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Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11

    • Product Name: Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 519492
    Material Polyamide 11 (PA11)
    Color Blue
    Form Fine powder
    Particle Size D50 35 µm
    Particle Size D90 70 µm
    Specific Gravity 1.04 g/cm3
    Bulk Density 0.45 g/cm3
    Melting Point 185 °C
    Water Absorption 24h 0.35 %
    Tensile Strength 45 MPa
    Elongation At Break 300 %
    Shore D Hardness 75
    Dielectric Strength 20 kV/mm
    Maximum Service Temperature 100 °C
    Minimum Service Temperature -40 °C

    As an accredited Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11 is supplied in 20 kg cardboard boxes with inner polyethylene liner for safe, moisture-protected handling.
    Container Loading (20′ FCL) Container Loading (20′ FCL): Load 20-foot container with Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11, securing evenly and protecting from moisture.
    Shipping Rilsan Fine Powders T BLUE 7174 MAC PA11 ships in sealed, moisture-resistant polyethylene-lined containers to prevent contamination. It is not regulated as hazardous for ground transport, but loads should stay dry and away from ignition sources. Use standard freight with secure palletizing and clear labeling to ensure safe handling.
    Storage Store Rilsan Fine Powders T BLUE 7174 MAC PA11 in its original, tightly closed container in a cool, dry, well-ventilated area. Protect from moisture, direct sunlight, and heat sources. Keep away from open flames, sparks, and strong oxidizers. Avoid generating dust; use grounded equipment and follow static electricity precautions.
    Shelf Life Shelf life is typically 2 years when stored unopened in original, dry, cool conditions, away from moisture and direct sunlight.
    Application of Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11

    Arkema Rilsan Fine Powders T BLUE 7174 MAC PA11 is supplied as a single-component thermoplastic coating powder; no stoichiometric hardener adjustment, induction time, or post-blend curing agent is required. The polymer is polyamide 11 derived from castor oil, with a crystalline melting point typically reported between 183°C and 187°C and a dry-service temperature envelope from -40°C to 90°C. The MAC designation identifies a fine-micronised cut intended for fluidized bed dip coating and electrostatic spray processes. Particle size distribution is lot-dependent and must be verified against the certificate of analysis because D50 and D90 values control fluidized bed expansion ratio, electrostatic transfer efficiency, and final film smoothness. Powder flow and moisture content are characterised according to the relevant parts of the ISO 8130 series. The material is thermoplastic, not thermoset; film formation relies on melting, coalescence, and recrystallization rather than crosslinking. Dry storage at 15–30°C in sealed containers is necessary to prevent moisture uptake. Powder exposed to relative humidity above 60% may require pre-drying at 70–80°C for 4–6 h before use. Contamination with epoxy, polyester, or polyamide 12 powders alters melt rheology, gloss, adhesion, and colour. Dedicated hoppers, cyclones, and sieve screens are required for changeover.

    What Limits Fluidized Bed Film Formation on Dishwasher Basket Wire Goods?

    Carbon steel wire goods for dishwasher baskets are degreased, grit-blasted to Sa 2½ per ISO 8501-1:2007, and preheated in a convection oven to 280–350°C. The preheat temperature must compensate for the thermal mass of the wire basket and for the residence time between oven and fluid bed. In the fluidized bed, porous polyethylene or sintered metal distributor plates fluidize the blue PA11 powder with compressed air dried to a pressure dew point below -40°C. Immersion time ranges from 2 s to 8 s, depending on wire diameter and target film thickness. A single dip can deposit 250–450 µm; thicker sections may require a second pass after surface reheating. Film thickness is measured after cooling by ISO 2178:2016 on magnetic steel. The critical defects are pinholes from moisture escaping the substrate or powder, thin edges from insufficient preheat, and webbing between closely spaced wires from excessive film build. Post-fusion is performed in a second oven at 220–250°C for 3–5 min to complete coalescence and to eliminate residual powder porosity. If the workpiece surface temperature falls below 183°C before contact with the powder, adhesion fails by dry fill rather than melt bonding. In production, basket jigs are designed to minimize contact marks, and compressed air blow-off is used to remove loosely deposited powder from drain holes. Salt spray resistance of the final blue coating is commonly checked using ISO 9227:2022, method NSS, for 1,000 h, with evaluation of rust creep from scribe according to ISO 4628-8:2012. Edge coverage on wire ends is the principal failure site because the sharp radius cools faster and the powder layer is thinner; minimum edge thickness below 80 µm is rejected in high-detergent service.

