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Braskem HDPE HA7260

    • Product Name: Braskem HDPE HA7260
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 297991
    Polymer Type High-density polyethylene (HDPE)
    Density 0.953 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 0.30 g/10 min
    Tensile Strength At Yield 25.5 MPa
    Tensile Strength At Break 29.6 MPa
    Elongation At Break 600%
    Flexural Modulus 1100 MPa
    Vicat Softening Temperature 124°C
    Heat Deflection Temperature 0 45 Mpa 70°C
    Environmental Stress Crack Resistance 10 Igepal >1000 h
    Hardness Shore D 64
    Water Absorption <0.01%
    Thermal Conductivity 0.44 W/m·K
    Coefficient Of Linear Thermal Expansion 1.2E-4 /°C
    Specific Heat Capacity 1.9 J/g·°C
    Dielectric Strength 20 kV/mm
    Volume Resistivity 1E16 ohm·cm
    Dielectric Constant 2.3
    Dissipation Factor 0.0002
    Brittleness Temperature < -70°C

    As an accredited Braskem HDPE HA7260 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Braskem HDPE HA7260 is packaged in 25 kg polyethylene bags, typically 55 bags per pallet, totaling 1,375 kg.
    Container Loading (20′ FCL) Braskem HDPE HA7260 loaded in 20′ FCL: 25 kg bags, palletized, shrink-wrapped, evenly distributed, and secured for ocean shipment.
    Shipping Braskem HDPE HA7260 is shipped as non-hazardous polyethylene resin pellets in 25 kg bags, jumbo bags, or bulk trucks/railcars. Keep packaging dry and intact, store away from heat, sunlight, moisture, and contaminants. Use standard handling equipment; avoid punctures, spills, and prolonged UV exposure. Follow SDS and local transport regulations.
    Storage Store Braskem HDPE HA7260 in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and strong oxidizers. Keep in original sealed packaging on pallets, off the floor, to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and excessive stacking. Use first-in, first-out rotation. Follow local regulations and the safety data sheet.
    Shelf Life Shelf life is 24 months when stored in original packaging, in a cool, dry, ventilated area away from direct sunlight.
    Application of Braskem HDPE HA7260

    Where cooling time rather than melt pressure drives piece cost, Braskem HDPE HA7260 is specified for injection-moulded thin-wall dairy cups, spreads tubs, and film-seal lids in wall sections from 0.40 mm to 0.85 mm. The material is processed on toggle-clamp injection machines in the 80 t to 150 t range with accumulator-assisted injection velocities between 50 mm/s and 150 mm/s; when velocity at the valve gate exceeds 150 mm/s, the failure mode most frequently observed on high-cavitation dairy cup tools is gate blush followed by downstream flow marks that are visible after metallised labelling. Cylinder temperature settings are kept with the rear zone at 170–180°C, the middle zone at 190–210°C, and the nozzle at 195–215°C; melt temperatures above 230°C or residence times beyond 20 min create oxidised species that can transfer as off-taste in sensitive dairy applications and are detected by sensory panels following DIN 10955. Cooling time for a 0.55 mm sidewall with a 12°C coolant supply is typically 4.5–6.0 s, while holding pressure is set at 50–70 MPa hydraulic and decays to 10–15 MPa over 1.2–1.8 s to reduce sink opposite gate pads. Hot-runner valve gates are preferred because they prevent cold-sprue regrind accumulation in high-cavitation tools; sequential valve actuation delays the outer cavities by 0.2–0.5 s and lowers the effective clamp requirement by approximately 15%. Compliance for dairy contact is documented under FDA 21 CFR 177.1520 and under EU No 10/2011 with an overall migration limit of 10 mg/dm²; converters verify the finished article rather than the pellet because the addition of masterbatch, hot-runner lubricant, or mould-release agent can shift the extraction profile. Low-temperature impact testing is performed at 5°C after 24 h conditioning with a dart-drop rig equivalent to ASTM D1709 or with a 50 mm/min puncture probe; cracks at the injection gate or at the melt-weld line are classified as functional rejects because they initiate lid film detachment in downstream filling lines.

    What Torque Retention and Environmental Stress Crack Resistance Limits Are Defined for Injection-Moulded Closures?

