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Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy

    • Product Name: Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 533407
    Materialtype Polylactic Acid/ABS Alloy
    Heatresistancelevel Medium
    Density 1.15 g/cm³
    Meltflowrate 6 g/10 min (190°C/2.16 kg)
    Tensilestrength 45 MPa
    Tensileelongationatbreak 20%
    Flexuralstrength 70 MPa
    Flexuralmodulus 2200 MPa
    Notchedizodimpactstrength 10 kJ/m²
    Heatdeflectiontemperature 85 °C at 1.82 MPa
    Vicatsofteningtemperature 100 °C
    Flammabilityrating HB
    Processingmethod Injection Molding
    Dryingtemperature 80 °C
    Dryingtime 4 h
    Melttemperature 190-230 °C
    Moldtemperature 40-80 °C
    Moldingshrinkage 0.4-0.6%
    Waterabsorption 0.2%

    As an accredited Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy is packaged in 25 kg moisture-resistant bags, palletized and shrink-wrapped.
    Container Loading (20′ FCL) Container Loading (20′ FCL): Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy in 25-kg bags, palletized, shrink-wrapped, non-hazardous, securely loaded.
    Shipping Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy is typically shipped as non-hazardous thermoplastic pellets in sealed, moisture-barrier bags or drums. Store below 30°C, keep dry, avoid sunlight and ignition sources. Handle per SDS; no special UN classification required for normal transport.
    Storage Store Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, sparks, and open flames. Keep containers tightly sealed to prevent moisture absorption and contamination. Maintain temperatures between 5–30°C and low humidity. Separate from strong acids, bases, oxidizing agents, and solvents. Handle with grounding to avoid static buildup.
    Shelf Life Shelf life is typically 12 months stored unopened in a cool, dry place, protected from moisture, heat, and direct sunlight.
    Application of Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy

    In automotive interior trim programs, melt residence time rather than peak barrel temperature often separates acceptable parts from lot-level scrap. The PLA phase in Biolloy KH420 undergoes ester hydrolysis and molecular weight loss when residual moisture exceeds 0.05 wt% at hopper entry; therefore production lines that replace ABS without upgrading dryer dew point typically observe splay and gate blush within the first 150–200 shots after startup. A desiccant dryer delivering a dew point of ≤ −40°C, an airflow of 0.4 m³/min per kg/h throughput, and a hopper residency of 4 h at 80°C reduces moisture-related surface defects to levels acceptable for grained door panel lowers and seat side shields. On single-screw injection machines with 20:1 to 25:1 L/D and compression ratio 2.0:1 to 2.3:1, the barrel setpoints are maintained between 200°C rear and 225°C nozzle; excursions above 235°C for more than 6 min residence produce an acidic odor and discoloration that cannot be removed by regrind dilution. The shaping process for interior trim uses clamp force of 500–1,200 t depending on tool size, shot volume of 30–70% of barrel capacity, mold temperature 40–60°C, and texture depth up to 40 µm with draft angles ≥ 1.5° from the part line. Formulation at the press is 100 parts by weight KH420 with closed-loop regrind capped at 15 wt%; color masterbatch is added at 2–3 wt%, and functionalized olefin impact modification is limited to 3–5 phr only for cold-crack clip towers because higher modification drops HDT under 1.8 MPa by 2–5°C. Terminal interior trim parts include lower door panel inserts, center console side covers, seat side shields, glove box outer panels, and HVAC vent louvers, all of which are non-airbag-deployment surfaces where medium heat resistance meets solar load requirements below 85°C.

    Compliance for these components is evaluated under FMVSS 302 and ISO 3795:1989 for horizontal burn rate, with a requirement of ≤ 100 mm/min for non-grain covered interior materials. VOC and odor requirements follow VDA 270; the grade must remain below the OEM-specific variant limit, typically grade 3.0 or better when molded at correct moisture, though published data for this specific configuration is limited and each lot should be screened under production conditions. REACH Regulation (EC) No 1907/2006 Annex XVII and the EU End-of-Life Vehicles Directive 2000/53/EC apply; grades containing no halogenated flame retardants or lead-based heat stabilizers should be used. Since the ABS phase is not universally permitted for direct food or skin-contact duties, parts are not specified for steering wheel rim surfaces without a protective coating.

