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Asahi Kasei Tuftec™ SEBS H1051

    • Product Name: Asahi Kasei Tuftec™ SEBS H1051
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 274776
    Polymer Type Hydrogenated styrene-butadiene-styrene (SEBS) block copolymer
    Styrene Content 42 wt%
    Ethylene Butylene Content 58 wt%
    Density 0.91 g/cm³
    Melt Flow Rate 230c 2 16kg 5.0 g/10 min
    Shore A Hardness 70
    Tensile Strength 30 MPa
    Elongation At Break 500%
    Modulus At 300 Percent 6 MPa
    Vicat Softening Temperature 80 °C
    Hydrogenation Degree >98%
    Appearance White pellets

    As an accredited Asahi Kasei Tuftec™ SEBS H1051 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Typically supplied in 25 kg multiwall paper bags, palletized and stretch-wrapped for industrial shipment and storage.
    Container Loading (20′ FCL) Asahi Kasei Tuftec™ SEBS H1051 is packed in 25 kg bags and loaded into 20′ FCL dry containers for bulk shipment.
    Shipping Asahi Kasei Tuftec™ SEBS H1051 is typically shipped as dry thermoplastic elastomer pellets in sealed bags, cartons, or bulk packaging. It is generally non-hazardous for transport, with no special UN hazard class normally required. Ship and store away from moisture, direct sunlight, and excessive heat, keeping packaging intact to prevent contamination.
    Storage Store Tuftec™ SEBS H1051 in a cool, dry, well-ventilated area away from direct sunlight, heat sources, moisture, and oxidizing or incompatible materials. Keep containers tightly closed and clearly labeled; prevent contamination, dust, and physical damage. Avoid prolonged high-temperature exposure and excessive stacking. Follow local regulations and manufacturer safety data sheet guidance for safe handling and storage.
    Shelf Life Typically 24 months from manufacture when stored dry, in original sealed packaging, below 30°C, away from direct sunlight.
    Application of Asahi Kasei Tuftec™ SEBS H1051

    Soft-feel instrument panel topper pads and door panel armrests produced from Tuftec™ H1051 compounds are specified when OEM scratch resistance at 10 N load, low-temperature ductility below -30°C, and low VOC emissions under VDA 278 are jointly required. In these compounds, H1051 is dosed at 30–45 wt% of the total polymer phase, while paraffinic white oil is metered at 20–35 phr, PP homopolymer at 15–25 wt%, and talc or calcium carbonate at 0–15 wt%. Production-scale compounding is carried out on a co-rotating twin-screw extruder with L/D 44:1, screw speed 400–600 rpm, barrel temperatures 200–240°C, downstream oil injection after the plastication zone, and vacuum devolatilization at -0.08 MPa. Pelletizing follows through a strand die and water bath; compounds with H1051 above 45 wt% exhibit strand tack and pellet agglomeration, while loadings below 30 wt% reduce scratch resistance and shift ductile failure close to -20°C. Injection molding uses melt temperature 190–230°C, mold temperature 30–50°C, and clamp force of 800–1200 t for large armrest substrates. Production records from injection moulders indicate that the dominant field defect is not tensile loss but delamination at the PP substrate interface when melt temperature drops below 190°C; conversely, barrel residence times above 6 min at 240°C accelerate oil migration and surface haze. Finished components include IP topper pads, door panel armrests, center console side bolsters, and knee bolster covers.

    Compliance and test matrix for H1051-based automotive interior soft-touch compounds
    Standard / test methodPropertyTypical specification windowRelevance
    VDA 278VOC / FOG thermal desorptionVOC ≤ 100 µg/g; FOG ≤ 250 µg/gInterior air quality
    VDA 270Odour≤ Grade 3.0Passenger compartment odour
    ISO 37Tensile strength / elongationexceeds 8 MPa / 450%Compound ductility
    ISO 815-1Compression set 22 h/70°C‹ 60%Long-term recovery
    ISO 34-1Trouser tear strengthexceeds 30 kN/mResistance to tear propagation

    Is H1051 an Effective Olefinic Impact Modifier Without Sacrificing Melt Flow?

