| HS Code | 458487 |
| Product Name | Arya Sasol HDPE 4261A |
| Manufacturer | Arya Sasol Petrochemical Company |
| Polymer Type | High Density Polyethylene |
| Grade | 4261A |
| Application | Blow molding |
| Density | 0.946 g/cm³ |
| Melt Flow Rate | 0.8 g/10 min |
| Melt Flow Rate Test Condition | 190 °C / 2.16 kg |
| Tensile Strength At Yield | 25 MPa |
| Elongation At Break | 600% |
| Flexural Modulus | 1100 MPa |
| Izod Notched Impact Strength | 60 J/m |
| Vicat Softening Point | 125 °C |
| Melting Point | 130 °C |
| Environmental Stress Crack Resistance | >1000 h |
| Hardness Shore D | 65 |
| Thermal Conductivity | 0.44 W/m·K |
| Specific Heat Capacity | 1.9 kJ/kg·K |
As an accredited Arya Sasol HDPE 4261A factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Arya Sasol HDPE 4261A is packed in 25 kg polypropylene woven bags, 55 bags per pallet, totaling 1,375 kg. |
| Container Loading (20′ FCL) | Arya Sasol HDPE 4261A is loaded in 20′ FCL containers, palletized 25 kg bags, shrink-wrapped and secured for safe ocean transport. |
| Shipping | Arya Sasol HDPE 4261A is not classified as dangerous goods for transport. It is typically shipped in 25 kg polyethylene bags, palletized and stretch-wrapped, in clean, dry containers. Store away from heat, sunlight, and moisture. Handle carefully to prevent package damage. Follow local regulations. |
| Storage | Store Arya Sasol HDPE 4261A in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, ignition sources, and moisture. Keep original bags sealed, palletized, and off the ground. Avoid contamination, dust generation, and static buildup. Protect from UV radiation and physical damage. Do not store near strong oxidizers. Maintain clean handling areas and follow local regulations and supplier guidance. |
| Shelf Life | 4261A shelf life: approximately 24 months when stored cool, dry, ventilated, away from sunlight and contaminants in sealed original packaging. |
At melt temperatures between 200 °C and 230 °C, Arya Sasol HDPE 4261A fills thin-wall dairy packaging geometries with sidewall sections as low as 0.45 mm without exceeding 110 MPa injection pressure. The grade exhibits a melt flow rate of 42 g/10 min at 190 °C/2.16 kg per ISO 1133-1:2022 and a density of 0.961 g/cm³ per ISO 1183-1:2019; typical flexural modulus for this high-flow density class falls between 1,200 MPa and 1,600 MPa under ISO 178:2019 at 2 mm/min. For this dairy-contact line, the compound is dry-blended at 96–98 wt% virgin HDPE 4261A, 2–4 wt% white polyethylene-based masterbatch, and, where low coefficient-of-friction denesting is required, 0.05–0.15 wt% erucamide-based slip additive. Regrind from same-line sprues and rejects is limited to 20 wt% and must be free of post-consumer material because milk-fat stress cracking can be amplified by degraded olefin fractions. The production process uses a valve-gated hot-runner tool with gate diameters of 0.8–1.2 mm, mould temperature held at 10–40 °C, holding pressure 30–60 MPa, and cycle time 6–12 s depending on shot mass. Compliance is anchored to EU Regulation (EU) No 10/2011 Annex I and Annex II with an overall migration limit of 10 mg/dm², 21 CFR 177.1520 paragraph (c) for olefin polymers, and GB 4806.7-2023 for polyolefin food-contact materials. Downstream articles emerging from this line include yogurt cups, dairy dessert pots, single-serve creamer tubs, and margarine tubs produced on high-speed packaging lines requiring stackability, sealing-ring flatness, and resistance to dairy oils.