    RequirementStandard/regulationTypical acceptance criterion for automotive interior
    Horizontal flammabilityFMVSS 302Burn rate ≤ 100 mm/min
    Interior odorVDA 270OEM-specific grade, typically ≤ 3.0
    Chemical restrictionREACH Annex XVIINo restricted plasticizers or heavy metals above cited limits
    End-of-life vehicle recyclability2000/53/ECMaterial coding and dismantling compatibility required

    How Medium Heat Resistance Limits Thin-Wall Consumer Electronics Housing Design

    Thin-wall enclosures for routers, set-top boxes, and portable docking stations expose the alloy to shear rates above 10,000 s⁻¹ and cooling times below 15 s, conditions that amplify orientation stress and reduce weld-line strength. The material is dried at 80°C for 4 h and processed at melt temperatures 210–230°C, with the lower half of the window used for wall sections below 1.2 mm to prevent PLA degradation and gate blush. Formulation ratio is 100 parts by weight KH420; for antistatic grades, a carbon black masterbatch is let down at 8–12 wt%, but this shifts surface resistivity from > 10¹² Ω/sq to 10⁶–10⁹ Ω/sq and reduces notched Izod impact by up to 35% when measured under ISO 180:2023, so drop-test validation per IEC 62368-1:2023 is required on corner welds and snap-fit hooks. Production equipment is a high-speed injection molding machine with accumulator-assisted injection, valve-gated hot runner, and clamp force matched to 40–60 MPa cavity pressure; mold temperature is 45–55°C, and ejection is delayed until the part surface reaches 60°C or below to avoid sink at ribs. The terminal product types include router top and bottom housings, set-top box front bezels, tablet keyboard base covers, display hub enclosures, and remote-control shells; continuous service above 85°C is outside the grade boundary because the PLA phase begins to creep at elevated board-level temperatures, so waste-gate or heatsink-adjacent walls are avoided unless ventilation airflow is confirmed.

    Compliance anchors are IEC 62368-1:2023 for audio/video and ICT equipment, RoHS Directive 2011/65/EU including the amended Annex II restricted substances, and REACH Annex XVII entries relevant to consumer articles. Flammability is assessed under UL 94; KH420 is generally specified at HB at 1.5 mm, and no V-0 claim is made without a validated flame-retardant package, which may compromise PLA thermal stability. The limitation is explicit: if the enclosure contains a lithium-ion cell, the material is used only for the outer shell, not as a cell holder, because melt viscosity and HDT are insufficient for direct cell-contact thermal barriers under IEC 62133 abuse conditions.

    Household Appliance Panel Weld-Line Integrity and Chemical Exposure

    Appliance panel production for washing machine detergent drawer facades, air conditioner louver assemblies, and robot vacuum dust-bin lids imposes multiple gate drops on large-area parts, making weld-line retraction the dominant rejection mode. KH420 is processed as neat resin at 100 parts by weight with custom color concentrate at 2–4 wt%; re-grind from the same family is capped at 20 wt% after incoming melt flow rate under ISO 1133-1:2022 at 220°C/10 kg shows a batch-to-batch shift of no more than ±8%. The process uses a sequential valve-gate hot runner with filling time 1.5–2.5 s for a 300 mm flow path, mold temperature 50–60°C, and packing pressure 60–80 MPa for 3–5 s per mm of nominal wall; weld-line strength measured by ISO 527-2 on a double-gate plaque typically retains 62–70% of the unwelded tensile strength, and lower values indicate moisture or excessive mold temperature drop. The terminal products are non-food-contact appliance exterior panels: detergent drawer facades, air conditioner louver assemblies, robot vacuum dust-bin lids, and dehumidifier control panels. Chemical exposure is limited to brief contact with detergents and hypochlorite solutions at pH 6–10; prolonged contact with chlorinated solvents or alkaline cleaning agents above pH 11 should be avoided because PLA-phase ester bonds undergo saponification and stress cracking.

    Compliance is assessed under IEC 60335-1:2020 for household appliance safety, UL 94 HB at 1.5 mm, and RoHS Directive 2011/65/EU. The material is not suitable for food-contact surfaces under EU 10/2011 because the ABS fraction is not positively listed for all food categories, and the PLA fraction cannot be assumed to cover the entire formulation. For UL-marked appliances, the relevant UL 746D polymer-grade recognition file should be requested from the supplier to confirm RTI and comparative tracking index, rather than relying on generic HDT data.

