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Braskem HDPE HF0144

    • Product Name: Braskem HDPE HF0144
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 290461
    Material Type High Density Polyethylene (HDPE)
    Density 0.954 g/cm³
    Melt Flow Rate 0.35 g/10 min at 190°C/2.16 kg
    Tensile Strength At Yield 27 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break 1000%
    Flexural Modulus 1200 MPa
    Notched Izod Impact Strength 80 J/m at 23°C
    Vicat Softening Point 125°C
    Heat Deflection Temperature 70°C at 0.45 MPa
    Shore D Hardness 60
    Environmental Stress Crack Resistance 1000 h at 10% Igepal
    Melting Point 130°C
    Thermal Conductivity 0.45 W/m·K
    Dielectric Constant 2.3

    As an accredited Braskem HDPE HF0144 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Braskem HDPE HF0144 is packaged in 25 kg polyethylene bags, palletized and stretch-wrapped for secure transport.
    Container Loading (20′ FCL) Braskem HDPE HF0144: 20′ FCL holds 1,000 × 25 kg bags, floor-loaded, totaling 25 MT net.
    Shipping Braskem HDPE HF0144 ships as non-hazardous polyethylene pellets in 25 kg bags, octabins, or bulk containers. It is not regulated for transport under DOT, IMDG, or IATA. Store dry, ventilated, away from direct sunlight, heat, and ignition sources. Follow local handling and environmental regulations.
    Storage Store Braskem HDPE HF0144 in original, closed packaging in a cool, dry, well-ventilated warehouse. Keep away from direct sunlight, heat, flames, and strong oxidizing agents. Protect from moisture, dust, and contamination; keep bags palletized off the floor. Avoid prolonged high temperatures. Do not expose to UV radiation. Use first-in, first-out rotation and follow the SDS.
    Shelf Life Braskem HDPE HF0144 has an indefinite shelf life when stored unopened, cool, dry, and protected from direct sunlight and contaminants.
    Application of Braskem HDPE HF0144

    What limits stable cavity fill in thin-wall dairy tubs below 0.8 mm nominal wall?

    For high-speed injection moulding of dairy tubs, lids and margarine containers with nominal wall thickness between 0.6 mm and 1.0 mm, the grade’s melt mass-flow rate of 14 g/10 min at 190 °C/2.16 kg per ISO 1133-1 and density of 0.960 g/cm³ per ISO 1183-1 place the polyolefin at the high-flow end for short injection times while retaining adequate melt strength for valve-gated hot-runner operation. Compliance for food-contact dairy packaging is evaluated under FDA 21 CFR §177.1520(c) as an olefin polymer and under EU Regulation No 10/2011 as amended, with the overall migration limit at 10 mg/dm²; for shipments into China, GB 4806.7-2016 controls food-contact plastic articles, and the converter is responsible for validating the finished article under the intended temperature, food type and food simulant. Formulation is normally neat resin plus LDPE- or HDPE-carrier white masterbatch at 2.0–4.0 wt%; if screw recovery becomes the cycle bottleneck in fast cycles below 5.0 s, a fluoropolymer processing aid may be added at 0.02–0.05 wt%, but addition above 0.10 wt% has been associated with gate blush and carbonaceous specks after 72 h of continuous operation. The polymer does not require pre-drying when stored in closed sacks, but surface moisture from damaged packaging is removed by hopper drying at 70–80 °C for 1–2 h to prevent splay; the screw barrel should use a compression ratio of 2.5:1 to 3.0:1 and an L/D of 20:1 to 24:1.

    Downstream processing on high-speed injection lines typically uses clamp force from 1500 kN to 3500 kN, 16- to 48-cavity hot-runner tools with valve-gate pin control, and melt temperature maintained between 200 °C and 240 °C at the nozzle; mould temperature is held at 10–30 °C with closed-loop water chiller delivery because higher surface temperatures increase cooling time and cause sticking in deep-draw tubs. Injection velocity is set between 180 mm/s and 320 mm/s, with holding pressure from 40 MPa to 60 MPa for 0.4–0.8 s before gate freeze, and total cycle time normally falls between 4.0 s and 8.0 s. A documented process conflict occurs when melt temperature is reduced below 210 °C to lower energy input: screw recovery time lengthens, non-return valve leakage becomes measurable, and cavity-to-cavity fill imbalance in hot-runner multi-drop tools can exceed 10 %, producing flash and short-shot defects in the same shot. Under these conditions the cushion should be maintained at 4–6 mm, decompression after plasticating kept below 3 mm, and rear barrel temperature not allowed to drop below 180 °C because feed-zone granule slip causes pressure instability. Terminal article types include margarine tubs, dairy dessert cups, snack dip containers, deli pots and injection-moulded thin-wall lids for flexible lidding films.

