| HS Code | 559015 |
| Product Name | Braskem HDPE GM7040G |
| Polymer Type | High Density Polyethylene (HDPE) Copolymer |
| Density | 0.953 g/cm³ |
| Melt Flow Rate | 4.0 g/10 min (190°C/2.16 kg) |
| Tensile Strength At Yield | 26 MPa |
| Tensile Strength At Break | 20 MPa |
| Elongation At Break | >500% |
| Flexural Modulus | 1200 MPa |
| Notched Izod Impact | 80 J/m at 23°C |
| Hardness Shore D | 65 |
| Vicat Softening Temperature | 125°C |
| Heat Deflection Temperature | 70°C at 0.45 MPa |
| Molding Shrinkage | 1.5-2.0% |
| Environmental Stress Crack Resistance | 100 h (F50) |
As an accredited Braskem HDPE GM7040G factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Braskem HDPE GM7040G is typically supplied in 25 kg bags, palletized and stretch-wrapped for secure industrial shipment. |
| Container Loading (20′ FCL) | 20′ FCL loading: Braskem HDPE GM7040G in 25 kg polyethylene bags, palletized, stretch-wrapped, and securely stowed for ocean freight. |
| Shipping | Braskem HDPE GM7040G is a non-hazardous high-density polyethylene resin supplied as solid pellets. It is typically shipped in 25 kg bags, 500–1,000 kg bulk bags/octabins, or bulk trucks/railcars. No UN hazardous classification applies for transport. Store dry, away from heat; keep containers closed. |
| Storage | Store Braskem HDPE GM7040G in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, and strong oxidizers. Keep original bags or octabins sealed, clean, and off the floor on pallets. Avoid moisture, dust, and contamination. Protect from UV radiation and prolonged high temperatures. Maintain ambient temperature and follow first-in, first-out stock rotation. Keep away from food, feed, and drinking water. |
| Shelf Life | Shelf life: Braskem HDPE GM7040G is stable indefinitely when stored cool, dry, and protected from UV light in original packaging. |
Industrial pails and buckets injection moulded from Braskem HDPE GM7040G use the resin at 100 pph as the matrix, with closed-loop regrind from runners and rejected parts added at 10–30 pph; regrind above 30 pph narrows the processing window and reduces notched Izod impact under ASTM D256, so pails intended for dangerous goods service are restricted to 20 pph regrind unless re-qualification is performed. Colour masterbatch is metered at 1–4 pph, and for outdoor storage a UV stabiliser masterbatch is added at 2–5 pph to retain impact strength after 1,000 h of ASTM D2565 xenon-arc exposure. Compliance for industrial pails includes 49 CFR 178.509 design-type testing for Packing Group II and III liquids, ASTM D1693 environmental stress-crack resistance, ASTM D638 tensile yield, and ISO 11469 material marking. Downstream production is injection moulding on a reciprocating-screw machine with L/D 20:1 to 24:1, clamp force from 2,000 kN for 5 L pails to 7,000 kN for 25 L pails, barrel temperatures 190–230 °C, mould temperature 10–30 °C, injection pressure 70–110 MPa, holding pressure 50–80 MPa, and cooling time of 12–20 s for a 2 mm sidewall. Terminal finished products include 1–25 L pails and buckets for paints, lubricants, water-based chemicals, adhesives, and food-grade honey or syrups when produced under a food-contact validation.
| Machine/process parameter | Range | Verification method or standard |
|---|---|---|
| Barrel feed temperature | 190–210 °C | Fixed thermocouple, ISO 9001 calibration |
| Barrel compression temperature | 210–225 °C | Melt pressure sensor 0–20 MPa |
| Barrel metering temperature | 220–230 °C | Melt temperature probe at nozzle |
| Nozzle | 220–230 °C | Nozzle thermocouple |
| Mould temperature | 10–30 °C | Water manifold flow meter |
| Injection pressure | 70–110 MPa | Machine transducer, ISO 9001 |
| Holding pressure | 50–80 MPa | Machine transducer |
| Cooling time | 12–20 s | Cycle timer |
In injection moulding of food storage containers, the main processing concern is gate freeze at thin-wall edges because it controls pack pressure and sink mark formation. GM7040G is used at 100 pph virgin material; in-house regrind is allowed at 0–20 pph only when generated from the same food-compliant article and segregated to prevent cross-contact with non-food colourants. White or pastel masterbatch is dosed at 1–3 pph, and no slip agent is added unless the specific additive is listed in EU 10/2011; when a demoulding aid is required, a food-grade polyolefin wax is limited to 0.2 pph. Compliance for food storage containers rests on FDA 21 CFR 177.1520(c), EU 10/2011 overall migration below 10 mg/dm², and EC 1935/2004 good manufacturing practice. The production process is cold-runner injection moulding with a multi-cavity tool, barrel temperature 190–220 °C, mould temperature 15–30 °C, injection speed 50–80 mm/s, and holding pressure 60–80 MPa; gates are sized at 0.8–1.2 mm depth to ensure pack and minimise gate blush on high-gloss surfaces. Terminal finished products include 200 mL–5 L food storage boxes, kitchen canisters, cereal containers, and refrigerator organisation trays.
