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Braskem HDPE SGM9450F

    • Product Name: Braskem HDPE SGM9450F
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 612320
    Density 0.945 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.05 g/10 min
    Melting Point 130 °C
    Vicat Softening Point 120 °C
    Crystallization Temperature 110 °C
    Tensile Strength At Yield 22 MPa
    Tensile Strength At Break 28 MPa
    Elongation At Break 700 %
    Flexural Modulus 900 MPa
    Izod Impact Strength Notched 150 J/m
    Dart Drop Impact 250 g
    Haze 15 %
    Gloss 45 60 %
    Water Vapor Transmission Rate 0.5 g/m²/day
    Oxygen Transmission Rate 2000 cm³/m²/day

    As an accredited Braskem HDPE SGM9450F factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Braskem HDPE SGM9450F comes in 25 kg polyethylene bags, typically palletized and shrink-wrapped for industrial transport.
    Container Loading (20′ FCL) Braskem HDPE SGM9450F is loaded in a 20-foot FCL, typically 25 kg bags, palletized, totaling approximately 18 metric tons.
    Shipping Braskem HDPE SGM9450F is shipped as solid polyethylene resin pellets in 25 kg bags, 500–1000 kg jumbo bags, or bulk containers. It is non-hazardous and typically transported by truck, rail, or sea freight. Store dry, clean, away from heat and sunlight; handle with standard PPE.
    Storage Store Braskem HDPE SGM9450F in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, sparks, and flames. Keep original bags sealed on pallets to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and excessive stacking pressure. Maintain moderate temperatures, use FIFO stock rotation, store separately from oxidizing agents and incompatible materials, and follow local regulations and supplier safety guidance.
    Shelf Life Braskem HDPE SGM9450F has a recommended shelf life of 24 months when stored in original, unopened packaging under cool, dry conditions.
    Application of Braskem HDPE SGM9450F

    Blown film conversion of SGM9450F for T-shirt grocery sacks requires a high-stalk bubble configuration. The resin is fed to a grooved-feed extruder with L/D 30:1 and a barrier screw optimized for high-molecular-weight HDPE. Melt temperature at the die is held between 190 °C and 220 °C. The die gap on a 400 mm annular die is set at 1.4 mm. The bubble is inflated to a blow-up ratio of 4:1. Stalk height is maintained at 6–8 die diameters. Frost line height is controlled by an internal bubble cooling system. Output on a 120 mm grooved-feed extruder is typically 220–260 kg/h. At these settings, melt pressure before the die usually remains below 450 bar. If the die gap is reduced to 1.0 mm for improved gauge uniformity, melt pressure can exceed 450 bar and initiate sharkskin on the film surface. If melt temperature exceeds 230 °C, gel particles from incipient polymer degradation appear as visible specks in 8–15 µm film. If melt temperature falls below 180 °C, the viscosity increase produces weld lines and bubble instability at the frost line.

    Film property release testing for T-shirt sacks produced from SGM9450F should follow ASTM D882 for tensile properties and ASTM D1709 Method A for dart impact. HMW-HDPE films at 12 µm gauge in this density class commonly show dart drop values above 200 g. Machine direction and transverse direction tensile strength at break are typically above 20 MPa. Elongation at break often exceeds 500 %. However, published data specific to SGM9450F at this exact gauge is limited. Processors therefore run capability studies before commercial sack production. Dart impact is sensitive to blow-up ratio and frost line height. A reduction in blow-up ratio from 4:1 to 3:1 increases machine direction orientation and lowers transverse direction dart impact. A frost line height below 5 die diameters tends to reduce transverse direction tear strength as measured by ASTM D1922. These interactions force a compromise between output rate and drop resistance. No pre-drying is normally required for SGM9450F because HDPE does not absorb moisture. Surface condensation on cold pellets should be removed by hopper heating at 60–80 °C to avoid bubble instability and surface defects.

