| HS Code | 802795 |
| Material Type | High Density Polyethylene (HDPE) |
| Grade | ME0433 |
| Color | Black |
| Density | 958 kg/m³ |
| Melt Flow Rate 190 C 5 Kg | 0.25 g/10 min |
| Tensile Modulus | 1100 MPa |
| Yield Stress | 25 MPa |
| Elongation At Break | >600% |
| Charpy Notched Impact Strength 23 C | 20 kJ/m² |
| Shore D Hardness | 64 |
| Vicat Softening Temperature | 125°C |
| Thermal Conductivity | 0.4 W/mK |
| Carbon Black Content | 2.5% |
| Oxidation Induction Time 200 C | >20 min |
| Pe Classification | PE 100 |
As an accredited Borealis HDPE ME0433 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Borealis HDPE ME0433 packaging: 25 kg moisture-resistant polyethylene bags, typically palletized, stretch-wrapped, labeled, and suitable for industrial handling and transport. |
| Container Loading (20′ FCL) | Borealis HDPE ME0433, non-hazardous polyethylene, 25 kg bags palletized, evenly loaded and secured in a 20′ FCL container. |
| Shipping | Borealis HDPE ME0433 is shipped as non-hazardous polyethylene pellets, typically in 25 kg PE bags on stretch-wrapped pallets. Transport in clean, dry trucks or containers, protected from moisture, direct sunlight, heat, and contamination. No dangerous goods labeling is required; follow normal industrial handling and storage practices. |
| Storage | Borealis HDPE ME0433 should be stored in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, and strong oxidizing agents. Keep original packaging sealed, palletized, and off the floor. Avoid moisture, UV exposure, and contamination. Maintain good housekeeping and prevent dust accumulation. Follow supplier SDS and local regulations. Do not store near food, beverages, or incompatible materials. |
| Shelf Life | Borealis HDPE ME0433 has a two-year shelf life when stored unopened in original packaging, dry, below 30°C, and protected from sunlight. |
Within liquid packaging board coating halls running at 350–600 m/min, Borealis ME0433 is melt-extruded through a flat die at die-lip temperatures between 285 °C and 315 °C onto corona-treated paperboard of 230–350 g/m² basis weight. The grade’s nominal melt flow rate of 7.5 g/10 min under ISO 1133-1:2022 and density of 945 kg/m³ under ISO 1183-1:2019 locate it in the high-speed extrusion coating window where melt curtain stability, draw-down, and neck-in behaviour are the primary yield constraints. The bimodal molar mass distribution reported for the Borstar production route contributes high melt strength relative to unimodal HDPE extrusion coating grades, which permits lower coating thickness without excessive edge instability. In carton stock, a three-layer construction commonly uses an outer ME0433 layer at 10–18 g/m², a paperboard core, and an inner LDPE sealing layer at 15–25 g/m²; the HDPE outer layer supplies moisture resistance, while the LDPE inner layer supplies heat-seal performance. The air gap is maintained at 200–280 mm and the chill roll at 10–20 °C to quench the melt before excessive fibre penetration or pinholing develops on the board surface. Food-contact status is derived from FDA 21 CFR 177.1520(c) 2.1, covering high-density olefin polymers with density ≥ 0.94 g/cm³, and from EU Regulation (EU) No 10/2011 as amended, with overall migration below 10 mg/dm² under EN 1186-1:2002 contact conditions. The upper thermal boundary is 325 °C; sustained operation above this point accelerates oxidation and produces gel specks that print as surface defects. The lower boundary is 280 °C; below this point coating weight variation increases on clay-coated board and adhesion to the paper surface drops. An internal deckle die, such as Cloeren EBR or Nordson EDI units with die gaps of 0.7–0.9 mm, permits edge bead adjustment while the line is running. Single-flight extruders with L/D 30:1 to 33:1 are operated with barrel profiles from 180 °C at the feed throat to 300 °C at the metering section, with adapter and die held at 300–315 °C. The resulting board is converted into aseptic and non-aseptic liquid packaging cartons for milk, juice, dairy alternatives, and dry beverage powders, where the HDPE layer resists moisture ingress, reduces product interaction, and maintains fibre-tear adhesion on die-cutting and creasing units.