Still-beverage caps demand a narrow sealing surface and a tamper-evident band that must retain hinge integrity at high speed, which places the processing window for Arya Sasol HDPE 4261A on the critical path. The blend ratio in closure manufacture is set at 97–99 wt% virgin HDPE 4261A, 1–2 wt% pigment masterbatch, and 300–800 ppm slip additive; regrind is held at or below 20 wt% and is typically excluded from cap classes intended for ultra-clean or organoleptically sensitive still-water products. In downstream processing, a 16- to 32-cavity cold-runner or hot-tip tool is used with melt temperatures of 210–240 °C, mould temperatures of 10–30 °C, and injection pressures of 70–120 MPa. The dominant process conflict is gate freeze time: if the hold pressure is removed before the 0.6–1.2 mm gate fully freezes, post-fill shrinkage in the cap deck can open a leakage path at the top seal. Production lines therefore set holding-time curves by ultrasonic gate-seal monitoring rather than by fixed timers, with hold pressures of 40–70 MPa on clamp units in the 1,000–2,500 kN range. Compliance for this segment follows EU Regulation (EU) No 10/2011, 21 CFR 177.1520, and EN 1186-1:2002 for total migration test methods; where closures are supplied for child-accessible household or non-food secondary uses, ISO 8317:2015 child-resistant package testing becomes an additional release criterion. Finished articles include 30/25 mm still-water caps, 38 mm juice and UHT-milk closures, and tamper-evident neck closures for non-carbonated drinks.
Overcap and cosmetic jar moulding uses the same high-flow HDPE 4261A but shifts the failure mode from filling pressure to thread-root stress cracking and torque decay after repeated opening cycles. The compound for overcap moulding contains 98–99 wt% virgin HDPE 4261A, 1–2 wt% custom color masterbatch, and 0.05–0.2 wt% antistatic additive when dust attraction on transparent display shelves is a concern; regrind at or below 15 wt% is permitted only with controlled moisture below 0.05 wt%. Tools are typically polished to SPI A-2 or A-3 surface finish in S136 steel, and mould temperatures of 20–50 °C are held above the dew point to prevent condensation marks on high-gloss surfaces. Melt temperature is set at 200–230 °C, injection pressure at 50–90 MPa, and holding pressure at 30–60 MPa; back pressure is capped at 15 MPa because excessive shear heating from high-flow HDPE can increase haze and reduce thread-root environmental stress crack resistance. Cycle times of 12–20 s are typical for jars with wall thicknesses of 1.5–3.0 mm. Compliance in this segment is governed by the packaging heavy-metal limit of 100 mg/kg for the sum of lead, cadmium, mercury, and hexavalent chromium under Directive 94/62/EC Article 11, with REACH Annex XVII restrictions applied to the masterbatch composition; the European Cosmetic Regulation (EC) No 1223/2009 does not replace packaging compatibility testing for aggressive ester-based formulations. End-of-line articles include shampoo overcaps, lotion closures, cosmetic jar bodies, and compact housings where thread torque retention and surface gloss are mandatory.
When toy components integrate snap-fit undercuts and wall thicknesses below 1.5 mm, Arya Sasol HDPE 4261A is processed at melt temperatures of 210–235 °C and mould temperatures of 20–40 °C to avoid sink marks opposite ribs and bosses. The recommended compounding split for this toy segment is 95–98 wt% virgin HDPE 4261A, 2–4 wt% toy-grade color masterbatch, and 0.05–0.2 wt% processing aid; clean in-house regrind is allowed up to 15 wt%, while post-consumer recycled content is excluded because trace heavy-metal variation complicates compliance. Downstream production uses high-injection-speed profiles with vent depths of 0.02–0.04 mm to prevent burn marks at flow-front convergence, ejection draft angles of 0.5–1.0°, and snap-fit radii of at least 0.3 mm at the root to reduce notch sensitivity. The processing conflict in this segment is not flow length but part ejection and impact toughness: moulding at excessive melt temperature or long residence time can shift the molecular weight distribution enough to lower Charpy notched impact strength when tested under ISO 179-1:2020 at 23 °C. Chemical compliance is anchored to EN 71-3:2019+A1:2021 for migration of certain elements, ASTM F963-23 for soluble heavy metals, and CPSIA Section 101 with a total lead limit of 100 mg/kg in accessible substrate material; all color masterbatches must also carry REACH SVHC clearance at ≤0.1 wt%. Moulded outputs include building blocks, stacking cups, shape sorters, play trays, and toy storage components.
