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Arkema Rilsamid AZM 30 BLACK T6LD PA12-GF30

    • Product Name: Arkema Rilsamid AZM 30 BLACK T6LD PA12-GF30
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 312432
    Product Name Arkema Rilsamid AZM 30 BLACK T6LD
    Polymer Type PA12 (Polyamide 12)
    Reinforcement Content 30% Glass Fiber
    Density 1.24 g/cm³
    Water Absorption Saturation 1.6%
    Tensile Modulus Iso 527 9500 MPa
    Tensile Strength At Break Iso 527 120 MPa
    Elongation At Break Iso 527 3%
    Flexural Modulus Iso 178 8300 MPa
    Flexural Strength Iso 178 165 MPa
    Charpy Notched Impact Strength At 23 C Iso 179 13 kJ/m²
    Melting Point Iso 11357 178°C
    Heat Deflection Temperature At 1 8 Mpa Iso 75 165°C
    Vicat Softening Point Iso 306 175°C
    Volume Resistivity Iec 60093 1.0E14 ohm·cm

    As an accredited Arkema Rilsamid AZM 30 BLACK T6LD PA12-GF30 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Rilsamid AZM 30 Black T6LD PA12-GF30 is supplied in 25 kg sealed bags, labeled with grade and batch info.
    Container Loading (20′ FCL) 20′ FCL container loading of Arkema Rilsamid AZM 30 BLACK T6LD PA12-GF30: palletized bags stowed securely, protected, and evenly distributed.
    Shipping Rilsamid AZM 30 BLACK T6LD is a PA12-grade thermoplastic reinforced with 30% glass fiber, supplied as black granules in sealed moisture-proof bags. Store in a dry, ventilated area away from sunlight and humidity. Avoid dust formation; use standard PPE. Not classified as dangerous goods for ADR/IMDG transport.
    Storage Store Rilsamid AZM 30 BLACK T6LD in its original, unopened packaging in a cool, dry, well-ventilated area. Protect from direct sunlight, heat sources, and moisture. Keep away from oxidizing agents and foodstuffs. Maintain temperatures below 50°C and avoid condensation. Under proper conditions, shelf life is typically two years from date of manufacture.
    Shelf Life Shelf life is typically two years from delivery if stored unopened in a dry, cool place away from direct sunlight and moisture.
    Application of Arkema Rilsamid AZM 30 BLACK T6LD PA12-GF30

    In SAE J2044 low-permeation fuel vapour circuits, Rilsamid AZM 30 BLACK T6LD is injection moulded into quick-connect couplers that join multilayer nylon 12 fuel lines to underhood manifolds. The 30 wt% glass fibre reinforcement is selected for creep resistance at insertion and release snap-fit features, not for fuel barrier improvement. The coupler body must remain round after 2000 h of thermal cycling between -40 °C and 125 °C. An assembly insertion force of 45 N to 90 N is typically specified on the female retaining clip, and the glass-filled PA12 body supports that clip without fretting wear under engine vibration.

    Before moulding, the granulate is dried in a desiccant dryer with a supply air dew point of -35 °C to -30 °C and a hopper inlet temperature of 80 °C. The target residual moisture is below 0.10 wt%. Drying time of 4 h to 6 h is applied unless the granulate has been exposed to ambient humidity above 60 % RH for longer than 8 h. In that case, drying is extended to 8 h and the hopper throat is purged with dry air. Feed throat bridging occurs when the black heat-stabilised granules are loaded hot into a cold machine throat at a temperature above 45 °C, causing condensed surface moisture to react with the hot melt. The result is silver streaking and a notched Charpy impact reduction that cannot be recovered by adding virgin material later in the run.

    The barrel profile is set as a reverse profile: 260 °C at the nozzle, 255 °C at the front zone, 245 °C in the centre zone and 235 °C at the rear zone. A screw with a compression ratio of 2.5:1 and a nitrided root is used because the glass filler erodes standard flight lands. Screw speed is limited to 80 rpm to 120 rpm on a 40 mm screw, with back pressure of 0.5 MPa to 1.0 MPa. The non-return valve clearance is checked after every 5000 shots. Gate location is placed away from the witness line of the retaining clip to avoid knit-line stress concentration at the snap finger root.

    The most severe process conflict in these couplers is the weld line generated by flow around the core pin for the inner bore. A direct gate at the side wall produces a glass-rich skin that folds at the weld and reduces burst pressure by 20 % to 30 % compared with an isotropic-flow gate. Production tools therefore use a fan gate of 6 mm width at the thickest flange, with a defined tin-gate break witness. The cavity steel is hardened to 52 HRC to resist glass-fibre abrasion at the gate land.

