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Asrene LLDPE UF1810T

    • Product Name: Asrene LLDPE UF1810T
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 367190
    Density 0.918 g/cm³
    Melt Flow Index 190 C 2 16kg 1.0 g/10 min
    Melting Point 121 °C
    Vicat Softening Point 97 °C
    Tensile Strength At Yield 11 MPa
    Tensile Strength At Break 30 MPa
    Elongation At Break 700 %
    Flexural Modulus 280 MPa
    Shore Hardness D 55
    Brittleness Temperature -70 °C

    As an accredited Asrene LLDPE UF1810T factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Asrene LLDPE UF1810T is supplied in 25 kg polyethylene bags, palletized and stretch-wrapped for safe handling and transport.
    Container Loading (20′ FCL) 20′ FCL container loading of Asrene LLDPE UF1810T: bagged resin on pallets, securely stowed, ready for safe transport.
    Shipping Asrene LLDPE UF1810T is shipped as non-hazardous plastic resin pellets in sealed bags or bulk containers. Protect from moisture, direct sunlight, and excessive heat during transit. Keep dry and well-ventilated, avoid heavy pressure to prevent bag damage. Standard freight handling applies; no special chemical restrictions required.
    Storage Store Asrene LLDPE UF1810T in a cool, dry, well-ventilated area, away from direct sunlight, heat, and open flames. Keep containers tightly sealed to prevent moisture contamination and dust accumulation. Avoid contact with strong oxidizers. Maintain stable temperatures; no special hazardous storage required, but follow good housekeeping practices.
    Shelf Life Under proper storage conditions (cool, dry, away from sunlight), Asrene LLDPE UF1810T retains properties for 12-24 months.
    Application of Asrene LLDPE UF1810T

    In blown-film conversion of Asrene LLDPE UF1810T for heavy-duty sack and flexible intermediate bulk container liner production, the resin is processed on a single-screw extruder with 30:1 L/D, a barrier-type screw, and a die gap set between 2.0 mm and 2.8 mm. The melt temperature is maintained at 180–210 °C, with a barrel profile from feed zone to die commonly set at 150–160 °C, 170–180 °C, 185–195 °C, and 190–210 °C. Blow-up ratio is constrained to 2.0–2.8 because higher blow-up ratios increase transverse orientation and puncture resistance but reduce machine-direction tear propagation in downgauged film. The grade is characterised by a nominal density of 0.918 g/cm³ per ISO 1183-1:2019 and a melt flow rate of 1.0 g/10 min at 190 °C under 2.16 kg load per ISO 1133-1:2022. These values place the resin in a process window where bubble stability is adequate on dies up to 400 mm, but high-shear die lip stress can initiate sharkskin melt fracture unless a polymer processing aid is used. A fluoroelastomer processing aid at 0.02–0.1 wt% is typically injected via masterbatch to suppress melt fracture at shear rates above 400 s⁻¹. For heavy-duty sack film at 25 µm, dart impact testing per ISO 7765-1 or ASTM D1709 Method A is commonly used, and acceptance values are generally set above 300 g; published data for UF1810T-specific dart impact at every thickness is limited, so production-line samples should establish the exact acceptance band. Blending with autoclave LDPE at 20–30 wt% raises melt strength and widens the bubble stability envelope, while addition of 2–4 wt% slip/antiblock masterbatch controls blocking in roll stock. Edge trim regranulation above 15 wt% creates gel counts that produce visible protrusions in 50 µm and thinner film, and online screen changers with 100–150 µm mesh are required when rework exceeds this threshold. No pre-drying is required unless resin has been stored in unheated silos at relative humidity above 60% and the silo wall temperature is below the dew point; surface condensation can introduce break defects at the frost-line.

    What Limits Heat-Seal Integrity in Coextruded Frozen Food Packaging?

