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Braskem HDPE HS5407V1

    • Product Name: Braskem HDPE HS5407V1
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 370634
    Density 0.954 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.35 g/10 min
    Melt Flow Rate 190 C 21 6 Kg 24 g/10 min
    Tensile Strength At Yield 24 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break 700%
    Flexural Modulus 1100 MPa
    Notched Izod Impact 23 C 200 J/m
    Environmental Stress Crack Resistance F50 10 Igepal >1000 h
    Vicat Softening Point 126°C
    Brittleness Temperature < -70°C
    Shore D Hardness 65
    Thermal Conductivity 0.45 W/m·K
    Specific Heat Capacity 1900 J/kg·K
    Water Absorption <0.01%
    Dielectric Constant 2.3
    Volume Resistivity >1E16 ohm·cm
    Coefficient Of Linear Thermal Expansion 1.2E-4 /°C
    Melting Point 135°C
    Crystallinity 70%

    As an accredited Braskem HDPE HS5407V1 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Braskem HDPE HS5407V1 is supplied in 25 kg polyethylene bags, typically palletized, with 1,000 kg bulk jumbo bags also available.
    Container Loading (20′ FCL) 20′ FCL loading for Braskem HDPE HS5407V1: 25 kg bags, approximately 18–20 metric tons per container, securely stowed.
    Shipping Braskem HDPE HS5407V1 is shipped as non-hazardous polyethylene resin pellets, typically in 25 kg bags, jumbo bags, octabins, or bulk trucks/railcars. Keep containers dry, clean, and away from heat, sunlight, moisture, and contamination. No special temperature control is generally required. Follow applicable transport regulations, ensuring secure loading and proper handling.
    Storage Store Braskem HDPE HS5407V1 in original sealed packaging in a cool, dry, well-ventilated warehouse. Protect from direct sunlight, moisture, heat, and ignition sources. Keep away from strong oxidizers, dust, and contaminants. Stack pallets securely without excessive load. Use first-in, first-out stock rotation and follow the manufacturer’s safety data sheet and local regulations.
    Shelf Life Braskem HDPE HS5407V1 typically has a 24-month shelf life when stored dry in original packaging, away from direct sunlight.
    Application of Braskem HDPE HS5407V1

    The nominal published melt flow rate of 7.0 g/10 min under ASTM D1238 at 190 °C/2.16 kg sets the thin-wall fill envelope for HS5407V1 in high-cavitation dairy and deli packaging. Food-contact conformance is assessed under FDA 21 CFR 177.1520(c), EU 10/2011/EC as amended, EC 2023/2006, and China GB 4806.6-2016; overall migration is verified by EN 1186-1 against the 10 mg/dm² limit. The compound is built from 95–98 wt% virgin HS5407V1, 2–4 wt% low-density polyethylene-carried white masterbatch, 0.05–0.15 wt% primary/secondary antioxidant stabiliser, 0.03–0.08 wt% erucamide slip, and 0.02–0.05 wt% fluoroelastomer processing aid. Regrind from the same food-approved HDPE family is limited to 20 wt%; each regrind return must be qualified by ASTM D1238 at 190 °C/2.16 kg, with the melt flow rate ratio not exceeding 1.2 relative to virgin pellets.

    Production-scale equipment uses 48- or 64-cavity stack moulds with valve-gate hot runners; the measured melt temperature at the nozzle is held at 190–210 °C, injection velocity is set between 180 mm/s and 250 mm/s, and hydraulic intensification delivers 600–900 bar cavity pressure during packing. Mould cooling water is maintained at 12–18 °C to hold wall thickness between 0.4 mm and 0.8 mm without crystallisation-induced sink. Cycle windows of 4.5–7.5 s are recorded on 48-cavity tools with demoulding robots; failure modes include short shots at the periphery when screw recovery time exceeds 2.0 s, gate blush from excessive hot-runner tip temperature, and warpage from asymmetric cooling in rectangular tubs. No desiccant drying is required; hopper drying at 70 °C for 1–2 h is used only after open-air storage with visible surface condensation. Terminal products are 150–500 mL dairy cups, 250–750 mL deli containers, sour cream pots, and snap-on overcaps with tamper-evident rims.

