiled in diameters up to 125 mm.

    On gas-pipe lines, the most frequent batch-to-batch processing defect is carbon black masterbatch surge when gravimetric feeder hoppers are refilled without anti-bridging agitation; this produces dark/light striping and localised loss of oxidative resistance. The corrective control is to set masterbatch feeder verification alarms at ±0.2 wt% of the target dosing rate and to stop extrusion for microtome sampling every 4 h.

    ISO 4437-2:2014 and ISO 18553:2002 carbon black acceptance matrix for PE100 gas pipe
    PropertyMethodAcceptance range
    Carbon black contentISO 69642.0–2.5 wt%
    Agglomerate sizeISO 18553:2002≤100 µm in 0.1 mm²
    Dispersion ratingISO 18553:2002≤2
    Melt volume-flow rateISO 1133-1:2022, 190°C/5.0 kgcompound-specific, typically 0.15–0.40 g/10 min for PE100 gas compound

    In gravity-flow stormwater and agricultural drainage networks, DHP0022 is extruded on corrugator lines with moving mold blocks that form a double-wall profile at output rates of 300–1,100 kg/h. The formulation for non-pressure drainage pipe is maintained with virgin DHP0022 from 85–100 wt% and clean plant regrind up to 15 wt% of the total compound; carbon black masterbatch is added at 2.0–3.0 wt% over the blend for UV stabilisation. Regrind is dried to below 0.05 wt% moisture and metered gravimetrically to avoid melt-pressure fluctuation and surging at the corrugator inlet. Compliance is set by EN 13476-3, ASTM F2306/AASHTO M294, and ISO 9969 for ring stiffness, with the final product specified by SN 4 to SN 16 stiffness classes for buried stormwater culverts, retention/detention chambers, agricultural land drains, and infiltration trenches. The downstream process requires a grooved-feed extruder delivering melt at 200–220°C into a corrugator with vacuum slots at -0.2 to -0.5 bar and internal air pressure of 0.05–0.20 bar to press the parison against mold blocks; product types include single-wall corrugated perforated drainage tile and double-wall stormwater pipe from 100 mm to 1,200 mm with bell-and-spigot joints and gasketed or welded couplings.

    At corrugator line speeds of 1–6 m/min, the vacuum forming window narrows when melt temperature falls below 200°C, causing incomplete inside-wall bonding and premature buckling under SN 4 loads. Production staff monitor the outside wall thickness between corrugation crests using laser micrometers and reject pipe sections where web thickness drops below 0.5 mm.

    When Geomembrane Welding Windows Narrow Under Carbon Black Loading

    Flat-die extrusion of DHP0022 into geomembrane sheet is selected when the final liner must meet GRI-GM13 and ISO 13438:2018 oxidative induction time thresholds for landfill, mining leach-pad, and irrigation impoundment applications. The formulation is maintained at 96.5–97.5 wt% HDPE with 2.0–3.0 wt% carbon black masterbatch and a resin producer-added antioxidant package; no mineral filler is added because filler particles above 75 µm reduce peel strength in wedge-welded seams and create stress concentrators under tensile load. Processing uses a single-screw extruder with L/D 30:1–33:1 feeding a 2,500–3,000 mm flat die at 220–230°C, followed by a three-roll polishing stack held at 70–90°C to control gloss, thickness, and residual stress. Sheet thickness is monitored by beta-gauge or X-ray backscatter at 1.5 mm, 2.0 mm, and 2.5 mm nominal thickness with tolerance of ±10% for smooth geomembrane. Terminal products include smooth HDPE geomembrane panels in 1.5 mm and 2.0 mm thickness for landfill caps, mining heap leach pads, and secondary containment liner systems, where seam welder temperatures of 350–450°C are validated against ASTM D6392 and peel strength is required to exceed 80% of sheet yield strength.

    Seam welder qualification failures at 350°C are frequently traced to residual moisture in carbon black masterbatch; pre-drying of masterbatch at 80°C for 4 h is mandated when warehouse relative humidity exceeds 60%. This limitation is operational rather than resin-specific: the failure mode appears as microporosity at the fusion boundary and reduces the acceptable welding-temperature window by 15–25°C.