    Polypropylene compounds formulated with Tuftec™ H1051 are produced for bumper end caps, wheel arch liners, and appliance structural housings requiring sub-zero impact resistance without peroxide crosslinking. The addition level of H1051 is set at 5–15 wt% in PP random copolymer, with processing stabilizer at 0.1–0.3 phr. Compounding on a co-rotating twin-screw extruder at 230–250°C yields dispersed SEBS domains that increase notched Izod impact under ISO 180 at -30°C. Melt flow rate measured under ISO 1133-1:2022 at 230°C/2.16 kg typically drops from approximately 25 g/10 min to 8–12 g/10 min at 10 wt% H1051, an outcome that constrains thin-wall flow length but improves low-temperature ductility and stress-whitening resistance. Production-scale injection operations monitor flow marks; compounding above 15 wt% H1051 raises viscosity enough to cause gate blush and short shots in parts with wall thickness below 1.5 mm. The same addition window is used to upgrade impact performance in filled PP systems where mineral fillers reduce Izod values by 30–40% relative to unfilled PP. Typical finished parts include bumper end caps, wheel arch liners, and structural brackets.

    Elastomeric Monolayer Cast Film and Hysteresis-Limited Stretch Recovery

    Cast-film lines processing high-molecular-weight SEBS for hygiene laminates use Tuftec™ H1051 as the elastic backbone at 50–70 wt%, with LLDPE at 20–40 wt%, PP at 0–10 wt%, and antiblock at 1–3 phr. The formulation is extruded on a single-screw cast-film line with L/D 30:1, die width 2.5 m, melt temperature 220–240°C, air gap 30–60 mm, and line speed 200–400 m/min. Film samples evaluated under ASTM D882 and ISO 527-3 show tensile anisotropy governed by draw ratio; elastic recovery after 200% elongation is measured under ASTM D5459, with published H1051 monolayer data indicating tension set below 15% when chill roll temperature is kept at 15–25°C. On production lines, H1051 loadings above 70 wt% elevate melt pressure above 210 bar and induce draw resonance; loadings below 50 wt% increase permanent set beyond acceptable levels for diaper side panels. Blocking is controlled with silica or synthetic antiblock at 1–3 phr, but excessive antiblock above 3 phr creates visible haze and reduces tensile strength by 10–20%. Terminal products include elastic side panels, waistbands, and medical gown cuffs.

    Medical TPE compounds based on H1051 at 40–60 wt% are used in disposable tourniquets, respiratory mask headgear, and fluid-handling components because the grade can be formulated without phthalates and retains flexibility after autoclave or gamma radiation. A typical medical formulation combines H1051 with medical-grade white oil at 25–40 phr, PP at 10–25 wt%, and antioxidant at 0.05–0.2 phr. Compounding is performed on a twin-screw extruder with vacuum devolatilization and underwater pelletizing; pellets are pre-dried at 80°C for 2 h when ambient RH exceeds 60%. Tubing extrusion employs a single-screw extruder with L/D 25:1, melt temperature 200–230°C, and cooling water at 15–25°C. End-product validation follows ISO 10993-5, ISO 10993-10, and USP Class VI; resin compliance is referenced to FDA 21 CFR 177.1810 for styrene block copolymers used in food-contact applications, with migration testing remaining a convertor obligation. Gamma irradiation above 50 kGy may reduce tensile retention by more than 20%, so irradiation dose mapping and peroxide-free stabilization are required before release for medical use. For thin-wall tubing below 1 mm wall thickness, a lower-viscosity SEBS or higher PP fraction is substituted to reduce melt pressure and dimensional variation.

    When Halogen-Free Flame-Retardant Compounds Fail Embrittlement Testing

    Halogen-free flame-retardant sheathing compounds designed for EV charging cable jackets and flexible power cords use Tuftec™ H1051 at 35–55 wt% to maintain elongation after mineral filler loading. The formulation combines fine-particle magnesium hydroxide or aluminium trihydrate at 40–60 wt%, PP at 5–15 wt%, processing aid at 1–3 phr, and antioxidant at 0.1–0.3 phr. Compounding is run on a Buss co-kneader or co-rotating twin-screw extruder with L/D 44:1; FR filler is side-fed after the polymer melt seal, and melt temperature is held at or below 210°C to prevent magnesium dihydroxide decomposition and water release. Cable extrusion follows at 180–210°C with pressure-controlled die packs. Compounds with filler above 60 wt% produce pressure spikes above 250 bar, die drool, and visible melt fracture; compounds with H1051 below 35 wt% show low-temperature elongation loss and may fail cable jacket tensile retention after aging at 136°C for 168 h under UL 1581. Single-burn vertical flame is evaluated under IEC 60332-1-2, acid gas generation under IEC 60754-1/2, and low-temperature flexibility under ISO 6722 at -40°C. Finished components include EV charging cable jackets, appliance cords, and data-center flexible power cables.

