| HS Code | 959643 |
| Material | Polyamide 11 (PA11) |
| Color | White |
| Particle Size D50 | 40 µm |
| Density | 1.04 g/cm³ |
| Bulk Density | 0.45 g/cm³ |
| Melting Point | 184-189 °C |
| Water Absorption | 1.2 % |
| Tensile Strength | 45 MPa |
| Elongation At Break | 300 % |
| Shore D Hardness | 72 |
| Abrasion Resistance | Taber wear < 15 mg/1000 cycles |
| Chemical Resistance | Excellent resistance to chemicals, oils and solvents |
| Electrical Insulation | High dielectric strength ~25 kV/mm |
| Bio Based Carbon Content | 100 % from renewable castor oil |
As an accredited Arkema Rilsan Fine Powders P6136 WHITE RDP 40 FB PA11 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | 25 kg bag of Arkema Rilsan Fine Powders P6136 WHITE RDP 40 FB PA11, white polyamide 11 powder for coating applications. |
| Container Loading (20′ FCL) | 20' FCL container loading of Arkema Rilsan Fine Powders P6136 WHITE RDP 40 FB PA11, polyamide powder, palletized and secured. |
| Shipping | Ship as non-hazardous fine polymer powder in sealed, moisture-resistant packaging. Keep dry and away from ignition sources and incompatible materials. Transport in clean, covered vehicles to prevent contamination. Ensure proper labeling with product name and handling precautions. Protect bags from damage, heat, and humidity during transit. |
| Storage | Store Rilsan Fine Powders P6136 WHITE RDP 40 FB PA11 in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Keep the original container tightly closed to prevent moisture absorption and contamination. Avoid dust accumulation and static discharge. Maintain temperatures below 40°C. Use appropriate grounding during handling. |
| Shelf Life | Shelf life is typically 12 months from manufacture when stored in original, unopened container under cool, dry conditions. |
Arkema Rilsan Fine Powders P6136 WHITE RDP 40 FB is a white polyamide 11 powder supplied for dry-process metal coating lines using fluidized-bed immersion and electrostatic spray deposition. The grade designation indicates a nominal median particle size of 40 µm, which balances fluidized-bed expansion against electrostatic wrap on edges and punched holes. Physical data for PA11 of this class are determined under ISO 1183-1:2019, with density in the 1.03–1.05 g/cm³ range, and under ISO 11357-3:2018, with the melting endotherm onset near 185 °C. That melting boundary defines the minimum practical metal preheat temperature; parts heated below the boundary retain unmelted powder at the substrate interface, producing pinholes and low adhesion at the coating base. Powder moisture is controlled to 0.15 wt% or below in accordance with ISO 15512:2019; storage or handling above 60 % relative humidity requires drying at 80 °C for 4–6 h in dehumidified air before the powder is returned to the fluid bed. Because P6136 WHITE RDP 40 FB is applied as a 100 wt% dry powder without solvent, co-reactant, or plasticizer dilution, the formulation addition ratio in all downstream scenarios is governed by film thickness control and optional dry flow aids rather than by liquid paint let-down.
In automotive seat belt mechanism coating lines, P6136 WHITE RDP 40 FB is applied to low-carbon steel stampings after alkaline degreasing and grit-blasting to Sa 2½ under ISO 8501-1. The blast profile provides mechanical anchorage; adhesion tested under ISO 2409:2020 falls below class 0 at dry-film thicknesses above 300 µm when the profile is not maintained. The parts are preheated in a gas-fired convection oven with an air temperature uniformity of ±5 °C across the load, with thin stampings reaching the lower preheat boundary of 280 °C in 8–12 min and thicker brackets requiring up to 20 min. Fluidized-bed immersion at 280–320 °C is carried out for 2–6 s in a bed charged with 100 wt% P6136 WHITE RDP 40 FB. The powder charge is not solvent-reduced; if bed expansion becomes uneven at relative humidity above 60 %, the only formulation adjustment is the dry addition of 0.1–0.3 wt% fumed silica. Post-fusion is conducted at 220–240 °C for 2–4 min, and the final coating thickness is maintained at 250–400 µm. A minimum of 250 µm is required because punched-hole edges below that value exhibit base-metal corrosion in ISO 9227:2022 neutral salt spray before 1,000 h. Acceptance commonly limits scribe creep to 2 mm and requires post-exposure cross-cut adhesion no lower than class 0. Terminal finished parts include seat belt height adjuster covers, parking brake cable guides, fuel filler flap springs, and bonnet release cable brackets.