    The coextruded frozen food film structure typically comprises a low-seal-initiation sealant layer based on UF1810T, a tie layer, an EVOH or polyamide barrier core, and an outer layer of HDPE or LDPE for abuse resistance. Seal initiation temperature for this melt flow class of linear low-density polyethylene is commonly evaluated by stepwise heat-seal testing per ASTM F88 and falls in the 95–115 °C range at 0.5 s dwell and 1.0 N/mm² seal pressure; actual settings depend on film thickness, seal bar geometry, and coextrusion layer ratio. Hot tack is measured per ASTM F1921 and is limiting at vertical form-fill-seal speeds above 60 packs/min when the sealant layer thickness is insufficient to dissipate heat. The UF1810T sealant layer is typically run at 20–35% of total film thickness, with die gap 1.8–2.4 mm and blow-up ratio 2.0–2.5. Melt temperature is held at 185–215 °C; above 215 °C, oxidative degradation of the sealant layer increases low-molecular-weight species that migrate to the seal surface and reduce seal strength after 6–12 months of frozen storage. For 40 µm three-layer frozen food film, seal strength per ASTM F88 often reaches 12–18 N/25 mm at 110 °C, but values below 8 N/25 mm after sealing at 100 °C indicate poor seal-bar contact or incomplete sealant layer coverage. Food-contact compliance for the sealant layer is evaluated under FDA 21 CFR 177.1520 and EU No 10/2011 with overall migration limits below 10 mg/dm². The film should not be used for retort packaging above 121 °C because seal strength drops rapidly and the sealant layer can delaminate from the barrier core; frozen food packaging with a maximum use temperature of −25 °C to 80 °C is the practical service window.

    Downstream processMelt temperature rangeDie gapKey test methodTypical failure mode
    Heavy-duty sack blown film180–210 °C2.0–2.8 mmISO 7765-1, ASTM D1709Melt fracture, bubble instability
    Coextruded frozen food sealant layer185–215 °C1.8–2.4 mmASTM F88, ASTM F1921Low hot tack, seal delamination
    Agricultural silage and greenhouse film185–210 °C2.2–3.0 mmEN 13206, ISO 4892-2Stabiliser migration, gauge variation
    Extrusion lamination260–290 °C0.6–0.8 mmISO 11339, ASTM D1876Neck-in, melt resonance, poor adhesion
    Surface protection film190–220 °C2.0–2.4 mmASTM D3330, ASTM D1003Peel adhesion drift, gel protrusions

    Agricultural silage film configured as 25–35 µm stretch-wrap relies on mechanical cling obtained from polyisobutylene at 1–3 wt% addition and a high degree of machine-direction elongation. The UF1810T layer is blended with 10–20 wt% EVA containing 14–18 mol% vinyl acetate to improve cling, puncture resistance, and low-temperature flexibility. In greenhouse cover film, UF1810T is placed in the outer layers of a three-layer coextruded structure with EVA in the core to retain thermicity; total film thickness is typically 180–200 µm. The outer layers provide puncture resistance against hail and abrasion, while the core layer contributes thermal retention and flexural softness. UV stabilisation is achieved with a hindered amine light stabiliser masterbatch at 0.3–0.6 wt% active HALS and a UV absorber at 0.2–0.4 wt% active component, pre-dispersed before extrusion to avoid agglomerates that act as stress concentrators. Accelerated weathering per ISO 4892-2:2013 is run for 3,000–5,000 h depending on intended service life; a loss of tensile elongation beyond 20% after 3,000 h generally indicates poor stabiliser dispersion or insufficient UV package. Tensile properties are measured per ISO 527-3:2018 on 200 µm greenhouse film, with machine-direction elongation at break typically above 600% for new material and tear resistance per ISO 6383-2:1983 used to assess hail damage tolerance. Processing conditions for agricultural film include melt temperature 185–210 °C, die gap 2.2–3.0 mm, and blow-up ratio 1.8–2.5. The addition of calcined kaolin at 5–8 wt% in greenhouse film improves infrared blockage but increases die pressure by 8–15%, requiring melt pressure below 35 MPa to protect screen packs and die seals. No pre-drying is required, but condensation on regranulated edge trim above 0.2 wt% moisture creates surface voids and reduces film tear strength.

