| HS Code | 694210 |
| Density | 1.23 g/cm³ |
| Melting Point | 185 °C |
| Tensile Strength At Break | 36 MPa |
| Elongation At Break | 350% |
| Flexural Modulus | 550 MPa |
| Shore D Hardness | 65 |
| Izod Impact Strength Notched 23 C | 30 kJ/m² |
| Water Absorption 24h | 0.7% |
| Vicat Softening Temperature B50 | 140 °C |
| Ul94 Flammability Rating | V-0 |
As an accredited Arkema Rilsan BESNO P40 W6 TL PA11 FR(30) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 25 kg sealed polyethylene-lined paper bags, palletized and shrink-wrapped for safe transport and lot traceability. |
| Container Loading (20′ FCL) | 20′ FCL: palletized bags of Arkema Rilsan P40 W6 TL PA11 FR(30) loaded, secured, protected from moisture and heat. |
| Shipping | Rilsan BESNO P40 W6 TL PA11 FR(30) is a flame-retardant polyamide 11 resin supplied as pellets. Ship as non-hazardous dry polymer in sealed multilayer bags or drums, protected from moisture and direct heat. No special transport classification required, though standard handling and clean, dry conditions are recommended. |
| Storage | Store Rilsan BESNO P40 W6 TL PA11 FR(30) in its original, sealed container in a cool, dry, well-ventilated area. Protect from direct sunlight, heat, and open flames. Keep away from strong oxidizing agents. Avoid moisture exposure, as humidity can affect performance. Maintain moderate temperatures and ensure containers are tightly closed when not in use. |
| Shelf Life | Shelf life is typically 2 years when stored unopened in original, dry, cool conditions away from moisture and sunlight. |
In high-voltage battery assembly, busbar insulation plates and module end supports are moulded from this 30% glass-fibre-filled flame-retardant PA11 compound where the dielectric requirement is not transient but continuous after temperature cycling and partial discharge exposure. The applicable compliance framework includes UL 94 V-0 at 0.8–1.0 mm on the finished moulded wall, IEC 60112 for Comparative Tracking Index, ISO 527-2 for tensile modulus and elongation at break, and ISO 178 for flexural strength after conditioning at 80 °C/85 % RH. The formulation addition ratio in this application is 100 % virgin pellets for all electrically live insulation surfaces; sprues and runners are returned at a maximum 25 wt% regrind level because higher regrind loading is known from production-scale trials to depress Comparative Tracking Index by 50–100 V and create ignition paths at weld lines. The downstream production process uses injection moulding with clamp force between 1,500 kN and 3,000 kN, a general-purpose screw of 20:1–25:1 L/D, and back pressure limited to 5–15 bar to avoid excessive shear heating of the flame-retardant package. Barrel profile is set from 240 °C in the feed zone to 260–270 °C at the metering zone; mould temperature is held at 60–90 °C to prevent premature skin solidification and glass-fibre read-through on sealing faces. At moisture above 0.12 wt%, gas splay and loss of gloss are observed on 2,500 kN hydraulic presses, while melt residence time beyond 6 min at 270 °C produces yellowing and a measurable loss of tensile impact. Terminal finished product types include busbar support plates, cell interconnect barriers, high-voltage connector bodies, battery management system housing covers, and module end plates.
Junction boxes and cable connection housings for rolling stock are selected not by material flammability alone but by the full fire safety assessment required for the assembled part. The PA11-FR(30) grade is evaluated against EN 45545-2 R23 for interior components and R24 for exterior components; hazard level HL2 is commonly targeted for junction boxes, but the final classification depends on component mass, exposed surface area, and grouping rules in the standard. NFPA 130 and ASTM E662 are referenced for transit projects in North America, with smoke density Ds values and toxic gas release limits defined per project specification. The addition ratio practice is neat moulding compound for parts with wall thickness below 2 mm; for thicker housings, 20 wt% reprocessed material from the same grade is permitted only after a vertical burn test at the minimum wall thickness has been repeated. Pre-drying is set at 80 °C for 4–6 h to 0.10 wt% moisture; any colour masterbatch added at 2–3 wt% must be revalidated for smoke density and toxicity because carrier resin chemistry can shift the overall emission profile. The downstream production process is injection moulding with wall section design from 2 mm to 4 mm, mould temperature 70–90 °C, and gate placement at thick cable entry bosses to reduce weld lines across the front face. Hot-runner systems are avoided where possible because the flame-retardant package begins to degrade under extended residence at 250 °C, raising CO emission during later burn testing. Terminal finished product types include underfloor junction boxes, trackside cable splice enclosures, saloon electrical cabinet brackets, CCTV equipment housings, and HVAC duct support flanges.