| Regulation / Standard | Test method or condition | Acceptance basis for liquid board |
|---|---|---|
| FDA 21 CFR 177.1520(c) 2.1 | Olefin polymer identity, density ≥ 0.94 g/cm³ | Grade density 945 kg/m³ |
| EU Regulation (EU) No 10/2011 | EN 1186-1:2002 overall migration | OML < 10 mg/dm² |
| ISO 1133-1:2022 | 190 °C, 2.16 kg | MFR 7.5 g/10 min nominal |
| ISO 1183-1:2019 | Method A, 23 °C | Density 945 kg/m³ |
| ISO 15106-1:2018 | 23 °C, 85% RH | Coating-weight-dependent; grade-specific published data limited |
Seal initiation temperature is the principal process boundary in unmodified ME0433 coatings on cupstock and folding carton board at 12–20 g/m². HDPE alone displays a higher seal initiation temperature than LDPE, so converting lines either blend 10–20 wt% LDPE into the extruder or coextrude a thin LDPE seal skin to move the seal initiation range to 115–125 °C and widen the hot-tack window. The HDPE component contributes bending stiffness, moisture resistance, and score-crack resistance in plates, trays, and cupstock outer surfaces. For paper and paperboard in contact with aqueous and fatty foods, the U.S. clearance is 21 CFR 176.170, while the polyethylene coating separately meets 21 CFR 177.1520(c) 2.1. Under EU Regulation (EU) No 10/2011, overall migration is evaluated with simulant A for aqueous foods and simulant D2 for fatty foods using EN 1186-1:2002 contact conditions appropriate to the intended use temperature. Bending stiffness after coating is measured by ISO 2493-1:2010; raising HDPE coat weight from 12 g/m² to 20 g/m² increases stiffness but can induce curl when one-side coating is used, requiring a reverse-side curl control layer or moisture balancing. On production lines, adhesion to clay-coated paperboard is achieved by corona treating the web to 38–42 mN/m immediately before coating, with surface energy verified by ASTM D2578-23. The lower chill roll boundary is 10 °C; colder surfaces freeze the melt before sufficient fibre penetration and cause delamination at die-cut creases. If an HDPE-only layer is used as the food-contact surface, organoleptic panel testing under EN 1230-1:2009 is required for each new package line qualification. Terminal products include die-cut trays, plates, cupstock, and folded cartons for dry and moist snack packaging.
When ME0433 is used as the outer web or extrusion lamination layer over 9 µm aluminium foil in aseptic and barrier laminates, the process conflict is between adhesion to the metal surface and neck-in control. The melt is extruded through a flat die with a die gap of 0.7–0.8 mm and an air gap of 150–250 mm; the foil is preheated to 40–60 °C to reduce pinholing and differential thermal contraction. To achieve cohesive peel, the foil surface is corona-treated to 40–44 mN/m under ASTM D2578-23, and the melt curtain surface is oxidatively modified by ozone. T-peel bond strengths greater than 2.0 N/15 mm are typical specification points under internal test procedures aligned with ISO 8510-2:2006, although published data for this specific configuration is limited. Coating weight ranges from 12 g/m² to 25 g/m²; at the upper bound, the HDPE layer raises puncture resistance of the finished laminate. Moisture barrier of HDPE-coated foil laminates is evaluated by ISO 15106-1:2018 at 23 °C and 85% RH; the aluminium layer dominates oxygen barrier, while the HDPE layer contributes water resistance and mechanical protection. Neck-in on production lines without edge encapsulation typically runs 25–45 mm per side, which reduces useful web width; an internal deckle die permits width adjustment during production. At line speeds above 400 m/min, unmodified HDPE can exhibit edge weave and melt curtain sag; adding 5–10 wt% LDPE reduces draw resonance but sacrifices a portion of the moisture barrier. If foil is stored at RH > 60%, adsorbed moisture must be removed before coating to avoid blister formation. The terminal laminates are aseptic pillow packs, tube stock, and barrier sachets for powdered nutritional formulations and desiccant-packaging applications.