    Where buried fibre-optic and high-voltage cable protection ducts are specified, DHP0022 is processed at melt temperatures of 210–230°C to preserve melt strength and achieve SDR 9 to SDR 13.5 wall uniformity at haul-off speeds of 2–8 m/min. Unlike pressure pipe, telecom conduit is not subject to long-term hydrostatic strength requirements but must pass crush resistance and ring stiffness tests under ASTM F2160-21 and EN 61386-24:2004; the product is typically black with 2.0–2.5 wt% carbon black content or grey/white with UV-stabilised colour masterbatch at 1.5–3.0 wt%. The extrusion line uses a grooved-feed single-screw extruder with L/D 30:1 and a mandrel die, vacuum sizing at -0.5 to -0.7 bar, and three-axis ultrasonic wall-thickness scanning with feedback to centering bolts on the calibration sleeve. Terminal products include HDPE ducts from 25 mm to 250 mm, microduct arrays, figure-eight duct, and subduct for cable blowing installations, supplied in coils up to 1,000 m and in straight lengths for urban backbone routes.

    Coiled microduct production with DHP0022 requires back-pressure at the die of 18–28 MPa to prevent melt fracture when draw-down ratios exceed 6:1; setup technicians adjust the breaker plate and screen packs to maintain pressure below 30 MPa and avoid premature screw wear.

    Industrial Slurry Transfer Pipe and Abrasion-Thickness Monitoring

    For industrial water and abrasive slurry transfer, DHP0022 is selected when the key processing constraint includes wall-thickness uniformity at SDR 7.4–SDR 17 because accelerated wear in elbows and fittings is monitored against DIN 8074:2011 and ISO 4427-2:2007 for dimensional stability. The formulation involves 96–98 wt% DHP0022 with 2.0–2.5 wt% carbon black masterbatch and up to 2 wt% clean internal regrind; no calcium carbonate filler is added because filler increases notch sensitivity and lowers tensile impact strength in slurry service. Extrusion takes place on a grooved-feed single-screw line with L/D 30:1 at 220–235°C melt temperature, followed by submerged cooling with internal air pressure of 0.05–0.15 bar to control inner diameter from 50 mm to 1,200 mm. End products include dredge floats, tailings lines, ash transport pipe, and chemical plant process water headers, with the pipe specified by minimum wall thickness and wear allowance rather than long-term hydrostatic design alone.

    Thick-wall SDR 7.4 pipe above 315 mm diameter requires cooling water temperature of 15–20°C and staged submersion to prevent shrinkage voids on the inner wall; destructive wall-thickness sampling is conducted at 50 mm intervals across the cut surface by ultrasonic or calibrated mechanical calipers.

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    Certification & Compliance
    More Introduction

    Braskem Idesa HDPE DHP0022 is a bimodal high-density polyethylene resin developed for extruded pressure pipe, thick-wall industrial pipe, and profile extrusion where long-term hydrostatic strength and slow crack growth resistance determine service life. The material is supplied as a pelletized natural resin; carbon black masterbatch or pre-compounded black variants are used for outdoor pressure-pipe applications. Melt flow rate at 190 °C under 2.16 kg load is 0.22 g/10 min when tested according to ISO 1133-1:2022. Density at 23 °C is 0.956 g/cm³ per ISO 1183-1:2019. The hydrostatic design basis places the grade within the PE100 category, corresponding to a minimum required strength of 10 MPa at 20 °C for 50 years under ISO 9080 and ISO 12162.

    How Does the Bimodal Molar Mass Distribution Limit Slow Crack Growth?

    The high slow crack growth resistance of DHP0022 results from a bimodal molar mass distribution in which the high-molar-mass fraction carries a higher density of interlamellar tie molecules. These tie molecules transmit stress across lamellar boundaries and reduce brittle crack propagation under sustained internal pressure. The density of 0.956 g/cm³ is a compromise between stiffness and stress-crack resistance; the bimodal architecture offsets the reduction in slow crack growth resistance commonly associated with higher crystallinity. In laboratory assessments using ASTM D1693 in 10% Igepal CO-630 at 50 °C, the resin exceeds 1,000 h F50 without brittle failure. For notched pipe testing under ISO 13479, the grade is evaluated on extruded pipe with an external notch to a depth of 20% of wall thickness at 80 °C. Published data for the DHP0022 full notch creep values under ISO 16770 is limited, but the PE100 classification itself requires statistically demonstrated long-term resistance at 20 °C, 60 °C, and 80 °C.