Welded carbon steel wire goods for dishwasher interiors are coated with P6136 WHITE RDP 40 FB by fluidized-bed dipping after zinc phosphating and passivation. The phosphate layer provides temporary corrosion protection and wet adhesion, but it does not serve as a paint primer; the PA11 powder is applied at 100 wt% solids with no solvent, no curing agent, and no plasticizer, so the addition ratio at the applicator is 100 % as supplied. The baskets are preheated to 300–350 °C in a continuous chain oven, with the upper boundary controlled to prevent zinc phosphate dehydration and the lower boundary controlled to produce full melt at wire intersections. Copper-free racking is used to avoid galvanic staining during preheat. Immersion lasts 2–5 s depending on wire diameter and basket geometry, after which residual heat completes fusion and air cooling follows. The resulting coating thickness is specified at 300–500 µm on the outer wire surface and at least 200 µm at wire intersections, because intersection regions are stress concentrations during loading and unloading. Food-contact compliance for the finished basket is assessed under Commission Regulation (EU) 10/2011, with overall migration testing according to EN 1186-1:2002; for North American hardware, the resin is evaluated under FDA 21 CFR 177.1500, with end-use extraction testing on the coated article. Detergent resistance is evaluated by immersion in 1 % sodium hydroxide and 1 % nonionic detergent solution at 60 °C for 24 h under ISO 2812-1:2017, with blistering or adhesion loss treated as rejection criteria. Terminal products include cutlery baskets, glass racks, small-item baskets, bottle holders, and dishwasher interior hooks.
Electrostatic deposition of P6136 WHITE RDP 40 FB on aluminium busbar segments for electric vehicle battery disconnect units is a multi-pass process in which 100 wt% dry powder is sprayed through corona guns charged to negative 60–80 kV. Aluminium is degreased and conversion-coated before preheating to 220–250 °C; the lower preheat boundary is set by the PA11 melting endotherm, while the upper boundary is constrained by conversion coating dehydration and substrate oxidation. A gun output of 80–120 g/min per nozzle is typical, with 2–4 spray passes required to reach a final coating thickness of 300–600 µm. Between passes, the substrate is held at 220–250 °C for 1–2 min to fuse the previous layer and prevent trapped air at layer interfaces. Final cure is 220–240 °C for 8–12 min, depending on busbar cross-section. Dielectric performance is tested according to IEC 60243-1:2019; published data for this specific grade and busbar geometry is limited, but PA11 insulation coatings of this class typically exhibit dielectric strength in the 18–25 kV/mm range. A 400 µm coating therefore has a theoretical withstand above 7 kV, yet pinhole-free coverage is the controlling parameter rather than bulk dielectric strength. Thinning at bend radii below 250 µm is a known failure mode, because electrostatic wrap is reduced on the outer radius; busbar bending after coating is therefore avoided, and pre-formed busbars are processed. DC holiday detection after final cure is performed at 1–3 kV per 100 µm of thickness, with any pinhole triggering rework. Corrosion resistance is verified on aluminium test coupons under ISO 9227:2022 for 1,000 h, with limited creep from intentional damage. Terminal finished products are insulated busbar segments, rigid cell interconnect plates, and high-voltage busbar bends in battery packs.
Marine deck hardware such as cleats, hinges, and light housings is subjected to chloride loading, UV exposure, and mechanical impact that thin polyester topcoats fail under scribe-creep conditions. P6136 WHITE RDP 40 FB is applied to blast-cleaned carbon steel or stainless steel at a thickness of 250–500 µm using fluidized-bed immersion. The formulation addition ratio is 100 wt% powder; no primer, topcoat, or solvent is used, and the final film is a single-layer structure rather than a multi-coat system. Preheating is 280–320 °C for forged steel hardware, with dwell time adjusted to section mass; thin stamped light covers are held at the lower preheat boundary to reduce thermal distortion. Immersion lasts 3–6 s, followed by post-fusion at 220–240 °C for 3–5 min and air cooling. Salt-spray acceptance for marine-grade hardware is commonly set at 2,000 h under ISO 9227:2022, with no blistering beyond 1 mm from the scribe and no base-metal corrosion on adjacent flat surfaces. The PA11 film resists chloride creep because it does not rely on hydrolytically unstable polyester binder groups; however, surface preparation controls performance more than excess film thickness, and carbon steel parts with chloride-contaminated blast media can fail before 500 h. Adhesion after exposure is evaluated under ISO 4624:2016 pull-off testing, with values above 10 MPa on blast profiles of 50–75 µm. Terminal products include deck cleats, hatch hinges, navigation light housings, railing brackets, and mast step fittings.
