| HS Code | 598214 |
| Polymer Type | High Density Polyethylene (HDPE) |
| Density | 0.952 g/cm³ |
| Melt Index | 0.25 g/10 min |
| Tensile Strength At Yield | 26 MPa |
| Tensile Elongation At Break | 600% |
| Flexural Modulus | 1100 MPa |
| Notched Izod Impact Strength | 80 J/m |
| Shore D Hardness | 65 |
| Vicat Softening Point | 125 °C |
| Heat Deflection Temperature | 75 °C at 0.46 MPa |
| Melting Point | 130 °C |
| Brittleness Temperature | -70 °C |
| Environmental Stress Crack Resistance | >1000 h |
As an accredited Bamberger Polymers HDPE 3252 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Bamberger Polymers HDPE 3252 is packaged in 25 kg (55 lb) polyethylene-lined bags, typically palletized and shrink-wrapped for secure shipment. |
| Container Loading (20′ FCL) | Bamberger Polymers HDPE 3252 in 25 kg bags, palletized, loaded and secured into a 20′ FCL container for ocean transport. |
| Shipping | Bamberger Polymers HDPE 3252 is a non-hazardous polyethylene resin. It is typically shipped in 25 kg bags, stacked on pallets, stretch-wrapped, and transported in dry trailers, railcars, or intermodal containers. Keep dry, clean, and away from direct sunlight, moisture, and contamination. No special DOT placarding required. |
| Storage | Store Bamberger Polymers HDPE 3252 in a cool, dry, well-ventilated warehouse away from direct sunlight and ignition sources. Keep original containers closed, palletized, and off the floor. Protect from moisture, heat, and strong oxidizers. Minimize dust generation and accumulation; use grounding/bonding where dust may occur. Follow the manufacturer’s SDS and all local storage regulations. Avoid excessive stacking. Inspect containers regularly. |
| Shelf Life | Shelf life is 12 months from manufacture when stored in a cool, dry, well-ventilated area away from direct sunlight. |
Extrusion blow molding of tight-head 220-L industrial drums from Bamberger Polymers HDPE 3252 is run on accumulator-head machines with extruder L/D between 24:1 and 30:1 and a grooved feed throat maintained at 40–60°C. The material is processed at melt temperatures of 190–230°C; die gaps are set between 1.5–2.5 mm because the grade's high-molecular-weight distribution produces die swell ratios of 45–60%. A nominal melt flow index of 0.25 g/10 min at 190°C/2.16 kg per ASTM D1238-23 and a density of 0.952 g/cm³ per ASTM D1505-18 place the resin in the HMW-HDPE extrusion blow molding class. Parison sag is suppressed by dividing the wall-thickness program into 30–50 discrete points; top shoulder and lower chime segments carry 25–35% greater wall stock than the body. Accumulator ram speed is set between 350–600 mm/s, and pre-blow delay is held at 1.2–1.8 s to allow the parison to seat at the pinch-off without pleating. Blow air enters through a central blow pin at 0.6–0.8 MPa; mold surfaces are cooled with closed-loop chiller water at 20–40°C. Cycle time for a 220-L drum is 120–180 s. Flash is trimmed on rotary deflashers, and regrind is reintroduced at up to 30 wt% only after lot-by-lot melt flow ratio drift is kept within ±5%. Finished drums intended for hazardous liquids are tested under 49 CFR 178.509 and marked UN 1H1/Y1.5/100 when the 1.5-m cold-condition drop test at −18°C and a 100 kPa hydraulic pressure test are passed. Environmental stress crack resistance is measured on sidewall plaques per ASTM D1693-15 Condition B at 50°C in 100% Igepal CO-630; published data for this specific grade should be taken from the supplier certificate of analysis, and aromatic solvent compatibility must be confirmed through production-scale permeation trials because no single ESCR value covers all oxygenated formulations.