Medium-voltage switchgear insulating barriers and contact supports represent a more severe electrical use than battery busbar mouldings because the polymer must retain dielectric strength after rapid temperature cycling and condensation induced by load cycling. The applicable standard framework is IEC 60664-1 for insulation coordination, IEC 62271-1 for high-voltage switchgear and controlgear, and UL 746B for long-term thermal ageing; Comparative Tracking Index is measured under IEC 60112, and mechanical strength is reported according to ISO 527-2 and ISO 178. Measured under ISO 62, the low water absorption of PA11 relative to PA6/PA66 is the dominant selection criterion for three-phase phase barriers with length over 200 mm, because dimensional change after conditioning at 80 °C/85 % RH remains small enough to preserve creepage and clearance distances. A formulation addition ratio of 20 wt% maximum regrind is used after internal electrical testing showed that higher ratios produce measurable reductions in Comparative Tracking Index and an increase in surface ash after glow-wire exposure. External release agents, nucleating agents, or impact modifiers are not added without retesting in the final wall thickness; an incompatible lubricant at 0.2 wt% can shift tracking resistance by more than 50 V. The downstream production process is injection-compression moulding to control glass-fibre orientation warpage across long barrier plates. Barrel profile is maintained at 230–250 °C in the feed zone and 250–270 °C in the metering zone; holding pressure is set between 60 MPa and 100 MPa; mould temperature is 80–100 °C. Brass or stainless steel threaded inserts are preheated to 120–150 °C before insert moulding so that the polymer skin does not freeze prematurely around the metal and produce microcracks at the insert interface. Terminal finished product types include phase barriers, arc chute side walls, busbar support insulators, terminal box bases, and auxiliary switch housings.
Thin-wall connector inserts introduce a separate processing boundary because the flame-retardant system is evaluated at the lowest wall thickness specified by the end-use standard, while mechanical strength and dimensional stability after heat ageing must be retained in the same moulding. The vertical burning test is run under UL 94 V-0 at 0.8 mm and IEC 60695-11-10; long-term thermal ageing is assessed through UL 746B Relative Thermal Index, and glow-wire end-product testing follows IEC 60695-2-11. Published data for this specific configuration are limited; the supplier technical data sheet may list a UL 94 V-0 class at 0.8 mm, but the rated performance of the connector insert must be verified on moulded parts with the actual gating and weld-line positions. The permissible regrind addition ratio is 15 wt% maximum because thin-section flow length and flame-retardant dispersion are more sensitive to polymer chain degradation from repeated melting than thick-wall industrial parts are. Drying to 0.08 wt% moisture or below is mandatory; residual moisture above this level creates surface defects near pin hole areas and reduces UL 94 repeatability. The downstream production process is high-speed injection moulding with melt temperature 245–255 °C, mould temperature 80–100 °C, and injection velocity 200–350 mm/s to fill 0.8 mm sections without excessive shear. Sequential valve gating is used when multiple pin sets create weld lines; hot-runner nozzle tips with 0.8–1.2 mm gate diameter are preferred over cold sprues to reduce pressure drop. The flame-retardant system limits melt residence time to 5 min; during production stoppages the barrel is purged to avoid black specks and localised loss of flame resistance. Terminal finished product types include industrial circular connector inserts, heavy-duty rectangular connector housings, servo drive connector bodies, PCB terminal block frames, and relay socket carriers.