    In electrostatic spray application to thin-wall spring steel clips, transfer efficiency is limited by Faraday cage geometry in V-bends and clip loops. The powder is charged by a corona gun at 60–80 kV and the parts are grounded through a conveyor with contact resistance below 1 MΩ. The fine particle size distribution of T BLUE 7174 MAC allows deposition on recessed areas, but film thickness in internal corners typically remains 40–60% lower than on flat surfaces. To compensate, the clips are preheated to 220–250°C before spraying so that the first particles melt immediately and build a conductive layer for subsequent deposition. Virgin powder is blended with reclaimed overspray at a ratio that maintains the D90 below the supplier's upper limit; for thin-film clips, reclaimed material is typically held at 10–15 wt% because higher fractions raise back-ionization and orange peel. Total film thickness is set between 150 µm and 250 µm for spring clips. Post-spray fusion is carried out at 220–240°C for 5–10 min; overheating above 250°C reduces the blue colour consistency and can raise the melt viscosity through thermal-oxidative branching. Finished clips are tested for impact resistance under ISO 6272-1:2011 at 2.5 J direct impact and for flexibility through 180° bending of spring steel. The coating must not crack at the bend radius because PA11 crystallinity developed during slow cooling can embrittle the film; water mist cooling is sometimes used to reduce crystallinity. Pre-cleaning uses alkaline degreasing followed by a phosphoric acid-based iron phosphate conversion coating not exceeding 1.5 g/m² coating weight, which is then rinsed and dried before powder application.

    When T BLUE 7174 MAC Is Selected for Outdoor Steel Furniture and Handrails

    Public outdoor steel furniture and handrails are coated with T BLUE 7174 MAC where the specification requires both corrosion protection and a controlled blue colour space that can be matched across multiple production batches. The steel is prepared to Sa 2½ or St 3 according to ISO 8501-1:2007. Fluidized bed dip coating is preferred for tubular frames because it produces a continuous 300–500 µm film around hollow sections. The powder is applied directly to hot steel at 300–360°C; the metal temperature must be high enough to flow out the powder within 30–60 s but not so high that the blue pigment oxidizes. Post-fusion at 220–250°C is needed for full densification. For outdoor exposure, ultraviolet radiation and humidity cycling cause gradual chalking and colour shift; the PA11 binder is less prone to hydrolytic degradation than short-chain polyamides, but the blue pigment may fade after several years of direct sunlight. Published multi-year weathering data for this specific blue grade is limited; a lot-specific weatherability study should be requested when exterior colour retention is part of the specification. Coatings in exterior service should be evaluated by ISO 16474-2:2013 or ASTM G154 for colour retention and by ISO 6270-1:2017 condensation testing for blistering. Abrasion resistance of handrails is measured with ASTM D4060-19, CS-17 wheel, 1,000 g load, with mass loss reported per 500 cycles. Impact at outdoor temperatures down to -20°C is checked because the coating must not shatter when struck by maintenance equipment. The terminal product is a colour-coded public furniture element with the same PA11 coating as industrial components; the blue shade is often used to distinguish pedestrian areas or municipal property.

    Cleanroom transit carts and surgical instrument racks made from austenitic stainless steel are coated with T BLUE 7174 MAC to provide electrical insulation, resistance to detergent washdown, and a low-glare coloured surface. Stainless steel is first degreased and lightly blasted with aluminium oxide to a profile of 2–4 µm; the blast profile must remain low to avoid deep anchor patterns that transfer through the film. Preheat at 280–320°C is lower than for carbon steel because stainless steel oxidizes less but releases heat more quickly; temperature uniformity across thin sheet is critical. Electrostatic spray or fluidized bed dip can be used; electrostatic spray is preferred for sheet metal because film thickness can be held at 150–250 µm without excessive edge build. The coated carts are fused at 230–250°C for 5–8 min and then cooled in still air. The finished surface is resistant to repeated cleaning with quaternary ammonium disinfectants, dilute hydrogen peroxide, and non-ionic detergents; resistance is evaluated by ISO 2812-1:2017 immersion or spot tests. If the coated part is classified as a medical device surface, biocompatibility testing according to ISO 10993-5:2009 and ISO 10993-10:2010 is the responsibility of the device manufacturer and cannot be inferred from powder composition alone. The coating also provides a dielectric barrier; breakdown strength is measured by ASTM D149-20 on flat coupons, and end-use specifications are set according to the equipment manufacturer's electrical safety requirements. The blue colour is used for zone identification in hospital logistics systems.