    Die-to-Nip Distance and Melt Curtain Stability in Extrusion Lamination

    Die lip opening, air gap, and die-to-nip distance jointly determine the melt curtain stability of UF1810T in extrusion lamination onto woven polypropylene, aluminium foil, and BOPET substrates. A T-die with die lip gap 0.6–0.8 mm, air gap 120–200 mm, and chill roll temperature 10–18 °C is used. Melt temperature is raised to 260–290 °C to promote oxidation-driven adhesion to aluminium foil and woven polypropylene, but the linear low-density polyethylene molecular architecture narrows the draw envelope below 12 µm at line speeds above 150 m/min. Blending with autoclave LDPE at 20–30 wt% reduces edge neck-in and improves the draw-down limit for thin coatings. Ozone treatment at 2–4 g/h and substrate preheating to 40–60 °C are specified for aluminium foil adhesion; without ozone, peel strength per ISO 11339 or ASTM D1876 commonly falls below 2 N/15 mm. The laminator web tension is maintained at 80–150 N/m to prevent substrate wrinkling and thermal distortion of BOPET. A fluoroelastomer processing aid at 0.05–0.1 wt% reduces die streak and stabilises melt curtain edges, while antioxidant level should not exceed 800 ppm because excess additives plate out on the chill roll within 4–6 h of continuous operation. The final laminated structure is tested for bond strength after 24 h conditioning at 23 °C and 50% relative humidity, and additional boiling-water adhesion testing at 95 °C for 30 min is applied when the laminate is intended for retort or high-moisture packaging.

    When UF1810T Replaces Autoclave LDPE in Coil-Coating Protection Films

    Substitution of autoclave LDPE in surface protection film for stainless steel coil, anodised aluminium, and automotive aperture masking is governed by the requirement for clean, age-stable peel and low gel protrusion. The coextruded construction comprises a skin layer of UF1810T at 20–30 µm with a POE or EVA tack layer at 5–10 µm. Corona treatment to 38–42 mN/m is specified on the exposed face before printing or lamination, while the adhesive layer is deliberately not corona-treated to avoid excessive adhesion growth on metal surfaces. Peel adhesion on 0.5 mm aluminium coil is measured per ASTM D3330 and controlled to 0.5–2.5 N/25 mm at 23 °C; higher adhesion after ageing at 60 °C for 168 h indicates migration of low-molecular-weight species from the bulk layer into the tack interface. The film is processed at 190–220 °C with die gap 2.0–2.4 mm and blow-up ratio 2.0–2.5. Optical haze per ASTM D1003 must remain below 15% for a 30 µm film to allow visual inspection of underlying coil defects. Edge trim reprocessing above 15 wt% increases gel counts and creates protrusions in the peel layer; an online screen changer with 100–150 µm mesh is required when recycled edge trim is used above this level. No slip or antiblock is incorporated in the adhesive layer because migration of erucamide or silica agglomerates lowers peel strength within 72 h, and the winder tension must be limited to 60–100 N/m to avoid compression set in the tack layer during roll storage.

    Pallet weather protective hoods and dunnage air-bag films extruded from UF1810T in width ranges 1.2–2.4 m require high tensile strength at break, low-temperature puncture resistance, and stable bubble geometry across wide dies. The film is typically a three-layer coextrusion with UF1810T in the core and lower-melt-index LLDPE or LDPE in the skin layers to improve melt strength. The bubble is run at a blow-up ratio of 1.8–2.2 and frost-line height 250–350 mm to balance impact toughness and transverse gauge uniformity. Thickness is usually 80–120 µm for dunnage air-bag inner bladders and 100–150 µm for weather protective transport hoods. Tensile properties per ISO 527-3:2018 are measured in machine and transverse directions, and dart impact per ISO 7765-1 at −30 °C is included because dunnage bags are inflated in cold-chain environments. Film gauge variation across the web is controlled below ±5% using a dual-lip air ring and automatic profile control; deviations above this range create thin spots that rupture at inflation pressures approaching 0.4 bar. The process melt temperature is kept at 180–210 °C, and die gap is set at 2.0–2.6 mm. Film blocking is controlled with 2–3 wt% silica-based antiblock masterbatch, but excess silica above 4 wt% reduces low-temperature impact strength and creates abrasive wear on downstream converting knives. No pre-drying is required for virgin resin, but edge trim rework must be kept below 20 wt% to avoid gel-related defects at 80 µm and below.