For injection moulded caps and closures, GM7040G is formulated at 100 pph with regrind limited to 10–20 pph because closures have thin tamper-evident hinge sections and thread geometries that are sensitive to molecular-weight reduction from repeated shearing. Slip masterbatch is added at 0.5–1.0 pph to control unscrewing torque on bottled water and juice closures; colour masterbatch is added at 1–3 pph with a heat-stable organic pigment package. The applicable compliance frame includes FDA 21 CFR 177.1520(c) for food-contact closures, EU 10/2011 for migration, ASTM D638 tensile yield for thread integrity, and ASTM D256 notched Izod for drop resistance at 0 °C. Downstream production uses high-speed injection moulding machines with L/D 20:1 to 24:1, hot-runner multi-cavity tools with 24–96 cavities, barrel temperatures 190–230 °C, mould temperature 10–20 °C, injection pressure 80–120 MPa, and cycle times of 5–8 s for standard 28 mm beverage closures. Terminal finished products include 28 mm and 38 mm mineral water and juice closures, tamper-evident caps for dairy bottles, and push-pull sport caps.
Because crates, totes, and waste containers are used in outdoor and rough handling conditions, the regrind fraction is the most critical formulation variable. The base formulation is 100 pph virgin GM7040G with clean in-house regrind added up to 40 pph; above 40 pph, the melt viscosity decreases from repeated shear history and the notched Izod impact under ASTM D256 can fall below 4.0 kJ/m², requiring either a lower regrind setting or an impact modifier addition limited to 2–5 pph of polyolefin elastomer. UV stabiliser masterbatch is added at 2–5 pph for outdoor waste bins; carbon black is specified at 2.0–2.5 wt% to meet ASTM D2565 weatherability after 2,000 h xenon-arc exposure. Compliance is primarily mechanical and marking-based: ASTM D638 tensile yield, ASTM D790 flexural modulus, ASTM D256 impact resistance, ISO 11469 material identification, and REACH Annex XVII substance restrictions. Downstream production is injection moulding on machines with clamp force 3,000–8,000 kN, L/D 20:1 to 24:1, barrel temperatures 200–240 °C, mould temperature 15–30 °C, injection pressure 80–110 MPa, holding pressure 60–80 MPa, and cooling time 15–25 s for wall thicknesses of 2–3 mm. Terminal finished products include stackable beer and dairy crates, agricultural harvest totes, refuse bins from 30–120 L, and industrial material-handling trays.
| Qualification parameter | Threshold / condition | Standard |
|---|---|---|
| Tensile yield stress | ≥28 MPa | ASTM D638 |
| Flexural modulus | ≥1,200 MPa | ASTM D790 |
| Notched Izod impact | ≥4.0 kJ/m² | ASTM D256 |
| ESCR | >500 h at 50 °C, 100% Igepal | ASTM D1693 |
| UV weatherability | 2,000 h xenon-arc, ΔE ≤3 | ASTM D2565 |
For housewares, storage boxes, and toy components, GM7040G is formulated at 100 pph with regrind from the same product family limited to 10–25 pph; toy parts subject to EN 71-1 mechanical testing use 0 pph regrind unless the recycled fraction is traceable to the same moulding line. Colour masterbatch is added at 1–4 pph, and for translucent storage boxes a clarified polyolefin-compatible masterbatch is limited to 0.5–2 pph; no antistatic agent is used in toy components unless it meets REACH Annex XVII. Compliance for this segment is split between food-contact kitchenware and toy safety: food-contact storage items are tested under FDA 21 CFR 177.1520(c) and EU 10/2011, while toy parts are tested under EN 71-1, EN 71-3 for migration of elements, and REACH. The downstream process is cold-runner injection moulding with multi-cavity tools, barrel temperatures 190–230 °C, mould temperature 15–30 °C, injection pressure 70–100 MPa, holding pressure 50–70 MPa, and cycle time 15–25 s for wall thicknesses of 1.5–2.5 mm. Terminal finished products include 2–50 L storage boxes, toy building blocks, play trays, kitchen drawer organisers, and stackable household bins.