    Closure moulding with this grade on 64- to 128-cavity stack tools is concentrated in twist-cap and tamper-evident ring applications where linerless sealing geometry must survive thread engagement and drop impact without cracking at the gate vestige. Food-contact compliance for closures is assessed under FDA 21 CFR §177.1520(c) and EU Regulation No 10/2011 for overall migration; sensory taint for dairy and water closures is often checked using ISO 13302:2003 or equivalent taint-test protocols, and the converter must verify that color masterbatch carriers and pigments do not raise total migration above the legal threshold. Formulation is typically natural resin or a spirit-toned white masterbatch at 1.0–3.0 wt%; slip additives are omitted or kept below 0.05 wt% because erucamide and oleamide migration alters cap removal torque and may contaminate aseptic filling lines. No desiccant drying is required for closed raw-material packaging, but the resin must not be mixed with external regrind that has been washed with alkaline detergents above 70 °C because residual stress-cracking agents can reduce environmental stress-crack resistance in the finished closure.

    Production is performed on electric or hydraulic toggle injection machines with clamp force from 1500 kN to 4500 kN, using hot-runner or cold-runner systems; melt temperature is controlled between 190 °C and 230 °C, and stack-mould cooling water is held at 5–25 °C to accelerate gate freeze. Injection velocity of 100–250 mm/s is balanced against gate diameter to avoid jetting at the small gate; cavity pressure at gate freeze is maintained between 55 MPa and 75 MPa, and cycle times in high-cavitation closure production normally range from 5.0 s to 9.0 s. A production-scale bottleneck is the tamper-evident bridge slitting station: bridge thickness variation from non-uniform cavity pressure causes inconsistent slit force and can generate dust that interferes with aseptic filling sensors; cavity pressure transducers in two or four cavities per stack half are recommended for continuous monitoring. Finished article types include mineral-water and soft-drink caps, aseptic dairy closures, sports push-pull caps and HDPE over-caps for glass bottles. Published data for this specific grade in long-term carbonated beverage closure tests is limited, so internal ESCR validation under ASTM D1693 or equivalent is required before substituting it into pressurized returnable containers.

    Injection-grade HDPE for open-head pails and conical bucket moulds

    Open-head pails and conical buckets with wall thickness between 2.0 mm and 4.0 mm are moulded from this resin for lubricant, paint, construction chemical and food-ingredient packaging because the grade combines high stiffness at density 0.960 g/cm³ with enough flow to fill large projected areas without excessive clamp force. Regulatory assessment for food-contact pails follows FDA 21 CFR §177.1520(c) and EU Regulation No 10/2011; pails exported to the United States must also satisfy CONEG Toxics in Packaging model legislation limiting the sum of lead, cadmium, mercury and hexavalent chromium in packaging inks and pigments to 100 mg/kg. Where a moulded pail is intended for regulated dangerous goods, the packaging design must be qualified under the UN Model Regulations Chapter 6.1 and applicable modal provisions of ADR/RID/IMDG, with drop and leakproofness tests conducted on the finished article rather than on resin alone. Pigment masterbatch addition for opaque pails is typically 2.0–5.0 wt%; outdoor weathering grades use a hindered amine light stabilizer masterbatch at 0.2–0.8 wt%, and electrostatic-dissipative pails use conductive carbon black masterbatch at 2.0–4.0 wt%, which raises melt viscosity and should not be combined with mineral fillers because the combined viscosity increase reduces flow length in thin pail rims.

    Processing on two-platen or single-face injection machines with clamp force from 5000 kN to 15000 kN requires shot-size selection between 40 % and 60 % of barrel capacity; larger shot percentages cause residence-time degradation and black specks. Barrel temperatures are set from 210 °C to 250 °C, mould temperature is maintained between 15 °C and 40 °C, and holding pressure is applied at 35–70 MPa until gate freeze, which for these wall thicknesses normally requires 8–15 s; total cooling time ranges from 12 s to 30 s. Observed failure modes on handle-bearing pail tools include sink formation at handle junctions when hold pressure falls below 35 MPa or hold time is shortened below 8 s, and rim ovality when demoulding occurs above 70 °C surface temperature measured by infrared pyrometer. Finished products include 2–10 L open-head pails, conical paint buckets, lubricant pails with tamper-evident lids and food-grade bulk ingredient pails.