    Test propertyMethodApplication checkpoint
    DensityISO 1183-1Confirms filler loading uniformity across batches
    Tensile strength at breakISO 527-2Bulk material acceptance after drying
    Notched Charpy impact at 23 °CISO 179-1/1eASnap-fit arrest behaviour after moulding
    Notched Charpy impact at -40 °CISO 179-1/1eACold-clip insertion integrity
    Heat deflection temperatureISO 75-2Underhood continuous heat threshold
    Residual moistureISO 15512Pre-processing moisture check

    Within 800 V battery thermal management platforms, coupler bodies and line brackets are injection moulded from the same compound because glycol-water media at 50:50 volume ratio attack unreinforced polyamides through plasticisation and hydrolysis. The 30 wt% glass network keeps creep below 1.0 % to 1.5 % after 3000 h of coolant exposure at 105 °C. This matters at threaded retention features that must maintain assembly torque after repeated cell-service disassembly cycles. PA66 competitors are screened out when dimensional growth exceeds 0.8 % in warm-water immersion, while PA12-GF30 is accepted with a design strain limit of 1.0 % to 1.5 % in short-term creep.

    The tool is gated at the thickest flange section with a fan gate of 6 mm width. Mould temperature is held at 90 °C to 120 °C with a pressurised water unit. Oil heating above 130 °C is avoided because it produces carbon black-rich cosmetic bloom on the black moulded surface. Hold pressure is set between 50 MPa and 70 MPa for 6 s to 10 s per millimetre of wall section. Regrind is capped at 20 wt% clean in-house material because fibre length decreases by 10 % to 15 % per pass and notched Charpy falls after two processing cycles.

    OEM coolant connector specifications reference ISO 527-2 tensile modulus retention after 1000 h at 120 °C in 50 vol% ethylene glycol. UL 94 HB flame performance is accepted for non-structural battery balance-of-plant parts. Under REACH Annex XVII, the black heat-stabilised formulation is not gated when the glass sizing contains no organotin compounds, but batch-level confirmation is required from the compounder.

    When Compressed-Air Handling Blocks Require Creep Resistance at 80 °C Dew Point

    Compressed-air valve manifolds are produced as multi-cavity injection mouldings on a 1200 kN clamp-force machine for a projected area of 400 cm². The cavity pressure during fill is kept below 35 MPa. Gates are shifted away from G 1/8 and G 1/4 port threads because fibre orientation planes at thread roots increase the risk of hydraulic cracking when flow fronts meet at the core. A mould temperature of 80 °C is maintained to balance thread roundness and surface gloss. The material is dried to below 0.08 wt% moisture before moulding, which is tighter than the general 0.10 wt% limit because threaded sections expose a higher surface-to-volume ratio and attack moisture during fill.

    The terminal product is a manifold block with integrated fittings for 8 mm to 16 mm pneumatic tubing. Thread forms are specified under ISO 228-1 G-series parallel pipe threads, and the downstream compressed-air quality is managed under ISO 8573-1:2010. The block is tested for leakage at 1 MPa after 5000 pressure cycles between 0.2 MPa and 1.0 MPa at 80 °C. Glass fibre reinforcement raises the pressure rating compared with unfilled PA12, but the weld-line factor must be verified by burst test on each cavity because the glass orientation at the last-filled thread root is the limiting defect location.

    Does a 30% Glass Loading Make PA12 Suitable for E-Coat Oven Carrier Frames?

    The direct answer is negative for full e-coat oven exposure. The heat deflection temperature of PA12-GF30 under a 1.8 MPa load is approximately 160 °C, which is below the 180 °C to 210 °C metal cure window used in electrophoretic coating. The compound is therefore not assigned to components that pass through the e-coat oven. It is assigned to post-paint carrier frames and locators that are attached after coating. These parts are moulded with a wall thickness of 3 mm to 4 mm and are not load-bearing during the coating process.

    When post-mould machining is required, holes are cored in the tool rather than drilled because cutting the glass-filled surface exposes fibre bundles that act as crack initiators. The acceptable continuous service temperature is 120 °C. Short peaks up to 160 °C for 30 min are tolerated only if dimensional checks confirm no boss distortion. Grade-specific HDT data must be confirmed from the Arkema datasheet before oven trials.

    Outdoor Electrical Housings and Cable Gland Thread Form Compliance

    Outdoor electrical connector bodies and cable glands made from Rilsamid AZM 30 BLACK T6LD are specified for UV-stabilised, non-conductive enclosures with ingress protection ratings. The carbon black package in the black grade provides weathering resistance under ISO 4892-2. The 30 wt% glass filler raises the modulus for internal thread retention, but also increases surface roughness at sealing faces. A two-stage injection profile with final fill velocity of 30 mm/s through the gate is used to prevent gas entrapment around moulded M20 and M25 thread forms. The threads are demoulded with unscrewing cores rather than collapsible cores because glass-filled PA12 shows high drag against moving steel.

    The terminal enclosure is tested under IEC 60529 for IP66 after assembly. For cable glands, the clamping range is defined by the manufacturer and verified with pull-out force according to EN 50262. The material is not a direct substitute for polyamide 6 in contact with aggressive process fluids because its glass fibres can wick moisture along the fibre-matrix interface. Published data for this specific configuration is limited; a sequential salt spray and thermal shock programme is required before outdoor deployment.

