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Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid

    • Product Name: Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 628879
    Product Name Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid
    Material Type Polylactic Acid (PLA) blend
    Processing Method Injection Molding
    Density 1.25 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 15 g/10 min
    Tensile Strength 50 MPa
    Tensile Modulus 3600 MPa
    Elongation At Break 3%
    Flexural Modulus 3800 MPa
    Flexural Strength 75 MPa
    Charpy Notched Impact Strength 23 C 2.5 kJ/m²
    Charpy Unnotched Impact Strength 23 C 15 kJ/m²
    Heat Deflection Temperature Hdt B 120 °C
    Vicat Softening Temperature 120 °C
    Melting Temperature 170 °C
    Processing Temperature 190-220 °C
    Mold Temperature 20-60 °C
    Drying Temperature 80 °C
    Drying Time 2-4 h
    Bio Based Content >80%

    As an accredited Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid is supplied in 25 kg moisture-barrier bags, palletized and shrink-wrapped.
    Container Loading (20′ FCL) Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid loaded in a 20′ FCL, palletized and secured for ocean freight.
    Shipping Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid is typically shipped as a non-hazardous solid in sealed moisture-barrier bags, fiber drums, or bulk containers. Keep dry, below 30°C, away from sunlight. Standard freight applies; consult SDS for exact transport classification and documentation.
    Storage Store Bio-Flex S 7514 in a cool, dry, well-ventilated area using sealed original packaging. Keep away from heat, flames, direct sunlight, and moisture. Recommended conditions: below 30°C, low humidity, with desiccant if needed. Avoid strong oxidizers. Use first-in, first-out rotation; reseal opened containers promptly. Protect packages from punctures, crushing, and stacking damage to prevent moisture pickup and degradation.
    Shelf Life Bio-Flex S 7514 has a typical shelf life of 12 months when stored in original, unopened packaging under cool, dry conditions.
    Application of Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid

    Bio-Flex S 7514 is a high-heat injection moulding grade of polylactic acid supplied as ready-to-mould pellets for rigid disposable and short-life durable articles. The material is processed on medium-hydraulic clamp injection machines between 800 kN and 1,500 kN clamp force, with the processing window defined by melt temperature, mould surface temperature, and hold pressure rather than by screw rotation alone. Desiccant drying at 80 °C for 4 h to a residual moisture below 250 ppm is the minimum start-up condition. When ambient relative humidity exceeds 60%, hopper residence time should be limited to 30 min unless closed-loop dry air conveying is installed. The barrel profile from feed throat to nozzle is maintained from 180 °C to 220 °C, and the melt temperature at the nozzle should not exceed 230 °C to avoid lactide formation, screw drool, and mould deposits. Screw configurations with L/D ratios between 20:1 and 24:1, compression ratios of 2.5:1 to 3.0:1, and low-shear mixing sections reduce viscous heating compared with polyolefin-specific screws. Back pressure is kept between 5 bar and 15 bar hydraulic, and decompression is applied before sprue break to prevent stringing from the nozzle tip. Heat deflection temperature under ISO 75-1/-2 at 0.45 MPa is the primary release parameter for hot-contact applications; values below 85 °C in moulded plaques indicate insufficient crystallinity or moisture-induced hydrolytic chain scission. Additive packages containing strong alkaline carriers or free amine groups should be avoided because they accelerate chain degradation at processing temperatures. The application-specific process boundaries and failure modes are summarised in Table 1.

    Application segmentWall thickness rangeMould surface temperatureStart-up hold pressurePrimary failure boundary
    Coffee capsule body0.61.2 mm85100 °C600900 barRim distortion when mould surface remains below 75 °C
    Disposable cutlery1.54.0 mm8095 °C500800 barHandle warpage and knit-line cracking
    Cosmetic jar and closure2.05.0 mm7590 °C400700 barCore voids from underpacking
    Food service tray0.81.5 mm80100 °C7001,000 barSealing flange shrinkage after hot fill
    Toy component1.53.0 mm7090 °C450750 barImpact failure at knit lines
    Office technical housing2.04.0 mm6080 °C500800 barBoss cracking at screw insertion

    Why do single-serve coffee capsule bodies require a mould surface temperature above the PLA cold crystallisation onset?