    Within high-cavitation housewares tooling, nominal wall sections of 2.0–4.0 mm are used for storage bins, drawer dividers and waste containers where the high flow of this resin reduces injection pressure drop across long flow paths and permits lower clamp force than lower-MFR grades at equivalent wall thickness. General consumer article requirements include REACH Regulation (EC) No 1907/2006 Annex XVII restricted substances and the General Product Safety Regulation (EU) 2023/988; for housewares that may contact dry or cold food, converters should verify the article under EU Regulation No 10/2011 or FDA 21 CFR §177.1520(c) because base resin compliance does not automatically cover post-added colorants or antistatic packages. Pigment masterbatch is added at 2.0–3.0 wt%; antistatic masterbatch may be used at 1.0–2.0 wt% for dust-sensitive storage applications, but surface resistivity should be verified after 72 h because quaternary ammonium antistats migrate to the surface over time. Slip agents are normally excluded where hot-stamping, pad printing or pressure-sensitive labels are applied, because surface bloom at concentrations above 0.05 wt% reduces ink adhesion and causes label lift-off at warehouse humidity above 60 % RH.

    Injection moulding of larger housewares such as waste containers and drawer towers is run on hydraulic toggle machines with clamp force from 1200 kN to 4500 kN, melt temperature between 200 °C and 240 °C, and mould temperature at 10–35 °C; injection speed is held between 80 mm/s and 160 mm/s to minimize shear heating at the gate, with holding pressure from 30 MPa to 50 MPa and total cycle time between 15 s and 35 s. For high-gloss show surfaces, mould cavity polish should be at least SPI A-2 or equivalent, and cooling water flow per circuit should be balanced to maintain cavity surface temperature variation below ±3 °C because differential cooling across long vertical ribs causes sidewall warpage. Terminal article types include stackable storage bins, drawer organizers, wastepaper baskets, clothes hangers and tray dividers.

    When stack-load creep and washdown chemical resistance dictate design in material handling trays

    Material handling trays and collapsible crates moulded from this grade are designed around top-load creep, washdown sanitation and low-temperature handling in food-processing and logistics environments. Regulatory coverage includes REACH Article 33 SVHC communication duties and, for direct food contact, EU Regulation No 10/2011 and FDA 21 CFR §177.1520(c), with specific migration data required for the finished tray because repeated commercial dishwashing and acid-based sanitation can change surface migration behavior over time. Formulation additions include a HALS/UV package at 0.20–0.50 wt%, hindered phenolic antioxidant at 0.05–0.15 wt%, and color masterbatch at 2.0–4.0 wt% for high-visibility logistics color coding; for freezer use, low-temperature impact resistance should be verified under ASTM D256 or ISO 180 because homopolymer HDPE impact strength declines with temperature, and field failures at sidewall bosses have been observed when trays are dropped at -20 °C without full crystallization. Conductive carbon black is not recommended for food-handling trays because surface carbon can transfer during wet washdown and interfere with optical sorting equipment.

    Production uses accumulator-assisted injection machines with clamp force from 4000 kN to 12000 kN because wall thicknesses are frequently between 3.0 mm and 8.0 mm; melt temperature is set between 210 °C and 250 °C, mould temperature between 20 °C and 50 °C, and fill speed is deliberately reduced to 50–120 mm/s to prevent jetting and weld-line voids at structural corner bosses. Holding pressure is maintained at 50–80 MPa for 12–25 s and cooling time ranges from 25 s to 60 s, depending on local wall thickness and gate location; sequential valve gating is preferred over open hot-runner systems because the material flow front can be advanced from the thickest section outward, moving weld lines away from high-stress bottom corners. Production-line audits show that uneven cooling of the base grid causes diagonal warpage above 3 mm per linear meter when mould halves differ by more than 5 °C; conformal cooling or baffled channels in the base plate reduce this variance. Finished products include collapsible crates, bakery trays, meat lugs, automotive dunnage and general-purpose logistics boxes.

    Compliance verification matrix by terminal article category
    Terminal article categoryPrimary regulatory referenceClause or test methodVerification point
    Thin-wall dairy tubs and lidsFDA 21 CFR§177.1520(c); EU 10/2011 OMLMigration under intended food simulant and use condition
    ClosuresFDA 21 CFR§177.1520(c); ISO 13302:2003Overall migration and taint/odor transfer
    Open-head pailsUN Model RegulationsChapter 6.1; ADR/RID/IMDGDrop, stack and leakproofness on finished pail
    HousewaresREACHAnnex XVII; EU 2023/988Restricted substances and general product safety
    Material handling traysFDA 21 CFR; EU 10/2011§177.1520(c); ISO 180Food-contact migration and low-temperature impact
    Cosmetic packagingRegulation (EC) No 1223/2009Article 17Packaging compatibility and finished product safety

