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Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11

    • Product Name: Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 411684
    Product Name Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11
    Material Polyamide 11 (PA11)
    Cas Number 25053-86-9
    Color Blue
    Density 1.04 g/cm³
    Melting Point 186 °C
    Glass Transition Temperature 45 °C
    Particle Size D50 50 µm
    Bulk Density 0.55 g/cm³
    Water Absorption 24h 1.0 %
    Tensile Strength 35 MPa
    Elongation At Break 300 %
    Shore D Hardness 70
    Abrasion Resistance Excellent
    Chemical Resistance Good resistance to solvents, oils, and mild chemicals

    As an accredited Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 25 kg net in a multi-layer paper bag with polyethylene liner, sealed to protect the fine blue PA11 powder from moisture.
    Container Loading (20′ FCL) Loaded in 20′ FCL, on palletized, stretch-wrapped packages, securely braced with dunnage to prevent shifting during transit.
    Shipping Rilsan ES BLUE 7413 MAC PA11 is a fine polyamide 11 powder shipped in sealed, moisture-protective packaging. Transport as non-hazardous dry goods in standard freight. Keep away from humidity, ignition sources, and excessive heat. No special dangerous-goods declaration required under normal shipping conditions.
    Storage Store Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11 in its original, tightly closed container in a cool, dry, well-ventilated area. Keep away from heat, sparks, open flames, and direct sunlight. Protect from moisture and humidity to prevent clumping or degradation. Avoid dust accumulation and ensure good housekeeping. Use within recommended shelf life.
    Shelf Life Shelf life is typically 2 years from production date when stored dry, cool, and in original unopened packaging.
    Application of Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11

    Electrostatic spray deposition of Rilsan Fine Powders ES BLUE 7413 MAC PA11 onto AISI 304 wire-formed dishwasher rack assemblies is specified at 100 wt% as-supplied powder with no solvent, co-binder, or crosslinker added to the feed hopper. Where ambient humidity exceeds 60% RH and fluidization becomes erratic, a dry-flow fumed silica additive is metered at 0.05–0.3 wt%; higher addition levels produce surface haze and gloss reduction measured under ISO 2813. If powder moisture uptake exceeds 0.2 wt% due to extended storage at > 60% RH, pre-drying at 70–80 °C for 2–4 h is required before spraying to prevent gun spitting and microfoaming in the fused film. The rack stock is degreased, grit-blasted with 80–120 µm alumina to Sa 2.5 per ISO 8501-1, and preheated in a convection tunnel to 200–220 °C before powder application. Electrostatic guns are operated at 60–80 kV with a powder output of 100–150 g/min per gun and booth airflow at 0.4–0.6 m/s; rack-mounted reciprocators are set to 120 mm stroke spacing to avoid Faraday cage artefacts at wire intersections. Film build is held at 180–220 µm, and the fused coating is cured at 190–210 °C for 5–8 min before air quenching. Under ISO 2409 cross-cut testing, the adhesion requirement is classification ≤ 1, and ISO 9227 neutral salt spray exposure of 1,000 h must not show base-metal corrosion at scribe lines. The finished article is a dishwasher rack or basket assembly for domestic and commercial sanitizing cycles at wash liquor up to 82 °C; continuous contact with highly alkaline detergents above pH 11 at peak temperature should be validated through FDA 21 CFR 177.1500 end-testing because the blue pigment package and PA11 matrix may have different extractive profiles under repeated sterilization.

    What Limits Adhesion When Coating Cast Iron Valve Bodies via Fluidized Bed Immersion?

    In fluidized bed immersion of graphite cast iron valve bodies and pump volutes, the PA11 powder is charged into a fluidizing vessel at 100 wt%; no primer or adhesion promoter is used when the surface is correctly blast-cleaned to Sa 2.5 per ISO 8501-1. The castings are degreased, grit-blasted with G25 chilled iron grit, and preheated in a forced-air oven to 280–320 °C; immersion time is controlled between 4–12 s to produce a fused coating thickness of 300–450 µm in cavitation-prone sections. Fluidization air velocity is maintained at 0.08–0.16 m/s; higher velocity ejects fines and increases electrostatic charging on the powder bed surface. After extraction, parts are post-cured at 185–200 °C for 10–15 min to complete melting and leveling. The coating must meet ISO 12944-2 C3/C4 exposure categories, ISO 2409 cross-cut classification ≤ 1, and ASTM D4060 Taber abrasion mass loss below 70 mg/1,000 cycles using a CS-17 wheel under 1,000 g load. A limiting factor in field application is the residual graphite in cast iron; if smearing occurs during machining and is not removed by blasting, adhesion failure appears as blistering under ISO 9227 neutral salt spray within 500 h. Avoid amine-cured epoxy primers beneath the PA11 layer because alkaline amine residues at the interface can reduce adhesion after thermal cycling. The finished components are valve bodies, pump impellers, and pipe spools for water treatment and mild chemical handling, where the PA11 layer replaces solvent-borne epoxy linings and eliminates volatile organic compound emissions during application.

