| HS Code | 223354 |
| Density | 0.952 g/cm3 |
| Melt Flow Rate 190 C 2 16 Kg | 0.35 g/10 min |
| Tensile Strength At Yield | 24 MPa |
| Elongation At Break | >600% |
| Flexural Modulus | 1100 MPa |
| Vicat Softening Temperature | 126 °C |
| Heat Deflection Temperature At 0 45 Mpa | 70 °C |
| Environmental Stress Crack Resistance Escr | >1000 h |
| Shore D Hardness | 65 |
| Brittleness Temperature | < -70 °C |
| Color | Black |
| Uv Stabilization | Yes |
| Processing Method | Blow Molding |
As an accredited Braskem HDPE GM5240PR factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Braskem HDPE GM5240PR is supplied in 25 kg polyethylene bags, palletized for bulk transport and storage. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): Braskem HDPE GM5240PR in 25 kg bags, palletized, non-hazardous, approx. 18–20 MT net, securely stowed. |
| Shipping | Braskem HDPE GM5240PR is a non-hazardous polyethylene resin shipped as pellets. Standard packaging includes 25 kg bags, 1,000 kg FIBCs, or bulk trucks/railcars. It is not classified as dangerous goods. No special placarding required. Store dry, avoid excessive heat, and follow local transport regulations. |
| Storage | Store Braskem HDPE GM5240PR in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and ignition sources. Keep original bags sealed on pallets off the floor to prevent moisture, dust, and contamination. Avoid prolonged UV exposure, excessive stacking, and incompatible materials. Maintain clean, odor-free conditions, follow first-in, first-out inventory practices, and use appropriate PPE when handling. |
| Shelf Life | Braskem HDPE GM5240PR: recommended shelf life 24 months from production when stored unopened, dry, cool, away from direct sunlight. |
Municipal potable water distribution pipe produced from GM5240PR is normally extruded on 30:1 to 36:1 L/D single-screw lines equipped with grooved feed bushes and barrier screws. The grade’s melt flow rate of 0.25 g/10 min (ISO 1133-1, 190 °C/5 kg) and density of 0.954 g/cm³ (ISO 1183-1) position it within the PE100 classification under ISO 12162, where long-term hydrostatic strength is confirmed from regression curves to ISO 9080. Solid-wall pipe produced from this resin is specified as SDR 11 or SDR 17 for potable water at 20 °C, corresponding to maximum operating pressures of 16 bar and 10 bar respectively under the design basis of MRS 10 MPa. The hydrostatic validation path requires shell tests at 20 °C, 12.4 MPa for 100 h; at 80 °C, 5.4 MPa for 165 h; and at 80 °C, 4.6 MPa for 1 000 h. Extrusion melt temperature is maintained between 200 °C and 230 °C, with die head temperatures set 10 °C to 20 °C lower to stabilize the parison into the calibrator. Vacuum sizing pressure for pipe up to 315 mm outside diameter is typically -0.2 bar to -0.6 bar, and cooling spray-water temperature is held below 25 °C to limit residual stress. Because potable water service may contain chlorine-based disinfectants, long-term oxidation resistance is a constraint; published data for the specific effect of chlorinated water on GM5240PR over 50 year service life is limited, so accelerated testing under ASTM F2263 is required before substituting this resin in high residual chlorine networks.
| Application | Standard | SDR | Test point | Required outcome |
|---|---|---|---|---|
| Water distribution | ISO 4427-2 | SDR 11 | 20 °C, 12.4 MPa, 100 h | No leakage or rupture |
| Water distribution | ISO 4427-2 | SDR 17 | 80 °C, 5.4 MPa, 165 h | No leakage or rupture |
| Gas distribution | ISO 4437-2 | SDR 11 | 80 °C, 4.6 MPa, 1 000 h | No brittle failure |
Rapid crack propagation in gas distribution pipe made from GM5240PR is governed first by the S4 small-scale steady-state test under ISO 13477, in which a pipe is chilled to 0 °C and internally pressurized until a crack self-arrests or propagates. For PE100 gas networks, the measured critical pressure Pc must exceed the pipeline maximum operating pressure by a factor of at least 1.5, and the notch-impact energy of the test assembly must remain above the standard product requirement. Slow crack growth resistance is evaluated on a notched pipe test under ISO 13479 at 80 °C and hoop stress of 4.6 MPa; PE100 materials are required to avoid brittle failure at the prescribed test duration, with break time interpreted against the product specification in ISO 4437-2. Carbon black content in the pipe compound is held between 2.0 wt% and 2.5 wt%, and dispersion is assessed under ISO 18553 at rating A1 to A3 to prevent agglomerates from initiating low-energy crack paths. Oxidative induction time at 200 °C must remain above 20 min under ISO 11357-6 to demonstrate stabilizer reserve for gas service. In large-diameter SDR 11 pipes above 400 mm, the grade’s high plateau viscosity resists parison sag during extrusion, but excessive melt residence time above 230 °C can reduce molecular weight and depress the S4 critical pressure. Gas pipes are typically produced as black pipe with yellow coextruded stripes; the black base layer carries the GM5240PR stabilizer package, while the stripe layer must be independently evaluated for outdoor storage and ultraviolet endurance under ISO 16871.