EV battery cooling line connectors and degassing chambers are moulded from the same 30% glass-fibre-filled PA11 flame-retardant compound when a single material must handle long-term exposure to glycol-water coolant at 80 °C and still pass flame-retardant inspection. The compliance framework includes ISO 19453 for road vehicle electrical and electronic equipment requirements, ISO 175 for chemical resistance after immersion in 50/50 vol% ethylene glycol-water, ISO 527-2 and ISO 178 for post-immersion mechanical properties, and UL 94 V-0 at 1.0 mm for material flammability. The formulation addition ratio is 100 % virgin pellets for pressure-bearing quick connectors and degassing chamber bodies; regrind is not recommended for parts exposed to continuous coolant pressure above 0.2 MPa because glass-fibre length attrition during regrinding reduces weld-line strength at internal bore junctions. Drying before moulding is set at 80–90 °C for 4–6 h to 0.10 wt% moisture; the desiccant dryer dew point must remain below −30 °C. The downstream production process uses two-plate injection moulding tools with side-core actions to form internal coolant passages without welding the bore in the critical sealing area. Melt temperature is held at 245–265 °C, mould temperature at 70–100 °C; holding pressure is applied until gate freeze, typically 60–80 MPa, to prevent sink marks around the connector sealing lip. After moulding, annealing at 80–100 °C for 2 h under nitrogen is used to relieve hoop stress in threaded closures and reduce the risk of stress cracking after exposure to the coolant blend. Terminal finished product types include battery coolant quick connectors, manifold flanges, drain valves, degassing chamber bodies, and heating/cooling line mounting brackets.
Rigid conduit from PA11-FR(30) is justified where PA6/PA66 conduits fail through moisture swell or stress cracking in chloride-containing service environments, and where flame propagation along wire protection systems must be limited. The applicable compliance framework includes IEC 61386-1 for conduit systems, IEC 61034 for smoke density on the finished conduit, EN 45545-2 for transit tunnel installations, and UL 94 V-0 at 1.5 mm for the raw compound. Addition ratio practice is 85 wt% virgin pellets to 15 wt% clean production regrind; external recycled PA11-FR(30) from post-industrial sources is not accepted for flame-retardant conduit in transit applications because thermal history from previous processing shifts viscosity and reduces the UL 94 V-0 margin. Pre-drying is conducted at 80 °C for 4–6 h to 0.10 wt% moisture before extrusion. The downstream production process is single-screw extrusion with 30:1–33:1 L/D screw, melt temperature 230–250 °C, vacuum degassing at −0.08 MPa, and downstream vacuum sizing to maintain circularity. Line speed is set between 2 m/min and 10 m/min according to outside diameter; excessive line speed produces melt fracture and wall thickness variation around corrugation valleys. Terminal finished product types include rigid round conduit, slotted wire protection channels, data centre overhead cable tray separators, transit tunnel cable management channels, and underground cable protection pipes.
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The Rilsan BESNO P40 W6 TL PA11 FR(30) grade is a plasticised, carbon-black-pigmented, flame-retarded polyamide 11 compound supplied as cylindrical granules. The BESNO block identifies a high-viscosity PA11 extrusion base; P40 denotes the plasticised series; W6 indicates the weathering-stabilised black modification. The FR suffix signals a flame-retardant formulation. The parenthetical 30 does not correspond to an ISO 1043-1 GF30 glass-fibre designation, which would be written as PA11-GF30. Published data for this precise FR(30) configuration is limited; the following technical description therefore separates baseline BESNO P40 W6 TL properties from the FR(30) modifier effects.
The product belongs to the Rilsan PA11 family, a castor-oil-derived polyamide 11. In comparison with PA6 and PA66, PA11 has lower saturated water uptake, typically 1.8% to 2.0% by mass under ISO 62, and lower density, near 1.04 g/cm³ for the unfilled plasticised grade under ISO 1183-1. The flame-retardant and filler content in the FR(30) variant can raise density and reduce the saturated moisture percentage on a filled-material basis. The W6 carbon-black package contributes UV stability and is the main visual distinction from the natural BESNO P40 TL grade.