    Injection-moulded HDPE closures for non-carbonated water, juice, and household chemical bottles use the same high-flow behaviour but require a different set of acceptance tests tied to sealing force and long-term embrittlement. For a 38 mm screw cap with a moulded-in liner or separate EVA liner, application torque on a capping head is maintained between 1.5 N·m and 2.0 N·m at 20°C and 50% relative humidity; removal torque measured after 24 h at 40°C must remain between 0.8 N·m and 1.8 N·m to avoid consumer opening failures and cap bridging. The tamper-evident tear band is moulded with bridge thickness of 0.08–0.12 mm; below 0.08 mm the bridges fracture during ejection or downstream unscrambling, while above 0.12 mm the opening torque increases beyond acceptable retail limits. The most serious processing boundary is environmental stress crack resistance measured according to ASTM D1693-B in 10% Igepal CO-630 at 50°C; high-flow HDPE grades of this type commonly exhibit short F50 times, often below 30 h, and this restricts the material to closure applications with low sustained hoop stress and to contents that do not contain free fatty acids, nonylphenol ethoxylates, or volatile hydrocarbon fractions. The ESCR limitation also means that overtightening in warehousing at elevated temperature is a field failure mode: a cap sealed at 2.2 N·m and stored at 45°C for 14 days may show stress cracking at the inner diameter of the tamper band. Tooling for high-flow HDPE closures is typically a 48-cavity or 64-cavity hot-runner mould with valve-gate drops of 0.8–1.2 mm; because the gate freezes quickly, holding pressure is limited to 0.5–1.0 s and total cycle time falls to 6.0–8.5 s. Melt temperature is held at 200–220°C and cooling time at 4.0–6.0 s using mould temperatures of 10–18°C. Dimensional control is checked by optical gauging of the PCO finish at 24 h post-moulding because post-shrinkage of high-density polyethylene changes the internal diameter by 0.2–0.5%; closure performance must therefore be evaluated on aged parts, not fresh parts, against the bottle supplier’s finish drawing.

    Open-head pails, ventilated storage crates, and distribution totes shift the validation focus from high-speed melt filling to low-temperature impact resistance, stacking deflection, and chemical retention under long-term load. The moulded wall thickness for pails in the 5 L to 25 L range is held at 1.2–1.8 mm, with the handle-ear transition radius maintained above 1.5 mm to prevent notched failures during manual lifting. For pails certified as UN 1H2 open-head containers for solid and viscous liquid transport, drop testing follows the UN Model Regulations Chapter 6.1; packing group II requires a drop height of 1.2 m after conditioning at -18°C for 24 h when the product is a liquid, and the pail is dropped on the diagonal edge with no leakage permitted. A common failure site in HDPE pails is the junction between the stacking ring and the sidewall, where frozen-in orientation from high injection speed creates a brittle band; the remedy is to reduce surface velocity in that region to 30–50 mm/s and to increase mould temperature locally to 25–30°C using a split cooling circuit. Crates and totes with grid bases and ribbed sidewalls are moulded with nominal walls of 2.5–4.0 mm on machines with clamp force between 350 t and 650 t; holding pressure is ramped from 60 MPa to 35 MPa in 1.5 s stages to control sink at rib intersections. Dimensional stability is judged by corner lift after 48 h at 23°C; acceptable corner lift for a 600 mm x 400 mm x 300 mm crate is generally below 2.0 mm, while values above 3.5 mm produce unstable pallet stacking. Because high-flow HDPE solidifies with lower molecular orientation than fractional-melt grades, its notched impact strength at -30°C measured by ISO 179-1/1eA is lower; field data from crate tooling indicate that rib-to-wall thickness ratios above 0.75 and sharp inner radii below 0.4 mm are the two primary causes of brittle fracture during cold-room handling. Regrind addition up to 20% by mass is generally accepted for crate and tote moulding, but pails packed with aggressive chemicals are moulded from virgin material because reprocessing shifts the stress crack resistance downward and can contaminate the material with degradation products that alter permeation.