    In commercial bakery and cold-chain food handling installations, T BLUE 7174 MAC is applied to steel wire racks, proofing frames, and trolley baskets by fluidized bed immersion. The wire goods are degreased, blasted to Sa 2½, preheated to 280–350°C, and immersed for 2–6 s to deposit a film of 250–450 µm. Post-fusion is carried out at 220–250°C for 3–5 min. Food-contact suitability of the finished article must be established under 21 CFR 175.300 or the equivalent regional food-contact regulation; compliance is article-dependent and requires extraction testing according to the relevant migration test method. The coating withstands repeated washing with low-concentration alkaline chlorinated cleaners at pH below 11, but immersion in strongly oxidizing sanitizers above 60°C may cause surface roughening; published data for specific sanitizer cycles is limited. The terminal product is a blue-zoned food handling rack that remains identifiable after repeated washdown and transport.

    Corrosion Protection of Valve Bodies and Pump Housings in Marine Atmosphere

    Centrifugally cast ductile iron valve bodies and pump housings are grit-blasted to Sa 2½, degreased, and preheated to 320–380°C before fluidized bed immersion in T BLUE 7174 MAC. The higher preheat is required because the thick metal sections cool rapidly during transfer; the powder must fuse within 5–15 s. Film thickness is specified at 350–600 µm for external surfaces exposed to marine salt spray. The final coating is post-fused at 220–250°C for 8–12 min and slow-cooled to ambient to reduce shrinkage stress around flanges and bolt holes. In marine atmosphere, the PA11 film functions as a barrier against chloride ingress; performance is tested by neutral salt spray ISO 9227:2022, NSS, 1,000–2,000 h, and by humidity condensation ISO 6270-1:2017. Adhesion is checked by ISO 2409:2020 cross-cut on witness panels and by ISO 4624:2016 pull-off where required; typical accepted pull-off values for this class of coating exceed 10 MPa. The blue coating also resists dilute inorganic acids up to 10% sulfuric acid at 23°C, aliphatic hydrocarbons, and seawater. Immersion in concentrated sulfuric acid above 50% or hot formic acid is not recommended; published data for long-term service in these media is limited. Machined sealing faces are masked before coating, and threaded connections are chased after fusion to restore dimensional tolerances. The terminal product is a coated industrial flow component identifiable by colour for maintenance and safety coding.

    Performance propertyTest methodTypical verification condition
    Dry film thicknessISO 2178:2016 / ISO 2360:2017Fluid bed 250–450 µm; electrostatic spray 150–250 µm
    AdhesionISO 2409:2020Cross-cut classification 0–1
    Impact resistanceISO 6272-1:20112.5 J direct impact, no cracking
    Salt spray resistanceISO 9227:2022Method NSS, 1,000 h, scribe creep <2 mm
    Abrasion resistanceASTM D4060-19CS-17 wheel, 1,000 g load, report mass loss after 500 cycles
    Chemical resistanceISO 2812-1:201730 d immersion in 10% NaOH, 10% H₂SO₄, mineral oil at 23°C
    Pencil hardnessISO 15184:2020Pencil range HB–F
    Dielectric strengthASTM D149-20Report breakdown voltage in kV/mm

    Acceptance values in Table 1 are application-specific starting points and must be confirmed against the lot certificate and the end-use specification.

    For line-side repair of mechanically damaged T BLUE 7174 MAC films, the damaged area is cleaned, preheated to 220–250°C, and the powder is applied by local flame spray or hot-tool fusion; the repair thickness must match the adjacent film within ±50 µm to avoid a visible step.

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    Certification & Compliance
    More Introduction

    Arkema Rilsan Fine Powders T BLUE 7174 MAC is a formulated polyamide 11 coating powder supplied for fluidised-bed dipping, electrostatic spray deposition, and hot-flocking operations on metallic substrates. The grade combines blue 7174 pigmentation with a modified adhesion and anti-corrosion package; the base polymer is a semi-crystalline polyamide 11 synthesised from 11-aminoundecanoic acid derived from castor oil. The renewable carbon fraction of the base resin can be quantified by ASTM D6866. The MAC designation indicates a metal-adhesion-corrosion additive system in addition to the blue pigment, but the exact stabiliser and pigment loading are formulation-specific and should be confirmed against the Arkema technical data sheet. The powder is not a generic natural PA11; it is intended for applications where a specified blue colour and improved adhesion behaviour under corrosive exposure are required.

