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Arkema Rilsan BZM 30 BLACK TL Nylon 11, 30% Glass Fiber Filled

    • Product Name: Arkema Rilsan BZM 30 BLACK TL Nylon 11, 30% Glass Fiber Filled
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 762271
    Density 1.26 g/cm³
    Glass Fiber Content 30%
    Tensile Modulus 7000 MPa
    Tensile Strength At Break 121 MPa
    Elongation At Break 3%
    Flexural Modulus 6500 MPa
    Flexural Strength 158 MPa
    Impact Strength Charpy Notched 6 kJ/m²
    Melting Point 189 °C
    Heat Deflection Temperature Hdt A 170 °C
    Water Absorption 24h 0.26%
    Linear Mold Shrinkage 0.1 - 0.4%

    As an accredited Arkema Rilsan BZM 30 BLACK TL Nylon 11, 30% Glass Fiber Filled factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Arkema Rilsan BZM 30 BLACK TL Nylon 11, 30% glass fiber filled, supplied in sealed 25 kg bags for safe transport and storage.
    Container Loading (20′ FCL) 20' FCL: load palletized bags of Arkema Rilsan BZM 30 BLACK TL securely, ensuring weight distribution and ventilation for safe transport.
    Shipping Arkema Rilsan BZM 30 BLACK TL is shipped as moisture-sensitive nylon 11 pellets in sealed, moisture-barrier packaging to prevent degradation. Standard transport is by truck, container, or palletized LTL, kept dry and away from extreme heat. No hazardous classification applies, but handle carefully to avoid dust and contamination.
    Storage Store in a cool, dry, well-ventilated area away from direct sunlight and heat sources. Keep the original container tightly sealed to prevent moisture absorption, as nylon 11 is hygroscopic. Avoid exposure to rain, humidity, or condensation. Recommended storage temperature is below 40°C (104°F). Under these conditions, shelf life is typically one year from date of shipment.
    Shelf Life Shelf life is typically two years from manufacture when stored unopened in a cool, dry place, protected from moisture and sunlight.
    Application of Arkema Rilsan BZM 30 BLACK TL Nylon 11, 30% Glass Fiber Filled

    Arkema Rilsan BZM 30 BLACK TL is charged directly at the press feed as a single-component compound with 30% by weight glass fiber already dispersed in a Polyamide 11 matrix; no secondary glass fiber, mineral filler, or unfilled PA11 let-down is introduced because any departure from the compounded 30% by weight fiber content alters shrink anisotropy and weld-line tensile capacity. In underbonnet sensor-mount and engine-control-unit bracket platforms, the material is specified where moisture-cyclic warpage of PA66 GF30 has been observed after conditioning to equilibrium at 23°C and 50% relative humidity according to ISO 291, and the lower equilibrium moisture uptake of Polyamide 11 is tracked under ISO 62. Material conformance is controlled through ISO 16396-1:2015 polyamide designation, ISO 527-2 tensile modulus, ISO 75-2 deflection temperature under 1.8 MPa, and IATF 16949 process controls at injection molding sites. Drying follows desiccant-air practice at 80°C to 90°C for 4 h to 6 h until residual moisture is below 0.10% by weight by Karl Fischer or ISO 15512. Melt is processed in three-zone screws with 20:1 to 25:1 L/D ratios using a bimetallic barrel and hardened screw tip, with melt temperature maintained between 220°C and 250°C and tool steel held at 30°C to 60°C. On multicavity tools requiring 1,000 kN to 1,500 kN clamp force, short-shot variability is reduced when shot volume remains between 25% and 75% of barrel capacity and decompression is limited to 3 mm; excessive decompression draws air into the glass-fiber melt and produces silver streaking at gate zones. Venting grooves are cut to 0.010 mm to 0.020 mm depth and 3.0 mm length to evacuate volatiles without trapping glass fibers. Terminal parts produced under these constraints include intake manifold support brackets, engine control unit mounting frames, accelerator sensor housings, and connector mounting rails, with gates placed away from bolt-bearing bosses to avoid glass-fiber weld lines at torque-bearing locations.

    What Limits Dimensional Stability in Coolant Circuit Housings After Ethylene Glycol Ageing?