    In single-serve beverage systems, capsule bodies and rim closures are injection-moulded with wall thicknesses between 0.6 mm and 1.2 mm. The finished part must survive a brewing cycle at 88 °C to 93 °C and internal pressure up to 9 bar without deformation of the rim seal or the puncture membrane. For Bio-Flex S 7514, the mould surface temperature is set between 85 °C and 100 °C to exceed the cold crystallisation onset of the polylactic acid matrix. If the mould surface remains below 75 °C, the part surface freezes in an amorphous state and the capsule body can distort during first hot-water contact. The part is processed as supplied without chain extenders or additional nucleating additives; any colour masterbatch must be PLA-compatible and is accepted only after hot-water immersion testing. Hot runner valve gates with individual nozzle shut-off are preferred for multi-cavity tools because open gates tend to string and leave vestiges that compromise the sealing flange. Hold pressure between 600 bar and 900 bar hydraulic is applied until gate freeze, and cooling time is extended by 2 s to 5 s compared with amorphous PLA to allow in-mould crystallinity. Shot weights are typically 1.5 g to 4.0 g per capsule body. Dimensional control at the sealing rim is verified by coordinate measurement; out-of-roundness above 0.15 mm can cause leakage under brewing pressure. The mould is run with sequential valve gating to move the weld line from the puncture area to the side wall. Residual crystallinity is not measured directly on the line; a periodic Vicat softening temperature under ISO 306 method A50 is recorded from a plaque specimen. If the Vicat value drops below 95 °C, mould temperature or cooling time is adjusted before further production. The terminal capsule body is evaluated for food contact under Regulation (EU) No 10/2011; lactic acid migration is screened against the assigned specific migration limit for the formulated compound. United States food contact status must be verified through the applicable Food Contact Notification for the specific Bio-Flex S 7514 formulation before export. Compostability of the rigid shell is assessed under EN 13432; the capsule must disintegrate within 12 weeks in industrial composting and meet heavy metal limits. A lined or dual-layer capsule arrangement may be required because polylactic acid alone does not provide the oxygen barrier of aluminium or multi-layer structures. Published data for high-pressure capsule configurations using this specific grade is limited; full-scale tool trials should confirm rim sealing under customer-specific brewing machines.

    Disposable cutlery in hot soup and sauce exposures

    For disposable cutlery exposed to hot soup, gravy, and sauce, the limiting variable is deformation resistance during short hot-liquid contact. Bio-Flex S 7514 is processed in high-cavitation cold-runner tools with shot weights from 4 g for teaspoons to 18 g for knives. The grade is injected as supplied, without blending of regrind above 15 wt% unless the regrind is dried and free of food residue. Mould surface temperature for spoons and forks is held at 80 °C to 95 °C, while knife handles may be processed at the lower end to reduce cycle time. The handle cross-section is designed with a minimum wall of 1.5 mm; thinner sections produce knit-line embrittlement at the junction between handle and bowl or blade. Fast injection speed fills the long flow path before the melt front freezes. Back pressure below 15 bar hydraulic limits shear heating. After ejection, cutlery is quenched on a flat cooling fixture; uneven cooling creates warpage along the handle axis. In production-floor trials, knife handles are the failure-prone regions because the transition from handle to blade has an abrupt cross-section change. Sink marks in the handle are reduced by gas-counterpressure or oscillating hold pressure, not by raising melt temperature, which increases lactide bloom. Food contact compliance is assessed under Regulation (EU) No 10/2011 with duplicate testing on the finished packaging scenario, not only raw pellets. Industrial compostability is evaluated under EN 13432; the cutlery is suitable for closed-loop venues, institutional catering, and airline meal service where organic waste sorting is present. Hot-water immersion in the laboratory uses 90 °C water for 10 min with no visible deformation at the bowl rim as an internal control. Very thin spork tines below 1.0 mm remain susceptible to bending at 94 °C. Use in microwave or conventional ovens is outside the operational boundary. The terminal cutlery is a short-service, single-use article intended for industrial composting, not for dishwasher re-use.