Hospital bed side rails and IV pole hooks coated with P6136 WHITE RDP 40 FB are processed on electrostatic spray lines similar to automotive bracket lines, but the acceptance criteria are shifted toward surface cleanliness and impact resistance rather than under-hood heat aging. The metal parts are stainless steel, degreased, and passivated before preheating to 220–250 °C. The PA11 powder is sprayed at 100 wt% solids with no solvent or curative; for complex tubular geometries, a second pass is added only where the first pass leaves dry-film thickness below 250 µm. Post-cure is 220–240 °C for 5–10 min, producing a coating thickness of 250–400 µm on accessible surfaces and not less than 200 µm at edges and welds. Because the raw powder is not itself a medical device, biocompatibility is assessed on the finished coated component by cytotoxicity screening under ISO 10993-5:2009, while the device manufacturer’s lot traceability and surface defect classification are controlled under ISO 13485:2016. Cleaning validation uses hospital-grade quaternary ammonium disinfectants and 70 % isopropanol wipes, with gloss change and softening inspected after repeated cleaning cycles. Steam sterilization at 121 °C is outside the continuous service temperature under load for PA11 coatings and requires component-specific validation before adoption. Terminal finished products include hospital bed side rails, IV pole hooks, wheelchair footrests, surgical table accessory rails, and medical cart castor housings.
Cast iron centrifugal pump impellers and valve bodies are coated with P6136 WHITE RDP 40 FB to reduce erosive wear and prevent metallic contamination in low-temperature chemical transfer. The powder is used at 100 wt% as supplied; no plasticizer or solvent is added, and the coating is not crosslinked, so localised damage can be repaired by reheating the component and applying additional powder to the affected area. Before coating, castings are degreased, blasted to Sa 2½ under ISO 8501-1, and preheated to 320–350 °C because heavy sections require a higher heat reservoir than sheet metal parts. Cast iron can outgas from residual casting oil during preheat; a degassing hold at the upper preheat boundary for 5–10 min is used before immersion. Fluidized-bed immersion lasts 5–10 s, followed by post-fusion at 240–250 °C for 5–10 min, producing a coating thickness of 400–800 µm. Chemical resistance is tested under ISO 2812-1:2017 by immersion in 10 % sodium hydroxide, 10 % sodium chloride, and an aliphatic hydrocarbon test fluid at 23 °C for 7 days; acceptance criteria are no blistering, no softening greater than 2 Shore D points under ISO 7619-1:2010, and no adhesion loss greater than one rating step under ISO 2409:2020. Continuous service is limited to aqueous chemical streams below 60 °C; above this limit, the PA11 coating softens under load and should not be specified for impeller service. Terminal products include centrifugal pump impellers, valve bodies, filter housings, and recirculation pump suction covers.
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Arkema Rilsan Fine Powders P6136 WHITE RDP 40 FB PA11 is a white-pigmented polyamide 11 powder supplied in a controlled fine particle-size cut for dry-powder coating of metallic substrates. The designation P6136 identifies the white formulation; RDP 40 denotes a particle-size class whose acceptance interval is reported on the certificate of analysis by laser diffraction under ISO 13320; FB indicates fluidized-bed compatibility. The base polymer is polyamide 11, a semi-crystalline thermoplastic synthesized from 11-aminoundecanoic acid of castor oil origin. In the cured film, the repeating amide group density—one amide linkage per eleven carbon atoms—produces lower moisture affinity than PA6 or PA66 while maintaining a higher melting point than PA12. The white variant contains titanium dioxide pigment dispersed in the PA11 matrix; this modifies dielectric constant, melt viscosity, and hiding power relative to unpigmented or black grades. Because titanium dioxide is refractory and non-melting, extrusion and milling conditions alter the apparent melt flow and particle shape. No batch acceptance decision should be made without the certificate of analysis reporting particle size distribution by ISO 13320, melt temperature by ISO 11357-3, and powder moisture content by ISO 15512 or Karl Fischer titration.
The primary differences are not limited to color. Black Rilsan ES grades commonly contain carbon black as a UV-stabilizing and charge-modifying pigment; carbon black lowers surface resistivity and can assist electrostatic transfer but limits color capability. P6136 WHITE RDP 40 FB contains titanium dioxide, which raises dielectric permittivity and slows charge decay. This alters back-ionization, transfer efficiency, and edge coverage in electrostatic spray compared with conductive black grades. The RDP 40 particle-size class is generally tighter than that of general-purpose ES powders, improving penetration into recessed areas while reducing the tolerable reclaim fraction in high-humidity application loops.