    Dimensional drift after ethylene glycol ageing is driven less by equilibrium water uptake than by differential expansion through the 30% by weight glass fiber orientation and partial extraction of low-molecular-weight amide oligomers at gasket interfaces; this is why coolant-contact parts are qualified using ISO 1110 accelerated conditioning, ISO 62 water absorption, ISO 527-2 tensile modulus, ISO 75-2 heat deflection under 1.8 MPa, and ISO 11359-2 coefficient of linear thermal expansion rather than a single unaged tensile value. The addition ratio at the molding feed is 100% as-supplied compound; clean sprues and runners generated in-house may be reintroduced at up to 20% by weight of total shot, but must be re-dried at 80°C for 4 h to 6 h because hydrolytic chain scission in Polyamide 11 accelerates when moist regrind is exposed to melt temperatures above 220°C. Injection molding of round thermostat-cover and flange geometries uses sequential valve gating to consolidate weld lines at bolt holes rather than across sealing faces; melt temperature is held at 230°C to 250°C, mold temperature at 40°C to 60°C, and hold pressure at 50 MPa to 70 MPa with gate freeze time above 1.0 s for 2.0 mm flanges. Component-level coolant pressure cycling is performed at 1.0 bar to 1.5 bar with 50:50 ethylene glycol/water at 120°C according to OEM durability schedules; no single ISO standard covers molded plastic housings under combined internal pressure, thermal cycling, and glycol over-temperature. Terminal product types include turbo coolant pipe flanges, thermostat covers, coolant manifold inserts, and sensor sealing bodies. For pressurized water pump volutes above 1.5 bar continuous, part-specific burst testing is required before release; published data for this specific configuration under pumped coolant fatigue is limited.

    Application sectorNormative referenceTest method designationTerminal part class
    Underbonnet brackets and sensor mountingISO 16396-1:2015, IATF 16949ISO 527-2, ISO 75-2, ISO 62ECU mounting frames, sensor housings
    Coolant circuit housingsISO 16396-2ISO 1110, ISO 62, ISO 11359-2Thermostat covers, coolant flanges
    Pneumatic push-in fittingsISO 14743, ISO 4414ISO 527-2, ISO 1133-1:2022Fitting bodies, manifold segments
    Cycling pedal bodiesISO 4210-2:2015ISO 527-2, ISO 179-1/1eA, ISO 178Pedal bodies, cleat retainers
    Marine deck hardwareASTM B117-19ISO 179-1/1eA, ISO 178, ISO 1110Deck cleats, sheave block cheeks
    Electrical terminal carriersIEC 60695-2-11, IEC 60664-1IEC 60093, IEC 60243-1Terminal blocks, relay sockets

    For compressed-air push-in fitting bodies exposed to -20°C to 80°C service temperatures and 0.8 MPa pressure pulses, the 30% by weight glass fiber loading of Rilsan BZM 30 BLACK TL provides hoop retention and limits thread-body creep under repeated tube insertion and removal cycles, while the Polyamide 11 matrix reduces hydrolytic fatigue that PA66-based fitting bodies may exhibit in wet pneumatic circuits. The formulation addition ratio at the molding feed remains 100% as-supplied compound; no external silicone mold release should be added because silicone migration onto sealing surfaces can reduce push-in connector retention force, and no secondary glass fiber concentrate is used beyond the as-compounded 30% by weight. Compliance is assessed under ISO 14743 for push-in connectors for thermoplastic tubes, ISO 4414 for pneumatic system safety, ISO 527-2 for weld-line tensile capacity when manifold sections include multiple gates, and ISO 1133-1:2022 for lot melt-volume-flow control. Injection molding of thread cores and undulating collet seats uses unscrewing tools or collapsible cores, with melt temperature at 220°C to 245°C, mold temperature at 30°C to 50°C, residual moisture below 0.10% by weight before plastication, and hold pressure at 50% to 65% of peak injection pressure to maintain collet lip roundness. Gate placement is positioned in the central bore rather than on the side wall; side-gated fitting bodies have shown ovality above 0.05 mm on single-cavity trial tools, which creates O-ring groove leakage during insertion cycling conducted according to ISO 14743. Terminal product types include push-in fitting bodies, flow-control valve bodies, modular manifold segments, silencer bodies, and swivel housings, with thread forms molded by unscrewing cores and collet retention ribs formed without post-machining.