Baseline property values for Rilsan BESNO P40 W6 TL are provided in the table below. These data are derived from Arkema technical datasheets for the unfilled black plasticised extrusion grade. The FR(30) variant, where the flame-retardant package includes inorganic synergists or mineral fillers, should be expected to shift tensile modulus upward and elongation to break downward relative to the unfilled material. The values are indicative single-point data and are not normalised for lot-to-lot variation.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1 | 1.04 g/cm³ |
| Melting temperature | ISO 11357-3 | 189 °C |
| Water absorption at 23 °C, 24 h | ISO 62 | 0.3 % |
| Water absorption at 23 °C, saturation | ISO 62 | 1.8 % |
| Tensile modulus | ISO 527-2/1A | 1200 MPa |
| Tensile stress at yield | ISO 527-2/1A | 46 MPa |
| Nominal strain at break | ISO 527-2/1A | >200 % |
| Charpy notched impact, 23 °C | ISO 179-1/1eA | 5 kJ/m² |
| Vicat softening temperature, B50 | ISO 306/B50 | 170 °C |
The tensile values refer to injection-moulded specimens conditioned according to ISO 291. In extruded tube applications, annular die orientation and calibration can produce higher machine-direction tensile values and lower hoop-direction tensile values. This anisotropy is a structural effect of the PA11 molecular alignment and must be incorporated into burst-pressure calculations rather than treated as a material defect.
At melt-processing temperatures, water above 0.08% by mass hydrolyses the amide chain and produces surface silver streaks. The recommended drying condition is a desiccant dryer at 80 °C to 85 °C for 4 h to 6 h, with a dew point not higher than -30 °C. Drying in ambient-air ovens above 80 °C for extended periods is not recommended because oxidative yellowing of the plasticised system and consumption of heat stabilisers can occur. A Karl Fischer titration reading is more reliable for this grade than some dielectric moisture probes because carbon black can influence the probe response.
Production-scale dryers connected to single-screw extruders with 24:1 to 30:1 L/D ratios are effective when the hopper throat is sealed and purge air maintains the -30 °C dew point. Batch-to-batch moisture variance is usually small in sealed original packaging, but storage in warehouses above 60% relative humidity increases the required drying time. The drying window is a process boundary, not a routine recommendation, because the FR additive package can be more thermally sensitive than the base PA11 melt.
Typical extrusion melt temperature for the flame-retarded compound is kept between 225 °C and 245 °C, with barrel zones from 200 °C at the feed throat to 240 °C at the metering section. The melt temperature should not exceed 250 °C for more than 10 min. Prolonged residence time can decompose the flame-retardant additive and deposit char on the screw root and breaker plate. Screen packs of 60/80/100 mesh are often specified; a head pressure rise above 300 bar indicates screen blinding. If the melt temperature is raised to clear high pressure, black specks and localised additive decomposition may increase.
For injection moulding, a barrel profile of 190 °C to 230 °C and a mould temperature of 50 °C to 80 °C are used. Clamp force is determined from projected area and a cavity pressure of 40 MPa to 60 MPa; flame-retarded PA11 may require higher pack pressure than unfilled PA11 because of reduced volumetric shrinkage. Weld-line performance is a known limitation in FR(30) variants. When two flow fronts meet around a core pin, the flame-retardant additive can concentrate at the weld line and reduce Charpy notched impact relative to the unfilled material. Direct weld-line testing against the incumbent part is required before substitution.
PA12 is often selected for flexible conduits and cable protection because of its low equilibrium moisture uptake and high extensibility. Rilsan BESNO P40 W6 TL PA11 FR(30) enters this application space when a flame-retarded polyamide with bio-based content and a lower processing temperature than PA66 is required. Compared with unmodified BESNO P40 TL, the W6 grade retains black pigmentation and weathering resistance under UV exposure, while the FR suffix modifies ignitability and smoke-related behaviour. The switch from PA12 is not a drop-in substitution because PA11 and PA12 differ in notched impact behaviour, hydrolysis resistance, and melt viscosity under the same temperature profile.
Accelerated weathering according to ISO 4892-2 is used to compare colour fade and surface micro-cracking. The carbon-black package in the W6 variant extends the period before visible surface micro-cracking, although the flame-retardant package may reduce tensile elongation retention under UV. In flexible conduit extrusion, the annular die gap and draw-down ratio must be re-qualified because flame-retardant additives can reduce melt strength at low shear rates. The material is not recommended for prolonged contact with strong mineral acids, phenols, or concentrated formic acid at elevated temperatures.
Electrical conduit and railway wiring protection represent the most common production-scale uses. The material should be evaluated against EN 45545-2 for rail interior components when smoke and toxic gas release are critical, and against IEC 61386 for conduit mechanical performance under low-temperature impact. In cable conduits, use of the FR(30) grade does not replace system-level fire testing because the installed assembly, not the pelletised compound, determines final flame-spread classification.