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Braskem HDPE GM7040G is a high-molecular-weight, bimodal high-density polyethylene extrusion blow molding resin specified for large-part industrial packaging, chemical containers, and barrier-treated fuel tank shells. The nominal melt flow rate is 0.40 g/10 min at 190°C under 2.16 kg load when tested according to ASTM D1238-20 or ISO 1133-1:2022; nominal density is 0.954 g/cm³ measured under ASTM D1505-18 or ISO 1183-1:2019. These indices place the resin in the low-flow blow molding class rather than high-flow injection molding. Published tensile data under ASTM D638-14 at 50 mm/min indicate a yield stress near 29 MPa and elongation at break greater than 600%, while flexural modulus is approximately 1,400 MPa under ASTM D790-17. Slow crack growth resistance, measured as F50 under ASTM D1693-21 Condition B in 100% Igepal CO-630, typically exceeds 1,000 h. Notched Izod impact at 23°C is approximately 30 kJ/m² under ISO 180:2019. The high stress crack resistance and high melt strength are the main classification features separating the grade from unimodal high-density polyethylene blow molding resins of comparable density.
Compared with high-flow HDPE injection molding grades having melt flow rates above 7 g/10 min, GM7040G is not suitable for thin-wall injection molding because the higher viscosity reduces flow length and increases clamp force requirements. Compared with lower density blow molding HDPE grades below 0.945 g/cm³, GM7040G provides greater stiffness but lower resistance to freezing-temperature impact; parts exposed to temperatures below -20°C require additional validation. The grade’s differentiating feature is not melt index alone but the bimodal molecular weight distribution, which allows stiffness, stress crack resistance, and melt strength to be retained without the processing penalty typically associated with very high molecular weight unimodal resins.
The simultaneous improvement of processability and environmental stress crack resistance arises from the separation of chain-length fractions. Low-molecular-weight chains reduce viscosity at extrusion shear rates, permitting surface finish and output; high-molecular-weight chains increase melt elasticity and tie-chain concentration in the semicrystalline structure. In slow crack growth, failure proceeds by disentanglement of tie chains linking lamellae. A high tie-chain fraction increases the time required for crack propagation through detergents, alcohols, and other polar stress-cracking agents. The broad distribution is indicated by the ratio between high-load melt flow rate and standard melt flow rate, approximately 35:1 under ASTM D1238-20, which is typical of bimodal blow molding grades.
At the low deformation rates associated with parison sag following die exit, the high-molecular-weight fraction contributes elevated zero-shear viscosity and extensional viscosity. In continuous shuttle blow molding on 80 mm to 120 mm extruders with 24:1 to 30:1 L/D barrier screws, the melt temperature at the die is normally maintained between 190°C and 220°C. At die temperatures below 180°C, surface melt fracture may appear as sharkskin; above 220°C, parison sag increases because zero-shear viscosity falls, and prolonged residence above 230°C can initiate molecular weight reduction. The practical operating window for wall-thickness control is therefore part-specific on large tools, often requiring active adjustment of die gap and melt temperature within ±10°C around the selected set point.
| Property | Test method | Typical value |
|---|---|---|
| Melt flow rate, 190°C/2.16 kg | ASTM D1238-20 | 0.40 g/10 min |
| High-load melt flow rate, 190°C/21.6 kg | ASTM D1238-20 | 14 g/10 min |
| Density | ASTM D1505-18 | 0.954 g/cm³ |
| Tensile yield stress, 50 mm/min | ASTM D638-14 | 29 MPa |
| Elongation at break | ASTM D638-14 | >600% |
| Flexural modulus | ASTM D790-17 | 1,400 MPa |
| Environmental stress crack resistance, F50 | ASTM D1693-21 Condition B, 100% Igepal CO-630 | >1,000 h |
| Vicat softening temperature | ASTM D1525-17e1 | 128°C |
| Hardness, Shore D | ASTM D2240-15e1 | 66 |
Process setup on accumulator-head machines requires attention to accumulator fill time, shot weight, and melt residence time. When the shot weight exceeds 70% of accumulator capacity, the melt history becomes less stable and the parison may show local temperature differences that affect wall distribution. Mold cooling water temperature is typically held between 10°C and 30°C; lower temperatures shorten cycle time but may reduce surface gloss and increase frozen-in stress near the pinch-off. Blow pressure is normally set from 0.6 MPa to 1.0 MPa, depending on wall thickness and mold venting. Clean post-industrial regrind can be incorporated up to 30 wt% if it is free of metal, paper, and crosslinked gel particles from degraded resin; higher regrind levels may reduce ESCR because oxidative chain scission lowers the high-molecular-weight fraction.
If color concentrate is used, the carrier resin should be HDPE or LLDPE. LDPE-carrier masterbatches at letdown ratios above 3 wt% tend to dilute the high-molecular-weight fraction and can lower ESCR and melt strength. Gravimetric dosing at the feed throat with a mixing section in the screw is sufficient for uniform color at 1 wt% to 3 wt% letdown; published data for higher letdown of filled masterbatches in GM7040G is limited.
Large containers and technical parts are generally produced on accumulator-head machines rather than continuous shuttle machines when the shot weight is too high to be extruded continuously without excessive parison sag. The accumulator-head process separates plasticating capacity from parison ejection: a screw plasticates melt into a chamber, and a plunger rapidly ejects the parison through a die ring. This reduces the time the parison hangs under its own weight and partly compensates for the low