    The molecular architecture responsible for slow crack growth resistance is associated with short-chain branching on the high-molar-mass species. Published data for the exact comonomer type and branch distribution of DHP0022 is limited; the certificate of analysis provides density, melt flow rate, and lot identification but not full chain-branching characterization. Oxidative induction time at 200 °C under oxygen, measured by ISO 11357-6, is used to verify stabilizer integrity after extrusion. For stabilized HDPE pipe compounds, OIT values commonly exceed 20 min; the lot-specific value for DHP0022 is reported on the certificate of analysis and should be monitored after multiple extrusion or regrind cycles.

    Oscillatory rheometry at 190 °C under nitrogen shows a broad molar mass distribution for this grade; published data for the full master curve is limited. The ratio of high-load melt index to low-load melt index, commonly reported as melt flow ratio, is used by converters to anticipate melt strength and extrusion backpressure. For PE100 pipe resins with a melt flow rate of 0.22 g/10 min at 2.16 kg, high-load melt index at 21.6 kg is commonly above 20 g/10 min; direct conversion measurements on DHP0022 should be obtained from the manufacturer’s certificate of analysis.

    Flexural modulus of 1,100 MPa and tensile stress at yield of 26 MPa are measured on compression-moulded specimens at 50 mm/min per ISO 527-2:2012 and ISO 178:2019; these values are not direct substitutes for pipe hoop stress design values. Ring stiffness of finished pipe is governed by outside diameter, wall thickness, and pipe modulus under ISO 9969, not by resin modulus alone.

    When DHP0022 Replaces PE80 Grade in an Existing Pipe Die

    When DHP0022 is substituted for an unimodal PE80 grade in an existing spiral mandrel or basket pipe die, the higher extensional viscosity and lower melt flow rate alter melt pressure, wall thickness control, and sag behavior. Published data for this specific configuration is limited; therefore a pilot extrusion trial is required before full production. Barrel temperature settings from 180 °C to 210 °C and die temperatures between 205 °C and 215 °C are typical for PE100 pipe on grooved-feed single-screw machines. Melt temperatures above 240 °C should be avoided because oxidative degradation produces gel particles and reduces long-term hydrostatic strength.

    For pipe diameters above 200 mm, spiral mandrel tooling with a compression ratio between 2.8:1 and 3.5:1 is preferred to minimize spider-leg weld lines. Weld lines generated by basket dies can produce local weakness in slow crack growth testing. The melt cushion and mandrel centering are adjusted until wall thickness variation is below 12% around circumference. Output rate on a grooved-feed extruder with L/D 33:1 is limited by melt temperature rise and backpressure rather than by screw speed.

    PropertyTest MethodTypical Value
    Melt flow rate, 190 °C/2.16 kgISO 1133-1:20220.22 g/10 min
    Density, 23 °CISO 1183-1:20190.956 g/cm³
    Tensile stress at yield, 50 mm/minISO 527-2:201226 MPa
    Elongation at breakISO 527-2:2012>600%
    Flexural modulus, 2 mm/minISO 178:20191,100 MPa
    ESCR, F50, 10% Igepal, 50 °CASTM D1693>1,000 h
    Vicat softening temperature, A50ISO 306:2022125 °C
    Shore D hardnessISO 86862

    These values are typical of compression-moulded specimens prepared under ISO 1872-2. They are not finished-pipe specification limits. Pipe certification is based on hydrostatic pipe testing under ISO 9080, not on plaque data.

    Carbon Black Dispersion and Ultraviolet Stabilization in Black Pipe Compounds

    Black pressure-pipe compounds containing DHP0022 use carbon black at 2.0–2.5 wt% to provide ultraviolet protection for outdoor storage and buried service inspection. Carbon black dispersion is assessed by ISO 18553; agglomerates larger than 0.15 mm are unacceptable because they create stress concentrations in slow crack growth tests. The grade does not require pre-drying when stored in closed, undamaged bags at relative humidity below 60%. If exposed to moisture, a drying step at 80 °C for 2 h in a desiccant dryer is applied, although published data for moisture uptake on this specific resin is limited.