    Because exterior surfaces of cosmetic jars and thick-walled personal-care packaging require specular gloss, zero gate blush and tight dimensional stability, these articles are moulded with high holding pressure and precisely controlled cooling. Packaging intended to store cosmetic formulations is assessed under Regulation (EC) No 1223/2009 for the finished cosmetic product, and the packaging itself must not release substances at levels that affect product safety; compliance statements under REACH Article 33 are also required when SVHC content exceeds 0.1 % w/w in an article. Colour masterbatch is added at 1.0–3.0 wt%, with pearlescent or mineral-effect masterbatch at 0.5–1.5 wt% for opaque high-gloss appearances; external lubricants are limited to 0.1 wt% maximum because higher levels generate orange-peel and mould deposit on polished cavities. Pre-drying is not required for the resin, but hygroscopic effect pigments must be dried separately at 60–80 °C for 1–2 h before blending to prevent surface splay.

    Thick-wall injection moulding of cosmetic jars and pump collars is carried out on hydraulic machines with clamp force from 2000 kN to 6000 kN, melt temperature between 200 °C and 230 °C, and mould temperature between 30 °C and 60 °C to promote surface replication of polished texture; injection speed is kept at 30–80 mm/s to avoid jetting into thick cross-sections, and packing pressure is set from 60 MPa to 90 MPa with hold time of 10–20 s until gate freeze is confirmed by cavity pressure drop below 55 MPa. For jars with wall thickness above 3.0 mm, total cooling time is usually 20–40 s; demoulding temperature should stay below 70 °C to avoid sink marks and boss-hole distortion. Mould-shop observations show that reducing mould temperature below 30 °C produces visible flow lines around engraved base lettering and hinge bosses, while excessive melt temperature above 230 °C increases yellowing and odour in white formulations. Terminal article types include cosmetic cream jars, compact cases, airless pump collars, over-caps for hair-care packaging and thick-walled sample containers.

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    Certification & Compliance
    More Introduction

    Braskem HDPE HF0144 is a high-density polyethylene resin developed for injection molding applications where rapid cavity filling, short cycle times, and thin-wall geometry are the primary process drivers. The grade’s published melt flow rate of 44 g/10 min under ASTM D1238 conditions of 190 °C and 2.16 kg places it near the high-flow end of the HDPE injection molding portfolio. Nominal density is 0.956 g/cm³ per ASTM D1505, which provides the stiffness, chemical resistance, and water-vapour barrier expected from HDPE while retaining a melt viscosity low enough for multi-cavity tools with short land lengths. Typical article classes include thin-wall containers, lids, overcaps, housewares, and toys; these are non-pressure applications in which cycle-time reduction and dimensional repeatability outweigh the high slow-crack resistance of higher-molecular-weight HDPE. The resin is not a blow-molding or blown-film grade, because the low melt strength associated with 44 g/10 min causes parison sag and film bubble instability on standard extrusion equipment.

    Does Shear History and Thermal Residence Govern Defect Rates?

    For high-flow HDPE, degradation is primarily thermal-oxidative and shear-induced. Processing should begin with barrel zones profiled from 160 °C at the feed throat to 210–220 °C at the nozzle. The melt temperature measured at the nozzle should be maintained between 180 °C and 220 °C. Extended operation above 240 °C increases chain scission, yellowing, and black speck generation; residence time at melt temperature should be kept below 15 min on conventional hydraulic machines. On general-purpose compression screws with 20:1 to 25:1 L/D ratios, screw speeds above 150 rpm can introduce shear heating and require downward temperature adjustments. Back pressure above 0.7 MPa usually prolongs recovery time without improving homogenisation because the melt has low viscoelastic memory. These boundaries are class-level starting conditions, not product specifications, and should be transferred to a specific tool through molding trials.

    Surface moisture is rarely a processing problem for HDPE because water absorption is below 0.01 wt%; however, condensation on cold pellets after outdoor silo storage or high-humidity transfer lines can cause splay and surface streaks at the gate. When visible moisture is present, pellets should be pre-dried at 80 °C for 2 h using desiccant equipment or a hot-air hopper dryer sized for the throughput of the molding cell.

    Representative physical property values for Braskem HDPE HF0144 are summarised in Table 1. Values are not batch certificates and should be confirmed against the current technical dossier.