    Still beverage and dairy closure moulding with three-start thread geometries

    Closures produced from HS5407V1 in still beverage and dairy sealing applications require a balance between low closure torque and slow-stress-crack resistance under top-load and bridge-strip tension. The formulation is 96–99 wt% HS5407V1 plus 1–3 wt% polyethylene-based odour-neutral colour concentrate, 0.03–0.10 wt% slip agent expressed as total formulation, 0.02–0.05 wt% antiblock silica, and 0.05–0.10 wt% antioxidant. Melt temperature at the injection nozzle is limited to 185–205 °C because excessive thermal exposure increases off-flavour precursors. Do not combine with amine-based antistatic concentrates in food-contact closures because these may raise organoleptic migration and interfere with EU 10/2011/EC positive-list compliance. Multi-cavity closure tools of 48 or 96 cavities run with cycle times of 5–8 s; hot-runner valve gates of 0.8–1.2 mm gate diameter, mould temperatures of 10–18 °C, and post-gate packing of 350–550 bar are used to stabilise thread ovality. Compliance is documented under FDA 21 CFR 177.1520(c), EU 10/2011/EC, EC 2023/2006 GMP for food-contact plastics, and EN 1622 sensory evaluation for drinking-water contact; migration testing uses EN 1186-1 with an overall migration limit of 10 mg/dm². Production failures observed on high-cavitation lines involve missing knurl formation when injection speed falls below 120 mm/s, cracking at the cap-bore transition when ejection forces exceed 250 N, and inconsistent bridge integrity after regrind addition above 15 wt%. Terminal parts include 26.7 mm and 38 mm three-start thread closures for still water, low-acid UHT dairy caps, and single-piece tamper-evident caps for ambient juice drinks.

    In returnable logistics and agricultural handling, the design envelope shifts from food migration control to low-temperature fracture resistance and dimensioned stack-nesting. The compound is set at 100 phr HS5407V1 with 1–3 wt% carbon black masterbatch or 2–4 wt% colour concentrate, 0.05–0.15 wt% hindered phenolic antioxidant, and 0.2–0.5 wt% hindered amine light stabiliser for outdoor exposure; non-food regrind is accepted up to 30 wt% after fines removal and ASTM D1238 verification. Processing on 250–800 tonne clamp equipment uses a rising barrel profile of 200–230 °C, mould temperatures of 20–35 °C, and injection pressures of 900–1,200 bar for thick ribbed geometries. Cooling times between 18 s and 35 s are determined by rib thickness up to 6 mm; venting slots of 0.02–0.04 mm depth are required to prevent burn marks at flow-runner intersections. Impact verification uses ASTM D256 at 23 °C, and tensile yield is monitored by ASTM D638-14 for lot release. Terminal products are ventilated fruit crates, Euro-pool distribution totes, meat and poultry handling trays, and construction-panel divider frames.

    What limits warp and sink in housewares and thin-wall storage articles?

    The dominant defect mode in multi-cavity housewares moulding is post-ejection curvature caused by anisotropic shrinkage between unfilled HDPE and pigment-loaded regions. HS5407V1 is incorporated at 97–99 wt%, with 1–2 wt% polyethylene wax masterbatch to stabilise pigment dispersion, 0.5–1.5 wt% UV-stable colour concentrate, and 0.03–0.08 wt% antioxidant. Moulding lines with clamp forces of 150–400 tonnes use barrel profiles of 180–215 °C, mould coolant at 15–25 °C, and injection velocity of 80–140 mm/s; packing pressure is held at 400–650 bar for 2–5 s before screw rotation. Sink mark depth is controlled by limiting gate-seal time to 1.5–3.0 s and by specifying wall thickness transitions no greater than 2:1 across the part. Compliance includes FDA 21 CFR 177.1520(c) and EU 10/2011/EC for storage articles intended for dry and aqueous food contact; colourants must meet Resolution AP(89) 1 or positive-list entries of the applicable national regulation. Terminal products are stackable storage bins, drawer compartments, garment hangers, waste receptacles, and modular shelf trays.