Compared with PA12 coating powders, PA11 exhibits a melting temperature approximately 8–12 K higher and a moderately higher dry-state modulus. Elongation at break and low-temperature impact are comparable when the powders are fully fused and free of microvoids. PA12 has a lower amide density and therefore lower equilibrium water absorption at 23 °C and 50% relative humidity, but the difference is small relative to PA6-based powders. In corrosion under insulation, stone-chip exposure, and mechanical wear service, PA11 grades are selected for their balance of flexibility, abrasion resistance, and adhesion to primed steel. Published data for this specific white formulation after ISO 9227 salt-spray exposure is limited and must be generated for each substrate class and conversion coating system.
| Property | Test method | PA11 homopolymer | PA12 homopolymer |
|---|---|---|---|
| Melting peak | ISO 11357-3 | 183–191 °C | 172–180 °C |
| Density, dry | ISO 1183-1 | 1.03–1.05 g/cm³ | 1.01–1.03 g/cm³ |
| Water absorption at 23 °C, 50% RH | ISO 62 | 0.7–0.9% | 0.5–0.7% |
| Tensile yield stress, dry | ISO 527-2 | 38–45 MPa | 35–42 MPa |
| Flexural modulus, dry | ISO 178 | 900–1100 MPa | 800–1000 MPa |
Electrostatic spray deposition of P6136 WHITE RDP 40 FB is normally performed with corona charging at 60–90 kV or tribo charging on dedicated equipment, followed by fusion in a convection or infrared oven. The powder is pneumatically conveyed from a fluidized hopper through injectors and spray guns. Conveying-air dew point should remain below 3 °C to prevent moisture pickup. Fluidization pressure is adjusted between 0.5 and 1.5 bar depending on hopper geometry, but these values are equipment-specific and cannot be transferred directly between installations. Film build is governed by particle charge-to-mass ratio, particle size, substrate grounding resistance, and gun-to-target distance. For white TiO₂-pigmented powder, charge acceptance is usually lower than for black conductive grades; gun voltage and current are therefore set at the upper end of the range while substrate grounding is maintained below 1 MΩ.
Substrate preheat must remain above the crystalline melting peak but below the temperature at which the pigmented melt oxidizes or yellows. For PA11, this typically places the substrate surface preheat between 240 °C and 300 °C. External heat loss and part mass require line-specific profiling with an infrared pyrometer rather than reliance on oven setpoint alone. Film thickness is controlled by part dwell time, powder cloud density, and number of gun passes. A single pass with a 40 µm-median powder often deposits between 60 and 120 µm of pre-fused layer; final fused film thickness is usually 150–300 µm for severe corrosion service. Overlap regions and internal corners retain less powder because of Faraday penetration effects. Auxiliary airstreams or ion collectors are required for blind holes smaller than 12 mm diameter unless gun configuration is specifically optimized for those geometries.
Fusion of the deposited powder is a two-step process: melting and coalescence of polymer particles, followed by diffusion of melt across particle boundaries and adhesion to the substrate or primer. The crystalline melting peak of PA11 occurs between 183 °C and 191 °C; however, melting peak alone is not sufficient for film densification. The substrate must supply enough heat to maintain the melt above crystallization temperature long enough for chain diffusion. In fluidized-bed coating, post-fusion ovens are often set at 200–230 °C for 2–5 min for sections up to 6 mm wall thickness. Thicker sections require longer soak to achieve uniform through-thickness temperature. For electrostatic spray, low substrate mass and rapid heat loss can prevent full coalescence. The resulting microvoids may not be visible as surface defects but reduce adhesion and salt-spray resistance. Cross-sectional examination by optical microscopy or SEM is used to verify void content below 2%.
Adhesion to steel is typically measured by pull-off per ISO 4624 or cross-cut per ISO 2409. Measured values depend on surface preparation and primer selection. The white formulation requires a pretreated substrate: zinc phosphate or nanoceramic conversion coating for carbon steel, or chromate-free conversion coating for aluminum. Without conversion coating, interfacial adhesion loss can occur even when the PA11 film itself is fully fused. Epoxy or zinc-rich primers may be used, but compatibility with PA11 melt must be verified. Amine-cured epoxy primers can generate interfacial porosity when heated above 200 °C, producing apparent blister defects after cure. The pigment phase in P6136 WHITE RDP 40 FB also raises melt viscosity slightly relative to unpigmented PA11, so longer coalescence time is sometimes required for the same substrate temperature.
