| HS Code | 164529 |
| Polymertype | Hydrogenated styrene-butadiene-styrene block copolymer (SEBS) |
| Chemicalcomposition | Styrene-ethylene-butylene-styrene block copolymer |
| Styrenecontent | Approximately 30 wt% |
| Density | Approximately 0.89-0.90 g/cm³ |
| Meltflowrate | Approximately 10 g/10 min at 230°C/2.16 kg |
| Shoreahardness | Approximately 65 |
| Tensilestrength | Approximately 20-25 MPa |
| Elongationatbreak | Approximately 500-600% |
| 300percentmodulus | Approximately 5 MPa |
| Glasstransitiontemperature | Approximately -55°C |
| Appearance | White powder or pellet |
| Moisturecontent | Typically below 0.5 wt% |
| Ashcontent | Typically below 0.1 wt% |
| Solubility | Soluble in aromatic and chlorinated solvents such as toluene |
As an accredited Asahi Kasei Tuftec™ SEBS H1387 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Asahi Kasei Tuftec™ SEBS H1387 is supplied in 20 kg moisture-resistant paper bags, palletized and securely wrapped for industrial shipment. |
| Container Loading (20′ FCL) | 20′ FCL: Asahi Kasei Tuftec™ SEBS H1387 packed in 25 kg bags on pallets, securely loaded and stowed for ocean transport. |
| Shipping | Tuftec™ SEBS H1387 is a non-hazardous thermoplastic elastomer supplied as pellets in 25 kg moisture-barrier bags or bulk bags, palletized. It is not regulated for transport—no UN number, hazard class, or special label required. Keep dry and avoid heat, moisture, and direct sunlight during shipping. |
| Storage | Store Asahi Kasei Tuftec™ SEBS H1387 in a cool, dry, well-ventilated area away from direct sunlight, heat, moisture, and oxidizing agents. Keep containers tightly closed and protect from contamination and physical damage. Avoid prolonged UV exposure and extreme temperatures. Follow the SDS and local regulations for handling and storage. |
| Shelf Life | Asahi Kasei Tuftec™ SEBS H1387 typically has a 24-month shelf life when stored cool, dry, and in unopened original packaging. |
Melt-compounded polypropylene-rich TPE formulations designed for automotive interior skin layers incorporate Asahi Kasei Tuftec H1387 at 25–45 wt% alongside a polypropylene random copolymer at 20–35 wt% and a paraffinic or naphthenic process oil at 15–30 wt%; the hydrogenated ethylene-butylene midblock suppresses chain scission during compounding in a co-rotating twin-screw extruder with L/D 44:1. Barrel zones are set from 170°C at the feed throat to 220°C near the die plate, with screw speed held at 350–600 rpm depending on the oil-absorption capacity of the batch, while a water-ring pelletizer with die-face temperature of 200–230°C prevents pellet agglomeration. Compliance for automotive interior compounds falls under VDA 278:2011 for VOC and SVOC desorption, with typical targets below 100 µg/g VOC and 50 µg/g fogging mass, plus DIN 75201:2011 gravimetric fogging and ISO 3795:1989 horizontal burn rate. The compound is subsequently injection molded on machines with clamp force from 1,200 kN to 3,500 kN, melt temperature 190–230°C, and mold surface temperature 20–50°C; gate freeze-off must occur before pressure decay to prevent surface splay and flow marks on textured surfaces. Terminal finished product types include instrument-panel lower skins, door-trim insert mats, center-console soft-touch covers, HVAC knob sleeves, and overmolded PP substrate components. Published formulation data for H1387 in exact talc-filled automotive systems is limited; when talc loading exceeds 10 wt%, the H1387 fraction should be reduced toward the lower bound of the cited range to avoid melt-fracture defects at injection speeds exceeding 60 mm/s.