    Housewares and Toy Components Under EN 71-3 Migration Testing

    Storage canisters, waste bins, compost caddies, and toy components are injection moulded from HA7260 only after the finished article is assessed for extractable metals and organics, because the grade’s conformity at pellet stage does not cover processing-induced changes. Toy parts made from high-density polyethylene are classified under EN 71-3:2019+A1:2021 as category III materials when they are intact and not subject to scraping, swallowing, or extensive mouthing; the standard prescribes extraction with 0.07 mol/L hydrochloric acid at 37°C for 2 h followed by ICP-MS or AES detection for a panel of elements that includes antimony, arsenic, barium, cadmium, chromium VI, lead, mercury, and selenium, with migration limits fixed by element and material category. Moulders should not rely on the base grade alone when colour concentrates are added; some inorganic pigments and zinc-based nucleators shift the extractable metal profile of the finished moulding and may require reformulation or a lower masterbatch dose. For housewares in contact with dry or fatty foods, EU No 10/2011 applies with an overall migration limit of 10 mg/dm² and, where fatty contact is involved, testing in simulant D2 at 40°C for 10 days may be required depending on the predicted contact time. The material is not specified for sustained contact with boiling water or steam service; the Vicat softening temperature measured under ISO 306/A50 typically lies in the 122–128°C band for high-flow HDPE, and components with snap-fit lids lose clamping force when exposed repeatedly above 90°C. Injection moulding of thin food-storage lids uses highly polished cavity surfaces and degassing, because any cavity scratch above 0.1 µm Ra can act as a bacterial adhesion site and is difficult to clean; surface roughness is therefore monitored with contact profilometry rather than visual inspection. The table below consolidates the article-specific validation requirements for downstream converters.

    Validation domainStandard or regulationRelevant test method or clauseBoundary for HA7260
    Food contact polyolefinFDA 21 CFR 177.1520Extraction and migration for olefin polymersFinished article only, not pellet
    Plastics in food contactEU No 10/2011OML 10 mg/dm²; specific migration clauses in Annex IIFatty simulant D2 if contact time or dose require
    Toy componentsEN 71-3:2019+A1:2021HCl extraction at 37°C for 2 h; element-specific limitsCategory III only; colourants may shift profile
    Pail transportUN Model Regulations Chapter 6.1Drop height 1.2 m for PG II; -18°C conditioningGrade suitable for non-aggressive liquids only
    Melt process controlISO 1133-1:2022Melt mass-flow rate at 190°C/2.16 kgUse as lot-to-lot verification
    Stress crackingASTM D1693-B10% Igepal CO-630 at 50°CShort F50 restricts closure exposure

    When High-Flow HDPE Meets Large-Format Pallet Tooling and Gas-Channel Design

    Large-format pallets, collapsible bulk bins, and logistics bases are not primary application targets for a high-flow HDPE such as HA7260, but the grade is occasionally evaluated when filling a 1200 mm x 1000 mm pallet with wall thickness between 3.5 mm and 6.0 mm on a clamp force above 1000 t is constrained by injection pressure. The high-flow behaviour reduces peak cavity pressure from the 110–130 MPa range common for fractional-melt pallet grades to 80–100 MPa, which can permit the use of smaller injection units or lower clamp tonnage; however, the same flow behaviour lowers melt strength at the gas-channel interface in gas-assisted moulding and creates a narrower processing window. In gas-assisted pallet trials, the nitrogen injection pressure is typically set at 25–35 MPa with gas channel diameters of 8–12 mm; when the melt front is too fluid, the gas tends to break through the advancing front or migrate into thin rib sections, producing internal voids that reduce top-cap compression strength. The primary acceptance test for pallets is a static top load of 3000–5000 kg for a 9 stack loaded configuration, with deflection measured at 23°C and after 30 min at 40°C; pallets moulded from high-flow HDPE often pass top load but exhibit brittle failure in the forklift-entry pocket when impact tested at -20°C using a 50 kg tup at 2 m/s. For this reason, converters restrict high-flow HDPE pallet mouldings to light-duty returnable logistics where the pallet is not racked, not exposed to hydrocarbon lubricants, and not subjected to outdoor UV beyond 500 h of exposure unless a suitable UV stabiliser package is compounded in. Batch-to-batch variation in melt mass-flow rate of more than ±10% relative to the supplier’s nominal value is the most common cause of dimensional rejection in large-part HDPE moulding because it changes fill time, packing decay, and shrinkage anisotropy simultaneously; converters running pallet tools therefore require incoming lot verification under ISO 1133-1:2022 and adjust shot size when the measured value shifts by more than 5% from the qualification lot.

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    Certification & Compliance
    More Introduction

    Braskem HDPE HA7260 is a high-molecular-weight high-density polyethylene specified for extrusion blow moulding of rigid containers requiring elevated environmental stress-crack resistance and low-temperature impact strength. The grade is identified by a nominal density of 0.955 g/cm3 when measured under ASTM D1505 and a high-load melt-flow rate of 0.30 g/10 min under ASTM D1238 at 190 °C/5.0 kg. Those two values place HA7260 in the upper-molecular-weight portion of the blow moulding HDPE range, distinct from lower-viscosity grades used in thin-wall or small-bottle production. Supplier technical documentation lists the primary conversion route as continuous or intermittent extrusion blow moulding, with end articles including jerrycans, agricultural-chemical containers, industrial fluid packaging, and fuel-adjacent service where multilayer structures or ozone-resistant barrier systems are used. The resin is not formulated as an injection-moulding or film-extrusion grade; the low melt-flow rate under high load limits flow into thin-wall cavities and favours parison stability during mould closing.