    For closed-loop office equipment housing programs, regrind stability and flatness after demolding determine whether the grade can replace ABS in printer side panels and scanner lids. The recommended formulation at the press is 70–85 wt% virgin KH420 with 15–30 wt% closed-loop regrind, provided the regrind is dried identically to virgin material and the melt flow rate under ISO 1133-1:2022 remains within ±10% of the virgin lot. The shaping process uses a conventional three-plate cold runner, a mold temperature of 45–55°C, and a clamp force sized to approximately 3–5 kN/cm² projected area; parts are ejected after achieving a surface temperature below 65°C and are immediately flat-stacked with edge support because thin sections below 2 mm may warp more than 0.5 mm over 300 mm span when cooling is non-uniform. Terminal office equipment types include printer side panels, scanner lids, monitor rear covers, and document feeder trays. These parts are not exposed to fuser temperatures above 85°C; fuser-adjacent components are excluded, or verified under ISO 75-2 HDT with a safety factor of 15°C below the measured value. Compliance priorities are ISO 11469:2016 for polymer marking if part mass exceeds 50 g, RoHS Directive 2011/65/EU, and the Blue Angel RAL-UZ 200 criteria for recycled-content documentation where applicable; no food-contact or toy-grade claims are attached to office equipment.

    When Retail Display Components Require Static Dissipation Without Polycarbonate Cost

    Retail point-of-sale display trays, shelf edge strips, and temporary fixture panels require lower warpage and antistatic surface properties without the impact budget of PC/ABS. KH420 is extruded into sheet at 2.0–5.0 mm thickness using a single-screw extruder with 30:1 L/D, barrier screw, melt pump, and polished three-roll stack set to 60–80°C; the polymer is pre-dried to ≤ 0.05 wt% moisture and processed at 200–225°C melt temperature to limit die deposition. For static dissipation, an antistatic masterbatch is added at 5–10 wt%, targeting surface resistivity between 10⁹ and 10¹¹ Ω/sq measured under IEC 61340-2-3; addition above 12 wt% causes sheet delamination at the die exit and reduces tensile elongation under ISO 527-2 by approximately 25–40%. The downstream process is vacuum forming on aluminum or epoxy tools at 120–140°C sheet surface, with plug assist for draw ratios above 1:2; the material is less thermally stable than PVC and must not be soaked in the oven for more than 45 s at setpoint to avoid PLA-phase yellowing. Terminal products include display trays, shelf edge strips, temporary promotional fixtures, and non-structural merchandise dividers. Compliance centers on UL 94 HB at 3.0 mm, RoHS Directive 2011/65/EU, and REACH Annex XVII; the material is not recommended for continuous outdoor use unless UV stabilization is validated. Published data for this specific configuration is limited, and parts should be screened under ISO 4892-2 before exterior specification.

    Extrusion-grade filament production for material-extrusion additive manufacturing uses KH420 as a rigid engineering feedstock where standard PLA lacks thermal toughness and standard ABS requires an enclosed machine with fume extraction. Twin-screw compounding is performed on a 40:1 L/D co-rotating extruder with vacuum venting at −0.08 MPa, screw speed 300–500 rpm, and melt temperature 210–230°C; the filament line pelletizes the compound and then extrudes through a single-screw filament extruder with water bath at 40–50°C, laser diameter control to 1.75±0.05 mm, and spooling tension 2–5 N to prevent ovality. Formulation ratio is 100 parts by weight KH420 with 0.1–0.3 phr chain extender in the compounding step to maintain melt strength; color masterbatch is added at 1–2 wt% only if the carrier is PLA-compatible, because styrene carrier masterbatch increases die swell and diameter variation. Terminal products are engineering filament spools for open or enclosed FFF/FDM machines, used for rapid tooling aids, assembly fixtures, and low-volume protective covers; printed parts are limited to ambient service below 80°C. Compliance for the filament itself includes RoHS Directive 2011/65/EU, REACH Regulation (EC) No 1907/2006, and UL 94 HB at 1.5 mm for flammability classification if the printed part is used in electrical enclosures; mechanical traceability is documented by ISO 527-2 for tensile and ISO 178 for flexural, with lot-specific certificates reporting filament diameter ovality and moisture content below 0.05 wt%. Amine-based additives are avoided in the filament formulation because amines accelerate PLA transesterification and create melt viscosity drift during compounding.