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    Certification & Compliance
    More Introduction

    Asrene LLDPE UF1810T is a butene-based linear low-density polyethylene resin produced by Lotte Chemical Titan under the Asrene polymer range. The grade is intended for blown film extrusion and is specified at a nominal density of 0.918 g/cm³ when tested according to ASTM D1505-18 and a melt flow rate of 1.0 g/10 min under ASTM D1238-20 at 190 °C and 2.16 kg. These values place UF1810T in the fractional-melt-index LLDPE classification, where film toughness and seal response are balanced for medium-to-heavy packaging, agricultural film, and lamination webs. The resin differs from high-pressure LDPE because it has a linear molecular backbone with short-chain branches and minimal long-chain branching. It also differs from metallocene-catalysed LLDPE because it has a broader comonomer composition distribution and a less uniform branch spacing.

    PropertyTest MethodRepresentative Value
    Melt flow rateASTM D1238-20, 190 °C/2.16 kg1.0 g/10 min
    DensityASTM D1505-180.918 g/cm³
    Tensile strength at yieldASTM D882-18, 50 μm blown film11 MPa MD / 11 MPa TD
    Tensile strength at breakASTM D882-1838 MPa MD / 31 MPa TD
    Elongation at breakASTM D882-18800% MD / 900% TD
    Dart impactASTM D1709-16a, method A110 g
    Elmendorf tearASTM D1922-15300 g MD / 420 g TD
    HazeASTM D1003-1313%
    Coefficient of frictionASTM D1894-140.10 kinetic

    What Limits Bubble Stability in UF1810T Blown Film Lines?

    Bubble stability in UF1810T is governed by extensional viscosity and strain hardening. Because the resin has little long-chain branching, it does not show the pronounced strain-hardening response that stabilises LDPE bubbles under high blow-up ratios. On production-scale blown film towers with 45 mm or 65 mm extruders and L/D 24:1–30:1, the die gap is usually set between 1.8 mm and 2.4 mm. A wider gap reduces melt fracture but lowers shear rate and may increase residence time in the die. A narrower gap raises head pressure and may cause sharkskin at output rates above 80 kg/h on a 65 mm line. The frost line height is maintained at 4 to 8 die diameters; lower frost lines cool the film too rapidly and raise haze, while higher frost lines increase bubble sway and thickness variation.

    Air-ring configuration matters. Dual-lip air rings are preferred because they generate a primary cooling stream at the die exit and a secondary stream further up the bubble. On one 45 mm line, keeping the lower lip air volume 15–20% higher than the upper lip reduced gauge variation from ±7% to ±4% at 2.5:1 blow-up ratio. This is an operational boundary, not a fixed property of the resin. Ambient air draughts from open warehouse doors can destabilise the bubble when frost line height exceeds 8 die diameters; shrouding around the tower may be required.

    Rheometric Fingerprint and Melt Temperature Boundaries

    The shear viscosity of UF1810T is more sensitive to shear rate than the melt viscosity of LDPE. At low shear rates the resin retains higher viscosity because of its narrow molecular weight distribution, while at high shear rates it thins more efficiently. In a capillary rheometer at 190 °C, this translates into lower head pressure at die shear rates above 200 s⁻¹ compared with a fractional-MI LDPE of equal density. The practical consequence is that UF1810T can run on blown film dies with small die gaps without exceeding 35 MPa head pressure, provided the screw speed is not pushed into high-shear heating.

    The melt temperature window is 190–230 °C. Operation below 190 °C can produce unmolten gels and poor dispersion of the antiblock additive. Sustained operation above 240 °C can lead to thermal-oxidative gel formation in stagnant zones of the die or screen pack. The screen pack should be inspected when head pressure increases by 20% above the initial value at constant output. Extruders with a Maddock mixing section or barrier screw provide more uniform melt temperature and reduce the probability of gel formation. Single-flighted screws without mixing elements may show higher melt temperature variation, especially above 70 rpm on a 65 mm extruder.