    Cosmetic packaging closures, thick-walled jars, and airless pump collars represent a non-food contact application in which Bio-Flex S 7514 replaces ABS and PP in short-run production. The thick wall sections from 2.0 mm to 5.0 mm create an asymmetric thermal profile: the outer skin solidifies quickly while the core remains molten and crystallises more slowly. Mould surface temperature between 75 °C and 90 °C is used to reduce surface haze from rapid quench. Vacuum voids in the core are controlled by increasing hold pressure to 700 bar and extending hold time until the gate freezes; a ring gate or diaphragm gate is preferred over pin gates that introduce shear heating and black specks. Colour masterbatches are selected from PLA-compatible carriers at let-down ratios of 2 wt% to 4 wt%; pigment concentrates containing more than 3 wt% titanium dioxide raise melt viscosity and can slow flow in thin lettering or embossed logos. Surface appearance criteria for cosmetic packaging require high gloss and low haze. The mould is conditioned with a chemical-etched surface of VDI 24 to VDI 30 equivalent, and the melt is injected with a slightly lower nozzle temperature to avoid splay. If splay appears at the gate, the desiccant dryer dew point is checked and the hopper loading interval is reduced. Dark-coloured thick parts can show visible flow lines; increasing mould surface temperature to 90 °C reduces the effect but adds cycle time. Compliance is assessed under REACH Annex XVII, RoHS 2011/65/EU for coloured components exported to electronics-adjacent packaging, and Regulation (EC) No 1223/2009 for packaging in contact with cosmetic formulations. The material is not intended for re-use with solvent-based nail polish removers or essential-oil-rich formulations without compatibility testing, because polylactic acid can exhibit stress cracking under esters and ketones. Terminal articles include jar bodies, closures, compact cases, and collar rings that are not sold with a compostability claim unless the entire multi-component package meets EN 13432 disintegration and heavy metal limits.

    When hot-fill food service trays replace PP/PS in short-run moulds

    Short-run food service trays and clamshell bases are moulded with wall thicknesses between 0.8 mm and 1.5 mm and a flow length-to-thickness ratio up to 150:1. The processing objective is to form a crystallised sealing flange that does not shrink when warm product is deposited. Mould surface temperature is set between 80 °C and 100 °C on the flange and base areas; movable inserts with separate thermocouple zones are used when tooling permits. Fill speed is set high to avoid premature solidification ahead of the flow front, while hold pressure is maintained at 700 bar to 1,000 bar hydraulic to pack the gate region. Tooling design often uses an insulated runner or hot runner to avoid excessive cold-runner scrap. The gate is located at the centre of the base and flow is directed toward the flange. During filling, venting at the flange edge must be sufficient to avoid burn marks from compressed air. The terminal tray is evaluated under Regulation (EU) No 10/2011 for food contact and under EN 13432 for industrial compostability if all components, including labels and adhesives, are compostable. Hot-fill exposure is limited to 88 °C to 93 °C with contact time below 2 min; sustained heating above 100 °C or microwave reheating with oil-rich spots can cause local distortion and is outside the operational window. The edge flange is the first region to fail in trial runs because residual orientation from the filling phase relaxes when the tray is stacked in a heated holding cabinet. Post-mould cooling in a restrained fixture for 5 s to 10 s after ejection reduces flange curl. Tray stacking trials are part of release testing, and the lower tray in a stack of 20 units should resist deformation under 40 °C ambient for 24 h when loaded with 500 g. Published data for this specific configuration is limited when product depths exceed 50 mm; a flow simulation and a pilot tool with heated sprue bush are recommended before full multi-cavity investment. The finished product is a rigid short-life food service tray intended for warm-fill distribution and industrial composting, not for long-term ambient storage of shelf-stable meals.