    High-stalk blown film operating window for SGM9450F on a 400 mm annular die
    ParameterLower limitUpper limitFailure mode outside range
    Die gap1.2 mm2.0 mmBelow: melt pressure over 450 bar and sharkskin; above: loss of orientation and low dart impact
    Blow-up ratio3:15:1Below: excessive MD tear anisotropy; above: bubble instability in side winds
    Stalk height5 die diameters8 die diametersBelow: low TD tear; above: bubble flutter and gauge variation
    Melt temperature190 °C220 °CBelow: melt fracture; above: gel formation and discoloration
    Frost line height900 mm1,200 mmBelow: TD tear loss; above: reduced production stability

    What Governs Slow Crack Growth Resistance in Industrial Can Liners?

    Industrial can liners made from SGM9450F are evaluated by environmental stress-cracking resistance under ASTM D1693 Condition B. HMW-HDPE film grades in the 0.945 g/cm³ density range typically report ESCR values above 600 h. Published datasheet values for SGM9450F may differ by test temperature and specimen preparation. A converter should not substitute another HDPE grade without confirming ESCR because can liners are exposed to surfactants, oily waste, and wet organic loads. Slow crack growth initiates at fold lines or at heat-sealed bottom gussets. The critical stress concentration occurs where the film is sharply compressed during stacking. At service temperatures below 10 °C, ESCR of high-density polyethylene generally falls. The material retains sufficient dart impact for 20–50 µm liners. Tensile yield strength is less relevant than low-strain creep behavior. For load-bearing liners, the maximum recommended sustained service temperature is 60 °C. Short-term exposure to 80 °C is possible only when the liner is not under mechanical stress. Chemical incompatibility must also be considered for can liners containing solvent-contaminated waste. Aromatic hydrocarbons and chlorinated solvents reduce ESCR. ASTM D543 provides a screening method for chemical resistance. Thermo-oxidative stability of the resin is checked by ASTM D3895. Typical HMW-HDPE film grades show oxidation induction time above 20 min at 200 °C. The actual value for SGM9450F should be confirmed on the supplier certificate.

    On blown film lines producing can liners, a die gap of 1.6–2.0 mm is preferred. Wider die gaps preserve molecular orientation balance and improve ESCR. Output is limited by film cooling rather than extruder capacity. On a 90 mm grooved-feed extruder with L/D 30:1, output for 25 µm film is typically 180–220 kg/h. Internal bubble cooling is used to maintain frost line height at 1,000–1,200 mm. The blow-up ratio is normally 3:1 to 4:1. Excessive drawdown at high stalk ratios can reduce ESCR. Operators monitor melt pressure and die pressure. Peak die pressure should stay below 400 bar. If die pressure rises, screw speed is reduced or the die gap is widened. Processors avoid regrind levels above 30 wt% without re-qualification because repeated extrusion reduces ESCR. Blends of post-industrial regrind with virgin SGM9450F are acceptable when the regrind fraction is kept below 30 wt% and the melt flow rate of the blend remains within the control range.

    Coextruded e-commerce mailer film can use SGM9450F as the strength layer in a three-layer structure. A typical layer ratio is 20/60/20 with an outer layer of linear low-density polyethylene and a core of SGM9450F. The high-density core provides puncture resistance measured by ASTM D5748. It also provides moisture barrier at low gauge. The film is produced on a 350 mm annular die with three extruders. The core extruder is a 100 mm grooved-feed machine. Melt temperature for the HDPE core is maintained at 200–220 °C. Total film gauge ranges from 40 µm to 80 µm. Puncture resistance of the coextruded structure is tested by ASTM D5748. Typical values for this product class are above 60 N at 50 µm, but published data for SGM9450F in this specific structure is limited. The coextrusion line must maintain a stable interlayer interface. If the core melt temperature exceeds 230 °C, the HDPE layer loses melt strength and the bubble sways. If the die gap is below 1.2 mm, melt fracture in the HDPE core can transfer to the outer layers. Post-industrial regrind at 15 wt% is common in e-commerce mailers. Physical property retention should be confirmed by ASTM D882 and ASTM D5748.