Fluidized-bed dip coating uses preheated parts immersed into a mechanically fluidized powder bed. P6136 WHITE RDP 40 FB is designed for this process because its particle-size distribution remains fluidizable at low air velocities and resists rat-holing or spouting. The fluidizing air is pre-dried and passed through a porous membrane with a pressure drop of 50–150 mbar; bed height is maintained between 300 and 600 mm. Immersion time controls the fused layer thickness. Typical dip times range from 2 to 8 s for substrates preheated to 270–320 °C. Thinner films require lower preheat or shorter dwell; thicker films require repeated dipping with intermediate fusion or higher stored heat.
For white powder, the emissivity of the part influences surface temperature measurement. Stainless steel and bright zinc-coated parts reflect infrared radiation and can produce false low readings. When coating galvanized steel, the zinc layer can outgas at the interface if heating exceeds 300 °C, producing pinhole formation along the coating–substrate boundary. Low-temperature grades or reduced preheat are preferred for electroplated zinc. Hydrogen embrittlement risk in high-strength fasteners must be managed with alternative plating or hydrogen-relief baking before coating. Powder reclaimed from the fluid bed must pass through a 500 µm screen to remove tramp metal and agglomerates. The white grade is sensitive to yellowing if reclaim is not blended with virgin powder at a ratio no higher than 30% reclaim to 70% virgin by mass; this ratio is a starting point and requires validation on the actual line.
Because titanium dioxide is photochemically active, exterior durability depends on the organic binder and on surface treatments of the pigment. In exterior service, chalking and gloss reduction can occur if ultraviolet stabilizers are not present. Exposure testing under ISO 16474-2 or ASTM G154 should be used to establish site-specific performance. The white powder is not inherently conductive. In electrostatic spray, powder that does not adhere to the part is recovered through a cyclone or filter. Recovered powder absorbs moisture and can lose charge acceptance. The supplier storage limits should be observed: keep powder below 30 °C and below 60% relative humidity, and consume opened containers within one shift in humid environments. Moisture content above approximately 0.10% by mass can cause spitting, pinholing, and inconsistent film thickness in both fluidized-bed and electrostatic processes.
| Standard or regulation | Relevant clause or method | Application requirement |
|---|---|---|
| REACH Regulation (EC) No 1907/2006 | Polymer registration and SDS | Verification through SDS section 3 and site-specific registration status |
| RoHS Directive 2011/65/EU | Restricted heavy metals | Confirm lead, cadmium, mercury, and hexavalent chromium below directive thresholds |
| FDA 21 CFR 177.1500 | PA11 homopolymer | Coverage limited to unmodified homopolymer; white pigmentation and additives require migration testing |
| ISO 9227:2022 | Salt-spray exposure | Not an intrinsic material value; depends on pretreatment, film thickness, and cure |
| ASTM D3359 | Cross-cut adhesion | Used after cure to verify interfacial failure mode on standardized steel panels |
Moisture uptake in PA11 powder is non-linear and accelerates above 60% relative humidity. Pre-drying is recommended if storage conditions exceed this threshold or if packaging has been breached. Desiccant-bed or vacuum drying at 80–90 °C for 2–4 h is typical for polyamide powders, but the exact time must be based on moisture analysis rather than fixed cycling. Drying above 90 °C can cause particle agglomeration, particularly in white grades with high titanium dioxide loading. Agglomerated powder passing through the spray gun produces spits and film defects that are not fully healed during oven fusion.
Electrostatic reclaim boundaries are more restrictive for white P6136 than for black conductive Rilsan grades because the white pigment reduces charge decay and increases sensitivity to fine-particle enrichment. Cyclone-separated fines may contain a higher fraction of titanium dioxide than the virgin powder, shifting both melt flow and opacity. Batch-to-batch variance in powder flow is observed after supplier milling campaigns; hopper level sensors and gun air pressure must therefore be rebalanced at each lot change. Production-scale fluidized-bed lines typically monitor bed expansion ratio and air pressure drop continuously. A falling bed expansion ratio at constant air flow indicates moisture pickup or fine-particle loss, while a rising pressure drop indicates membrane blinding. Both conditions require shutdown and powder conditioning before film quality deteriorates.