Processing parameters shift when ME0433 is applied to woven polypropylene tape fabric at coating weights between 15 g/m² and 30 g/m². Unlike paperboard, oriented polypropylene tape has low surface energy and needs corona treatment to 42–44 mN/m immediately before coating, measured by ASTM D2578-23. Even after corona treatment, unmodified HDPE does not form fibre-tear adhesion to PP, so a maleic anhydride-grafted PE tie layer at 3–5 g/m² is coextruded, or the fabric is primed with an adhesion promoter of the type used for woven sack lamination. Melt temperature at the die is held at 290–310 °C, nip roll pressure is set to 3–5 bar, and line speed is limited to 150–300 m/min by web tension and heat shrinkage of the PP tape. The HDPE layer provides moisture resistance in cement, fertiliser, pet food, and mineral bulk bags; the terminal product is a laminated flexible intermediate bulk container or valve sack. Under REACH, industrial packaging requires no food-contact clearance, but residual monomers and oligomers are managed through the safety data sheet and workplace exposure limits for extrusion fumes. The critical process boundary is rapid quenching: if the chill roll is maintained below 15 °C, curl and tunnel delamination occur at the fabric-coating interface.
HDPE-coated medical paper for pouch and reel stock is assessed for material transfer and seal continuity under ISO 11607-1:2019. ME0433 is applied at 10–18 g/m² to bleached kraft paper of 60–90 g/m² to produce a fibre-free sealant surface. Gamma irradiation at 25 kGy causes comparatively low oxidative embrittlement in HDPE; above 40 kGy, colour shift and a measurable reduction in elongation at break may occur, so the coating is not normally specified for high-dose terminal sterilisation. Ethylene oxide sterilisation is compatible, but coated stock must be aerated to meet residual EtO limits given in ISO 10993-7:2008. Steam autoclaving at 121 °C for 30 min is an operational boundary because the Vicat A50 softening temperature of ME0433 is approximately 125 °C under ISO 306:2022; unloaded flat packs may survive short exposure, but sealing pressure or constrained shrinkage during autoclaving can produce deformation. The terminal products are peelable pouches for syringes, catheters, and surgical instruments, where the peel interface is formed between the HDPE coating and a heat-seal lacquer or fibrous sealant; seal strength is measured according to ASTM F88/F88M-23 and EN 868-5:2018. Cytotoxicity is evaluated by ISO 10993-5:2009, and the resin must meet FDA 21 CFR 177.1520(c) 2.1 for U.S. primary packaging.
| Standard / Designation | Measurement | Acceptance condition for medical paper |
|---|---|---|
| ISO 11607-1:2019 | Packaging system integrity | Coated paper tensile and seal peel |
| ISO 10993-5:2009 | Elution cytotoxicity | No cytotoxic effect |
| ISO 10993-7:2008 | Residual ethylene oxide | Below specified limits |
| ASTM F88/F88M-23 | Seal peel strength | Product-dependent, greater than 1.0 N/15 mm |
| ISO 306:2022 | Vicat A50 softening temperature | Approximately 125 °C, steam autoclave limitation |
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Borealis HDPE ME0433 is an injection-moulding high-density polyethylene grade supplied in pellet form for rigid packaging components, specifically caps and closures, where environmental stress crack resistance must be balanced against consistent thin-wall filling in high-cavitation tools. The grade is produced on a bimodal polymerisation platform, which broadens the molecular weight distribution relative to single-reactor HDPE and modifies shear-thinning behaviour in the melt. In production-scale closure manufacturing, bimodal HDPE of this class is typically processed on high-speed injection moulding machines with hot-runner tools, valve-gated drop counts of 32 to 96, and hydraulic clamp forces sized to the projected part area; published failure-mode data for Borealis HDPE ME0433 in independent literature are limited. The product should therefore be specified from the manufacturer’s current technical datasheet for lot-release values of density, melt mass-flow rate, tensile yield stress, and environmental stress crack resistance. The grade is differentiated from general-purpose high-flow HDPE closure resins by its polymer architecture and by the resulting slow crack growth response under constant-strain test conditions, not by a single melt-flow value.