    Cycling Pedal Body Fatigue and Cleat Retention Under ISO 4210-2:2015

    Pedal bodies molded from 30% by weight glass fiber Polyamide 11 are used in flat-pedal and clipless-retainer platforms where repeated spindle bending induces tensile strain at cage edges and where PA6 GF30 has shown lower low-temperature impact retention after conditioning at -10°C for 24 h. The addition ratio is maintained at 100% as-supplied compound; mixing with unfilled PA11 or PA12 regrind is not permitted on the same tool because differential glass-fiber content causes warped pedal platforms and inconsistent cleat engagement force. Compliance is verified under ISO 4210-2:2015 for pedal strength and fatigue, with material lot acceptance via ISO 527-2 tensile modulus, ISO 179-1/1eA Charpy impact, and ISO 178 flexural strength. Processing on vertical rotary injection machines with 2+2 or 4+4 cavity layouts requires balanced runner geometry and sequential injection sequence; mold temperature is set at 30°C to 50°C, melt temperature at 225°C to 245°C, and hold pressure at 55% of peak injection pressure to minimize sink at spindle boss ribs. Gate location is placed at the spindle bore and flow paths arranged so glass-fiber orientation follows the long axis of the pedal body; transverse gating creates weak knit lines at the leading edge where stone impact from trail obstacles concentrates. External mold release spraying is avoided because residual release agent prevents subsequent pad-printed graphics and reduces overmolded elastomer adhesion on clipless retention surfaces. Terminal products include flat-pedal bodies for mountain and commuting cycles, clipless engagement frames, and protective crank caps. Finished-assembly fatigue testing according to ISO 4210-2:2015 is mandatory for load-bearing pedals; published data for this specific glass-filled Polyamide 11 configuration under off-road impact schedules is limited.

    When Marine Hardware Must Survive Salt Spray and Mooring Impact Without Creep Failure

    In marine deck and mast-base components where cyclic wetting, salt spray, and rope impact occur simultaneously, the dimensional stability of a 30% by weight glass fiber Polyamide 11 compound reduces the progressive slack that unreinforced PA6 components develop after repeated water absorption; however, the glass-fiber phase makes surface fiber wicking possible if the part is not delivered with an integral resin-rich surface. The material is fed at 100% as-supplied compound; blending with PA6 GF30 regrind, polyethylene, or unspecified maleated adhesion promoters is not specified because Polyamide 11 and PA6 do not form a co-crystalline structure and the resulting interface can reduce impact resistance. Material qualification uses ISO 178 flexural strength, ISO 179-1/1eA Charpy impact, and ISO 1110 moisture conditioning, while salt fog exposure is evaluated on finished parts under ASTM B117-19 for periods calibrated to OEM durability schedules, typically 240 h to 1,000 h, with periodic measurement of torque retention on embedded inserts. Injection molding for thick-section cleats uses melt temperature at 230°C to 250°C, mold temperature at 40°C to 60°C, and hold pressure at 60 MPa to 80 MPa to avoid internal voids at bosses that receive stainless-steel threaded inserts; inserts are installed after molding by thermal staking or ultrasonic insertion to avoid molding-induced stress cracking. Drying to below 0.10% moisture by weight is essential before processing because marine production runs often occur in 60% relative humidity warehouses, and moisture above 0.15% produces surface splay at gate areas. Terminal products include deck cleats, sheave block cheeks, mast foot bases, and anchor windlass guides. Published data for this specific configuration after prolonged seawater immersion is limited; project-specific static load and salt-water ageing tests are required before use in safety-critical mooring assemblies.

    Assessing Glow-Wire Ignition Resistance in Low-Voltage Terminal Carriers

    Electrical terminal carriers and relay sockets molded from 30% by weight glass fiber Polyamide 11 require evaluation under finished-component glow-wire conditions because geometric wall sections, glass-fiber orientation, and carbon black level in the BLACK TL formulation all influence ignition endpoint and hot-wire ignition current. The addition ratio at the molding feed is 100% as-supplied; no carbon black masterbatch should be added because the grade already contains carbon black and additional black concentrate may alter volume resistivity and increase ionic conductivity at elevated humidity. Material lot acceptance under IEC 60093 for volume resistivity and IEC 60243-1 for dielectric strength is used for comparing batches, while finished terminal carriers are tested under IEC 60695-2-11 at the end-product wall thickness because glow-wire performance is thickness-dependent and cannot be inherited from raw material alone. Creepage and clearance distances are evaluated under IEC 60664-1 for the intended overvoltage category. Injection molding uses thin-wall tools with gate land lengths between 0.5 mm and 1.0 mm, melt temperature at 220°C to 245°C, mold temperature at 40°C to 60°C, and injection speed high enough to fill 0.8 mm ribs before freeze-off; sharp corners are radiused to at least 0.4 mm to prevent glass-fiber aggregation that reduces dielectric breakdown strength. Terminal product types include relay socket carriers, terminal block bases, actuator coil bobbins, and connector housings for low-voltage control circuits. For applications requiring a specific UL 94 flame class, a separate certified flame-retardant grade is required because published data for this specific glass-filled Polyamide 11 configuration under UL 94 is limited.