    Compared with polyamide 6 and polyamide 66 coating powders, the polyamide 11 backbone carries a lower amide-group frequency because of its longer 11-carbon repeat sequence. This structural feature reduces equilibrium moisture uptake and improves dimensional retention in humid service. Typical base-resin values measured under ISO 62 place polyamide 11 saturation water absorption at 1.8%–2.0%, whereas polyamide 6 grades absorb 9.0%–9.8% and polyamide 12 grades absorb 1.5%–1.7%. Density measured under ISO 1183-1 is typically 1.03–1.05 g/cm³ for polyamide 11, 1.13–1.15 g/cm³ for polyamide 6, and 1.01–1.02 g/cm³ for polyamide 12. These are base-resin ranges, not grade-specific maxima for the blue MAC powder. The lower moisture uptake of PA11 becomes significant when coated components are exposed to repeated condensation, alkaline washdown, or outdoor weathering where PA6 coatings may exhibit measurable dimensional movement and adhesion stress.

    Why is moisture uptake the first discriminator when replacing PA6 powder on a coating line?

    Polyamide 6 provides higher short-term stiffness, but its moisture absorption changes both film modulus and corrosion-barrier behaviour in washdown environments. Production-scale fluidised-bed lines running PA6 often require sealed powder hoppers with desiccant beds to hold powder moisture below 0.20% during humid summer months. With polyamide 11, the lower equilibrium uptake relaxes the drying boundary: typical PA11 coating powders are pre-dried at 80–90 °C for 4–6 h in dehumidified-air ovens to a residual moisture target below 0.15%, while PA6 may require longer residence or vacuum drying to reach the same point. Bulk density and powder fluidisation are also affected by moisture because water films on particle surfaces increase interparticle cohesion. For a fluidised-bed line with a 600 mm porous plate, this cohesion appears as channel formation and bed collapse when the feed air dew point drifts above 0 °C. The blue MAC grade should be treated as moisture-sensitive during transfer from storage to feed hoppers.

    Particle-size control, melt viscosity, and thermal transitions in the blue 7174 MAC grade

    Melting behaviour determined by differential scanning calorimetry according to ISO 11357-3 shows the main endotherm near 186 °C for PA11, with crystallisation onset near 150–160 °C under standard 10 K/min cooling; the exact peak shape for the blue grade is influenced by pigment nucleation and is batch-specific. Melt flow rate for coating-grade PA11 is commonly measured at 235 °C under 2.16 kg load according to ISO 1133-1:2022. The exact value for T BLUE 7174 MAC should be taken from the lot certificate, but pigmented coating grades are generally adjusted into a controlled melt-viscosity window to promote film coalescence without excessive sag on vertical surfaces. Sag resistance is more sensitive to melt viscosity than to particle size, and a tight melt-flow window of ±15% around the nominal lot value is required for automated electrostatic spray lines. The grade is not intended for rotational moulding or extrusion; its particle-size distribution is optimised for powder deposition processes.

    Representative base-resin property contrast for polyamide 11, polyamide 12, and polyamide 6 coating powders
    Property / test method Polyamide 11 Polyamide 12 Polyamide 6
    Density, ISO 1183-1 1.03–1.05 g/cm³ 1.01–1.02 g/cm³ 1.13–1.15 g/cm³
    Water saturation, ISO 62 1.8%–2.0% 1.5%–1.7% 9.0%–9.8%
    Melting peak, ISO 11357-3 186 °C 176–178 °C 220–222 °C
    Shore D hardness, ISO 868 70–77 62–68 75–80
    Tensile modulus, ISO 527-2 1200–1500 MPa 1000–1300 MPa 2500–3000 MPa

    For fine powder coating grades, particle-size distribution is controlled by laser diffraction per ISO 13320-1. Typical fine powder electrostatic spray grades maintain a median particle size below 80 µm, but the blue 7174 MAC grade may be adjusted toward finer tails to reduce orange peel in thin films. Dry-bulk density measured per ISO 60 and tapped density per ISO 787-11 should be monitored on incoming lots because changes above ±10% shift gravimetric hopper feed rates and bed expansion height. A production line using gravimetric dosing at 2.5 kg/h and an electrostatic gun with a flat-spray nozzle can generate coating thickness in the 80–200 µm range, but the exact deposition efficiency depends on grounding continuity and powder resistivity. Surface resistivity of PA11 powder typically falls in the 1010–1013 Ω range under IEC 61340-2-3 test conditions; this range supports electrostatic charging without rapid self-discharge.

    When the deposition method shifts from fluidised-bed dipping to electrostatic spray on cold parts

    The thermal mass of the substrate controls the practical preheat strategy. In fluidised-bed dipping, steel parts are heated to 300 °C ± 10 °C and lowered into the fluidised powder for 5–20 s to build a fused coating; sections above 8 mm wall thickness may require a higher oven setpoint or longer recovery to avoid under-fusion at the powder/metal interface. For electrostatic spray on cold parts, the powder is applied to a degreased and phosphatised surface, then post-fused at 200–260 °C for 5–15 min depending on part mass. The key process conflict is that a high post-fusion temperature accelerates film flow and removes porosity, but a temperature above 280 °C can initiate yellowing of the blue pigmentation and may reduce impact-absorbing molecular weight through chain scission. On a continuous mesh-belt oven with a 3.5 m heated zone and belt speed of 0.8 m/min, the effective dwell is approximately 4.4 min; this may be sufficient for thin-film electrostatic deposition but marginal for heavy fluidised-bed sections unless the oven includes infrared preheating.