Hot-melt adhesive producers evaluating Tuftec H1387 as the styrenic block copolymer backbone for sprayable and slot-die coated pressure-sensitive adhesives load the polymer at 15–35 wt%, with a fully hydrogenated C9 or C5/C9 tackifying resin at 40–60 wt% and a paraffinic or naphthenic oil at 10–25 wt%; total melt viscosity at 180°C measured by ASTM D3236-88(2014) determines the upper H1387 loading because formulations exceeding 35 wt% polymer can surpass 15,000 mPa·s in slot-die equipment and produce edge-bead instability. Production-scale batches are compounded in sigma-blade or planetary roller mixers at 150–180°C under vacuum, then transferred through heated recirculation lines to a slot-die coater running at 15–80 m/min; line operators report that cold spots below 140°C increase gel formation in SEBS hot melts, requiring temperature control within ±3°C. For food-contact indirect packaging applications, the final adhesive must satisfy FDA 21 CFR 175.105 for pressure-sensitive adhesive components and, where relevant, EU 10/2011 migration limits for multilayer laminates; REACH Regulation EC 1907/2006 SVHC declarations and supplier SDS data for target organ toxicity are standard prerequisites in B2B purchase specifications. Terminal finished product types include repositionable label adhesives, hygiene disposable laminate adhesives, automotive trim bonding tapes, and nonwoven attachment adhesives in diaper chassis and adult incontinence assembly. Published data for H1387-specific peel and shear profiles at the stated addition levels is limited; each converter must run ASTM D903-98(2017) peel and ASTM D3654-06(2019) shear trials on the selected facestock because liner interactions and coat weight influence the failure mode.
In glass-fiber–reinforced polypropylene recycling streams, the addition of 5–15 wt% Tuftec H1387 to post-industrial PP regrind raises notched Izod impact values measured by ISO 180:2023 from brittle values below 3 kJ/m² to ductile values above 8 kJ/m², provided the recycled PP melt flow rate is between 15 and 35 g/10 min at 230°C/2.16 kg per ISO 1133-1:2022. The compounding line is a co-rotating twin-screw extruder with L/D 40:1; H1387 is fed at the main throat with PP regrind, temperature zones are held at 200–230°C, and a side feeder introduces 10–20 wt% chopped glass fiber at zone 7. Process troubleshooting in such lines identifies screw wear at the side-fed glass-fiber injection point as the dominant cause of batch-to-batch viscosity drift; nitrided barrel sections and 60° kneading blocks reduce drift to less than 5% MFI change over 100 batches. The final compound must meet REACH Regulation EC 1907/2006 restrictions for polycyclic aromatic hydrocarbons in extender oils, RoHS 2011/65/EU as amended by EU 2015/863 for lead, cadmium, mercury, hexavalent chromium, PBB, PBDE and four restricted phthalates at 0.1 wt% homogeneous material thresholds, and relevant OEM recycled-content specifications where ISO 22628:2002 road vehicle recyclability calculations are required. Injection molding of the modified regrind uses melt temperature 200–230°C and clamp force from 1,000 kN to 4,000 kN depending on part size. Terminal finished product types include wheel-arch liners, underbody panels, internal-combustion engine battery brackets, storage bin walls, and appliance base frames where post-industrial recycled content is permitted. Published data for H1387 in high-glass recycled PP at the lower addition bound is limited; processors should not exceed 15 wt% when glass loading exceeds 25 wt% because excessive SEBS can lower tensile yield strength below 25 MPa in ASTM D638-14 Type I specimens.
Low-smoke halogen-free cable jacket compounds based on ethylene-vinyl acetate or linear low-density polyethylene incorporate Tuftec H1387 at 10–20 phr as a midblock modifier to restore elongation at break after high loadings of aluminum trihydroxide and magnesium dihydroxide, which normally reduce extensibility to less than 150% in ISO 527-2:2012 Type 5 tensile specimens. The production-scale mixing sequence uses a kneader or co-rotating twin-screw extruder with L/D 44:1; flame-retardant filler is added by side feeder at 150–180°C after the polymer phase is melted, and extruder torque is kept below 90% of gearbox rating to avoid shear-induced release of hydration water from the metallic hydroxide fillers. The compounding section is maintained below 200°C because magnesium dihydroxide decomposition onset can occur between 190°C and 220°C depending on particle size and surface coating; this thermal boundary makes SEBS a technically relevant modifier only when the flame-retardant system is surface-stabilized. Cable jacket compounds must meet IEC 60754-1:2011 for halogen acid gas content, IEC 60754-2:2011 for pH and conductivity, IEC 60684-2:2011 for flexible insulating sleeving where applicable, and ISO 6722:2022 for 60 V/600 V automotive cables when extruded onto copper conductors. Jacket extrusion uses a single-screw extruder with L/D 25:1 to 30:1 and compression ratio 2.5:1 to 3.5:1, melt temperature 160–190°C, and crosshead die temperature 170–200°C; feed-zone screw cooling prevents pre-crosslinking from residual moisture. Terminal finished product types include automotive low-voltage battery management system cables, industrial motor leads, control cabinet wiring with UL 62 recognition, and portable EV charging cable jackets where halogen-free specifications are contractual. Published data for H1387 in low-smoke halogen-free cable jacket formulations is more limited than for dedicated SEBS/EVA grades; compounders must verify tensile strength at break, elongation at break, and heat aging per ISO 6722:2022 before substituting into a qualified formulation.