    PropertyTypical valueTest method
    Melt flow rate, 190 °C/2.16 kg44 g/10 minASTM D1238
    Density0.956 g/cm³ASTM D1505
    Tensile yield strength27 MPaASTM D638
    Elongation at break>300%ASTM D638
    Flexural modulus1100 MPaASTM D790
    Notched Izod impact30 J/mASTM D256
    Vicat softening temperature124 °CASTM D1525
    Heat deflection temperature, 0.455 MPa72 °CASTM D648
    Hardness, Shore D64ASTM D2240
    Mold shrinkage1.5–2.5%ASTM D955

    The tensile and flexural data indicate that HF0144 provides adequate stiffness for thin-wall containers but should not be used where slow crack growth is the controlling failure mode. The high melt flow index is inversely related to molecular weight; therefore environmental stress crack resistance, as assessed by bench tests such as ASTM D1693, is typically lower than values reported for fractional-melt high-molecular-weight HDPE grades. Published data for this grade under stress-crack testing is limited, so continuous exposure to detergents, alcohols, or organic oils in pressurised or flexed parts should be validated with article-specific testing. The thermal deformation limits shown by 72 °C heat deflection temperature at 0.455 MPa and 124 °C Vicat softening mean that steam sterilisation or hot-fill conditions above 80 °C should be evaluated for dimensional change.

    Lower-Melt-Index HDPE Grades Are Not Direct Replacements in Thin-Wall Tools

    A reduction in melt flow rate from 44 g/10 min to a fractional-melt or blow-molding range of 0.3–8 g/10 min increases melt viscosity, shortens spiral flow length, and raises filling pressure for equivalent wall section. Injection tools designed for HF0144 may have gate diameters, runner geometries, and vent depths matched to low-viscosity HDPE; substituting a lower-MFR grade can produce short shots, weld-line splitting, and molded-in stress near the gate. Conversely, using HF0144 in thick-wall parts designed for a lower-MFR HDPE can lead to sink marks and low impact because the higher-flow grade consolidates less packing at long hold times.

    Compared with LDPE and LLDPE, HDPE HF0144 has higher density, higher tensile yield strength, and lower extrinsic tear resistance. The material is therefore more suitable for rigid injection-molded parts than for flexible or film-based designs. Blends with LLDPE can improve hinge flex resistance, but the addition alters melt flow and should be evaluated through ASTM D1238 and ASTM D790 before production. Vent depths below 0.010–0.015 mm may be insufficient for this high-flow grade in rapid-fill tools, contributing to gas traps and gate blush.

    Table 2 provides initial molding parameters for a mid-sized hydraulic injection molding machine with a general-purpose compression screw and 120–250 t clamp force. These conditions are based on standard high-flow HDPE processing practice and must be modified for hot runner geometry, wall thickness, and part mass.

    ParameterRecommended range
    Melt temperature180–220 °C
    Mold temperature10–40 °C
    Injection pressure60–120 MPa
    Holding pressure40–70 MPa
    Back pressure0.3–0.7 MPa
    Screw speed80–150 rpm
    Decompression3–6 mm
    Pre-dry, if surface moisture80 °C for 2 h

    In thin-wall applications with flow-to-wall-thickness ratios above 100:1, the nozzle temperature should be kept in the upper half of the melt range, and injection velocity should be increased to prevent premature freeze-off. The use of a decompression distance above 6 mm can create air entrapment and splay; use the shortest decompression that prevents drool. In multi-cavity hot-runner systems, the pressure drop across the runner should be measured and balanced to within 5–10% of the mean cavity-to-cavity value to avoid weight variation. Mold temperature below 10 °C can produce visible flow lines on the surface; mold temperatures above 40 °C extend cycle time without significant property gain in unstabilised natural grades.

    Regulatory Status and Chemical Exposure Boundaries

    For food-contact use, high-density polyethylene homopolymer falls within olefin polymers according to FDA 21 CFR 177.1520. Compliance of the final food-contact article requires assessment of antioxidant and processing stabiliser residues, pigments, and any masterbatch; the grade’s regulatory status therefore transfers only when the final formulation meets the applicable end-use conditions. In the European Union, the base resin may be evaluated under Regulation (EU) No 10/2011; overall migration and specific migration testing are article-dependent. Braskem should be requested to supply a food-contact statement for the specific lot and grade.

    No intentional additions of substances restricted under RoHS Directive 2011/65/EU are indicated in standard HDPE compounds, but end-use declarations should be verified with the resin supplier. Chemical resistance follows general HDPE behaviour: the material resists most aqueous solutions, dilute acids, bases, and polar solvents at ambient temperature, but prolonged exposure to aromatic hydrocarbons, chlorinated solvents, and strong oxidising acids should be evaluated under ASTM D543. Service above 60 °C in aggressive media is not recommended without specific qualification.

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