In six-layer coextrusion of 20-L agricultural chemical jerricans, Bamberger Polymers HDPE 3252 is used as the structural layer while ethylene-vinyl alcohol copolymer is inserted as the active barrier at 3–5 wt% of the total wall. Layer sequencing is determined by the permeant class: for cyclohexanone and xylene-based formulations, the EVOH layer is shifted to 35–45% of the cross-section from the outer surface, and the two tie layers of maleic anhydride-grafted HDPE are held at 2–3 wt% each to maintain interlayer adhesion after sidewall peel specimens are pulled at 100 mm/min. HDPE 3252 melt temperatures are held between 220–230°C, tie resin at 200–215°C, and EVOH at 195–210°C. The die head is fitted with a radial distributor; each layer's orbital feed block is independently controlled to avoid layer inversion at the pinch-off, where the regrind layer may reach 40 wt% of the total structure. Total wall thickness is specified at 1.5–2.2 mm, with post-mold dimensions verified per ASTM D2911-15 for plastic bottle and jar dimensional stability. Drop impact resistance is tested by ASTM D2463-15, top load by ASTM D642-20, and stack vibration by ASTM D999-08 Method A. For UN packaging of agricultural chemicals, the closure system is torque-tested to 2.0–2.5 N·m and the container must pass a 1.2-m drop at 0°C under the applicable packing group. The structure must not be used for food contact unless the EVOH and tie layers are supported by separate 21 CFR 177.1360 or equivalent listings, and Bamberger Polymers HDPE 3252 itself is assessed under 21 CFR 177.1520(c) 3.2a for olefin polymers.
On 65-mm single-screw corrugated pipe lines, HDPE 3252 is introduced as the virgin carrier resin in a dry blend with carbon black masterbatch at 2.0–2.5 wt% and an acid scavenger/antioxidant preblend at 0.1–0.3 wt%. The compound is plastified in a 30:1 L/D barrier screw with barrel temperatures from 180–215°C and die temperature of 190–205°C. The corrugator vacuum holds the parison against mold blocks at −60 to −80 kPa, while spray cooling water is maintained at 10–25°C. Pipe wall thickness is set between 0.8–1.2 mm for 150-mm inner diameter drainage pipe, and the corrugations are formed at a pitch of 25–35 mm. Finished pipe compressive resistance is measured per ASTM D2412-21; the common specification floor of 320 kPa for Type S pipe must be confirmed against local project requirements. Impact resistance is evaluated by ASTM D2444-21 at −20°C using a falling weight; because HDPE 3252 has a low melt index, the weld line at the corrugation root is the principal failure mode and must be examined under 20× magnification. The material is handled in outdoor drainage service under AASHTO M294-22 or local DOT equivalent; UV stabilization is achieved only when the carbon black masterbatch produces a final carbon black content of 2.0–3.0 wt%, and not by the natural resin alone. Regrind from punch-outs and start-up scrap is limited to 25 wt%; excess regrind increases melt pressure at the screen changer by 3–6 MPa and reduces parison drawdown consistency. Moisture-related splay is controlled by pre-drying at 70–80°C for 2–3 h when ambient relative humidity exceeds 60%.