Processors producing soft-touch overmolded grips on glass-filled nylon substrates dilute Tuftec H1387 into a TPE compound at 30–50 wt%, with polypropylene at 15–25 wt% and a paraffinic white oil at 15–30 wt%; Shore A hardness measured by ASTM D2240-15 typically falls between 45 A and 70 A, and the addition of 5–10 wt% maleic anhydride-grafted polyolefin improves adhesion to the nylon substrate when bond strength is evaluated by VDI 2019:2018. The overmolding process uses a two-shot injection molding cell with a first barrel for the rigid substrate at 260–290°C and a second barrel for the H1387 compound at 190–230°C; the rotating platen mold surface temperature is held at 40–70°C to promote interfacial entanglement without distorting the nylon core. Chemical resistance of the final assembled part is evaluated against sunscreen, isopropyl alcohol, and artificial sweat by DIN EN ISO 105-E04:2013 or the automotive OEM’s internal methods; REACH Regulation EC 1907/2006 and RoHS 2011/65/EU Annex II restrictions are standard B2B purchase declarations for consumer-facing hand tools. When sold into toys or repeated food-contact handles, the compounder must also confirm compliance with EN 71-3:2019+A1:2021 heavy metal migration limits or FDA 21 CFR 177.2600 for rubber articles; the selected pigment masterbatch cannot contain azo colorants restricted by Annex XVII Entry 43 of REACH. Terminal finished product types include cordless drill overmolded handles, rechargeable toothbrush bodies, personal-care razor grips, kitchen tool handles with rigid PP cores, and robotic vacuum bumper skins. Published data for H1387 in exact nylon overmolding bond-strength configurations is limited; adhesion promoter addition and nylon surface roughness from chemical etching are required to achieve cohesive failure in VDI 2019:2018 pull-off tests, and the absence of such promoters commonly yields interfacial delamination.
Extrusion-grade TPE film for pharmaceutical unit-dose packaging and medical device overwrap presents a stricter qualification path than industrial sheet because the final compound must pass ISO 10993-5:2009 cytotoxicity, ISO 10993-10:2010 skin sensitization, and ISO 10993-11:2017 systemic toxicity assessments; whether a USP Class VI master file is available for Tuftec H1387 must be confirmed with the supplier because converters frequently generate their own biological evaluation and leachables profile. In this segment, H1387 is added at 20–35 wt% within a TPE compound containing polypropylene at 15–25 wt%, white oil at 15–25 wt%, and a clarifying masterbatch at 1–3 wt%; the use of low-odor, low-SVOC process oil is mandatory to avoid leachable failures in the finished multilayer structure. Film production is performed on a single-screw or twin-screw extruder feeding a flat die with a barrel temperature profile of 180–220°C, chrome-polished chill rolls at 20–40°C, and a downstream corona treater at 0.5–2.0 kW to raise surface energy above 38 mN/m for lamination or printing. Heat-seal strength is tested by ASTM F88/F88M-21 at seal-bar temperatures of 110–140°C, while burst strength is verified per ASTM F2054/F2054M-17; for pharmaceutical packaging, EU 10/2011 and FDA 21 CFR 177.2600 may apply to the final multilayer structure, along with the drug product’s stability protocol at 40°C/75% RH. The operational boundary includes predrying at 80°C for 2 h in a desiccant dryer when the raw material has been stored at relative humidity above 60%, because residual surface moisture can cause flow marks and seal voids. Terminal finished product types include unit-dose pharmaceutical blister lidding membranes, medical device overwrap films, breathable patch backing layers, and secondary pouches for sterilizable devices, provided the manufacturing facility maintains ISO 13485:2016 quality systems and ISO 14644-1 cleanroom classification appropriate to the device class. Published data for H1387 in pharmaceutical-grade film is limited; qualification loads, seal strength, and migration data are frequently proprietary to the converter and must be generated on the intended film line.