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    Certification & Compliance
    More Introduction

    Biolloy KH420 Medium Heat Resistance Polylactic Acid/ABS Alloy is a melt-compoundable thermoplastic positioned within the medium heat distortion segment of PLA/ABS blends. The grade combines the high modulus and bio-based carbon content of polylactic acid with the notch-insensitive ductility and wider processing tolerance of an ABS-rich continuous phase. Published data specific to Biolloy KH420 is limited; the following treatment therefore uses class-typical data for medium heat resistance PLA/ABS alloys, and lot-specific release documents from the manufacturer should be consulted before tooling is finalized or process parameters are fixed.

    What Limits the Continuous Service Temperature of Biolloy KH420?

    Thermal stability in this alloy class is governed by two competing requirements: the PLA phase begins to lose modulus above its glass transition near 55–60°C unless crystallinity is enhanced, while the ABS phase tolerates short-term service at 80–95°C before rubber-phase oxidation becomes significant. Medium heat resistance grades are typically formulated with nucleating agents and compatibilizers that raise heat deflection temperature under 0.45 MPa to approximately 80–100°C and under 1.8 MPa to 60–75°C when tested according to ISO 75-2. Vicat softening temperature measured by ISO 306/A50 is generally 90–105°C. Continuous service under mechanical load should remain below the 1.8 MPa heat deflection temperature; for an unfilled alloy this usually corresponds to an application limit of 55–65°C when dimensional stability is critical. Grades in this segment achieve the improvement through controlled PLA crystallinity rather than through excessive filler loading, which would raise modulus but reduce weld-line strength and flowability. Differential scanning calorimetry at 10°C/min per ISO 11357-1 typically shows a PLA melting peak near 150–165°C after annealing. Published data for Biolloy KH420 specifically is limited; class-typical values should be validated on production plaques and final parts.

    Pre-drying is mandatory when relative humidity exceeds 60% or when regrind content is above 20%. A desiccant dryer with a dew point of −40°C and air flow of 0.5–1.0 L/min per kg/h throughput should be set to 70–80°C for 4 h. Moisture content must remain below 0.025% to suppress hydrolysis of the PLA ester linkages during melting. Twin-screw compounding or direct injection molding on a screw with L/D ratio of 36:1 to 40:1 is recommended. Barrel temperatures from feed to nozzle should be profiled between 170°C and 210°C, with melt temperature not exceeding 230°C because the PLA fraction undergoes unzipping depolymerization and the ABS butadiene phase forms gel particles at higher thermal load. The usable melt-temperature window is narrow: below 180°C the PLA spherulites may not fully disperse, and above 220°C the butadiene rubber phase begins to crosslink, producing black specks. A die-temperature control band of ±5°C is required on production lines. Screw speed for a 40 mm laboratory extruder is usually 200–300 rpm; production-scale lines with 75 mm diameter should reduce speed to maintain specific energy below 0.20 kWh/kg. Injection molding under ISO 294-4 conditions requires mold temperatures between 30°C and 60°C; lower mold temperatures reduce cycle time but freeze in amorphous PLA, lowering heat deflection temperature, whereas higher mold temperatures promote crystallization but increase sink marks. Packing pressure of 50–80 MPa and back pressure of 0.5–1.5 MPa are typical for maintaining dimensional tolerance. Production-scale strand pelletizing lines with water-ring pelletizers often edge tear when melt temperature falls below 180°C, generating fines above 0.5% by weight.

    Rheological and Mechanical Specification Benchmarks for Medium Heat PLA/ABS Alloys

    The following table presents class-typical values for medium heat PLA/ABS alloys. These are not guaranteed release limits for Biolloy KH420 but serve as engineering benchmarks for grade selection.

    PropertyTest MethodTypical Range
    DensityISO 1183-11.10–1.14 g/cm³
    Melt mass-flow rate, 220°C/10 kgISO 1133-115–30 g/10 min
    Tensile stress at yieldISO 527-2/1A35–50 MPa
    Tensile modulusISO 527-2/1A2,200–2,600 MPa
    Elongation at yieldISO 527-2/1A2–5%
    Elongation at breakISO 527-2/1A5–15%
    Flexural strengthISO 17855–70 MPa
    Flexural modulusISO 1782,000–2,400 MPa
    Charpy notched impact, 23°CISO 179-1/1eA6–12 kJ/m²
    Charpy notched impact, −30°CISO 179-1/1eA2–5 kJ/m²
    Heat deflection temperature, 0.45 MPaISO 75-2/B80–100°C
    Heat deflection temperature, 1.8 MPaISO 75-2/A60–75°C
    Vicat softening temperature, A50ISO 30690–105°C
    Mold shrinkage, parallelISO 294-40.4–0.8%
    Water absorption, 24 hISO 620.5–1.0%