    High-Torque Handgrip Overmolding and Adhesion Boundaries with Engineering Thermoplastics

    Overmolding trials on power-tool handles use H1051 at 25–40 wt% to achieve Shore A hardness of 45–55 under ASTM D2240 while retaining a dry, non-migrating surface. The compound is formulated with PP at 15–25 wt% and white oil at 20–35 phr. Insert injection molding is performed at melt temperature 200–230°C, mold temperature 30–50°C, back pressure 5–10 MPa, and clamp force 150–500 t. Tear strength is measured under ISO 34-1; compression set under ISO 815-1 at 70°C/22 h is typically below 60%. Bond strength to PP substrates is maintained without primer, whereas PC/ABS and PA substrates require a PP-based tie layer or surface pretreatment because H1051-rich formulations do not form strong chemical adhesion to amorphous engineering thermoplastics. Above 40 wt% H1051, injection pressure increases by 15–25% and thin ribs below 1 mm show flow hesitation; below 25 wt%, surface tack and abrasion resistance fall below OEM requirements. Final parts include cordless drill grips, high-torque screwdriver handles, and electric shaver overmolds, with compliance to RoHS 2011/65/EU and REACH SVHC as declared by the formulator.

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    Certification & Compliance
    More Introduction

    Supplied as a pelletized hydrogenated styrenic block copolymer, Asahi Kasei Tuftec™ SEBS H1051 is classified under ISO 18064 as a thermoplastic elastomer styrenic. The molecular architecture comprises a saturated ethylene-co-butylene soft midblock and 20 mass % terminal styrene hard blocks. The low styrene-to-rubber ratio produces a Shore A hardness of 65 and a tensile strength at break of 23 MPa when tested in accordance with ASTM D638. Table 1 lists representative neat-grade data from Asahi Kasei technical documentation; these values are not lot-release specifications and should be revalidated against the current certificate of analysis.

    Table 1. Representative physical properties of neat Tuftec™ SEBS H1051
    PropertyTest methodTypical value
    Specific gravityASTM D7920.91 g/cm³
    Bound styrene contentManufacturer data20 mass %
    HardnessASTM D224065 Shore A
    Tensile strength at breakASTM D63823 MPa
    Elongation at breakASTM D638700 %
    Melt flow rateASTM D1238 at 230 °C/2.16 kg0.8 g/10 min

    The product is distinct from unhydrogenated styrene-butadiene-styrene block copolymers because the polybutadiene midblock is catalytically hydrogenated to an ethylene-butylene sequence. This saturation removes most main-chain unsaturation and thereby reduces susceptibility to ozone cracking and oxidative embrittlement. Compared with a higher-styrene SEBS grade of equivalent molecular weight, H1051 provides lower room-temperature tensile modulus and higher elongation because the hard-phase volume fraction is reduced. The grade is used in polyolefin modification, soft-touch compounds, halogen-free wire and cable jacketing, and profile seals where a reprocessable elastomer behavior is required.

    What Distinguishes the Hydrogenated Midblock from SBS and EPDM?

    Hydrogenation of the midblock converts polybutadiene repeat units into ethylene-co-butylene sequences. This structural change is quantified in practice by a reduction of olefinic unsaturation; residual unsaturation in commercial SEBS is low enough to provide measurable resistance to ultraviolet embrittlement under ASTM D1148 and to heat aging under ASTM D573. Compared with SBS, H1051 does not require an antioxidant package for short-term outdoor exposure, although long-term weathering compounds still require UV stabilizers. Compared with EPDM, the SEBS system remains thermoplastic; no sulfur or peroxide vulcanization is required, and edge trim or rejected parts can be reground. The trade-off is compression set. Under ASTM D395 at 70 °C, neat SEBS exhibits higher permanent set than dynamically vulcanized EPDM, which limits continuous dynamic seal performance above approximately 80 °C unless the formulation is selectively crosslinked or blended with a thermoplastic vulcanizate.