    Toy components manufactured from Bio-Flex S 7514 are evaluated under the chemical migration requirements of EN 71-3:2019+A1:2021 and the mechanical safety requirements of EN 71-1:2014+A1:2018. Small parts intended for children under 36 months must pass the cylinder test after conditioning, so moulded items with loose breakable features are designed with wall thickness above 1.5 mm and radiused corners. The material is processed with a mould surface temperature of 70 °C to 90 °C and a lower hold pressure of 450 bar to 750 bar hydraulic because overpacking brittle PLA can raise residual stress and reduce impact resistance under ISO 179-1. The mould cavity texture is typically a fine chemical-etched finish because the material replicates surface detail with low shrinkage. On production-scale toy lines, the main processing bottleneck is consistent ejection from deep-draw moulds. Because the material has low surface tack after crystallisation, ejection is usually reliable when the mould polish direction follows the draw axis. Release of small sculpted details without tearing requires a draft angle of at least 1.5°. Migration testing under EN 71-3 restricts soluble elements including barium, cadmium, chromium, lead, and mercury; the final compound must be screened for each colour masterbatch because some pigments are based on metal salts that may exceed Category III limits. Terminal articles include building blocks, board game tokens, sorting puzzles, and sensory toys produced for closed-loop brand owners. The compostability claim under EN 13432 may be used for mono-material toys only when every decorative element and adhesive is certified. The final toy parts are not approved for hot-water sterilisation or dishwasher cleaning; repeated exposure to water above 60 °C may anneal the surface and alter snap-fit clearances. Contact with solvent-based paints and some essential-oil-based sensory liquids should be tested separately because ester-containing formulations can reduce surface gloss and promote stress cracking.

    Office equipment and non-food technical housings

    Non-food technical housings in desktop equipment are moulded with nominal wall thicknesses from 2.0 mm to 4.0 mm and require dimensional stability for screw bosses, living hinges, and snap-fit closures. The high-heat nucleation package in Bio-Flex S 7514 is used to reduce post-mould shrinkage after assembly, but the mould must still accommodate linear shrinkage in the 0.4% to 0.7% range depending on part geometry and mould temperature. Processing uses a low-compression screw with L/D 20:1 to 24:1 to reduce screw drool and black specks; the metering zone is controlled to avoid excessive melt temperature at the nozzle above 220 °C. Mould surface temperature for technical housings is set at 60 °C to 80 °C when maximum heat resistance is not required; this lower range supports faster cycle times but yields lower crystallinity. The terminal parts comply with RoHS 2011/65/EU and REACH SVHC restrictions for non-food consumer goods. Flame retardant requirements are a critical limitation: Bio-Flex S 7514 is not supplied with a UL 94 V-0 rating at 1.5 mm, and any additive package intended to achieve flame retardancy must be evaluated for hydrolytic stability and mould deposit formation. Boss cracking at screw insertion is controlled by using thread-forming fasteners designed for plastics and by specifying a pilot hole diameter at 0.8 times the screw outer diameter. The housing surfaces can be laser-marked or pad-printed; adhesion should be validated under ISO 2409 cross-cut after 72 h at 23 °C and 50% relative humidity. Published data for this specific configuration is limited for office machines requiring long-term mechanical load above 50 °C; accelerated ageing under ISO 4892-2 is recommended before production release. The finished article is a non-food technical housing intended for indoor use and is not sold as a compostable package because electronic or metal inserts would prevent the part from passing EN 13432.

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    Certification & Compliance
    More Introduction

    Bio-Flex S 7514 High Heat Injection Molding Polylactic Acid is a nucleated, unfilled poly(lactic acid) compound supplied in pellet form for screw-fed injection moulding machines with three-zone general-purpose screws. The grade is characterised by the supplier using ISO 1183-1 density, ISO 1133-1 melt flow rate, ISO 527-2 tensile properties, ISO 178 flexural properties, ISO 179-1/1eA Charpy impact, ISO 306 Vicat softening temperature, and ISO 75-2 heat deflection temperature. The product is distinguishable from standard extrusion and injection PLAs by its crystallisation package, which raises thermal resistance after mould-temperature-induced crystallisation without relying on mineral fillers or petroleum-based impact modifiers. Typical manufacturer literature values include density of 1.27 g/cm³, melt flow rate of 6 g/10 min at 190 °C under 2.16 kg, tensile modulus of 3.5 GPa, and Vicat A softening temperature of 105 °C under method A50. These figures are typical and not lot-release specifications; the certificate of analysis should be checked for incoming quality control. The product is used where rigid parts must tolerate short-term heat exposure above the service range of amorphous PLA, including hot beverage accessories, domestic appliance components, office equipment housings, and industrial covers.