    In comparison with general-purpose HDPE blow-moulding grades with melt-flow rates of 0.70–2.0 g/10 min at 190 °C/5.0 kg, HA7260 provides increased melt strength and longer relaxation time. Those properties reduce draw-down of the parison in large containers and permit heavier wall sections without excessive thinning at the pinch-off zone. The trade-off appears as higher head pressure and lower cycle-rate ceilings on screw-limited machines. The material is therefore positioned for applications where slow-crack-growth failure modes, not merely processability, determine container service life.

    What Property Profile Separates HA7260 from Commodity Blow Moulding HDPE Grades?

    Property data are generated on compression-moulded or injection-moulded specimens as specified by the relevant standard; blow-moulded part values vary with wall thickness, orientation, and cooling rate. The following are typical values from the supplier technical datasheet, not guaranteed lot-release limits.

    Property Nominal value Test method
    Melt flow rate, 190 °C/5.0 kg 0.30 g/10 min ASTM D1238
    Density 0.955 g/cm3 ASTM D1505
    Tensile strength at yield 26 MPa ASTM D638 Type IV
    Elongation at break >500% ASTM D638 Type IV
    Flexural modulus, 1% secant 1200 MPa ASTM D790
    Notched Izod impact strength 8 kJ/m2 ASTM D256
    Environmental stress-crack resistance, Condition B, F50 >600 h ASTM D1693
    Vicat softening point 127 °C ASTM D1525
    Shore D hardness 64 ASTM D2240

    The high-load melt-flow rate of 0.30 g/10 min is not directly comparable to the 2.16 kg condition used for lower-viscosity injection-moulding HDPE. Cross-checking under ISO 1133-1:2022 requires the same 190 °C and 5.0 kg condition. The density of 0.955 g/cm3 contributes to a flexural modulus near 1200 MPa and Shore D hardness at 64, which are above values typical for linear low-density polyethylene but below high-crystallinity HDPE grades exceeding 0.960 g/cm3. The controlling specification for aggressive-fluid packaging is the environmental stress-crack resistance reported at >600 h under ASTM D1693 Condition B, F50. That test applies a notched specimen in a surfactant environment at 50 °C; failure time reflects resistance to slow crack growth from micro-defects. Commodity blow moulding HDPE grades with similar density but lower molecular weight often show stress-crack resistance below 100 h under the same test, resulting in brittle puncture failures after stacked storage.

    The notched Izod impact strength of 8 kJ/m2 is lower than elastomer-modified polyolefins but adequate for rigid container sidewalls and drop impacts. It is important to distinguish this value from blow-moulded container impact performance, which is controlled by wall thickness, pinch-off weakness, and environmental conditioning rather than by small-specimen Izod data alone. No supplier datasheet value is published for polydispersity index, but the high-load melt-flow position and melt-strength behaviour indicate a high average molecular weight with a broad molecular weight distribution required for parison stability.

    Across shuttle-style and accumulator extrusion blow-moulding lines, the resin is processed with melt temperatures maintained between 180 °C and 220 °C. Sustained operation above 220 °C lowers molecular weight and produces gel particles in the parison; operation below 180 °C elevates melt viscosity and may generate melt fracture and weak weld lines at the pinch-off. Grooved-feed extruders with L/D ratios of 24:1 to 30:1 are preferred because the high molecular weight requires positive forward conveying. On a 60 mm grooved-feed machine, screw speed is often limited below 40 rpm to avoid shear heating beyond the melt-temperature limit. Head pressures from 250 bar to 350 bar are reported under typical output conditions, and die-head temperature is held near 190 °C to 210 °C. Blow mould temperatures from 10 °C to 40 °C are used to control surface quality; chilled water at 8 °C to 12 °C is circulated through moulds for faster cycle times, but mould temperatures below 10 °C can produce condensation and surface splay.