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When compounders require a hydrogenated styrenic block copolymer with a higher styrene endblock fraction than conventional oil-extended SEBS grades, Asahi Kasei Tuftec™ SEBS H1387 is specified as a styrene-ethylene-butylene-styrene triblock resin. The terminal styrene domains provide physical crosslinking at service temperature while the saturated ethylene-butylene midblock contributes elastic recovery. Because the midblock is hydrogenated, the material does not carry the same residual unsaturation as unhydrogenated SBS and is therefore less prone to oxidative gel formation during high-temperature processing and subsequent outdoor ageing.
The H1387 grade is evaluated in three technical contexts: as a neat elastomer for elastic films and profiles; as a modifier in polyolefin compounds; and as a base resin for oil-filled soft-touch formulations. Representative melt mass-flow rate for this grade is published in the 6–12 g/10 min range at 230°C and 2.16 kg according to ISO 1133-1. The exact lot value depends on molecular weight distribution, diblock content, and styrene block fraction. Density is typically reported in the 0.95–0.98 g/cm³ range according to ISO 1183-1; hardness is normally published in the 85–90 Shore A range under ISO 48-4.
The H1387 grade is classified among high-styrene Tuftec SEBS types. Lower-styrene reference grades H1041 and H1051 are often cited with styrene contents near 30 wt% and 42 wt%, respectively. H1387 is positioned at a styrene level typically between 60 wt% and 70 wt%; this higher aromatic fraction increases the volume fraction of phase-separated styrene domains and raises Shore hardness, tensile modulus, and Vicat softening point while reducing elongation at break and oil retention capacity. The melt viscosity of high-styrene SEBS is generally lower at conventional processing temperatures than that of lower-styrene grades of comparable triblock molecular weight because the higher styrene content favours fluid-like behaviour above the glass transition of the styrene domains; nevertheless, shear history and diblock content create lot-specific differences.
Compared with unhydrogenated SBS, H1387 contains a saturated ethylene-butylene midblock. The absence of backbone double bonds reduces susceptibility to free-radical chain degradation during twin-screw compounding and colour shift under ISO 4892-2 weathering. Against conventional thermoset EPDM, H1387 requires no sulfur cure; scrap can be reground and reprocessed through thermoplastic equipment. However, the absence of covalent crosslinks limits the upper service temperature to approximately 90–110°C under low load, and the material is not a direct substitute for vulcanized rubber in continuous high-strain dynamic applications.
The order of oil absorption among selected Tuftec grades follows the styrene content: H1221, with approximately 12 wt% styrene, absorbs more oil than H1062 at approximately 18 wt%, which absorbs more than H1041 at approximately 30 wt%, which exceeds H1051 at approximately 42 wt%. H1387, with the highest styrene fraction in this comparison, has the lowest oil uptake. This oil uptake gradient permits formulators to choose H1387 when the compound must retain tensile strength and reduce surface tack after oil addition, but it also limits the lowest attainable hardness without adding a complementary low-hardness elastomer.
Typical tensile stress at break for high-styrene SEBS of this class is reported between 20 MPa and 30 MPa when tested according to ISO 37 at 500 mm/min; elongation at break is commonly below 500% for unplasticised high-styrene grades, whereas lower-styrene Tuftec grades can exceed 700%. These differences are attributable to the glassy polystyrene domains, which increase modulus but reduce chain extension before domain yielding.