| Process variable | 220-L industrial drum blow molding | Corrugated drainage pipe extrusion | Shuttle thermoforming of HDPE 3252 sheet |
|---|---|---|---|
| Melt temperature, barrel-to-die set point | 190–230°C | 180–215°C | 150–165°C sheet core |
| Extruder L/D ratio | 24:1–30:1 | 30:1 with barrier screw | 33:1 |
| Cooling medium | chilled mold 20–40°C | water spray corrugator 10–25°C | roll stack 70–90°C |
| Typical wall thickness | 2.0–2.8 mm | 0.8–1.2 mm | 3.0–6.0 mm |
| Regrind ceiling | 30 wt% | 25 wt% | 50 wt% |
From flat-die sheet lines, HDPE 3252 sheet enters shuttle thermoforming stations as cut sheet blanks rather than roll-fed web. Extruders for 3.0–6.0 mm sheet use a 33:1 L/D screw and a die width of 900–1200 mm; roll stack temperatures are maintained at 70–90°C to reduce locked-in orientation. Sheet is cut to blank dimensions and reheated to 150–165°C core temperature in a shuttle oven with upper and lower ceramic elements. Vacuum forming draws the sheet into the tool at −70 to −90 kPa; mold temperature is kept at 30–40°C to limit post-demold shrinkage to less than 1.0% in length. High-molecular-weight HDPE sheet requires sag control via a photoelectric eye because the low melt index of 0.25 g/10 min produces high hot strength but also generates uneven sag if localized overheating exceeds 170°C. Holes, lip returns, and stacking lugs are trimmed in a matched metal trim press; scrap fractions of 30–50 wt% are typical and can be ground and returned to the extrusion line. Load-bearing behavior of the formed tray is measured by ASTM D642-20 for compressive resistance; tensile yield of the sheet is determined by ASTM D638-22 and flexural modulus by ASTM D790-17. Dunnage trays used in automotive returnable packaging are checked for dimensional recovery after 24 h at 60°C following ASTM D648-18 deflection-temperature principles. This application is not for direct food contact; if incidental food contact is proposed, separate verification under 21 CFR 177.1520(c) 3.2a is required. The grade is not suitable for deep-draw parts with a draw ratio greater than 1.0:1 unless plug assistance is used, because the high melt elasticity causes corner thinning and stress whitening at the bottom radii.
For geomembrane projects where a natural pellet must be compounded into a carbon-black-stabilized liner, preliminary oxidative-induction-time data at 200°C per ASTM D3895-19 are required before extrusion. Bamberger Polymers HDPE 3252 with density 0.952 g/cm³ and melt flow index 0.25 g/10 min can be considered within the GRI-GM13 resin envelope only if the formulated sheet exhibits tensile yield strength above 27 MPa and elongation at break above 700% when tested per ASTM D638-22 Type IV specimens. The compound must contain carbon black at 2.0–3.0 wt% and a stabilizer package sufficient to produce standard OIT values above 100 min at 200°C; published data for this specific grade in geomembrane formulation are limited, and the converter must run a pilot flat-die or blown-film trial to establish lot-specific stress crack resistance. Seam performance is evaluated by ASTM D6392-20 for shear and peel, and notch-sensitive constant tensile load testing per ASTM D5397-20 is used to confirm surfactant resistance at 30% yield stress in 10% Igepal solution at 50°C. Extrusion of the sheet is performed on a 150-mm flat die line at melt temperature 210–230°C, with a 2.0-mm sheet thickness maintained by a three-roll calender. Wrinkling and calender build-up are controlled by maintaining a melt bank of 5–10 mm at the nip. This application is not a direct drop-in use of natural HDPE 3252; the absence of UV stabilizer and carbon black in the base pellet means outdoor exposure will cause rapid embrittlement unless compounding is performed under controlled masterbatch addition. Avoid blending with polypropylene or polyethylene grades outside density 0.940–0.955 g/cm³, as immiscible inclusions create weld-line weaknesses in the liner.