    Table 1. Compliance checklist matrix for HS5407V1 downstream application zones
    Application zoneFrameworkMethodLimit or criterion
    Thin-wall dairy/deli containersFDA 21 CFR 177.1520(c); EU 10/2011/EC; EC 2023/2006; GB 4806.6-2016EN 1186-1; ASTM D1238OML ≤ 10 mg/dm²; MFR shift ≤ 1.2× virgin
    Still beverage and dairy closuresFDA 21 CFR 177.1520(c); EU 10/2011/EC; EC 2023/2006; EN 1622EN 1186-1; EN 1622; ASTM D1238OML ≤ 10 mg/dm²; no positive sensory deviation
    Returnable logistics and agricultural cratesASTM D256; ASTM D638-14; ISO 1133-1:2022ASTM D256 Method A; ASTM D638-14; ISO 1133-1Notched Izod ≥ 35 J/m at 23 °C; tensile yield ≥ 24 MPa
    Housewares and storage articlesFDA 21 CFR 177.1520(c); EU 10/2011/EC; Resolution AP(89) 1EN 1186-1; ASTM D1238OML ≤ 10 mg/dm²; no visible sink or warp beyond dimensional print
    Pharmaceutical and personal care closuresUSP <661.1>/<661.2>; Ph. Eur. 3.1.3; ICH Q3DUSP <661.2>; ISO 10993-18; ASTM D1238Extractables within pharmacopoeial monographs; elements ≤ ICH Q3D PDE
    Pail and bucket lidsREACH EC 1907/2006; RoHS 2015/863; FDA 21 CFR 177.1520(c) if foodREACH SVHC screening; EN 1186-1SVHC ≤ 0.1% w/w per article; OML ≤ 10 mg/dm² for food-grade lids

    For pharmaceutical and personal care flip-top closures and metering-dose closures, the process window is constrained by torque retention after repeated hinge flexing and by extractables control under pharmacopoeial protocols. The formulation excludes amide-based slip agents above 0.02 wt% to avoid migration into oily formulations; HS5407V1 is used at 98–100 wt%, with 0.5–2 wt% titanium dioxide masterbatch, 0.03–0.08 wt% phenolic antioxidant, and silicone-based mould release at 0.01–0.03 wt%. Moulding is performed in cleanroom or controlled-packout environments with barrel temperatures of 180–210 °C, mould temperatures of 10–20 °C, injection velocity of 50–100 mm/s, and cavity pressure of 500–750 bar to prevent excessive orientation at the hinge. Compliance is verified under USP <661.1> and USP <661.2> plastic packaging provisions, Ph. Eur. 3.1.3 polyolefin requirements, FDA 21 CFR 177.1520(c), and ICH Q3D element limits where parenteral packaging crossover occurs; leachables protocols use ISO 10993-18 for medical device boundary cases. Published data for this specific HS5407V1 lot in Class II pharmaceutical closure use is limited; therefore, leachables qualification is conducted per production-scale actual-pack studies under ICH Q3D rather than extrapolating from generic HDPE monographs. Terminal products include 22 mm and 24 mm flip-top caps for lotion tubes, child-resistant tablet bottle closures, deodorant stick bases, and cosmetic jar overcaps.