    The HDPE layer contributes stiffness and dead-fold characteristics. Dead-fold is not routinely specified by a single standard but is evaluated by crease recovery angle. In mailer converting, the film is folded and heat sealed on high-speed lines. Heat seal initiation temperature for the LLDPE skins is often between 100 °C and 120 °C. The HDPE core does not govern seal initiation but supports seal strength through its crystalline backbone. Seal strength is measured by ASTM F88. A stable bubble is critical for layer thickness uniformity. On a 350 mm die, layer thickness variation should be held below ±5 % to avoid seal failure at folded edges. Adjustable die lip heaters and internal bubble cooling are used for this purpose. Poor purging during product changeovers can create die streaks that persist in the HDPE layer. These streaks appear as gauge bands at the sealing jaw and reduce seal strength below 20 N/15 mm.

    When Moisture Barrier Function Governs Dry Food Liner Selection

    Dry food liner converting frequently specifies a water vapour transmission rate below 5 g/m²·day at 38 °C and 90 % RH. HDPE film of 25 µm gauge in the 0.945 g/cm³ density class normally falls in the range of 4–6 g/m²·day when measured by ASTM F1249. SGM9450F can be considered for cereal, cracker, and dry mix liner film. The converter must verify compliance with FDA 21 CFR 177.1520 for food-contact use and EU Regulation (EU) No 10/2011 for overall migration. These compliance routes are resin formulation dependent. No single grade can be self-declared as food-contact compliant without review of the full formulation, including stabilizers and processing aids. The film is intended for dry foods with low free fat content. High-fat dry mixes can absorb migratory low molecular weight species. Migration testing under EU No 10/2011 requires overall migration below 10 mg/dm² for food simulants. For fatty simulants, the test is run with 95 % ethanol or isooctane substitute according to EN 1186.

    Compliance checklist for dry food liner applications
    RequirementStandard or regulationControl value
    Melt flow rateASTM D1238 / ISO 1133-1:2022High-load MFR within datasheet control range
    DensityASTM D15050.945 g/cm³
    Food-contact migrationEU No 10/2011<10 mg/dm²
    Food-contact resinFDA 21 CFR 177.1520Conformance by resin supplier formulation review
    Water vapour transmissionASTM F12494–6 g/m²·day at 25 µm, 38 °C, 90 % RH
    Heavy metal migrationEU No 10/2011 Annex IISpecific migration limits as listed

    Process control for dry food liner film demands low gel counts. Gels larger than 200 µm can cause pinholes that destroy moisture barrier. A gel counter based on camera inspection is placed after the collapsing frame. When gel counts exceed 5 per m², melt temperature is checked and the screw is purged. The typical melt temperature range for dry food liner extrusion is 190–210 °C. At 220 °C, gel count increases after 4 h of continuous run if the extruder has dead spots. The die gap is set at 1.4 mm to balance barrier and mechanical strength. Blow-up ratio is held at 3.5:1 to maintain gauge uniformity. Gauge variation outside ±8 % increases localized WVTR above specification. Heat sealing of dry food liners is done at 120–140 °C via impulse or thermal bar sealing. Seal strength by ASTM F88 should exceed 15 N/15 mm for typical cereal liner film. SGM9450F alone can be sealed, but the hot-tack window is narrower than LLDPE. If the sealing jaw temperature exceeds 150 °C, seal thinning occurs. Converters often use a coextruded skin layer to widen the seal window. The HDPE core still provides the moisture barrier.