Short-shot defects in thin-walled HDPE closures are controlled by the interaction between melt rheology, tool temperature, injection velocity, and gate freeze time. For wall sections of 0.4 mm to 0.8 mm, fill speed is set high enough to prevent gate freeze before pack pressure transfer, but low enough to avoid jetting and flow-mark defects. Injection moulding machines used for HDPE closure production typically have screw diameters from 35 mm to 55 mm and L/D ratios of 20:1 to 25:1; the screw compression ratio is maintained between 2.0:1 and 2.5:1 to achieve melting without excessive shear heating. Melt temperature is generally held between 200°C and 250°C for high-density polyethylene closure grades; the upper limit depends on the stabiliser package and average residence time. Mould temperature is usually controlled between 10°C and 30°C with turbulent cooling-channel flow, and a Reynolds number above 10,000 is used where cycle-time reduction is critical. Holding pressure is set to compensate for volumetric shrinkage after gate solidification, and hold time that is too short produces sink marks and dimensional instability. Back pressure is commonly held between 50 bar and 200 bar for gentle homogenisation. Grade-specific optimisation for Borealis HDPE ME0433 should be derived from the manufacturer’s recommended barrel profile and from a structured design of experiments on the intended tool, because published data for this specific configuration are limited.
In moulds with valve-gated hot runners, gate freeze is the process limit that determines hold-pressure decay and screw recovery. Gate land length is normally set between 0.8 mm and 1.5 mm, with a gate diameter from 0.6 mm to 1.2 mm for HDPE closure walls of 0.4 mm to 0.8 mm. When the gate diameter is too small, shear heating at the gate can exceed the stabiliser package’s short-term tolerance and produce colour shifts or surface streaking. When the gate diameter is too large, the pack pressure window narrows and cycle time increases because the gate remains molten. Mould venting depth is kept below 0.02 mm to 0.03 mm for high-density polyethylene to prevent flash while allowing gas escape; insufficient vent depth produces burn marks at the flow front and contributes to short shots on remote cavities.
Hot-runner thermal uniformity is critical because gate freeze occurs earlier at outer drops. A manifold imbalance above 5°C can produce measurable shot-weight variation across a 64-cavity valve-gated tool. The shear rate at the gate during velocity-controlled filling can exceed 10,000 s-1; at these rates, high-density polyethylene exhibits shear thinning that is sensitive to molecular weight distribution. A broader-distribution resin such as Borealis HDPE ME0433 therefore requires capillary rheometry data across 100 s-1 to 10,000 s-1 before final gate sizing.
Plasticisation capacity is matched to cycle time by calculating the shot volume against the screw recovery rate. For a 48-cavity closure tool with a total shot mass of 50 g to 120 g, the screw recovery should be complete within the cooling time; otherwise cycle time is set by plasticisation rather than part solidification. The use of a grooved-barrel extruder or an upstream melt pump is not standard for HDPE closure moulding; a conventional three-zone screw with a non-return valve and controlled decompression is sufficient. Decompression after recovery should be limited to avoid air aspiration and oxidation; a screw-back distance above 5 mm can introduce air into the melt and reduce ESCR in the finished part.
On production lines, batch-to-batch variation in melt flow rate can shift shot weight by 1% to 2%; periodic lot-to-lot melt flow testing under ISO 1133-1:2022 is used to adjust barrel temperature or fill speed. This is a normal process-control response and is not by itself a failure mode.
Closure and rigid-packaging grades are specified for ESCR because constant-strain contact with surfactants, oils, and sterilising agents can induce brittle failure at stresses far below the short-term yield stress. Bimodal HDPE grades with controlled comonomer placement generally show longer failure times in the bent-strip method of ASTM D1693-15 or the notched constant tensile load method of ISO 22088-3 than unimodal resins of equivalent density and melt flow rate. Organoleptic suitability is evaluated by taste and odour methods such as EN 1622:2006 for water contact, while food-contact conformity is demonstrated under Regulation (EU) No 10/2011 and its amendments, and under FDA 21 CFR 177.1520 for olefin polymers. REACH Regulation (EC) No 1907/2006 applies to the substance and mixture status, and Directive 2011/65/EU applies only if the finished article is within the scope of electrical and electronic equipment.