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    Certification & Compliance
    More Introduction

    Arkema Rilsan BZM 30 BLACK TL is a black-pigmented, thermally stabilized polyamide 11 (PA11) injection-molding grade reinforced with nominally 30% glass fiber by mass. The base polymer is obtained from 11-aminoundecanoic acid and belongs to the long-chain aliphatic polyamide family; the 11-carbon backbone produces a melting point near 189 °C determined by ISO 11357-1/-3 and lower equilibrium moisture uptake than PA6 and PA66. Under ISO 16396-1, the material is designated as PA11-I, GF30. The TL suffix denotes a stabilized and internally lubricated injection-molding formulation; the exact antioxidant and lubricant package is not itemized in the public technical data sheet. The principal effect of the glass-fiber phase is to raise tensile modulus from approximately 1.1 GPa for the unfilled polymer to 5.8–6.8 GPa, while tensile strain at break drops below 5%. Density increases from approximately 1.04 g/cm³ for unfilled PA11 to 1.25 g/cm³ for the reinforced grade.

    What Does the Manufacturer Report for Density, Stiffness, and Impact in This 30% Glass-Filled Polyamide 11?

    Table 1 summarizes typical dry-as-molded property values obtained from injection-molded ISO multipurpose test specimens. The data correspond to the manufacturer’s standard published values and are sensitive to gate orientation, mold temperature, and fiber alignment; production-part values can be 10–20% lower at knit lines and at sharp changes in wall thickness.

    PropertyTest standardUnitValue
    DensityISO 1183-1g/cm³1.25
    Tensile modulusISO 527-1/-2MPa6500
    Tensile stress at breakISO 527-1/-2MPa105
    Tensile strain at breakISO 527-1/-2%4.5
    Flexural modulusISO 178MPa5800
    Charpy notched impact strength, 23 °CISO 179-1/1eAkJ/m²12
    Charpy notched impact strength, −30 °CISO 179-1/1eAkJ/m²9
    Heat deflection temperature, 1.8 MPaISO 75-2/Af°C160
    Melting pointISO 11357-1/-3°C185–190
    Mold shrinkageISO 294-4%0.4–0.7

    The notched impact value at room temperature is below that of unfilled PA11 and indicates pronounced notch sensitivity. Rib roots, bosses, and gate positions therefore require generous radii and controlled tool-surface temperature. The modulus increase is approximately five- to six-fold relative to unfilled PA11, while the density penalty is approximately 20%. The flexural modulus of 5800 MPa supports load-bearing brackets and housings, but creep resistance must be separately validated under the maximum service temperature and clamp load.

    Predrying of BZM 30 BLACK TL is required before melt processing when ambient relative humidity exceeds 60%. The recommended desiccant-dryer condition is 4–6 h at 80–90 °C to a dew point of −30 °C or lower, with residual moisture held below 0.10% by ISO 15512 Karl Fischer titration. Melt temperature should be controlled between 240 °C and 270 °C. Barrel profiling from feed throat to nozzle typically moves from 220 °C to 260 °C, while mold temperature should remain between 60 °C and 90 °C to develop adequate surface translation of the glass phase and reduce jetting. Extended hold time above 260 °C accelerates oxidative degradation of the PA11 matrix, shifting melt viscosity and lowering Charpy impact. On reciprocating-screw presses of 80–130 t clamp force, hardened bimetallic barrels and screws with compression ratios of 2.5:1–3.0:1 are used; glass-fiber wear increases check-ring clearance over several thousand operating hours unless nitrided or bimetallic surfaces are specified. Injection velocity is set low enough to prevent gate blush and surface delamination. The velocity threshold must be established by short-shot fill studies because fiber orientation at the part surface is shear-dependent. Published wear-rate data specific to BZM 30 BLACK TL is limited; maintenance intervals are normally established by shot-to-shot cushion variability and recovery-time drift rather than by fixed hours alone.

