| HS Code | 375576 |
| Material Type | Biodegradable polylactic acid (PLA) compound |
| Polymer Base | Polylactic acid (PLA) blend |
| Product Form | Pellets |
| Processing Method | Blown film extrusion |
| Density | approx. 1.25 g/cm³ |
| Melt Flow Rate | approx. 2-4 g/10 min at 190°C/2.16 kg |
| Melting Temperature | approx. 110-120°C |
| Glass Transition Temperature | approx. 55-60°C |
| Vicat Softening Temperature | approx. 55-65°C |
| Tensile Strength | approx. 20-30 MPa |
| Elongation At Break | approx. 300-500% |
| Tensile Modulus | approx. 1000-1500 MPa |
| Biobased Carbon Content | > 50% |
| Biodegradability | Soil degradable |
| Recommended Film Thickness | approx. 20-100 µm |
| Recommended Melt Temperature | approx. 160-180°C |
As an accredited Bio-Flex N 21310 Blown Film Soil-Degradable Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-resistant, foil-lined paper bags on pallets, clearly labeled Bio-Flex N 21310 Blown Film Soil-Degradable Polylactic Acid. |
| Container Loading (20′ FCL) | 20′ FCL: Bio-Flex N 21310 soil-degradable PLA blown film resin, palletized bags, loaded in dry container, ambient, secured for transport. |
| Shipping | Bio-Flex N 21310 is shipped as non-hazardous, soil-degradable PLA pellets in moisture-barrier bags or lined octabins. It is not regulated for transport under DOT, IMDG, or IATA. Keep containers sealed, dry, and away from excessive heat. Handle with standard industrial hygiene; no special shipping labels required. |
| Storage | Store Bio-Flex N 21310 in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and moisture. Keep material in tightly sealed original packaging, preferably at 5–30°C and low humidity. Protect from dust, contamination, and physical damage. Use first-in, first-out stock rotation. Avoid prolonged storage in humid conditions because PLA compounds can absorb moisture, affecting processing. |
| Shelf Life | Shelf life is approximately 12 months when stored dry, below 30°C, away from sunlight, moisture, and contaminants in sealed original packaging. |
Compliance standard for soil-biodegradable mulch film is EN 17033:2018, which in Clause 4.2 requires 90% ultimate soil biodegradation relative to microcrystalline cellulose within 24 months under ISO 17556:2019 at 25 °C ± 2 °C, and Clause 4.3 requires an earthworm acute toxicity test according to ISO 11268-1:2012, plus a plant emergence test according to OECD 208:2006. Formulation addition ratio: 100% Bio-Flex N 21310 as supplied is used for 15–25 µm black mulch on a 45 mm single-screw extruder with L/D 30:1 and a 250 mm spiral mandrel die; where perforated field trials record dart impact failure below 350 g under ISO 7765-1:2018, 20–30 wt% PBAT is blended in the hopper with 2–3 wt% carbon black masterbatch to maintain opacity. Downstream production process: the compound is pre-dried at 80 °C for 4 h in a desiccant dryer to a dew point of −40 °C and moisture below 250 ppm, then extruded at a melt temperature of 168–175 °C with die zone 165 °C, die gap 0.8 mm, blow-up ratio 2.8:1, layflat width 1,100 mm, and frost line height 850–900 mm; in-line perforation at 300 mm spacing for drip irrigation produces holes 8 mm diameter. On a production line, die-lip deposit formation becomes visible after 72 h when hopper moisture exceeds 300 ppm; melt pressure above 180 bar and bubble flutter at the frost line are early process failures requiring a shutdown to purge degraded PLA oligomers. Terminal product types: black and white co-extruded soil-biodegradable mulch films, 12–25 µm thickness, in 1.2 m and 1.5 m rolls. Published data for Bio-Flex N 21310 in the precise 12 µm black mulch configuration is limited; the following table characterises PLA/PBAT blown-film behaviour reported in peer-reviewed agricultural film studies using the same ISO test methods.