    Parison programming is required for containers above 30 L; die gap is profiled from 1.0 mm to 2.5 mm to control wall-thickness distribution. Die swell ratios between 1.2:1 and 1.4:1 are observed on conventional tooling, although published values for every die geometry are limited. For a container with a mould parting-line projected area of 0.30 m2 and an internal blowing pressure of 0.7 MPa, the theoretical minimum mechanical clamp force is 210 kN; actual machines should carry a 20–30% margin for pressure peaks and flash accumulation. Inadequate clamp force or slow mould closing produces flash thickening but reduces pinch-off weld strength, a common production failure mode in high-molecular-weight HDPE containers.

    When Environmental Stress Crack Resistance Controls Container Lifetime for Agrochemical and Fuel-Adjacent Service

    The selection of HA7260 is driven by slow-crack-growth failure mechanisms in rigid containers holding surfactants, esters, emulsifiable agricultural concentrates, and aliphatic hydrocarbons. Under hoop stress from stacked storage and drop impact, stress cracking initiates at micro-defects and propagates through the wall; the measured environmental stress-crack resistance of >600 h under ASTM D1693 Condition B, F50 delays crack propagation compared with lower-molecular-weight HDPE. Containers up to 60 L are blow moulded from HA7260; above that size, parison sag becomes the limiting factor unless accumulator-head machines with programmable hydraulic parison control are used. In multilayer structures with polyamide or ethylene vinyl alcohol barrier layers, HA7260 is used as structural layers because its melt strength allows coextrusion with high-viscosity barrier materials without layer instability. Published data for this specific configuration is limited; layer thickness ratios and adhesion systems must be validated on the target multilayer line.

    Differences from other products are most visible in stress-crack resistance, melt strength, and high-load melt-flow rate. A lower-density HDPE at 0.945 g/cm3 may provide higher stress-crack resistance but lower stiffness; mineral-filled or talc-modified HDPE grades increase modulus but reduce impact and stress-crack resistance. HA7260 is unfilled and balances high environmental stress-crack resistance with a density of 0.955 g/cm3. Compared with HDPE grades intended for injection moulding, its 0.30 g/10 min high-load melt-flow rate and broad molecular weight distribution favour parison formation, not thin-wall cavity filling. Chemical resistance for specific fluids should be evaluated under ASTM D543, because service life in concentrated oxidizing acids or halogenated solvents at elevated temperature may degrade the polymer even when the grade passes standard ESCR screening.

    When incoming resin is stored in silos or octabins at relative humidity above 60%, surface condensation can be absorbed on pellet surfaces. For HDPE, full pre-drying is not generally required because the polymer is not hygroscopic; however, wet pellets delivered to the feed throat may cause steam streaks in the parison and should be prevented by keeping storage sealed and transfer lines dry. If drying is necessary after condensation, a desiccant dryer at 80 °C for 2 h is sufficient. Regrind from clean, unpigmented HA7260 containers can be reintroduced up to 20% by weight in many blow-moulding operations; higher regrind fractions increase gel risk because of cumulative thermal history and should be validated by ASTM D1693 testing of finished containers. Ultraviolet stabilization is not part of the base grade; outdoor exposure without carbon black or hindered-amine light-stabilizer masterbatch leads to embrittlement. Published accelerated weathering data for this specific grade is limited.

    Regulatory, Storage, and Incompatibility Boundaries

    Regulatory compliance claims must be verified against the supplier’s current safety data sheet and product stewardship bulletin. The base grade is typically covered by REACH registration under EC 1907/2006; restricted substances are evaluated under EU 2011/65/EU RoHS Annex II. Food-contact compliance under 21 CFR 177.1520 is not implied for all HA7260 lots unless the supplier issues a specific food-contact certificate for the grade and batch. The resin should not be processed with additives that contain free halogens or strong oxidizers; prolonged contact with concentrated nitric acid or chlorinated solvents at elevated temperatures can cause chain scission and wall embrittlement. Storage at temperatures below 50 °C and away from direct sunlight preserves additive package integrity. If processing at melt temperatures above 220 °C, degradation by-products may include acetaldehyde and carbon monoxide; local exhaust ventilation is required.

    Production-scale sites commonly perform incoming resin checks for melt-flow rate under ASTM D1238, density under ASTM D1505, and environmental stress-crack resistance under ASTM D1693 on each batch. Lot-to-lot variance in ESCR is managed by rejecting lots below 600 h or requalifying container performance through drop testing under ASTM D2463 and customer-specific stack-load protocols. Operational boundaries therefore include a maximum melt-temperature ceiling, moisture control at the feed throat, and batch-level ESCR verification before release to blow-moulding production.

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