| Parameter | Method or reference | Test condition or scope |
|---|---|---|
| Density | ISO 1183-1:2019 | Method A, immersion at 23°C |
| Melt mass-flow rate | ISO 1133-1:2022 | 190°C, 2.16 kg |
| Tensile yield stress | ISO 527-2:2012 | Type 1A specimen, 50 mm/min |
| Tensile modulus | ISO 527-2:2012 | Type 1A specimen, 1 mm/min |
| Flexural modulus | ISO 178:2019 | 3-point bending, 2 mm/min |
| ESCR | ASTM D1693-15 | Igepal CO-630, 50°C, F50 |
| Food contact | Regulation (EU) No 10/2011 | Overall migration and specific migration limits |
| Food contact | FDA 21 CFR 177.1520 | Olefin polymers for end-use conditions |
| Chemical inventory | REACH 1907/2006 | SVHC screening and Article 33 communication |
| RoHS | Directive 2011/65/EU | Lead, mercury, cadmium, hexavalent chromium, PBB, PBDE |
No single table substitutes for the current lot-release specification. Property values for Borealis HDPE ME0433 vary with polymerisation campaign, additive package, and test specimen preparation; independent published data for this specific configuration are limited, and values used for tool design should be taken from the manufacturer’s technical datasheet or from qualified production-scale trials. For applications involving repeated contact with fatty foods or aggressive detergent solutions, additional migration testing under the intended time-temperature conditions is necessary, because standardised regulatory conformity does not guarantee performance in every end-use formulation.
Additive migration kinetics in the polymer matrix are temperature- and crystallinity-dependent. For food-contact articles, the overall migration limit under Regulation (EU) No 10/2011 is 10 mg/dm² for general food contact, but the applicable limit must be read in the context of the specific simulant and article geometry. A single oxidative induction time value generated under ISO 11357-6 is not a substitute for migration testing where food-contact status is claimed.
The substitution of a bimodal, stress-crack-resistant HDPE into a tool designed for a high-flow, narrow-molecular-weight-distribution closure grade is not neutral. If the incoming grade has a lower melt mass-flow rate, the pressure drop across the hot runner and gate increases, and the processor may need to raise melt temperature, reduce gate land length, or increase injection velocity to maintain the same filling time. In a 64-cavity valve-gated tool, a hot-runner manifold imbalance above 5°C can shift gate freeze and produce shot-weight variation; the effect is more visible in lower-MFR grades because the viscosity rise during cooling is more difficult to compensate with pack pressure. The measured melt flow rate is therefore not sufficient to predict filling behaviour; capillary rheometry across a shear-rate range of 100 s-1 to 10,000 s-1 is required. The difference in ESCR between Borealis HDPE ME0433 and conventional high-flow HDPE grades is usually larger than the difference in tensile yield stress, so the grade is selected where long-term slow crack growth rather than short-term stiffness controls field failure. In closure hinges and tamper-evident bands, repeated flexural fatigue and stress-whitening resistance become additional critical-to-quality properties; these are not characterised by standard tensile tests alone and require part-level testing under the intended use conditions. Comparisons between datasheets should also confirm that tensile values are generated using the same standard, because ISO 527-2:2012 and ASTM D638-14 differ in specimen geometry and strain rate and are not numerically interchangeable.
Pre-drying is not normally required for unopened HDPE packaging when storage is below 60% relative humidity and the silo or hopper temperature is maintained above the dew point. Surface moisture, however, can appear when cold pellets are moved into a warm moulding hall; the resulting splay and inconsistent shot weight are process faults rather than evidence of polymer degradation. Clean regrind from rejected closures can be reintroduced in standard HDPE closure operations at addition levels often up to 30% by mass, but any reuse ratio for Borealis HDPE ME0433 must be validated against organoleptic performance and ESCR retention. Storage under direct sunlight or at temperatures above 40°C for prolonged periods can accelerate depletion of the stabiliser package and should be avoided. The material should not be combined with polypropylene, polystyrene, or PET bottle flake in regrind streams, because incompatible contaminants reduce ESCR and can produce delamination in the finished closure.