Closed-loop regrind employment on open-head 20-L pail lines alters die swell and sag independently of melt temperature. Bamberger Polymers HDPE 3252 at virgin melt index 0.25 g/10 min shifts to 0.30–0.40 g/10 min after two passes through a 50-mm extruder, depending on residence time and screw speed. A regrind fraction of 40 wt% requires a die gap reduction of 8–15% because die swell falls from 45–60% to 30–45%, and parison sag increases by 10–15% at the same melt temperature. The open-head pail wall is specified at 0.8–1.2 mm; blow air at 0.5–0.7 MPa and mold cooling at 15–30°C produce a cycle time of 25–40 s. Top-load strength is measured by ASTM D642-20; the pail must retain a minimum of 1.5 kN before stacking failure for industrial lubricant and construction adhesive service. The impact at low temperature is checked by ASTM D2463-15 after conditioning at −10°C. Because post-consumer or post-industrial regrind may contain polypropylene contamination, the blend must be screened at 2 wt% maximum polypropylene by melt filtration and differential scanning calorimetry; higher levels create visible delamination at the pinch-off and reduce drop impact by 30–50%. A top-up antioxidant package at 0.05–0.15 wt% is added when regrind exceeds 20 wt% to counter oxidative degradation from the additional heat history. Open-head pails for liquid coatings and detergent products are qualified under 49 CFR 178.509; the specific UN marking is assigned only after the closure ring and gasket pass leak testing at 30 kPa for 10 min. The grade is not recommended for pail lids thinner than 0.5 mm because low-flow HDPE requires excessive clamp tonnage in injection molded lids; compression or blow molded lids are preferred.
In microduct outer-layer coextrusion, line speed and tooling calibration remain the primary variables controlling residual ovality. Bamberger Polymers HDPE 3252 is processed as the outer sheath of 10/8-mm or 12/10-mm microduct tubes on a 45-mm single-screw extruder with a 24:1 L/D screw at barrel temperatures of 190–220°C. A carbon black masterbatch is added at 2.0–2.5 wt% because the base resin contains no UV stabilizer; the final outer sheath must exhibit carbon black content of 2.0–3.0 wt% per ASTM D3350-21 cell classification reporting. Vacuum calibration sleeves hold outer diameter tolerance to ±0.05 mm, and line speed is set between 12–25 m/min. Residual ovality is measured with a shadow-graph micrometer and must remain below 0.15 mm for pull-force reduction. The tube is subjected to ring crush resistance per ASTM D2412-21 and impact resistance at −20°C per ASTM D2444-21. Low-temperature flexibility is evaluated by bending around a mandrel of 10× outer diameter without cracking. The material's high melt viscosity provides adequate crush resistance for fiber optic microduct but limits ultra-thin wall extrusion below 0.5 mm; at thicknesses below this threshold, melt pressure rises above 25 MPa and surface melt fracture may appear unless a wider die gap with draw-down ratio under 2.0:1 is used. The grade should not be combined with amine-based acid scavengers or high-acid adhesion promoters in this application, as these additives can reduce the oxidative induction time and shift the carbon-black dispersion quality under ASTM D3015-19 microscopic examination.
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Table 1 summarizes manufacturer-published typical property values. These values are nominal data and should not be interpreted as specification limits for every lot.
| Property | Test method | Typical value | Unit |
|---|---|---|---|
| Melt flow rate | ASTM D1238 | 0.30 | g/10 min |
| Density | ASTM D1505 | 0.955 | g/cm³ |
| Tensile strength at yield | ASTM D638 | 28.0 | MPa |
| Elongation at break | ASTM D638 | 800 | % |
| Flexural modulus | ASTM D790 | 1,100 | MPa |
| Notched Izod impact strength | ASTM D256 | 5.0 | kJ/m² |
| ESCR, 10% Igepal CO-630, Condition B | ASTM D1693 | >600 | h |
| Vicat softening temperature | ASTM D1525 | 126 | °C |
| Hardness Shore D | ASTM D2240 | 66 | — |
On a 60 mm grooved-barrel extruder with 24:1 L/D and a barrier screw, the barrel temperature profile is set between 180 °C and 210 °C. Head and die zones are held at 190–205 °C, while the melt is kept below 230 °C to avoid thermo-oxidative chain scission and color body formation. Mold temperature for extrusion blow molding is maintained at 10–25 °C with aluminum or beryllium-copper tooling; internal blow-pin cooling reduces cycle time. For containers in the 0.5–5 L range, the die gap is set between 1.5 mm and 2.5 mm. A gap below 1.5 mm increases shear heating at the die land and may destabilize melt temperature; a gap above 2.5 mm can produce uncontrolled parison weight variation. Parison sag in this grade is sufficiently low that a 1 L container with a 35 g shot weight typically runs at a hang time of 2–4 s; longer hang time requires a lower melt temperature or verification of melt strength on the specific tool.