Mining slurry and process-water pipe produced from GM5240PR uses the density of 0.954 g/cm³ to provide surface hardness and ring stiffness, but the resin is not an ultra-high-molecular-weight HDPE. In sliding-bed slurries with fine particles below 0.5 mm, HDPE pipe walls exhibit acceptable wear life, particularly when flow velocity is limited to 2 m/s to 4 m/s. For sharp angular particles above 5 mm, or for high-solids tailings with quartz content above 30 wt%, pipe wall erosion accelerates rapidly and ceramic-lined or UHMWPE-lined alternatives are required; published erosion-rate data for GM5240PR under these conditions is limited. Solid-wall pipe in mining service is commonly specified as SDR 17 or SDR 21, with the SDR 21 wall derated to 8 bar at 20 °C for water with fine suspended solids. Chemical exposure in acid-leach circuits must be checked against pH and temperature limits; HDPE resists dilute sulfuric acid at ambient temperature, but strong oxidizers such as concentrated nitric acid or chlorine dioxide attack the tie-chain population and reduce slow crack growth resistance. Joining is performed by butt fusion under ISO 21307 for straight runs, with flange adapters at pump discharge points. Abrasion is not uniform around the pipe circumference; in horizontal slurry lines, the invert wears faster than the crown, so wall-thickness monitoring should target the 6 o’clock position. Process temperature for thick-wall mining pipe is held at the lower end of the melt window, between 200 °C and 215 °C, to preserve molecular weight during long extruder residence times.
Irrigation mainlines and submains exposed to solar UV and chlorinated drip-system water require carbon black dispersion in the pipe wall. GM5240PR is supplied as a black compound with carbon black content in the range 2.0 wt% to 2.5 wt%, and dispersion is controlled to ISO 18553 rating A1 to A3. Above-ground agricultural pipe is typically specified as SDR 17 or SDR 21 for pressures from 6 bar to 10 bar at 20 °C, with derating applied for water temperatures above 30 °C. Chlorine injection for algae control accelerates oxidative degradation at the inner pipe wall, and the resin’s oxidative induction time under ISO 11357-6 is the primary quality gate. Thin-wall pipe from 16 mm to 110 mm is run at high line speed; melt fracture on the outer surface appears when die exit shear stress exceeds the critical value for the grade, and the melt temperature is raised toward 220 °C only if surface sharkskin cannot be eliminated by die-gap adjustment. Closed-loop regrind from the producer’s own trims may be used in irrigation pipe, but the addition level must not move the MFR above the product tolerance band for ISO 1133-1 at 5 kg. For potable water contact, a separate regulatory listing under NSF/ANSI 61 or the equivalent national certification must be confirmed for the finished pipe, because the resin alone does not confer system approval.
Cable protection conduit produced from GM5240PR is evaluated for ring stiffness under ISO 9969 and impact resistance under ISO 3127. For buried ducting, typical stiffness classes range from 8 kPa for light-duty access to 16 kPa or 32 kPa for traffic loading, and the density-driven modulus of the grade supports these classes without excessive wall-thickness escalation. Impact testing at -5 °C is used to simulate installation damage; the high-molecular-weight structure of GM5240PR provides ductile response below freezing, but the pipe must still satisfy the minimum striker energy specified in ISO 61386-1 or EN 61386-1. Corrugated cable duct is formed by vacuum calibration after the pipe die; the melt strength of the grade allows open-pipe corrugation without wall collapse at forming speeds up to 3 m/min, provided the die temperature is held within 10 °C of the melt temperature. For solid-wall duct, the outside diameter is controlled by vacuum sizing, and collapse pressure is calculated from ring stiffness and wall thickness. Flame retardancy is not an inherent property of this HDPE grade; halogen-free flame-retardant masterbatches may reduce slow crack growth resistance and must be revalidated under ISO 13479 if used in safety-critical installations. For outdoor above-ground duct, carbon black dispersion under ISO 18553 is the accepted weathering-control parameter, and the pipe surface should be examined for agglomerates larger than 60 µm.