    What separates a nucleated high-heat PLA from unfilled amorphous PLA?

    The primary separation is not biobased content but the degree of crystallinity achievable inside a conventional injection moulding cycle. Unfilled amorphous PLA typically exhibits Vicat A softening near 55–60 °C and ISO 75-2 method B values below 55 °C; these articles soften or distort when filled with fluids above coffee-brewing temperatures. Bio-Flex S 7514 is compounded with a nucleating package that reduces crystallisation half-time when the melt contacts a hot mould surface. The moulded article develops spherulitic regions with greater resistance to chain motion, shifting the Vicat A softening range to approximately 100–110 °C and the method B heat deflection temperature into the 90–100 °C band after adequate crystallisation. The trade-off is reduced optical clarity: high crystallinity produces haze, whereas unfilled amorphous PLA can remain transparent. Users requiring both high clarity and heat resistance must select a different technical route, such as stereocomplex PLA or chemical crosslinking, because the present grade cannot deliver both properties simultaneously.

    Pre-drying is a mandatory processing boundary for Bio-Flex S 7514. The supplier’s processing guide specifies desiccant drying at 80 °C for 4 h to reach residual moisture below 250 ppm. In high-humidity plants, the hopper dryer should maintain a dew point below −40 °C and an air-flow rate above 1.8 m³/h per kg/h of throughput. Hydrolysis in the melt is the limiting failure mode: at moisture contents above 400 ppm, polymer chain scission lowers melt viscosity, reduces impact strength, and produces acrid odour and silver streaking. Injection moulding technicians should not rely on visual pellet dryness because PLA can appear dry while retaining more than 300 ppm of internal moisture. Processing melt temperature is typically 180–220 °C; the melt should not be held above 220 °C for more than 10–15 min total residence time, as lactide reformation accelerates at high temperature and generates plate-out on the mould venting surfaces. Barrel zones may be set with a flat or slightly ascending profile, for example rear 180 °C, middle 190 °C, front 200 °C, and nozzle 210 °C, provided the actual melt temperature measured by an insertion probe remains within the accepted envelope.

    When mould temperature controls crystallisation and dimensional stability

    Shear history and mould temperature determine whether the high-heat mechanism is actually obtained. If the mould wall is maintained below 60 °C, the part surface quenches into an amorphous state and the crystallinity at the core may be insufficient to achieve the rated Vicat A temperature. Differential scanning calorimetry according to ISO 11357-3 then shows a large cold-crystallisation exotherm on first heating, indicating that the material retains latent crystallinity rather than realised thermal resistance. In this condition, the article remains vulnerable to distortion in hot-water immersion tests or close proximity to heating elements. Raising the mould temperature into the 80–110 °C band increases the spherulite nucleation rate; on water-heated moulds, the achievable surface temperature is often limited to 95 °C, which is within the effective cooling range but requires cycle extension. Pressurised water or oil mould-temperature units operating at 105–120 °C are used when maximum heat deflection is required, but they increase energy consumption and can complicate ejection because the part remains softer at demoulding. Shrinkage and warpage also shift with crystallinity: the semi-crystalline moulding often exhibits higher mould shrinkage than the amorphous quench from the same tool, and the dimensional change should be established using ISO 294-4 plaques rather than assumed from amorphous PLA shrinkage tables. Post-mould annealing at 100 °C for 30 min is an alternative for parts with simple geometry; it can raise crystallinity after demoulding, but it may produce anisotropic shrinkage and must be validated on the production tool.

    Comparative typical literature values for Bio-Flex S 7514 and an unfilled amorphous PLA under identical test methods are shown below.