| Downstream segment | Melt temperature (°C) | Mould temperature (°C) | Injection pressure (MPa) | Maximum regrind (wt%) | Dominant processing risk |
|---|---|---|---|---|---|
| Thin-wall dairy containers | 200–230 °C | 10–40 °C | 80–110 MPa | 20 wt% | Sealing-ring warpage from premature gate freeze |
| Still-beverage caps | 210–240 °C | 10–30 °C | 70–120 MPa | 20 wt% | Gate-seal timing and cap-deck leakage |
| Personal care overcaps | 200–230 °C | 20–50 °C | 50–90 MPa | 15 wt% | Thread-root stress cracking from high back pressure |
| Toy components | 210–235 °C | 20–40 °C | 80–110 MPa | 15 wt% | Notch sensitivity and ejection-induced impact loss |
| Drainage and cable-duct fittings | 210–240 °C | 20–35 °C | 90–130 MPa | 20 wt% | Weld-line depth and slow crack growth |
| Laboratory consumables | 190–220 °C | 15–30 °C | 70–100 MPa | 0 wt% | Reagent interaction and particulate contamination |
High-flow HDPE 4261A is acceptable for non-pressure drainage and cable-duct fittings, but it is not a substitute for bimodal extrusion-grade HDPE in pressure-rated electrofusion sockets; the lower melt viscosity and high flow of the injection grade reduce slow crack growth resistance compared with pipe-grade resins evaluated under ASTM D1693-21 Condition B at 50 °C. For black drainage fittings, the dry-blend proportions are 97–99 wt% virgin HDPE 4261A, 1–3 wt% carbon black masterbatch containing 40 wt% carbon black, and 0.05–0.2 wt% processing aid; regrind from non-food drainage moulding is limited to 20 wt%. Downstream production of elbows, couplers, and inspection chamber components uses sequential valve-gated multi-cavity tooling to reduce weld-line depth in thick bosses. Melt temperatures are set at 210–240 °C, mould temperatures at 20–35 °C, injection pressures at 90–130 MPa, and holding times at 10–25 s because wall sections of 2.5–6.0 mm require longer gate-seal time to control sink. Vent depths of 0.02–0.04 mm are maintained to avoid diesel burning at flow ends. Compliance is anchored to EN 1329-1:2014/AC:2016 for soil and waste discharge pipes and fittings inside buildings, and IEC 61386-1:2008/Amd 1:2017 for conduit systems; UV-stabilised black compounds are evaluated under ISO 4892-2:2013 for artificial weathering. End-of-line fittings include cable-duct elbows, conduit couplers, non-pressure drainage access covers, gully components, and underground cable draw-pit liners.
Laboratory racks, microplate storage trays, and diagnostic kit housings require replication of fine well identifiers and low particulate release, which makes HDPE 4261A a candidate when moulding is performed without external release agents. Resin feed is at 100 wt% virgin HDPE 4261A, with 0–1 wt% grey or white masterbatch and 0.05–0.2 wt% antistatic additive only when specified for automated plate handling; regrind and post-consumer content are excluded because trace contamination can interfere with downstream analytical sensitivity. The production process uses a cleanroom-compatible injection moulding cell with positive-air-pressure mould area, polished stainless-steel hopper, and dehumidified resin feed at ≤0.05 wt% moisture. Melt temperature is held at 190–220 °C, mould temperature at 15–30 °C, injection velocity high enough to reproduce micro-texture, and holding pressure at 25–45 MPa to avoid overpacking fine ribbed arrays. Mould release is mechanical or air-assisted; silicone-based sprays are incompatible because residue can contaminate wells. Compliance for non-patient-contacting laboratory packaging falls under REACH Regulation (EC) No 1907/2006, RoHS Directive 2011/65/EU Annex II for restricted substances, and CLP Regulation (EC) No 1272/2008; if a finished diagnostic device body is later classified as a medical device, resin supply does not confer ISO 10993-1:2018 biocompatibility and evaluation must be completed at the finished-device level. Moulded articles include test tube racks, microplate storage trays, non-infectious sample transport containers, and diagnostic kit outer housings.