    A retail merchandise bag converting line with post-gusset sealing places different demands on heat seal initiation temperature. SGM9450F at 18–25 µm gauge is extruded with a blow-up ratio of 3:1. The bubble is collapsed and side-gusseted. Heat seal jaws operate at 125–135 °C. Seal strength is measured by ASTM F88. The film is printed by flexography before bag formation. Surface treatment to 38–42 dyn/cm is required for ink adhesion. Treatment is measured by ASTM D2578. Bag line speed is limited by seal dwell time and film blocking resistance. Blocking resistance is tested by ASTM D3354. A high coefficient of friction can jam the wicket punch. The film should have a kinetic coefficient of friction below 0.5 measured by ASTM D1894. Published data specific to SGM9450F for coefficient of friction is limited. Converters generally add a slip package during film manufacture. The type and level of slip agent must not impair heat seal strength.

    For heavy-duty industrial sacks used in resin, fertilizer, and construction dry mix packaging, blown film of SGM9450F is produced at 60–120 µm gauge. Impact resistance is measured by ASTM D1709 Method A on thick film. Tear resistance is measured by ASTM D1922 and ASTM D1004. On a 160 mm grooved-feed extruder, output reaches 300–400 kg/h at 220 °C. A die gap of 2.0 mm is used for heavy-gauge film. A blow-up ratio of 3:1 improves tear balance. The bubble is cooled with high-capacity external air rings. Frost line height is maintained at 1,200 mm. Gauge variation must be below ±10 % for sack handling. Seal strength of bottom seams is measured by ASTM F88. Sacks are subjected to drop testing per ASTM D5276. Published data specific to SGM9450F in heavy-duty sack configurations is limited. Converters typically run capability trials with filled sack drop weights of 25 kg. Moisture ingress into the packed product is controlled by the HDPE moisture barrier. If the product is hygroscopic, an inner liner of LLDPE is used. The HDPE outer bag provides abuse resistance and stacking stability. Overloading beyond 25 kg increases the risk of seal creep failure at storage temperatures above 40 °C.

    High-Stalk HDPE Film Layers in Laminated Flexible Packaging

    In laminated flexible packaging structures, a high-density polyethylene ply contributes puncture resistance and moisture barrier. SGM9450F is extrusion-coated or adhesive-laminated as a sealant web in pouches for dry powders, pet food, and industrial sachets. The film gauge for this use is commonly 20–40 µm. Puncture resistance is measured by ASTM D5748. Moisture barrier is measured by ASTM F1249. The HDPE film is corona treated to 40–44 dyn/cm for lamination. Lamination bond strength is measured by ASTM F904. Values below 2 N/15 mm after 24 h indicate insufficient surface treatment or adhesive coverage. The HDPE web must be free of centre-fold wrinkles. A high-stalk bubble with internal bubble cooling provides the dimensional stability needed for lamination. The film is slit to width on razor or shear slitting stations. Slitting edge quality affects lamination runnability. A dull shear blade causes a rough edge and generates trim dust that can contaminate adhesive. Line speed for laminating HDPE film is typically 120–180 m/min. If the film has gauge variation above ±8 %, adhesive coating weight varies at the laminator. This produces tunneling or delamination in the final pouch. For adhesive lamination, the adhesive supplier’s technical bulletin should be followed for open time and nip temperature. The HDPE film should be tested for heat seal strength after lamination by ASTM F88. The laminated structure is not a monolayer HDPE application; SGM9450F is one ply in a multi-material package. The operational limitation is that HDPE cannot provide oxygen barrier. If oxygen barrier is required, an EVOH or metallized polyester layer must be added. The HDPE ply remains the moisture barrier and mechanical abuse layer.

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    Certification & Compliance
    More Introduction
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    Braskem HDPE SGM9450F is a pelletized high-density polyethylene extrusion blow-molding resin designed for rigid packaging applications. The material is specified by a density of 0.953 g/cm³ under ASTM D1505 and a high-load melt-flow index of 6.0 g/10 min under ASTM D1238-13, condition 190°C/21.6 kg. The low-load melt index at 190°C/2.16 kg is normally below 0.5 g/10 min. Consequently, the resin exhibits pronounced shear thinning in converging die flow, which is useful for parison control in continuous extrusion blow molding. The specification envelope positions SGM9450F for containers in the approximate range of 0.5 L to 10 L where balanced melt strength, surface definition, and cycle time are required.