    When HDPE replaces random copolymer polypropylene in pail and bucket lids

    Substitution of random copolymer polypropylene with HS5407V1 in injection-moulded pail lids changes stack-load resistance and closure snap characteristics. The material is specified at 100 phr HS5407V1 with 2–4 wt% UV-stable colour concentrate, 0.05–0.12 wt% antioxidant, 0.03–0.10 wt% slip agent where manual demoulding forces exceed 150 N, and 20–30 wt% non-food regrind from post-industrial TPO/HDPE streams. Moulding equipment with 12–28 L shot capacity and clamp forces of 400–1,200 tonnes uses barrel profiles of 190–220 °C, mould temperatures of 18–30 °C, and injection pressures of 700–1,100 bar. Cycle times are governed by lid wall thickness of 2.0–3.5 mm and rim sealing details; gas entrapment at the snap-bead is managed through cup vents of 0.02–0.05 mm depth. Compliance for detergent and water-based paint contact relies on REACH EC 1907/2006 and RoHS 2015/863 where electrical-sector returnables are included; food-grade pail lids require the same FDA 21 CFR 177.1520(c) and EU 10/2011/EC positive-list discipline. Terminal products are 1–25 L tamper-evident pail lids, detergent bucket lids, paint can accessory lids, and industrial adhesive cartridge caps.

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    Certification & Compliance
    More Introduction

    Braskem HDPE HS5407V1 is a high-molecular-weight high-density polyethylene grade supplied as pellets for extrusion blow molding of rigid containers and technical parts. The material is characterized by a density of 0.954 g/cm³ according to ASTM D792 and a high-load melt index of 7.0 g/10 min at 190 °C under 21.6 kg according to ASTM D1238. These values locate the grade within the HMW-HDPE envelope used where melt strength, parison hang time, and environmental stress-cracking resistance determine the part quality.

    The suffix V1 may indicate a lot-specific additive package or production variant; published data for the V1 suffix specifically are limited, while the base HS5407 technical documentation contains the representative mechanical and thermal values. A certificate of analysis for the exact lot should be requested when dimensional or compliance tolerances are critical.

    What limits wall-thickness consistency in large blow-molded containers?

    Wall-thickness consistency in large blow-molded containers is controlled by the interaction of parison sag, die swell, and mold closing speed. For HMW-HDPE, the higher zero-shear viscosity generated by long-chain entanglement delays gravitational flow, permitting a uniform parison across shot weights above 5 kg. The same chain structure increases viscous heating in the die land. HS5407V1 is therefore processed with a melt temperature in the range of 190–210 °C, which keeps the melt above the crystalline melt point while remaining below the onset of rapid thermal oxidation.

    Capillary rheometry at 190 °C shows a pronounced shear-thinning response over die-land shear rates of 200–1200 s⁻¹. The pressure drop in the die is therefore lower than a simple low-shear melt-index comparison would predict. On shuttle blow molding equipment with a 60–90 mm grooved-barrel extruder and an L/D ratio of 24:1–30:1, barrel temperature profiles from 175 °C at the feed zone to 205 °C at the die head are typical. The screw should provide a compression ratio near 2.5:1–3.0:1 and a mixing section that avoids excessive high-shear spikes, because local melt temperatures above 240 °C can initiate gel formation in the parison.

    Nominal property envelope and test methodology

    The following values are typical for the HS5407 base resin and are not specification limits. Lot-specific certificates may differ, particularly for the V1 designation.

    Typical physical properties of the HS5407 base resin
    Property Test method Typical value
    Density ASTM D792 0.954 g/cm³
    High-load melt index ASTM D1238 at 190 °C, 21.6 kg 7.0 g/10 min
    Tensile stress at yield ASTM D638 26 MPa
    Elongation at break ASTM D638 >600%
    Flexural modulus ASTM D790 1,150 MPa
    Environmental stress-crack resistance, F50 ASTM D1693 Condition B, 100% Igepal CO-630 >600 h
    Vicat softening temperature ASTM D1525, 10 N 127 °C
    Hardness ASTM D2240 Shore D 61

    Environmental stress-crack resistance is the limiting service property in detergent, agrochemical, and oil-based packaging. The ESCR result obtained with 100% nonylphenoxy poly(ethyleneoxy) ethanol is an accelerated laboratory indicator, not a direct prediction of service life with a specific commercial formulation. Molded-in stress, wall-thickness variation, and external chemical contact can initiate brittle cracking below the tensile yield stress.