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Arya Sasol HDPE 4261A is an injection-moulding high-density polyethylene supplied in pellet form. The grade belongs to the PE-HD family under ISO 17855-1. Its nominal melt mass-flow rate is 26 g/10 min when determined at 190 °C under a 2.16 kg load using ISO 1133-1:2022. Its nominal density is 0.956 g/cm³ when measured according to ISO 1183-1:2019. These values place the resin among high-flow HDPE injection grades used for thin-wall food packaging, caps, closures, crates, and technical components. Injection-moulding shrinkage is commonly reported as 1.0–2.0 % in the flow direction and 1.2–2.2 % transverse to flow under ISO 294-4:2018; actual shrinkage depends on mould temperature, wall thickness, gate location, and cooling layout. Published data for certain mechanical properties of this specific grade is limited, so load-bearing verification should rely on lot-specific testing of moulded plaques rather than generic HDPE datasheet values.
For injection moulding of HDPE 4261A, the melt temperature is ordinarily set between 200 °C and 240 °C, while the mould surface temperature is maintained at 10–40 °C. The lower mould temperatures reduce cooling time but increase the likelihood of weld-line weakness and orientation-induced shrinkage anisotropy. Because the resin has a relatively low melt viscosity for HDPE, excessive barrel residence time above 240 °C accelerates chain scission and can shift the MFR upward, producing flash and loss of mechanical stiffness. General-purpose screws with L/D of 20:1 to 24:1 and compression ratio of 2.5:1 to 3.5:1 are adequate for homogenisation; high-shear screws are not required and may generate over-shearing in hot-runner systems. Back pressure should be kept low, typically 0.5–1.0 MPa, to avoid excessive temperature rise. Pre-drying is not required under normal storage because HDPE is non-hygroscopic; if surface condensation forms after cold storage, hot-air drying at 70–80 °C for 1–2 h before hopper loading is sufficient.
In multicavity closure tooling, processing bottlenecks on production-scale hydraulic and electric injection machines are most often observed at the gate freeze-off point and in the packing-pressure transition. With a high-MFR grade such as 4261A, fill pressures in short-flow thin-wall cavities are lower than those required for lower-flow HDPE, but the packing window narrows because gates freeze quickly at cold mould temperatures. Machine operators frequently compensate by raising hold pressure, which can produce mould deflection and flash if clamp force is marginal. Projected-area calculations should use cavity pressure near the gate of 30–40 MPa during filling and 10–20 MPa during packing for thin-wall HDPE parts; however, these values depend on gate geometry and flow length. Published data for this specific configuration is limited, so process development on the actual tool remains necessary. Gate shear rates in thin-wall HDPE moulding frequently fall between 1,000 s⁻¹ and 10,000 s⁻¹; viscosity under these conditions is not captured by the low-shear MFR test. Fill-time and pressure predictions therefore require capillary or slit rheometry data rather than reliance on ISO 1133-1 alone.
| Selection parameter | Arya Sasol HDPE 4261A | Lower-flow HDPE injection grade | Impact-copolymer PP |
|---|---|---|---|
| Melt mass-flow rate | 26 g/10 min | 3–8 g/10 min | 8–25 g/10 min |
| Density | 0.956 g/cm³ | 0.950–0.960 g/cm³ | 0.900–0.905 g/cm³ |
| Flexural modulus, typical | 1100–1250 MPa | 900–1200 MPa | 1000–1500 MPa |
| Notched impact strength at 23 °C, typical | 3–5 kJ/m² | 8–20 kJ/m² | 15–45 kJ/m² |
| Environmental stress crack resistance | Lower than lower-flow HDPE | Higher | Not directly comparable |
| Typical converting process | Injection moulding, thin wall | Injection moulding, thicker sections, sheets | Injection moulding, caps, automotive parts |
The values in the table are representative industrial data for high-flow HDPE, lower-flow HDPE, and impact-copolymer polypropylene; they are not lot-specific specifications for 4261A. Differences arise from molecular architecture and crystalline morphology. The high MFR of 4261A reduces fill pressure and cycle time but also reduces notched impact strength and environmental stress crack resistance compared with lower-flow HDPE of similar density. Against impact PP, HDPE 4261A has higher density and lower low-temperature impact, but may provide better water-vapour barrier and different chemical resistance. Comparative data should be generated under ISO 527-2:2012, ISO 178:2019, and ISO 180/A:2019 when replacing one of these materials in an existing tool.