    Corrosion Protection of Automotive Brake and Fuel Tubing: A Three-Zone Cure Profile

    When zinc-phosphated double-wall steel tube is transferred from the preheat station to the electrostatic booth, the PA11 powder is applied as a 100 wt% single-component coating at 150–200 µm dry film thickness. The three-zone line consists of a preheat zone set at 220–250 °C, a powder application zone using 60–80 kV electrostatic charging, and a cure zone held at 190–210 °C for 5–10 min. Tube ends are masked to prevent coating ingress into flare fittings, and the post-coating water quench reduces the substrate temperature to below 60 °C before bundling. The finished coating is tested for adhesion under ISO 2409 classification ≤ 1, bend resistance under ISO 1519 on a 10 mm mandrel without cracking, and neutral salt spray resistance under ISO 9227 for 720 h with no red rust. For fuel-line use, the coating must be compatible with SAE J30 fuel hose assembly pressures and with aromatic hydrocarbon splash; if the coating is to contact methanol-blended fuels, chemical resistance should be validated under ISO 1817 for volume swell and hardness retention. A production constraint is that the blue pigmented layer should not be exposed to continuous dry heat above 160 °C in the engine bay, because oxidative yellowing of the PA11 matrix may shift the specified colour within 2,000 h. Terminal finished product types are bundled brake tubing, fuel line assemblies, and clutch tube bundles.

    For food processing conveyor flights in dry-goods handling lines, the powder is deposited at 100 wt% as supplied, grit-blasted stainless steel 304/316 is preheated to 200–230 °C, electrostatically sprayed at 60–75 kV to 250–350 µm, and cured at 190–210 °C for 6–10 min; compliance is anchored to FDA 21 CFR 177.1500 and EU 1935/2004, adhesion to ISO 2409 classification ≤ 1, and the finished product is a conveyor screw flight, guide rail, hopper liner, or vibratory feeder bowl.

    Electrical Insulation of EV Busbar Joints and Terminal Blocks

    The adoption of PA11 powder as an insulating envelope on copper and aluminium busbar joints in battery pack distribution systems is specified at 100 wt% as-supplied powder; no solvent-borne varnish or adhesive layer is employed. Busbar edges are radiused to at least 1.5 mm before degreasing; the preheat temperature is held at 220–260 °C. Depending on joint geometry, the powder is applied by electrostatic spray at 60–80 kV or by fluidized bed immersion for 4–8 s, producing a fused film of 250–450 µm. Cure is carried out at 190–210 °C for 5–10 min. The coated busbars are subjected to dielectric withstand testing under IEC 60243-1; the test voltage is derived from IEC 60664-1 based on system voltage and pollution degree 2, not from the powder grade alone. Flame classification is verified to UL 94 HB on the actual metal-backed coated substrate, not on free film, because the thermal mass of the busbar alters the burning behaviour. Published data for this specific blue grade in EV busbar configurations is limited, so coating thickness for a given system voltage must be validated on the final assembly rather than extrapolated from unfilled PA11 film data. A process limitation is that sharp corners on copper lugs create low-thickness regions; automatic edge radius verification is required before coating to avoid dielectric weakness below 100 µm film thickness. The terminal finished product types are insulated busbar segments, terminal block covers, and inter-module power distribution rails.

    ApplicationCompliance anchorsRequired condition or test designation
    Dishwasher racksFDA 21 CFR 177.1500; EU 10/2011; ISO 9227; ISO 2409Extractives stability; 1,000 h neutral salt spray; cross-cut ≤ 1
    Cast iron valve bodies and pump impellersISO 12944-2; ISO 2409; ASTM D4060; ISO 9227C3/C4 exposure; cross-cut ≤ 1; Taber loss < 70 mg/1,000 cycles; 1,500 h salt spray
    Automotive brake and fuel tubingISO 9227; ISO 2409; ISO 1519; SAE J30720 h neutral salt spray; cross-cut ≤ 1; 10 mm mandrel bend without cracking; fuel compatibility
    Food processing conveyor componentsFDA 21 CFR 177.1500; EU 1935/2004; ISO 14159; ISO 2409Food contact extractives; hygienic design; cross-cut ≤ 1
    EV busbar insulationIEC 60664-1; IEC 60243-1; UL 94Insulation coordination; dielectric withstand; HB classification on metal-backed substrate
    Offshore handrails and ladder rungsNORSOK M-501; ISO 20340; ISO 9227; ISO 16474-2Cyclic ageing; 1,000 h neutral salt spray; 1,000 h accelerated weathering