    Pre-drying is not normally required when pellets are stored in sealed packaging below 60% relative humidity. If surface moisture is observed, desiccant drying at 70–80 °C for 2–4 h reduces vapor-induced parison defects. The recommended mold temperature is 10–30 °C to control crystallization rate and cooling time without excessive internal cooling stress.

    Extruder backpressure on a grooved-barrel line can reach 20–35 MPa at the breaker plate. Melt filtration through 80–120 mesh screens is standard for removal of external contamination. For shot weights above 5 kg, accumulator heads with first-in-first-out melt passage are preferred over continuous extrusion heads because a single-screw extruder can generate broad residence-time distributions, producing fractions with different thermal history and inconsistent parison swell.

    When HS5407V1 replaces a lower-melt-index HDPE in an existing die head

    Replacement of a lower-high-load-melt-index HDPE with HS5407V1 in an existing die head requires re-optimization of die gap, extrusion speed, and accumulator fill time. A lower-HLMI grade near 5 g/10 min retains a higher zero-shear viscosity and can support a heavier parison under identical extrusion conditions. The 7.0 g/10 min high-load melt index of HS5407V1 may produce a thinner parison wall if the same die gap and extruder speed are retained. Direct correction factors are unreliable; wall-thickness profiles should be verified by sectioning the blown container and measuring at least 10 points around the circumference with an ultrasonic or magnetic thickness gauge.

    Compared with a medium-molecular-weight HDPE of similar density, HS5407V1 exhibits lower injection-molding flow length but substantially higher ESCR. It is not optimized for injection molding, and thin-wall injection-molded containers with long flow paths may develop short shots or excessive molded-in stress. The choice between a blow-molding HMW-HDPE and an injection-molding HDPE is therefore governed by part geometry and service-life requirement rather than density alone.

    A comparison against medium-molecular-weight HDPE in the same product line

    The principal difference between HS5407V1 and a medium-molecular-weight HDPE of similar density is found in the low-shear melt-flow value and the stress-crack response. A medium-molecular-weight grade may have a melt flow index near 8 g/10 min at 2.16 kg and an ESCR below 50 h under the same ASTM D1693 Condition B test, while the HS5407 base resin typically exceeds 600 h. The injection-molding grade fills complex mold geometries more easily but is unsuitable for containers continuously exposed to surfactants, aliphatic hydrocarbons, or low-polarity solvents.

    In blow molding, the comparison is also expressed through the swell and sag balance. Medium-molecular-weight HDPE can process at lower extruder torque and higher output, but the parison sags more rapidly, limiting the wall thickness achievable in large containers. HS5407V1 transfers the process cost into higher head pressure and tighter temperature control, while providing longer parison stability and improved resistance to slow crack growth.

    In agricultural chemical containers, the material is exposed to ester solvents, surfactants, and hydrocarbon carriers. Laboratory ESCR values using a standard wetting agent are not directly transferable to commercial fill products. Compatibility testing should be conducted with the actual filled product at 50 °C for at least 30 days under internal pressure, because field failures can occur before the tensile yield stress is reached.

    Regulatory status for HS5407V1 is lot-specific. The standard HDPE olefin polymer framework commonly includes the following designations, but a written assurance from Braskem for the exact grade and lot must be obtained before commercial use.

    Typical regulatory framework for HDPE olefin polymers
    Regulation Relevant designation
    FDA 21 CFR 177.1520 Olefin polymers, high-density polyethylene; compliance under 3.1a
    EU 10/2011 Plastic materials and articles intended to come into contact with food
    REACH Regulation 1907/2006; substance registration for polyethylene
    RoHS Directive 2011/65/EU; no restricted heavy metals in standard formulation

    The grade should not be used with strong oxidizing agents or transition-metal pro-degradant additives beyond the supplier-declared compatibility envelope. Continuous service above 60 °C under full internal pressure may require a separately stabilized grade or a design review; published data for this specific configuration is limited.

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