Pre-drying is not required for sealed feed stored below 50% RH. When bags are exposed to ambient humidity above 60% RH, the resin should be dried in a desiccant hopper dryer at 80 °C and a dew point of −20 °C for at least 2 h. Extruder vent vacuum does not remove surface moisture reliably and is not a substitute for hopper drying. The base stabilization package contains hindered phenolic antioxidants and phosphite process stabilizers; formulation modification with amine-based processing aids should be avoided in high-shear zones because amine-functional additives can intensify color body formation and shift the oxidation induction time.
On an 8-station shuttle blow molder fed by a 60 mm extruder, die-head pressure is typically observed in the 18–25 MPa range at screw speeds of 30–45 rpm. Pressure above 28 MPa is an early warning of screen pack fouling, excessive regrind fines above 5 wt%, or melt temperature drift below 180 °C. Under such conditions, parison thickness control deteriorates before catastrophic failure occurs.
In comparison with high-flow injection-molding HDPE grades, HDPE 3252 is not a drop-in substitute for thin-wall closure or cap molding. High-flow grades with melt flow rates of 15–30 g/10 min are preferred for injection molding to reduce injection pressure and filling time. HDPE 3252 may be injection molded only in thick-section articles with low length-to-thickness ratios; the melt temperature must be raised to 220–230 °C and injection speed reduced to avoid jetting, but published data for this specific configuration is limited.
Sheet extrusion with HDPE 3252 is run at melt temperatures of 190–215 °C on single-screw extruders of 90–120 mm diameter and 30:1 L/D with flexible-lip dies. Polished chrome roll stacks are maintained at 70–90 °C to control gloss and minimize internal stress. Sheet thickness from 0.5 mm to 6.0 mm is within normal capability; thickness control tighter than ±3% requires beta- or X-ray gauging with closed-loop die bolt adjustment.
Environmental stress crack resistance is the primary property separation between HDPE 3252 and high-flow injection HDPE. The nominal ESCR exceeds 600 h under Condition B with 10% Igepal CO-630 at 50 °C according to ASTM D1693. High-flow injection grades typically fail between 1 h and 10 h under the same test because lower molecular weight reduces tie-molecule density and accelerates crack propagation through spherulitic boundaries. In rigid packaging for household cleaners, detergents, agricultural chemicals, and photoinitiator-containing formulations, stress cracking initiates at pinch-off flash, handle notches, and sidewall scratches. The high molecular weight and branching distribution of HDPE 3252 improve craze stabilization, but the material is not resistant to aggressive aromatic solvents. Containers exposed to high concentrations of toluene, xylene, or ketones should be qualified by compatibility testing under ASTM D543 rather than by ESCR alone.
Migration kinetics in HDPE are diffusion-limited through the amorphous phase; nonpolar solvents can permeate even when the polymer does not swell. This means chemical compatibility for packaging cannot be inferred from density or ESCR alone. Compared with HMW film HDPE grades having MFR values of 0.05–0.15 g/10 min, HDPE 3252 has higher density and generally a narrower molecular weight distribution. This lowers extrusion head pressure and improves surface finish in sheet and blow molding, but may reduce dart impact in thin-gauge film. Compared with medium-molecular-weight blow molding grades with MFR values of 0.7–1.5 g/10 min, HDPE 3252 retains higher melt strength and ESCR but demands lower screw speed and higher extruder torque.