    Compared with unmodified PLA, Biolloy KH420 class materials show at least a twofold increase in Charpy notched impact energy due to the ABS impact modifier phase. Standard PLA typically measures 3–5 kJ/m² under ISO 179-1/1eA, while medium heat PLA/ABS alloys are typically 6–12 kJ/m². The ABS phase also reduces notch sensitivity and improves flow length in thin-wall sections. Compared with neat medium-impact ABS, the PLA phase increases tensile and flexural modulus from approximately 1,600–2,000 MPa to 2,200–2,600 MPa, but reduces Vicat softening temperature from the 95–110°C range typical of ABS to 90–105°C. Bio-based carbon content determined by ASTM D6866 or ISO 16620-2 typically ranges from 20% to 40% in this alloy class; product-specific certification for Biolloy KH420 must be verified separately. The grade should not be treated as a direct replacement for PC/ABS, where heat deflection temperatures under 1.8 MPa frequently exceed 100°C according to ISO 75-2/A.

    When a Medium Heat PLA/ABS Alloy Replaces Standard PLA in Structural Enclosures

    For enclosure components such as appliance control panels, audio equipment housings, office equipment frames, and automotive interior trim, replacement of standard PLA by Biolloy KH420 class material is justified when the part must withstand intermittent surface temperature rise from internal heat sources without exceeding 60–70°C under load. Final qualification should include heat aging per UL 746B or IEC 60335-1; class-typical relative thermal index for unfilled PLA/ABS alloys is often 50–70°C, but a Biolloy KH420 UL yellow card must be obtained for specific electrical or mechanical RTI values. Thin-wall mold filling at thicknesses from 1.2 mm to 2.0 mm is improved compared with standard PLA because the ABS continuous phase lowers viscosity at shear rates above 1,000 s⁻¹. Spiral flow length measured on a 2 mm channel can be 300–500 mm at 800 bar injection pressure for class-typical grades. Clamp force requirements are similar to amorphous engineering thermoplastics at 3–5 kN/cm² of projected area. Unfilled medium heat PLA/ABS alloys generally burn with a horizontal rating of HB under UL 94; a vertical V-2 rating requires flame retardant additives that may reduce heat deflection temperature and Charpy impact.

    CharacteristicStandard PLANeat ABSMedium Heat PLA/ABS Alloy Class
    Heat deflection temperature, 1.8 MPa50–60°C75–95°C60–75°C
    Charpy notched impact, 23°C3–5 kJ/m²15–30 kJ/m²6–12 kJ/m²
    Flexural modulus3,000–3,500 MPa1,600–2,000 MPa2,000–2,400 MPa
    Bio-based carbon fraction>95%0%20–40%
    Resistance to hot-water hydrolysisLowModerateModerate to low
    Melt-temperature processing ceiling~200°C~250°C~220°C

    Solvent Exposure, Hydrolysis, and Annealing Behaviour

    The ester backbone of the PLA phase is susceptible to hydrolytic degradation in hot aqueous environments. Continuous contact with water above 60°C or with alkaline cleaners above pH 9 should be avoided; hydrolysis reduces molecular weight and causes a rapid drop in Charpy impact energy. Resistance to aliphatic hydrocarbons and oils is acceptable for short-term exposure, but ketone, ester, and aromatic solvents attack the ABS phase and cause stress crazing under molded-in residual stress. Outdoor UV exposure requires carbon black or UV stabilizer packages; unpigmented PLA/ABS chalks and loses impact within 1,000–2,000 hours in ISO 4892-2 accelerated weathering. Annealing at 70–80°C for 1–2 h increases PLA crystallinity and raises heat deflection temperature by 5–10°C, but reduces notched impact by 20–40%; annealing should therefore be reserved for non-impact-loaded brackets and frames. For regulatory compliance, Biolloy KH420 must be covered by current RoHS Directive 2011/65/EU and REACH EC 1907/2006 declarations; the PLA/ABS alloy class typically contains no intentionally added phthalates or brominated flame retardants, but product-specific SVHC content must be confirmed. Avoid amine-based additive masterbatches during compounding without prior testing; basic additives can accelerate transesterification of the PLA fraction.

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