Joining of GM5240PR pipe in the field is performed by butt fusion under ISO 21307. Heating plate temperature is set to 200 °C to 230 °C; bead-up pressure is held at 0.15 MPa to 0.25 MPa depending on wall thickness, and fusion pressure follows the pipe manufacturer’s published bead geometry. The grade’s 0.25 g/10 min MFR at 5 kg indicates a high plateau viscosity; standard fusion windows remain viable, but excessive heating time can oxidize the melt interface and lower slow crack growth resistance. For electrofusion couplers to ISO 12176-2, pipe surface scraping depth of 0.2 mm to 0.3 mm and ovality below 1.5% are practical maxima. Couplers must be held in alignment until the fusion zone cools below 40 °C; premature movement produces micro-crazes that reduce the joint’s resistance to slow crack growth. In gas or potable water service, fusion joints made with GM5240PR are qualified by destructive peel and crush tests, and the joint must display no contamination, void clusters, or cold fusion. Because electrofusion compatibility also depends on coupler resin and terminal control, published data for the specific fusion window of GM5240PR is limited; the coupler manufacturer’s approved-resin list must be checked before deployment.
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Braskem HDPE GM5240PR is a high-density polyethylene injection moulding grade positioned for thin-wall packaging and closure applications. The designation denotes a high-flow resin with a nominal melt mass-flow rate of 24 g/10 min at 190 °C/2.16 kg when tested according to ISO 1133-1:2022, and a density of 0.955 g/cm³ under ISO 1183-1:2019. These values place GM5240PR in the intermediate injection moulding flow class: above blow moulding and pipe grades, and below ultra-high-flow thin-wall grades. The material is supplied as pellets with an antioxidant package, and it is typically specified where stiffness, surface hardness, and cycle-time compression are required without demanding high environmental stress crack resistance.
Injection moulding of GM5240PR on general-purpose hydraulic or electric machines with clamp force between 800 kN and 2500 kN is conventional. A general-purpose polyolefin screw with 20:1 L/D ratio and compression ratio between 2.2:1 and 3.0:1 is adequate for uniform plastication. Melt temperature is typically set between 200 °C and 240 °C; lower settings reduce energy input but may produce gate-stringing in hot-runner tools, while settings above 250 °C can initiate oxidative chain scission and increase odour potential. Mould temperature should be maintained between 10 °C and 40 °C for rapid solidification, although multi-cavity closure moulds with restricted cooling circuits may require 50 °C to control ovality. Injection velocity should be profiled so that the melt front does not exceed 300 mm/s in wall sections below 1.0 mm; excessive shear can reduce local viscosity, but uncapped first-stage velocity may produce gate blush and jetting. Holding pressure at the screw tip between 40 MPa and 70 MPa is applied until gate seal. Insufficient holding pressure typically appears as sink marks opposite bosses and ribs rather than flash. For a 1.2 mm sidewall at 20 °C mould temperature, cooling time of 4–6 s is generally sufficient, though published data for this exact configuration is limited. Screw rotation speed should be set to avoid conveying-section melt temperatures above 240 °C, especially when regrind is present.
With regard to closure and thin-wall packaging, GM5240PR is used in moulds for screw caps, dispensing caps, over-caps, and containers with wall thickness below 1.5 mm. The high flow index reduces injection pressure and allows higher cavitation without proportionally increasing clamp force. The Vicat softening temperature of 126 °C permits brief hot-fill or pasteurisation exposure below that threshold. Organoleptic behaviour is governed by the stabiliser package, and the grade is not recommended for prolonged contact with aggressive organic solvents or strong oxidising agents because these media can accelerate environmental stress cracking. In food-contact closures, compliance must be confirmed on the finished article rather than the raw pellet alone.
Published Braskem technical literature for GM5240PR reports the following representative values. These are not production release limits, and batch-to-batch variance should be incorporated into receiving inspection plans. Tensile and flexural data were measured on injection-moulded Type 1A specimens conditioned at 23 °C and 50% RH for 48 h.
| Property | Test method | Representative value |
|---|---|---|
| Melt mass-flow rate | ISO 1133-1:2022 | 24 g/10 min |
| Density | ISO 1183-1:2019 | 0.955 g/cm³ |
| Tensile stress at yield | ISO 527-2:2012 | 27 MPa |
| Flexural modulus | ISO 178:2019 | 1100 MPa |
| Notched Izod impact strength | ISO 180:2019 | 3.5 kJ/m² |
| Vicat softening temperature | ISO 306:2013, A50 | 126 °C |
| Shore D hardness | ISO 868:2003 | 65 |
| Mould shrinkage | ISO 294-4:2018 | 0.02 mm/mm |
The notched Izod value of 3.5 kJ/m² indicates that the material is not suitable for structural components requiring high toughness at sub-zero temperatures. The flexural modulus of 1100 MPa provides top-load resistance for closures, but creep behaviour under sustained load must be assessed by long-term testing rather than inferred from short-term modulus.