    The slip and antiblock additives in UF1810T are not chemically grafted to the polyethylene chain. Slip agent molecules migrate through the amorphous phase to the film surface after extrusion. At 23 °C, the kinetic coefficient of friction of 30 μm film measured by ASTM D1894-14 typically stabilises after 72–96 h. At 40 °C, migration is faster and can produce a surface slip level high enough to reduce winding tension control on center winders. Winding tension should be reduced after 24 h ageing or the slitting schedule adjusted to account for the changed surface friction.

    When UF1810T Replaces Butene-Based Cast Film Grades in Side-Seal Web Lines

    When UF1810T is evaluated as a replacement for a cast-film butene LLDPE of similar melt flow rate, the extrusion profile should be lowered by 5–10 °C because blown film dies operate at higher temperatures than chill-roll cast lines. Side-seal web lines with servo-driven sealing jaws require seal initiation temperatures below 105 °C for high cycle rates. UF1810T is expected to seal at temperatures above those of metallocene-catalysed LLDPE and below those of fractional-melt LDPE of equivalent density. Published data for this specific configuration is limited; seal initiation should be measured on the packaging machine using ASTM F88/F88M-21 and compared with the incumbent resin.

    The difference from metallocene LLDPE is measurable in dart impact. In 50 μm blown film, metallocene grades can exceed 200 g under ASTM D1709-16a, while UF1810T is specified near 110 g. The trade-off is extrusion pressure: UF1810T runs at lower head pressure and is more tolerant of older screws with shallow compression ratios. This distinction matters when allocating products across idle blown film assets.

    A comparison of butene-based and hexene-based LLDPE films under ASTM D1709-16a and ASTM D1922-15 typically shows a 15–25% reduction in dart impact and Elmendorf tear for the butene-based grade at equivalent density. This differential narrows at lower film thickness and is affected by blow-up ratio. Published data for this specific configuration is limited; the comparison should be conducted on the same blown film line using the same die gap. Compared with high-pressure LDPE of similar melt flow rate, UF1810T shows lower melt extension at the die and lower strain hardening. The density of 0.918 g/cm³ is lower than HDPE film grades, giving higher elongation and impact but lower modulus. Puncture resistance can be compared by ASTM D5748-19 and Elmendorf tear by ASTM D1922-15.

    Seal initiation temperature is affected by density and comonomer type. Butene-based LLDPE has a lower hot-tack strength than hexene-based LLDPE at the same density because of shorter inter-crystalline tie chains. In form-fill-seal lines requiring hot-tack strength above 1.5 N/15 mm before seal cooling, UF1810T may require higher seal bar temperature or longer dwell time than hexene-based grades. Hot-tack should be measured by ASTM F1921-18.

    Regulatory / Compliance DimensionReferenceBoundary
    US food contact olefin polymerFDA 21 CFR 177.1520(c)Use conditions E–G; additive package must meet FDA 21 CFR 178 sections separately
    EU food contact plasticCommission Regulation (EU) No 10/2011, Annex IOverall migration ≤ 10 mg/dm² in food simulants
    REACH SVHC declarationRegulation (EC) No 1907/2006, Articles 7, 33No SVHC > 0.1 wt% per supplier declaration

    Blending UF1810T with LDPE at 10–20 wt% lowers head pressure and improves bubble handling without altering the density specification of the final film to a large degree. At addition levels above 30 wt%, the film loses dart impact and the seal initiation temperature moves upward. Processors using automatic winders should not blend UF1810T with polypropylene or high-melt-flow HDPE because the difference in crystalline melting ranges can generate gel-like domains and reduce Elmendorf tear. Drying is generally not required when the resin is stored indoors below 60% relative humidity. If surface moisture is present after outdoor storage, dry-air hopper treatment at 60 °C for 2 h is sufficient. UF1810T should not be blended with polypropylene or high-melt-flow HDPE because the difference in crystalline melting ranges can generate gel-like domains and reduce Elmendorf tear. Coextrusion with EVOH or PA is possible in tie-layer structures, but the sealant skin must be tested for hot-tack and seal strength according to ASTM F1921-18 and ASTM F88/F88M-21.

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