    On a production twin-screw compounding line, the high molecular weight of H1051 creates measurable processing constraints. A 40:1 L/D co-rotating extruder is typically configured with barrel temperatures of 150 °C to 210 °C and melt temperature held at 220–230 °C. Pre-drying for 2–4 h at 70 °C is recommended when storage relative humidity exceeds 60 % RH; residual moisture target is below 0.05 wt %. Screw design should use dispersive kneading elements downstream of the polypropylene melt and starve feeding upstream to limit viscosity-induced torque spikes. Specific energy input commonly falls near 0.20–0.35 kWh/kg, depending on screw speed and oil injection point. Melt temperature excursions above 240 °C should be avoided because thermal degradation of the styrene hard block can generate gel particles and yellowing. Residence time above 5 min at temperature has the same effect and is especially relevant during purging or line stoppages. Paraffinic or naphthenic process oils are used to lower hardness; because the low styrene content permits high oil uptake without immediate bleed-out, compounds in the 35–55 Shore A range are prepared by adding process oil and polypropylene rather than by changing to a softer SEBS grade.

    Rheological Boundaries and Molding Parameters in High-Viscosity SEBS Compounds

    Melt flow rate determination under ASTM D1238 yields 0.8 g/10 min at 230 °C/2.16 kg. This places H1051 in the high-viscosity region for styrenic thermoplastic elastomers. Neat H1051 on a 75-ton injection molding machine with a 20 mm screw can short-fill thin-wall sections below 1 mm unless compounded with polypropylene or high-flow SEBS. For overmolding, melt temperatures of 200–220 °C and mold temperatures of 20–50 °C are typical. Gate diameters should remain above 1.0 mm, and runner lengths should be minimized to reduce pressure drop. In single-screw extrusion, a 24:1 L/D screw with a gradual compression zone stabilizes output across die temperatures of 190–210 °C. The high melt strength of H1051 assists profile die stability and blow-molded parison uniformity, but the same property reduces draw rates in thin-gauge sheet extrusion.

    When Formulation Hardness Is Lowered by Oil Extension Instead of Grade Substitution

    Compounds based on H1051 and paraffinic oil can cover hardness from 35 Shore A to 65 Shore A without switching to a styrene-butadiene rubber of entirely different morphology. High oil acceptance is a direct consequence of the saturated midblock and low styrene phase. Oil extension up to approximately 100 phr is possible in many formulations; flame-retardant cable compounds may combine the grade with magnesium hydroxide or aluminum trihydrate at addition levels from 120 phr to 180 phr. For such filler loadings, the high melt viscosity assists in dispersing inorganic filler without excessive shear heating. Wire and cable evaluations typically include tensile testing, hot-set testing, and smoke density under IEC 60811 procedures. In polypropylene overmolding, H1051 compounds are processed at 200–220 °C to promote fusion bonding with the substrate. Adhesion to untreated polyolefins is mechanical and thermal; the low styrene content reduces interfacial modulus mismatch but does not provide polar coupling. For PC/ABS or polyamide substrates, an intervening tie-layer or surface treatment is required. Published data for specific adhesion strength on polar substrates is limited; converter trials are required before design freeze.

    Converter verification of regulatory compliance is required before commercial shipping of finished articles. Table 2 identifies standards commonly applied to compounded styrenic block copolymer articles. Food-contact determinations are end-article-specific and depend on final formulation, extraction conditions, and processing history.

    Table 2. Regulatory and standards matrix for compounded styrenic block copolymer articles
    RequirementReference or standardVerification point
    Thermoplastic styrenic elastomer classificationISO 18064Supplier technical datasheet
    Styrene block copolymer food-contact status21 CFR 177.1810Finished-article extraction testing
    EU plastic food-contact overall migrationEU 10/2011Overall migration under final-use time/temperature
    Restriction on hazardous substancesRoHS Directive 2011/65/EURaw-material supplier declaration; article-level screening
    Tensile testingASTM D638 / ISO 527-2Incoming raw material and final molded plaque
    Hardness testingASTM D2240 / ISO 7619-1Compression-molded test specimen

    The nonpolar hydrocarbon nature of H1051 limits compatibility with polar engineering thermoplastics, alcohols, and aqueous acids. Prolonged contact with aromatic hydrocarbons, chlorinated solvents, and strong oxidizing acids plasticizes the matrix and increases extractable content. Service temperature is bounded by oxidative attack on the saturated midblock and by creep of the styrenic hard domains. For neat H1051, short-term peaks near 110 °C are tolerated for limited duration, but sustained exposure above 80 °C under load typically produces permanent deformation. These boundaries should govern grade selection when the application involves dynamic seals, hot-melt adhesives, or under-hood automotive components.

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