    PropertyTest methodReported value
    High-load melt-flow indexASTM D1238-13 / ISO 1133-1:2022, 190°C/21.6 kg6.0 g/10 min
    DensityASTM D15050.953 g/cm³
    Tensile yield stressASTM D638-14, 50 mm/min28 MPa
    Elongation at breakASTM D638-14>800%
    Flexural modulus, 1% secantASTM D790-171,250 MPa
    Notched Izod impact at 23°CASTM D256-105.5 kJ/m²
    Vicat softening temperatureASTM D1525-17e1, 10 N126°C

    The low-load melt index is not the primary release criterion for this grade. The practical reason is that flow at 190°C/2.16 kg is too low to resolve normal lot-to-lot variation on a standard extrusion plastometer. Processors therefore use high-load melt-flow index and melt-flow ratio between the 21.6 kg and 2.16 kg conditions as indirect indicators of die swell and parison sag. The reported mechanical values are typical of a high-density polyethylene with intermediate crystallinity; tensile yield stress and flexural modulus provide resistance to top-load deformation in stacked containers, while the notched Izod value indicates the resin retains limited ductility at standard conditioning.

    What Limits the Operating Envelope on Grooved-Feed Extrusion Blow Molders?

    On a 60 mm grooved-feed extruder with a 25:1 L/D ratio, barrel temperature settings used in production are commonly 175°C, 185°C, 195°C, and 195°C, with a die head temperature of 200°C. These settings produce a die-entry melt temperature between 185°C and 205°C when screw rotation is held within the normal processing range. Sustained melt temperature below 180°C can leave unmelted gel particles in the pinched-off base region and produce variable parison wall thickness. Sustained melt temperature above 220°C increases parison drawdown under gravity; above 230°C, measurable reductions in elongation at break and notched Izod impact can occur after multiple extrusion passes because of thermomechanical degradation.

    Mold temperature is typically controlled between 10°C and 25°C. Cooling time is the dominant cycle-time factor for this grade because the parison solidifies against the mold wall at a rate set by part thickness and coolant temperature. Blow pressure is commonly set between 0.6 MPa and 1.0 MPa. Excessive blow pressure on a thin parison can generate internal stress concentrations at corners, while insufficient pressure produces poor replication of the pinch-off and handle regions. Die gap programming should be adjusted to maintain uniform wall thickness after parison swell.

    Rheological data for high-density polyethylene grades of this class indicate that apparent viscosity at 190°C and shear rate 100 s⁻¹ falls between 2,000 Pa·s and 4,000 Pa·s, while at 1,000 s⁻¹ it falls between 400 Pa·s and 700 Pa·s. The power-law index is usually between 0.35 and 0.45. These values are compatible with continuous shuttle blow molders, accumulator-head machines for smaller tooling, and rotary wheel systems when the extruder is configured with appropriate barrel cooling.

    Applications of Braskem HDPE SGM9450F are concentrated in household and industrial chemical bottles, agrochemical containers, personal-care rigid packaging, and compact food containers where migration requirements are validated for the finished article. In agrochemical and detergent packaging, environmental stress-crack resistance is evaluated under ASTM D1693-15e1, condition B. Published data for filled-container environmental stress-crack resistance with specific ester-based or surfactant-based formulations are limited; therefore, bottle shelf-life must be verified by drop-impact testing in accordance with ASTM D2463-15 and hydraulic burst testing in accordance with ASTM D1599-18. These evaluations should be performed at both 23°C and 5°C because impact resistance and craze growth can shift across the service temperature range.