On a 40:1 L/D co-rotating twin-screw extruder with 12 barrel sections, a representative profile for H1387 begins at 160°C in the feed zone and rises stepwise to 210–230°C at the die. Screw speed is typically held between 300 rpm and 600 rpm. The first kneading block after the third barrel section disperses pellet boundaries; a reverse screw element before a side stuffer forms a melt seal for oil injection at barrel section six; downstream distributive elements homogenize without excessive shear heating. If melt temperature exceeds 240°C because of high screw speed or insufficient barrel cooling, the strand may become tacky and strand pelletizing may fail. Drying at 70–80°C for 2–4 h is recommended when storage relative humidity exceeds 60%, although equilibrium moisture absorption of SEBS is low.
H1387 is used as a modifier in polypropylene at loadings from 10 wt% to 60 wt%. At 10–25 wt%, it increases instrumented impact toughness and reduces flexural modulus measured by ISO 178; at 50–60 wt%, the compound becomes soft-touch and its hardness is controlled by paraffinic oil addition. Higher-styrene H1387 absorbs less oil than lower-styrene H1041; when oil loading exceeds the block-specific saturation point, the oil migrates to the surface and causes tack, gloss change, and elevated fogging measured by DIN 75201 or VDA 278. Paraffinic oil with kinematic viscosity between 40 mm²/s and 100 mm²/s at 40°C is preferred because aromatic oils plasticize styrene domains and reduce service temperature.
Batch-to-batch variation in styrene block content alters flow length and compound hardness. Incoming inspection therefore includes melt flow rate and Shore hardness measurements on a standardised compound, in addition to the raw-pellet MFR. This reduces the risk of extrusion torque drift on high-output lines and limits variability in subsequent injection moulding operations.
In thin-wall components, H1387 is often blended with high-MFR polypropylene to achieve compound MFR above 20 g/10 min. This reduces fill pressure but depresses melt strength, which can cause jetting and gate blush if injection velocity exceeds 100 mm/s without a proper fan gate. Production trials on hydraulic injection moulding machines with clamp force from 80 t to 220 t are used; melt temperature is controlled between 200°C and 240°C, mould temperature between 30°C and 60°C. Rapid cooling produces finer styrene domain morphology and may improve optical clarity but can increase shrinkage anisotropy. Published data for this specific configuration is limited; therefore, part drafts and gate dimensions are validated according to ISO 294-1 specimen preparation and ISO 527-2 tensile testing.
Soft-touch overmoulding onto polypropylene is a representative application. Adhesion to PP is achieved through melt interdiffusion and the close solubility parameter of the hydrogenated midblock with polypropylene; adhesion to ABS is less reliable and normally requires a tie layer or polar modification. The H1387 grade is also considered for non-tacky elastic films, conveyor timing profiles, and automotive interior ancillaries that require low fogging. In each case, final odour and fogging values depend on the oil package and antioxidant system, not on the SEBS resin alone.
| Property | Test method | Representative condition |
|---|---|---|
| Density | ISO 1183-1:2019 | 23°C, method A |
| Melt mass-flow rate | ISO 1133-1:2022 | 230°C, 2.16 kg |
| Shore hardness | ISO 48-4:2018 | 15 s reading, Shore A |
| Tensile stress at break | ISO 37:2017 | 500 mm/min, elastomer test piece |
| Tear strength | ISO 34-1:2022 | Angle or trouser, without nicked specimen |
| Accelerated weathering | ISO 4892-2:2013 | Xenon arc, method specified by final part standard |
Lot acceptance relies on a small number of physical properties previously described. For melt flow rate, ISO 1133-1:2022 is used; for density, ISO 1183-1:2019; for hardness, ISO 48-4:2018; for tensile and tear, ISO 37:2017 and ISO 34-1:2022. These methods do not guarantee compatibility with a specific food-contact or medical application. The raw resin may be used as a component in materials subject to EU 10/2011, FDA 21 CFR 177.1810, or ISO 10993 evaluated finished articles, but migration and biocompatibility data must be generated on the final compound. No statement in this document replaces the supplier certificate of analysis.
For compounds that undergo irradiation sterilisation, polypropylene impact modifiers may produce odour and radical-induced yellowing. H1387 is saturated in the midblock but the styrene domains can still form chromophores under high-dose gamma irradiation; dose tolerance should be evaluated according to ISO 11137. If the part is intended for cleanroom assembly, particulate contamination from pellet fines must be controlled at the compounder’s extrusion and packaging steps.