| Blend ratio Bio-Flex N 21310 / PBAT (wt%) | Tensile strength MD (MPa, ISO 527-3:2018) | Elongation at break MD (%, ISO 527-3:2018) | Dart impact (g, ISO 7765-1:2018) | Soil biodegradation at 24 months (%, ISO 17556:2019) |
|---|---|---|---|---|
| 100/0 | 38–44 | 180–260 | 180–240 | ≥ 90 |
| 80/20 | 28–36 | 300–400 | 350–480 | ≥ 90 |
| 70/30 | 22–30 | 400–550 | 550–720 | ≥ 90 |
For household organic waste separation, the 18–25 µm blown film is converted into bottom-sealed gusseted caddy liners where certification under EN 13432:2000/AC:2005 and ASTM D6400-21 requires ≥ 90% biodegradation of the organic carbon fraction within 180 days at 58 °C ± 2 °C under controlled composting, and disintegration must leave no more than 10% of original dry mass on a 2 mm sieve after 12 weeks under ISO 16929:2021. Formulation addition ratio: 75–85 wt% Bio-Flex N 21310 with 15–25 wt% PBAT is typical when the 7-day wet waste puncture test shows failure below 1.5 J under ISO 527-3:2018; 1.5–3.0 wt% of a slip/antiblock masterbatch is added to prevent blocking on the winder. Downstream production process: a 50 mm single-screw extruder with L/D 28:1 and a 200 mm mono-layer die runs at melt 165–172 °C, die gap 0.6 mm, BUR 3.2:1, and film gauge 18 µm; in-line perforation at 4–6 mm diameter spaced 50 mm provides air exchange; bag conversion uses constant-heat seal bars at 115–125 °C with 0.3 s dwell and a gusset width of 8–12 cm. Field data from municipal caddy liner production show that moisture above 250 ppm in the compound causes bubble tears at the frost line and lactide deposits on the die face; operators must set the winder contact pressure below 1.2 bar to avoid blocking when the film temperature at the collapsing frame exceeds 38 °C. Polyethylene contamination above 2 wt% causes melt fracture, translucency defects, and non-compostable fragments under EN 13432. Terminal product types: 5 L, 10 L, 20 L, 30 L and 120 L municipal organic waste bags, vented caddy liners, and compostable bin liners.
Compliance standard for printed retail carrier film is EU Directive 94/62/EC Annex II for heavy metal limits (sum of Pb, Cd, Hg, Cr(VI) < 100 mg/kg) and EN 13432:2000/AC:2005 for industrial compostability; US-bound shipments require ASTM D6400-21 and 16 CFR Part 260 for environmental marketing claims. Formulation addition ratio: 100% Bio-Flex N 21310 is used with 2–5 wt% pigment/antiblock masterbatch for colours; when the carrier bag must hold 12 kg for 20 minutes without handle tear, 10–15 wt% PBAT is added and film gauge increases from 22 µm to 30 µm. Downstream production process: the film is blown on a 55 mm extruder with L/D 30:1, die gap 0.8 mm, BUR 3.0:1, then corona treated to 42–46 mN/m for flexo ink adhesion; conversion includes bottom seal, side gussets, and die-cut handle holes, with heat sealing at 110–125 °C and a dwell of 0.25–0.40 s. Melt temperature above 190 °C causes handle-hole stress cracks after storage at 50% RH; static charge above 5 kV at 35% RH causes double sheets, requiring 0.5 wt% antistat masterbatch. Terminal product types: retail carrier bags, boutique shopping bags with soft-loop handles, and promotional film bags.
Root-zone temperature maintenance in horticultural propagation tunnels imposes a 9–18 month above-ground service conflict with the 24-month soil degradation window of EN 17033:2018; for Bio-Flex N 21310, the 25 µm perforated floating film is laid over hoops where the standard's mechanical property provisions for tensile strength above 18 MPa and elongation above 180% under ISO 527-3:2018 remain the key acceptance thresholds. Formulation addition ratio: 100% Bio-Flex N 21310 is used for 3–6 month seed-starting film; for winter propagation exceeding 6 months, 1–2 wt% of a non-azo UV stabilizer masterbatch is added, and 20 wt% PBAT is introduced when 12 × 15 cm root-training pouches must withstand root pressure without splitting. Downstream production process: a 45 mm extruder with L/D 25:1 and a 150 mm die runs at melt 165–170 °C, die gap 0.7 mm, BUR 3.0:1, with in-line perforation holes of 2 mm at 40 mm spacing for aeration; root-pouch fabrication uses a rotary heat sealer at 118 °C and 0.5 s dwell to create non-wicking seams. Terminal product types: propagation tunnel film, nursery root-pouch sleeves, seed-starting strips, and biodegradable plant propagation bags.
Compliance standard for dry goods secondary packaging is EN 13432:2000/AC:2005 for industrial compostability plus EU No 10/2011 for overall migration below 10 mg/dm² where the film directly contacts food; non-food dry goods packaging must still comply with REACH Article 33 communication if SVHC content exceeds 0.1 wt%. Formulation addition ratio: 80–90 wt% Bio-Flex N 21310 with 10–20 wt% PBAT or thermoplastic starch is used to lower seal initiation temperature to 105–115 °C and raise dart impact above 250 g under ISO 7765-1:2018; 1–3 wt% of an antiblock masterbatch and 0.5–1 wt% slip reduce blocking on the winder. Downstream production process: three-layer A/B/A co-extrusion on a 60 mm line with L/D 30:1 places the slip/antiblock masterbatch in the 4 µm skin layers and the reground edge trim up to 30 wt% in the 17 µm core layer; die gap is 0.9 mm, BUR 2.8:1, and melt temperature is 168–175 °C. Published data for Bio-Flex N 21310 in three-layer A/B/A dry goods packaging film is limited; converter trials should validate seal initiation temperature under ISO 527-3:2018 and static heat seal strength under ASTM F88/F88M-20 before committing to high-speed bag machinery. Amine-based masterbatch carriers accelerate ester bond scission in the PLA phase and must be excluded. Terminal product types: transparent dry goods bags, apparel polybags, hardware pouches, and compostable e-commerce mailers.