High-flow HDPE grades such as 4261A generally exhibit lower environmental stress crack resistance than lower-MFR polyethylene grades of similar density. The reduction is linked to shorter chain length and lower tie-molecule concentration in the solid state, which limits resistance to slow crack growth in the presence of surfactants, alcohols, or oils. Where a container or closure must withstand long-term contact with aggressive liquid formulations, the part designer should request lot-specific ESCR data generated according to ASTM D1693-21, using 100% Igepal CO-630 at 50 °C. Published data for this specific configuration is limited; therefore, acceptance criteria should be evaluated on an application-specific basis. If the geometry cannot tolerate stress cracking, a lower-flow HDPE or a purpose-modified bimodal HDPE may be substituted, accepting higher fill pressure and longer cycle time.
For thin-walled caps and closures produced on 48-cavity and 96-cavity hot-runner systems, the primary processing failure modes include incomplete filling from flow imbalance, core deflection, gate stringing, and post-moulding ovality. The 4261A grade’s high MFR shortens filling time and permits lower melt temperature in some tools, but the low melt strength can produce drool at hot nozzle tips during mould-open time. Nozzle tip temperatures are typically set 10–20 °C below the barrel front-zone setpoint to reduce drool. Maintaining mould-water supply temperature in the range 10–20 °C with turbulent flow improves consistency of part release and dimensional control. Cooling time for a 1.0 mm wall closure in a chilled tool is often 4–8 s; actual values depend on tool steel, cooling-circuit placement, and part mass. These production-scale observations are general to high-flow HDPE injection moulding and should be confirmed with side-by-side trials on the target tool.
Food-contact suitability of articles made from 4261A is not an inherent resin property; it depends on additive package, polymerisation residuals, colourants, regrind content, and end-use conditions. The olefin polymer base may fall within 21 CFR 177.1520(c) for high-density polyethylene when the grade is manufactured and used under applicable FDA food-contact conditions. For EU markets, the finished plastic article should comply with Regulation EU 10/2011 as amended, including the overall migration limit of 10 mg/dm² for plastic materials and articles intended to come into contact with food. Specific migration of additives must be checked against the positive list and any relevant SML. REACH Regulation EC 1907/2006 applies to the resin as a substance or mixture; a Safety Data Sheet should be consulted for handling and disposal. Heavy-metal limits for packaging and packaging waste under Directive 94/62/EC as amended by 2004/12/EC specify that the sum of lead, cadmium, mercury, and hexavalent chromium shall not exceed 100 ppm by weight. RoHS Directive 2011/65/EU may apply to electrical and electronic equipment components, but it is not a general food-contact requirement. Processors should request lot-specific compliance declarations from the resin supplier before use in regulated packaging.
Storage of pellet feedstock at ambient temperatures below 40 °C away from direct sunlight and moisture reduces oxidative degradation and surface contamination. Regrind from sprues, runners, and rejected parts may be reincorporated only after melt filtration and consistent drying; the proportion of regrind should be limited to 20 wt% or lower to avoid viscosity drift and black-spec formation in thin-wall parts. During purging, a low-MFR PE or a commercial purge compound can be used; the barrel should be purged thoroughly after processing heat-sensitive colourants to prevent cross-contamination. These handling constraints define the operational boundary for high-cavitation injection moulding with 4261A.