    When Salt-Spray Resistance of Offshore Handrails Must Exceed 1,000 Hours

    To achieve offshore handrail protection with a single-coat PA11 system, the carbon steel fabrication is blast-cleaned to Sa 2.5 per ISO 8501-1 with a surface profile of 50–100 µm Rz. The powder is applied at 100 wt% as received, and the preheat step is set at 280–320 °C for fluidized bed immersion. Immersion dwell is 5–12 s, giving a final film thickness of 300–450 µm; after dipping, parts are post-cured at 185–200 °C for 10–15 min. The coated handrails are tested under ISO 9227 neutral salt spray for 1,000 h with no blistering greater than density 0(S0) under ISO 4628-2, and cyclic ageing under ISO 20340 for offshore service. The finish must also satisfy NORSOK M-501 system 1 requirements for atmospheric exposure; if the handrail is installed in the splash zone, additional topcoat may be specified by the owner, but the PA11 base layer remains the primary barrier. A limitation is that the blue colour may shift under prolonged UV if the supplied grade is not specifically UV-stabilized; therefore, ISO 16474-2 accelerated weathering should be run to 1,000 h before architectural acceptance. Finished products are offshore walkway handrails, ladder rungs, and cable tray covers.

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    Certification & Compliance
    More Introduction

    Arkema Rilsan Fine Powders ES BLUE 7413 MAC is a blue-pigmented polyamide 11 (PA11) powder grade supplied for fusion-bonded protective coatings on metallic substrates. The material belongs to the Rilsan fine powders ES series, which is processed by electrostatic spray, fluidized-bed dipping, and oven coalescence into continuous films. Representative values for the ES series include a melting peak of 184 °C to 188 °C by ISO 11357-3, density of 1.03 g/cm³ to 1.05 g/cm³ by ISO 1183-1, and median particle diameter between 35 µm and 55 µm by ISO 13320-1. The grade suffix 7413 MAC identifies a blue pigment package and a specific additive set; Arkema lot-specific certificates of analysis should be consulted for the exact particle-size distribution and melt-flow characteristics. This powder is not formulated as a melt-compounding resin and should not be introduced into injection molding or twin-screw extrusion feed streams.

    When fused into a coating, PA11 chemistry typically exhibits water absorption at saturation of 1.8% to 2.0% by ISO 62, Shore D hardness of 70–75 by ISO 868, and elongation at break above 100% when tested on free film specimens according to ISO 527-2. The blue colour is used for visual identification and inspection contrast; however, the pigment package can alter charge acceptance and decay relative to natural ES grades. Production electrostatic lines that reclaim overspray should re-verify charge-to-mass ratio with a Faraday pail when reclaim fraction exceeds 30%.

    Representative property values for Arkema Rilsan Fine Powders ES BLUE 7413 MAC PA11
    PropertyUnitTest methodTypical range
    Melting peak (DSC)°CISO 11357-3184–188
    Densityg/cm³ISO 1183-11.03–1.05
    Median particle diameterµmISO 13320-135–55
    Bulk densityg/cm³ISO 600.42–0.50
    Water absorption, saturation%ISO 621.8–2.0
    Shore D hardnessISO 86870–75
    Elongation at break, fused film%ISO 527-2>100
    Recommended dry film thicknessµmISO 2178250–400
    Typical substrate preheat range°CProcess control240–340
    Shelf life in unopened original containermonthsSupplier recommendation24

    How does ES BLUE 7413 MAC compare with PA12 and lower-cost polyolefins in immersion service?

    Compared with PA12 fine powders, the PA11 backbone provides a higher melting point and greater resistance to stress cracking in the presence of diesel and glycol-water coolants. PA12 may show lower saturation water uptake; the gap is modest, with PA12 typically around 1.3% to 1.6% and PA11 around 1.8% to 2.0% by ISO 62. Against PA6, the advantage of 7413 MAC is dimensional stability and much lower moisture absorption, although PA6 can develop higher tensile yield strength. Against polyolefin powder coatings, PA11 exhibits higher abrasion resistance, better fuel resistance, and a harder surface, but it requires a more tightly controlled preheat window.