    PropertyTest standardBio-Flex S 7514Unfilled amorphous PLA
    DensityISO 1183-11.27 g/cm³1.24 g/cm³
    Melt flow rate at 190 °C/2.16 kgISO 1133-16 g/10 min8–15 g/10 min
    Tensile modulusISO 527-2/1A3.5 GPa3.0–3.3 GPa
    Vicat A softening temperatureISO 306 A50105 °C55–60 °C
    Heat deflection temperature, 0.45 MPaISO 75-2 method B95–105 °C50–55 °C
    Charpy notched impact, 23 °CISO 179-1/1eA2.5 kJ/m²2.0–3.0 kJ/m²

    Machine configuration influences the actual melt history more than the nominal set point. General-purpose screws with L/D ratio of 20:1 to 24:1 and compression ratio of 2.5:1 are recommended; high-shear barrier screws can generate local melt temperatures above 230 °C even when the barrel set point remains at 200 °C, resulting in viscosity loss and black specks. The shot size should be between 50% and 80% of the barrel capacity to limit cumulative residence time and avoid dead spots. Gate design should provide a minimum land length sufficient to freeze after packing, but not so small that shear rates exceed 100,000 s⁻¹ in thin-walled parts; excessive shear causes molecular orientation, warpage, and micro-cracks at the gate. The use of standard hot-runner systems is possible with open-pipe hot runners that do not trap molten PLA in stagnant zones. Purging between colour or material changes should be done with a PLA-based purging compound or a cast-acrylic purging resin; polyolefin purges are incompatible and must be avoided because residual polyethylene or polypropylene phases weaken weld lines and reduce impact strength.

    Rheology, gate shear, and moisture-sensitive degradation pathways

    The melt flow rate of 6 g/10 min at 190 °C and 2.16 kg defines a medium-viscosity PLA suitable for wall thicknesses down to approximately 1.0 mm in simple flow geometries. At processing temperatures, the shear-thinning behaviour of PLA means the apparent viscosity at gate shear rates is substantially lower than capillary viscometry data at low shear rates; however, the compound retains a relatively sharp transition from solid-like to fully molten flow. This produces higher pressure drop in long, thin sections than impact-modified grades. Moulders should use injection speeds fast enough to avoid premature freeze-off but slow enough to prevent jetting; a filling time of 0.5–2.0 s is often appropriate for thin-wall parts. Moisture-related degradation during processing is not linear with time: a small increase in residual moisture from 250 ppm to 500 ppm can reduce melt viscosity by more than half and lower notched impact strength below the expected datasheet range. The odour threshold for thermal degradation is also relatively low; acrid, sweet-smelling fumes indicate lactide formation and should trigger a process audit.

    In production, batch-to-batch variation in melt flow rate is normally controlled by the supplier within ±10% of nominal; incoming melt flow rate verification under ISO 1133-1 at 190 °C/2.16 kg is an effective screening test. Lot changes can shift filling pressure by 5–10 bar in multi-cavity cold-runner tools, particularly where runner balance is marginal. Tooling should therefore provide sufficient pack pressure reserve, and cavity pressure sensors are preferred over machine hydraulic pressure readings when validating process transfer between presses. In thin-wall components, moulds with conformal cooling or beryllium-copper inserts near heavy sections reduce the local temperature differential that otherwise produces sink marks and differential crystallinity. Weld lines remain a known weakness in semi-crystalline PLA because crystallisation across the meeting front is disrupted; keeping venting at the weld line and maintaining melt temperature above 195 °C improves weld-line integrity, but weld strength should be measured on the production tool rather than inferred from bulk tensile data.

    In food-contact applications, the final moulded article must be assessed under Regulation (EU) No 1935/2004 and, where applicable, Regulation (EU) No 10/2011 for overall migration and specific migration limits under intended use. The supplier can provide a raw material compliance statement, but the converter is responsible for validating that storage time at elevated temperature and contact area do not exceed the tested end-use conditions. The grade is not recommended for continuous exposure to boiling water, dishwasher sanitizing cycles above 85 °C combined with high mechanical load, or direct steam sterilisation without thermal ageing validation. It is also incompatible with deliberately added amine-based nucleating agents and certain metal carboxylate additives that can accelerate chain scission; converters should not compound this product with additional masterbatches unless compatibility has been confirmed by capillary rheometry and retained molecular weight testing.

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