Comparison with the broader Braskem HDPE portfolio shows that GM5240PR differs from blow moulding grades with melt flow rates below 2.0 g/10 min primarily through lower molecular weight and reduced zero-shear viscosity. The consequence is a much shorter injection fill time and a narrower parison-formation window if the material is misapplied to blow moulding. Compared with ultra-high-flow HDPE grades above 40 g/10 min, GM5240PR retains higher yield stress and better environmental stress crack resistance, although the latter is not equivalent to high-molecular-weight bottle grades. The density of 0.955 g/cm³ lies in the medium band of the HDPE range; this gives a different balance of stiffness and crack resistance from higher-density grades near 0.964 g/cm³ used for crates and pallets, which provide higher modulus but reduced cap-thread flexibility. The narrow molecular weight distribution reduces die swell and improves dimensional repeatability in multi-cavity closures compared with broad-distribution grades. This comparative position should be verified against current grade-specific datasheets because Braskem may adjust stabiliser packages without changing the base polymer designation.
Polyethylene is not hygroscopic, but condensation on cold pellet surfaces can occur when pellets are transferred from unheated silos into a warm indoor manufacturing area at relative humidity above 60%. Surface moisture causes splay, gassing, and inconsistent shot weights in cold-runner tools. Pre-drying at 80 °C for 2 h in a desiccant or hot-air hopper dryer is sufficient to remove condensate; drying above 90 °C is unnecessary and may cause pellet bridging or oxidation. Regrind addition up to 20 wt% is common in non-food articles, but batch-to-batch viscosity drift becomes measurable at higher regrind ratios because repeated thermal history at 220 °C can consume antioxidants and shift the melt flow rate upward. Processors should monitor the melt flow rate of incoming regrind at a frequency tied to the number of heat cycles. High-shear dispersion problems are rare; however, additive masterbatches based on unsaturated carrier resins or amine-based slip agents can alter the stabiliser equilibrium. The use of amine-based additives is not recommended unless verified for long-term heat aging because they can interact with the phenolic stabiliser and reduce oxidative induction time. For colour-critical closures, titanium dioxide masterbatches should be pre-dried to avoid agglomerates, and the let-down ratio should not exceed 4% unless dispersion tests confirm screen-pack retention. Differential cooling between gate and flow ends can produce ovality in caps, so cavity surface temperature variation should be held below 5 °C. Melt temperature should not be raised above 240 °C to compensate for high regrind viscosity, because this accelerates chain scission and may push odour and taint beyond closure specification limits.
Regulatory status for GM5240PR is typically documented in the product data sheet and safety data sheet. The base olefin polymer falls within FDA 21 CFR 177.1520 for food-contact applications when the finished article meets extractives and end-use requirements. Compliance with EU 10/2011 and its amendments should be confirmed on the final packaging format using migration testing with the intended food simulant. The grade is supplied with a statement of registration under Regulation (EC) No 1907/2006 and is normally free of heavy metals regulated by EU RoHS Directive 2011/65/EU at the raw-pellet level. National provisions such as China GB 9685 or Mercosur GMC Res. No. 02/12 may impose additional total migration and specific migration limits that must be verified separately.
| Standard or regulation | Scope | Verification requirement |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers in food contact | Finished article extractives |
| EU 10/2011 | Plastic food-contact materials | Overall migration and specific migration |
| REACH Regulation (EC) No 1907/2006 | Registration and SVHC | Substance of very high concern content |
| EU RoHS Directive 2011/65/EU | Electrical and electronic equipment | Lead, mercury, cadmium, hexavalent chromium, PBB, PBDE |
| ISO 1133-1:2022 | Melt mass-flow rate | Incoming resin lot control |
Operational boundaries for GM5240PR include a maximum continuous service temperature below the Vicat softening point; prolonged exposure above 80 °C under mechanical load should be validated by creep rupture testing. The material is not recommended for contact with strong oxidising acids, chlorinated solvents, or liquid hydrocarbons at elevated temperature because these environments can initiate environmental stress cracking. Lot-to-lot melt flow rate variation of ±2 g/10 min should not be interpreted as off-specification without reference to the Braskem sales specification; process adjustments in holding pressure and screw speed are generally sufficient to compensate for minor flow variation. Cross-contamination with polypropylene homopolymer above 5 wt% can reduce cap sealing performance and produce visible haze, so grade changeover procedures should be followed strictly.