    When the Component Is Cycled Between −40 °C and 120 °C in Fuel and Zinc Chloride Environments

    The long-chain PA11 backbone provides lower saturation water uptake than PA66. For fuel-system clips, sensor brackets, and battery-cooling connectors, dimensional change after humidity conditioning is correspondingly smaller. Chemical resistance of the grade is assessed using ISO 175 immersion in standardized test fluids. Alcohol-gasoline blends can plasticize the matrix and reduce tensile modulus, but the 30% glass phase limits gross swelling because the glass phase is insoluble and constrains matrix expansion. Temperature cycling is performed under automotive environmental test procedures such as ISO 16750-4. The grade is not a drop-in replacement when the part includes living hinges or snap-fit features designed around unfilled PA11 elongation, because the reinforced material fails at much lower strain. The material is rated UL 94 HB at the standard thickness; no flame-retardant mechanism beyond the polyamide matrix is claimed. Resistance to aggressive methanol or high-aromatic fuel blends in this specific black stabilized grade is not fully characterized in the public technical data sheet, so OEM validation is required.

    Molding trials of glass-reinforced polyamide 11 show that weld-line tensile strength can be 40–60% of the un-welded value depending on glass-fiber length distribution, melt temperature, and mold temperature. Critical load-bearing features should therefore be gated so that weld lines are placed outside the maximum stress zone. The linear mold shrinkage of 0.4–0.7% per ISO 294-4 is anisotropic; flow-direction shrinkage is lower than transverse shrinkage because of fiber orientation. Tooling allowances for unfilled PA11 should not be reused without recutting because unfilled PA11 commonly shrinks 1.4–2.0%. Boss designs should employ a minimum outside diameter of approximately twice the screw major diameter and a base radius no smaller than 0.25 mm. Glass-fiber reinforcement also lowers coefficient of linear thermal expansion relative to unfilled PA11, but the difference between flow and transverse directions means that round parts may ovalize after ejection if cooling is nonuniform.

    Comparative Dimensional Stability and Processing Against PA12-GF30 and PA66-GF30

    The nearest long-chain polyamide alternative is PA12-GF30. PA11 has a melting point approximately 11 °C higher than PA12, as determined by ISO 11357-1/-3. This can permit a higher continuous-use temperature when the controlling failure mode is thermal softening rather than oxidation. Density is similar, but PA11 typically exhibits lower equilibrium water uptake than PA66-GF30. PA66-GF30 offers higher dry-as-molded tensile modulus and heat deflection temperature, but its higher saturated moisture absorption becomes a design boundary in applications requiring stable snap-fit engagement after exposure to 50% relative humidity. Mold shrinkage of PA66-GF30 is also higher and more anisotropic; differential shrinkage can cause warpage in thin-walled connectors. In zinc chloride service, long-chain polyamides are generally less susceptible to stress cracking than PA66, but final welded or clipped assemblies must be tested because glass fiber reinforcement increases residual stress at knit lines. Mineral/glass hybrid grades, by contrast, trade some tensile modulus for lower warpage and more isotropic shrinkage. They are not direct replacements for BZM 30 BLACK TL when stiffness under 1.8 MPa HDT is the controlling criterion.

    Operational boundary conditions include avoidance of continuous contact with strong acids, phenol-based cleaning agents, and concentrated formic acid at elevated temperature. Long-term hot-water immersion above 80 °C hydrolyzes the amide backbone; fitness for hot-water or coolant contact must be evaluated by ISO 175 with the specific service fluid. The grade is supplied in black, and carbon black contributes UV screening. If the black pigment is substituted or if the part is painted, weathering performance must be revalidated by ISO 4892-2. Direct food-contact status has not been established in the public technical data sheet for this black stabilized glass-reinforced grade; migration testing under EU Regulation (EU) No 10/2011 or 21 CFR 177.1500 would be required for any food-contact proposal. Published data for continuous exposure to concentrated methanol, dimethylformamide, or chlorinated solvents in this specific configuration is limited; chemical compatibility must be confirmed using coupons fabricated from the production tool geometry.

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