Where municipal collection of pet faeces must meet home compostability, the 12–18 µm blown film is converted into 250 mm × 300 mm mini-rolls with perforated tear lines and a bottom star-seal that must withstand a 1.0 kg pull force at the seal when tested under ASTM F88/F88M-20. Compliance standard: the pet waste bag must meet EN 13432:2000/AC:2005 or NFT 51-800:2015 for home compostability, with the latter requiring ≥ 90% disintegration within 180 days at ambient home composting temperatures; if certified under ASTM D6400-21, the marketing claim must specify industrial composting conditions. Formulation addition ratio: 70–80 wt% Bio-Flex N 21310 plus 20–30 wt% PBAT is used to prevent puncture from paw pressure, and 1–2 wt% of a process lubricant masterbatch is added to reduce melt fracture at 18 µm gauge. Downstream production process: the film is extruded on a 40 mm single-screw extruder with L/D 25:1 at melt 165–172 °C, die gap 0.5 mm, BUR 3.5:1, then converted on a rotary bag machine with photoelectric registration at 300 bags/min; a dwell of 0.2 s at 120 °C seals the star bottom without pinholing. Terminal product types: home-compostable dog waste bags, pet litter liners, and diaper disposal bags.
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Polylactic acid compounds intended for blown film are specified by melt-flow response, melt strength, and soil-biodegradation kinetics rather than the injection-molding rheology of unmodified PLA. Bio-Flex N 21310 Blown Film Soil-Degradable Polylactic Acid is processed as a compound in which PLA forms the renewable backbone and a biodegradable copolyester or plasticizer contributes melt extensibility. The material is dried before extrusion at 60 °C for 4 h to achieve residual moisture below 250 ppm; undried pellets exposed to relative humidity above 60 % RH can exceed 0.4 % moisture, producing hydrolytic chain scission, bubble perforation, and a 20–40 % loss in tensile elongation. Melt-flow control is determined by ISO 1133-1:2022 at 190 °C under 2.16 kg, with typical values for this film grade in the 3.5–5.0 g/10 min interval. Density measured by ISO 1183-1:2019 is approximately 1.25–1.27 g/cm³. The grade is used in short-life flexible packaging, agricultural mulch film, and compostable waste bags where film toughness must be achieved without abandoning renewable carbon content. Because soil-degradation half-lives are matrix-specific, converter-side validation under the intended soil pH and temperature is required. Processors attempting to run this grade on low-shear, general-purpose polyethylene screws often see gel formation and bubble tears; barrier screws with 25:1–30:1 L/D ratios are specified for stable output.
| Property | Test method | Representative value |
|---|---|---|
| Melt flow rate, 190 °C, 2.16 kg | ISO 1133-1:2022 | 4.0 g/10 min |
| Density | ISO 1183-1:2019 | 1.26 g/cm³ |
| Tensile strength at break, machine direction | ISO 527-3:2018 | 38 MPa |
| Tensile strength at break, transverse direction | ISO 527-3:2018 | 30 MPa |
| Elongation at break, machine direction | ISO 527-3:2018 | 300 % |
| Elongation at break, transverse direction | ISO 527-3:2018 | 350 % |
| Tensile modulus, machine direction | ISO 527-3:2018 | 900 MPa |
| Elmendorf tear, machine direction | ISO 6383-2:1983 | 16 N/mm |
| Elmendorf tear, transverse direction | ISO 6383-2:1983 | 20 N/mm |
| Dart drop impact F50 | ASTM D1709A | 5.5 g/µm |
| Moisture content after drying | ISO 15512:2019 | <250 ppm |
Representative values for a 25 µm blown film; verify against the current certificate of analysis before specification.