    Batch-to-batch variance in blue pigment dispersion can shift the electrostatic charge-to-mass ratio. If powder reclaimed from overspray is blended with virgin powder above 35% by mass without controlling fine-particle content, deposition rate may become unstable because fines charge more rapidly and can produce back-ionisation. A process limit observed on automatic lines is a reclaimed-to-virgin ratio below 30% unless the powder recovery cyclone is equipped with a classifier that returns only particles above 10 µm to the feed hopper. For the MAC grade, metal-adhesion modifiers may increase powder moisture sensitivity, so storage in sealed containers at 20–25 °C and 30–50% RH is required before transfer to the fluidised bed. In continuous lines, hopper residence time should be kept short to prevent fines segregation induced by vibration.

    Adhesion of the blue MAC grade is evaluated after substrate preparation to ISO 8501-1 cleanliness Sa 2.5 with a blast profile of 40–75 µm Rz measured by ISO 4287. Zinc phosphate or iron phosphate conversion layers can further stabilise the coating-to-metal interface; however, residual phosphate sludge in blind holes or tapped threads may cause delamination under thermal cycling. Pull-off adhesion measured by ISO 4624 on prepared steel typically exceeds 10 MPa for PA11 coatings at 250–350 µm thickness, with cohesive failure in the coating layer being the dominant mode. Cross-cut classification under ISO 2409 is generally 0–1 for a properly fused PA11 film on grit-blasted steel, but the exact result for the blue MAC grade depends on film thickness and substrate geometry. Where sharp edges are present, edge rounding is necessary before coating because PA11 melts retract from sharp edges during post-fusion, leaving localised thin spots below 50 µm.

    Chemical and photochemical resistance thresholds in corrosive industrial washdown service

    Polyamide 11 coatings resist aliphatic hydrocarbons, diesel fuel, hydraulic oils, and alkaline cleaning media under ISO 175 immersion testing. Aromatic solvents, strong mineral acids, phenols, and cresols attack the polyamide chain and remain outside the recommended service envelope. In neutral salt spray testing to ISO 9227, production-coated steel panels at 250–350 µm film thickness commonly show scribe creep below 3 mm after 1,000 h when a zinc phosphate conversion layer is present; published data for the specific blue MAC formulation is limited because end-user surface preparation and edge geometry control the result more than the polymer itself. Cleaning protocols using 2.0% sodium hydroxide at 60 °C for 30 min cycles do not normally hydrolyse PA11 rapidly, but continuous exposure to hot caustic above 80 °C can reduce molecular weight and should be validated by tensile testing of free films before line qualification. Pigmented grades may exhibit colour shift under ultraviolet exposure; accelerated weathering by ISO 4892-2 is therefore required when appearance retention is a specification point.

    Typical test designations used for lot release and application qualification of polyamide 11 powder coatings
    Property / requirement Standard Typical condition or reference
    Melt flow rate ISO 1133-1:2022 235 °C, 2.16 kg
    Melting peak ISO 11357-3 186 °C base resin
    Particle-size distribution ISO 13320-1 Fraction below 80 µm
    Surface preparation ISO 8501-1 Sa 2.5
    Adhesion rating ISO 2409 Cross-cut classification
    Salt spray resistance ISO 9227 Neutral salt spray, scribe panel
    Chemical resistance ISO 175 Immersion in specified fluid

    Pigmented PA11 coating powders must be kept away from moisture, direct sunlight, solvents, and silicone-based release agents. Silicone contamination even at monolayer levels causes cratering during film fusion. The powder should not be dry-blended with epoxy or polyester powder coatings because differences in melt viscosity and charge decay rates produce phase separation and surface defects. The MAC grade contains metal-adhesion additives; therefore, blending with natural polyamide 11 reclaim may reduce the concentration of these additives below the intended active level. In production-scale fluidised beds, powder exposed to relative humidity above 60% should be dried in a desiccant-air oven before returning to the bed. The upper storage temperature should not exceed 35 °C to prevent sintering of low-melting fines. Under these conditions, PA11 coating powders are typically stable for 12–24 months in sealed original packaging; however, lot-specific shelf life must be confirmed from the technical data sheet.

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