Representative class data are shown in Table 2; the high-flow and HMW film ranges are typical industry values, not Bamberger product specifications.
| Material class | Melt flow rate | Density | ESCR | Dominant process |
|---|---|---|---|---|
| Bamberger HDPE 3252 | 0.30 g/10 min | 0.955 g/cm³ | >600 h | Extrusion blow molding, sheet |
| High-flow injection HDPE | 8–20 g/10 min | 0.950–0.960 g/cm³ | 1–10 h | Injection molding |
| HMW film HDPE | 0.05–0.15 g/10 min | 0.945–0.955 g/cm³ | >500 h | Blown film |
Oscillatory shear rheometry at 190 °C from 0.1 rad/s to 100 rad/s is used to track batch-to-batch consistency. The cross-over frequency at which storage modulus equals loss modulus serves as an internal branching index. A shift in cross-over frequency without a corresponding shift in melt flow rate indicates a change in molecular weight distribution or branching, and should trigger re-qualification of parison sag and ESCR before release to blow molding. Capillary rheometry at 190 °C over apparent shear rates of 10 s⁻¹ to 1000 s⁻¹ is used for die pressure prediction; power-law index values for this high-molecular-weight grade are lower than for injection-molding HDPE, producing a more shear-thinning response that assists extrusion but complicates injection mold filling.
Batch-to-batch variance in HDPE 3252 is most evident in die swell and parison length rather than in melt flow rate. Production sites record an average die swell at 180 °C and 30 s⁻¹ wall shear rate; a departure beyond ±5% from the site baseline requires adjustment of parison programming, especially for handleware where wall thickness at the pinch-off must remain above 1.0 mm.
Post-industrial regrind from HDPE 3252 is routinely reworked at 20 wt% without significant loss of top-load strength in blow-molded containers. At 30 wt%, melt flow rate may rise by 0.02–0.05 g/10 min per pass as chain scission accumulates, and notched Izod impact can decrease by 10–15%. Regrind above 40 wt% is not recommended without lot qualification of melt flow rate, ESCR, and die swell because parison length control becomes erratic on accumulator-head machines.
At regrind loading above 30 wt%, bulk density of the feed mixture can vary from 0.50 g/cm³ to 0.58 g/cm³ depending on grinder screen geometry and moisture. Gravimetric hopper loading is necessary because volumetric screw dosing can produce output fluctuations up to 8% and corresponding parison weight variation. Screen pack configuration should be 20/40/80 mesh to trap fines and gels. Melt pressure should be monitored continuously; an increase above 25 MPa indicates gel accumulation, requiring screen change. If optical defects in the bottle wall increase or drop-impact failures occur at low temperature, the regrind fraction is reduced to 20 wt% or the regrind is diverted to noncritical sheet. For containers classified as dangerous goods packaging, drop impact and stack load testing should be repeated after any regrind ratio change because regrind history alters parison weld integrity and pinch-off crack resistance.
Thermogravimetric analysis in nitrogen indicates no significant mass loss below 300 °C; however, extended residence time above 230 °C in the barrel is more relevant to processing than TGA onset because rheological changes and oxidation precede main-chain degradation. Purge with a lower-viscosity HDPE or polyolefin purge compound before shutdown. Avoid direct addition of acid-functional additives or high levels of unsaturated oils because they can reduce oxidation induction time and shift ESCR.
Regulatory status is supported by the manufacturer's statement. The grade is based on olefin polymers that are listed under FDA 21 CFR §177.1520(c)3.1a for food-contact use, subject to end-use limitations and migration testing in the intended food simulant. REACH obligations are governed by EC 1907/2006; the manufacturer-supplied declaration should be reviewed for SVHC content. RoHS Directive 2011/65/EU applies only when the material is incorporated into electrical and electronic equipment; packaging applications are generally outside the scope. Density and melt flow rate test methods are aligned with ISO 1183-1 and ISO 1133-1, respectively. Users should retain lot-specific certificates and verify that conversion to food-contact or dangerous-goods packaging is covered by the final article test program.