Polymer melt temperature at the die lip is held between 150 °C and 175 °C. At feed throat temperatures below 40 °C, pellet bridging occurs because softened PLA granules can compact in the grooved feed section. Barrel zone settings typically start at 145 °C in the feed compaction zone, 155 °C in the compression zone, 165 °C in the metering zone, and 160 °C in the die adapter; melt temperatures above 180 °C initiate lactide reformation and plate-out on the die lip, observable as white deposits. Die temperature variation should be limited to ±5 °C around the setpoint; wider swings create gauge bands and bubble flutter. Extruders with 25:1–30:1 L/D ratios and double-flight barrier screws produce the most stable melt curtains; low-shear general-purpose screws can leave unmelted PLA gels that break the bubble at drawdown ratios above 3:1. Die gap is maintained at 0.8–1.2 mm, and blow-up ratio is kept between 2.5:1 and 3.5:1. Frost line height is set within 2–5 die diameters; excessive frost line distance increases transverse direction orientation and causes CD shrink above 9 % at 60 °C hot-air exposure. Melt pressure before the filter pack is normally below 320 bar; higher values indicate screw wear or excessive moisture. Dual-lip air rings with venturi cooling are specified for high-stalk bubble stability. At drawdown ratios below 3:1, the bubble can sag and contact the air ring, while ratios above 7:1 can create machine-direction weak tear paths.
Where Bio-Flex N 21310 replaces unmodified PLA 4032D film, the most significant departure is elongation at break. Unmodified PLA blown film typically fails at 4–8 % elongation under ISO 527-3:2018, whereas this grade is formulated to exceed 250 % in the machine direction. The modulus falls from roughly 3500 MPa for unmodified PLA to 900–1200 MPa, which reduces stiffness but allows conversion on conventional bag-winding equipment without microcracking at fold lines. Against PBAT-rich flexible film compounds, Bio-Flex N 21310 exhibits higher tensile modulus and lower low-temperature impact toughness. A PBAT-dominant film may show tensile modulus below 200 MPa and dart-drop values above 10 g/µm; this PLA-based grade is stiffer and may show reduced impact at 0 °C unless the formulation is tuned with a higher copolyester fraction. Compared with PBAT-rich alternatives, the grade offers a higher renewable carbon fraction, although exact bio-based content is measured by ASTM D6866 or EN 16640, and supplier documentation is required.
| Comparison parameter | Bio-Flex N 21310 | Unmodified PLA 4032D | PBAT-rich film |
|---|---|---|---|
| Tensile modulus | 900–1200 MPa | 3500 MPa | 80–200 MPa |
| Elongation at break, machine direction | 250–350 % | 4–8 % | 400–700 % |
| Dart drop impact F50 | 5–7 g/µm | 1–2 g/µm | 10–15 g/µm |
| Melt temperature range | 150–175 °C | 160–180 °C | 130–160 °C |
| Degradation mechanism | Bulk hydrolysis of PLA phase | Bulk hydrolysis, slow ambient soil | Enzymatic surface erosion of aliphatic-aromatic copolyester |
In 25 µm film, seal initiation temperature on side-seal equipment is typically 95–105 °C; because PLA-based films are stiffer and more heat-sensitive than LDPE, seal jaws must be PTFE-coated with dwell times of 0.3–0.5 s. Corona discharge is set to 38–42 mN/m wetting tension; levels above 50 mN/m produce surface oxidation without improving lamination adhesion. Ink adhesion under ISO 2409 cross-cut requires a minimum level of 40 mN/m. Coefficient of friction measured by ISO 8295:1995 should be specified with slip masterbatch because neat PLA films can exhibit static coefficient of friction above 0.6. Blocking pressure at 50 °C can exceed 0.8 N/cm² when stored without antiblock; the film must be cooled below 35 °C before contact winding. Flexographic printing with water-based ink systems is preferred; ethyl acetate in solvent-based inks can attack exposed PLA surfaces and reduce heat-seal strength by more than 10 %.
Quality-control release should include film gauge measurement by ISO 4593:1993 after 50 m of line output. A gauge variation above ±5 % across the web width is normally corrected by adjusting die gap rather than air-ring pressure. The grade is not intended for injection molding or thermoforming without independent melt-rheology adjustment. In agricultural mulch, film thickness is typically 12–25 µm; in compostable waste bags, 20–50 µm is common. Exact capillary rheometry data are not published in the supplier datasheet and should be measured before die geometry decisions are finalized.
Under ISO 17556:2019, soil biodegradation is measured as the percentage of theoretical CO₂ evolved during the test period; a PLA compound may require 6–24 months depending on soil temperature. Because PLA hydrolysis is temperature-dependent, burial at 25 °C proceeds slowly; soil contact alone does not guarantee rapid mass loss. Composting certification under EN 13432:2000 requires 90 % mineralization within 180 days at 58 °C, which is a different biological environment from ambient soil. Therefore, a soil-degradable claim for Bio-Flex N 21310 should be supported by project-specific testing in the target soil, and not inferred from industrial compostability certificates alone. Field data on production-scale blown film equipment indicate that bubble stability in the 150–175 °C window responds to changes in ambient relative humidity; converters running at RH above 60 % without moisture-controlled hoppers observe intermittent gel formation and splice failures at the winder. If a film must satisfy home compostability, AS 5810 or NF T51-800 is tested separately because EN 13432 is an industrial-composting standard and does not cover ambient soil or home compost conditions.