    Comparative property ranges for coated films of PA11, PA12, and PA6 powders
    PropertyPA11 ES BLUE 7413 MACPA12 fine powderPA6 fine powder
    Melting peak (°C) by ISO 11357-3184–188176–180215–225
    Saturation water absorption (%) by ISO 621.8–2.01.3–1.69.0–10.0
    Shore D hardness by ISO 86870–7565–7075–80
    Elongation at break (%) by ISO 527-2>100>200>50
    Density (g/cm³) by ISO 1183-11.03–1.051.01–1.031.12–1.14

    The blue pigment in 7413 MAC differentiates it from natural and black PA11 grades. Natural grades can be specified where colour is irrelevant and lower pigmentation cost is required. Black grades containing conductive carbon may reduce surface resistivity and support thicker film build in electrostatic application; the blue pigment is generally non-conductive, so transfer efficiency may be more sensitive to humidity and gun voltage. Published data for this specific blue-pigmented configuration is limited with respect to long-term ultraviolet colour retention and hot-water immersion; those parameters should be tested under the intended service conditions.

    Surface preparation should remove scale and provide a blast profile sufficient to anchor a coating of 250 µm to 400 µm dry film thickness. Carbon steel substrates are typically abrasive-cleaned to Sa 2.5 per ISO 8501-1, with a peak-to-valley surface profile of 50 µm to 75 µm measured per ISO 8503-1. Preheat oven setpoints are mass-dependent; production lines treating heavy sections with wall thickness above 5 mm frequently operate between 300 °C and 340 °C, while thin sheet workpieces may require 240 °C to 280 °C to avoid overheating. The part-surface temperature at the point of powder application should stay above the crystalline melting point of PA11 but below 350 °C; temperatures above 350 °C can cause oxidative darkening of the blue pigment and film surface defects. Substrates below 200 °C commonly produce incomplete inter-particle diffusion, pinholes, and reduced adhesion.

    Electrostatic spray equipment should be configured for corona charging in the 60 kV to 80 kV range, with powder output adjusted to the part profile and line speed. Powder gun-to-substrate distance, typically 150 mm to 250 mm, must be tuned to avoid excessive back-ionization when reclaim fraction rises. In fluidized-bed dipping, the air supply should be dried to a pressure dew point below -40 °C to limit moisture pickup; fluidization air velocity is set just above minimum fluidization to avoid elutriation of fine particles. Post-fusion levelling is generally conducted at 190 °C to 210 °C for 5 min to 15 min on thin sections; heavier sections require longer hold times based on oven temperature profiling.

    Powder exposed to relative humidity above 60% for more than 4 h should be dried at 70 °C to 80 °C for 3 h to 4 h. Reclaimed powder should be blended with virgin material at no more than 30% unless particle-size distribution is checked by ISO 13320-1 and charge decay is verified by Faraday pail. Blending 7413 MAC with natural or black PA11 powders in fluidized-bed processes is not recommended without colour-matching trials, because pigment segregation during fluidization can produce visible banding.

    On multi-gun electrostatic lines with reclaim systems, the most frequently reported process bottleneck is not fusion but charge decay and back-ionization driven by accumulated fines below 10 µm. Sieving reclaimed powder through a 100 µm screen before re-blending reduces film defects and maintains transfer efficiency.

    Chemical exposure limits for fused PA11 films

    Fused PA11 coatings resist aliphatic hydrocarbons, automotive fuels, anti-icing salts, and alkaline cleaning solutions. Resistance to strong mineral acids and oxidizing agents is limited; hydrolysis can occur in hot acidic media with pH below 2 at temperatures above 60 °C. For continuous immersion in water at 80 °C, published data for this specific blue-pigmented configuration is limited; long-term performance should be validated using ISO 18777 or equivalent. Contact with ketones and phenols may plasticize or dissolve the film and should be excluded from service conditions.

    Compliance status for food-contact use should be verified against FDA 21 CFR 177.1500 for polyamide resins; end-use migration testing under 21 CFR 175.300 remains the responsibility of the coater. The product is handled under REACH. RoHS Directive 2011/65/EU restricted substances are not expected above the stated maximum concentration values, but the supplier declaration should be obtained for each lot. Occupational exposure to powder dust should be controlled by local exhaust ventilation and protective equipment as specified in the safety data sheet.

    Film-thickness measurement should be performed in accordance with ISO 2178, with accept/reject limits tied to the specified dry film thickness range. Adhesion may be assessed by cross-cut classification per ISO 2409; acceptable classifications on blasted steel are normally 0 or 1. Impact resistance can be evaluated by ASTM D2794, but the test is comparative rather than a substitute for field exposure.

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