    Where This Grade Diverges from Lower-HLMI Extrusion Blow-Molding and Injection-Molding HDPE Grades

    Compared with a lower high-load melt-index extrusion blow-molding HDPE class in the range of 2.5–4.0 g/10 min, SGM9450F has lower parison hang strength. It is therefore less suitable for containers above approximately 10 L or for parison drop heights exceeding 1 m, where gravitational drawdown can cause thinning near the upper parison wall. Conversely, its lower melt viscosity at die shear rates can permit higher throughput and more rapid parison programming on smaller bottles. The material also differs from general-purpose injection-molding HDPE grades, which have much higher low-load melt index and are designed for thin-wall mold filling under high injection pressure.

    AttributeSGM9450FLower-HLMI extrusion blow-molding HDPE classGeneral-purpose injection-molding HDPE class
    High-load melt index at 190°C/21.6 kg6.0 g/10 min2.5–4.0 g/10 minnot a primary release property
    Melt index at 190°C/2.16 kg<0.5 g/10 min0.15–0.30 g/10 min5–30 g/10 min
    Density0.953 g/cm³0.953–0.958 g/cm³0.950–0.965 g/cm³
    Primary conversion processextrusion blow moldinglarge-part extrusion blow moldinginjection molding
    Parison hang strengthintermediatehighnot applicable

    The differences are not limited to melt-flow indices. Unimodal injection-molding HDPE grades generally have lower molecular weight and lower orientation in the finished wall, which can produce lower drop-impact crack resistance in pinched-off container bases. SGM9450F has higher die swell and lower melt extension at low shear rates, which is undesirable in thin-wall injection molds but useful for maintaining constant parison thickness after die exit. Compared with lower-density HDPE blow-molding resins near 0.945 g/cm³, SGM9450F provides higher top-load stiffness and better surface hardness, but environmental stress-crack resistance is generally reduced. Compared with higher-density HDPE grades near 0.960 g/cm³, the material provides a wider processing window for stress-crack-sensitive contents but lower room-temperature modulus.

    Regulatory Status and End-Use Compliance Boundaries

    Food-contact status is not self-executing. HDPE resins in this class may be evaluated for olefin polymer compliance under 21 CFR 177.1520(c) 3.1/3.2 when the conversion conditions, intended food type, and additive formulation are specified. For European markets, compliance with Regulation (EU) No 10/2011 requires specific migration testing of the finished article, including processing aids, color concentrates, and regrind. Braskem’s current material safety data sheet and regulatory declaration should be consulted before using SGM9450F in food-contact packaging because formulation changes can alter overall migration. REACH SVHC status and RoHS statements are also additive- and supply-chain-dependent rather than inherent to the base polymer.

    Operational boundaries include storage and drying. HDPE is not hygroscopic, but condensation from cold pellet handling can introduce surface moisture above 0.1 wt%. If surface condensation is observed, pre-drying at 70°C for 1 h is usually sufficient. Chemical incompatibility should be assessed for aggressive fillings. Strong oxidizing acids, halogenated solvents, and some aromatic hydrocarbons at elevated temperatures can degrade polyethylene, while environmental stress-crack resistance may be reduced by certain nonylphenol ethoxylate-based surfactants and cyclic silicone oils. These limits are particularly relevant for industrial chemical containers where long-term contact occurs under internal stress.

    When Regrind Ratios Exceed 20 wt% in Molded Bottles

    Regrind generated from flash, start-up scrap, and rejected containers can be reused in extrusion blow molding, but the recycled fraction introduces additional thermal history. At regrind levels up to 20 wt%, if the regrind is clean, dry, and ground from the same grade, process stability is normally retained. Above 20 wt%, particle-size variation and lowered bulk density can produce feed-bridging in grooved-feed extruders and a measurable shift in high-load melt-flow index. Ultrasonic wall-thickness measurement is recommended to track shoulder-thickness variability because regrind-induced changes in die swell can be larger than the normal percent variation in bottle weight. If burst strength under ASTM D1599-18 falls below production minimums, the regrind fraction must be reduced or the regrind re-stabilized before further use.

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