    Regrind incorporation is limited to 10–15% by weight because repeated extrusion reduces the high-molar-mass fraction and lowers slow crack growth resistance. DHP0022 should not be combined with chlorinated or amine-based additives because these can generate acid species and catalyze chain scission at processing temperatures. Masterbatch carriers should be ethylene-based; polypropylene carriers can reduce weld strength in butt fusion and electrofusion joints.

    Finished pipe made from DHP0022 is qualified by sustained internal pressure testing at 20 °C under 12.0 MPa, at 60 °C under 5.0 MPa, and at 80 °C under 5.0 MPa according to ISO 1167-1. Failure must be ductile within the first test window; brittle failure at 20 °C indicates insufficient fusion, notched defects, or resin degradation. The process capability of the extrusion line is monitored by wall thickness ultrasonics, ovality gauges, and melt pressure residence time logs.

    Preventing Melt-Fracture Defects on High-Output Single-Screw Lines

    On high-output grooved-feed single-screw lines running above 400 kg/h, sharkskin or melt fracture on the outer pipe surface indicates excessive shear stress at the die lip. For HDPE pipe grades, critical shear stress is typically in the range of 0.2–0.4 MPa. Reducing screw speed, raising die temperature by 3–5 °C, or adding a fluoropolymer processing aid at 200–500 ppm can shift the melt into a stable surface regime. The exact critical shear stress for DHP0022 has not been published for all die geometries.

    Butt fusion of DHP0022 pipe is performed under ISO 21307:2017 with heating plate temperature from 200 °C to 220 °C. The heating and cooling pressures are determined from pipe wall area and interfacial pressure, typically 0.15 MPa for heating and 0.15 MPa for cooling on PE100 grades. Electrofusion joining requires removal of the oxidized surface by mechanical scraping, cleaning with isopropanol, and restraint during cooling. Fusion joints should not be pressure-tested before the joint has returned to ambient temperature.

    For gas service and water applications in cold climates, resistance to rapid crack propagation is assessed using ISO 13477 full-scale S4 tests or ISO 13478 for critical pressure. DHP0022, as a PE100 bimodal resin, is expected to show ductile arrest at temperatures down to -5 °C in the S4 test; published data for this specific grade is limited and must be generated on finished pipe.

    Regulatory Compliance Is Documented Through the Following Standard Cross-Reference

    RequirementReferenced StandardStatus
    PE100 long-term strength classificationISO 9080 / ISO 12162MRS 10 MPa
    Pressure pipe system designISO 4427-2PE100 design stress 8.0 MPa
    Butt fusion weldingISO 21307:2017PE100 procedure
    Carbon black dispersionISO 18553Classified by agglomerate size
    UV resistance of black pipeISO 16871Required for outdoor exposure
    Food-contact base resinFDA 21 CFR 177.1520As nominated by manufacturer
    European chemicals regulationREACHAs declared by manufacturer

    The table summarizes compliance pathways for typical potable-water pipe applications; it does not replace project-specific certification. Finished pipe manufacturers must perform product qualification on their own extrusion lines because pipe extrusion conditions, regrind ratios, and carbon black masterbatch selection influence final long-term hydrostatic strength.

    DHP0022 differs from injection-moulding HDPE grades such as HDI0861U in melt flow rate by approximately two orders of magnitude. HDI0861U is reported with a melt flow rate near 8.6 g/10 min, whereas DHP0022 is 0.22 g/10 min. The low MFR of DHP0022 provides the high melt strength and slow crack growth resistance required for pressure pipe but makes the material unsuitable for high-speed injection moulding of thin-wall closures. Compared with a blow-moulding HDPE grade near 0.35 g/10 min, DHP0022 has a higher molar mass and higher melt viscosity, leading to reduced sag during large-diameter pipe extrusion but higher motor load and melt pressure on single-screw extruders.

    Start-up and shutdown procedures for DHP0022 follow standard PE100 practice: purge with a lower-viscosity HDPE transition material, avoid extended residence above 220 °C, and limit in-plant regrind ratio to 10–15% of total throughput unless finished-pipe qualification demonstrates otherwise. These limits preserve the molecular weight distribution and minimize gel formation in long production campaigns.

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