    Where brass gear segments are replaced by injection-moulded PA12-GF30 in rotary actuator drives, the 30 wt% glass filler raises wear resistance under non-lubricated sliding but also reduces the limiting PV value compared with unfilled PA12. Published data for this specific configuration is limited, so an application-specific ISO 7148-2 wear test is required before release. For cam rollers in textile machinery, the gear runs against hardened steel at a surface pressure of 4 MPa and a sliding speed of 0.5 m/s under intermittent duty. The processing envelope is tightened to a melt residence time below 5 min to prevent thermal degradation of the heat stabiliser package. A shot-to-shot variance of ±5 °C in barrel zone 2 produces visible colour shift and is rejected.

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    Certification & Compliance
    More Introduction

    Arkema Rilsamid AZM 30 BLACK T6LD is a 30% by weight glass-fibre-reinforced polyamide 12 injection-moulding compound supplied in black. Under ISO 16396-1:2022, the material is classified as PA12-GF30, with the GF30 designation corresponding to a nominal glass fibre weight fraction of 30%. The T6LD suffix identifies a heat-stabilised, internally lubricated grade; the exact additive identity and loading are not disclosed in published technical literature. The formulation is intended for semi-structural injected parts that require dimensional stability in humid environments, resistance to hydrocarbons and oils, low density, and consistent black appearance. Representative property values are summarised below; all values are dry-as-moulded unless otherwise noted and are not specification limits.

    What Distinguishes AZM 30 BLACK T6LD from Unfilled PA12 and Other Glass-Filled Polyamide Compounds?

    Relative to an unfilled PA12 injection or extrusion grade, the 30% glass fibre reinforcement raises tensile modulus from approximately 1.4–1.5 GPa to 6.8–7.5 GPa when tested according to ISO 527-1/2. It also reduces tensile elongation at break from values above 100% for unfilled PA12 to 3–5%, indicating a semi-ductile failure mode. The coefficient of linear thermal expansion declines from approximately 110×10⁻⁶ K⁻¹ for unfilled PA12 to 25–35×10⁻⁶ K⁻¹ parallel to flow, measured by ISO 11359-2. This reduction narrows shrinkage anisotropy and improves the fit of dimensionally critical parts.

    Compared with PA66-GF30 and PA6-GF30, PA12-GF30 absorbs substantially less water. Saturation water absorption at 23°C under ISO 62 is 1.5–2.0% for this grade, whereas PA66-GF30 and PA6-GF30 typically absorb 7.0–8.5% and 8.5–10.0% respectively. The lower moisture uptake stabilises tensile modulus and dimensions across humid service conditions, but it is accompanied by a lower heat deflection temperature under ISO 75-2/Af. The material is therefore not a direct thermal upgrade from PA66-GF30; it is a low-water-uptake, low-density engineering polyamide with a lower maximum continuous service ceiling.

    Drying before injection moulding is required after moisture-barrier packaging has been opened. In plant environments above 60% relative humidity, the sealed-bag recommendation is to dry for 4–8 h at 80–100°C in a dehumidifying hopper dryer with a dew point of −20°C or lower. The residual moisture before processing should be below 0.10% by weight, determined by ISO 15512 or Karl Fischer titration. Moisture contents above 0.15% are associated with surface splay, nozzle drool, and a measurable loss of weld-line burst strength in pressure-containing connectors due to hydrolysis-induced molecular weight reduction during melt residence.

    Melt temperature control is more critical than for unfilled PA12. A reciprocating-screw injection moulding machine with a general-purpose screw, L/D ratio 20–24, and a screw diameter of 25–40 mm should be operated with barrel set points of 240–270°C and mould temperatures of 40–90°C. The lower mould temperature range is used for thin-wall parts, while higher values improve knit-line strength and surface finish. Melt residence time above 8 min at temperatures above 270°C should be avoided because PA12 begins to discolour and evolve volatile thermal degradation products. Hot-runner systems require insulated gates and careful temperature calibration to prevent local overheating.

    Glass fibre attrition during processing reduces mechanical properties. Fibre length is preserved by keeping screw back pressure below 1.0 MPa hydraulic when allowed, limiting screw speed to the range commonly recommended for filled polyamides, and avoiding excessive shear during plastication. Hardened non-return valves and wear-resistant barrels are necessary because glass fibre reinforcement is abrasive. Published fibre-length distribution data for this specific grade is limited; general compounding literature indicates that residual fibre length, fibre orientation, and weld-line position determine final tensile strength and impact resistance. Regrind use above 25% by weight is not recommended unless validated because glass fibre length reduction lowers tensile strength and notched impact.

    Representative Physical, Mechanical, and Thermal Data

    Representative values from Arkema’s published data and standardised specimens are given below. The values are not specification limits. Specimens are dry-as-moulded except where conditioned at 23°C and 50% relative humidity.

    PropertyTest methodDry-as-moulded valueConditioned at 23 °C, 50 % RH
    DensityISO 1183-11.24–1.26 g/cm³
    Tensile modulusISO 527-2/1A6800–7500 MPa4500–5500 MPa
    Tensile stress at breakISO 527-2/1A100–115 MPa70–85 MPa
    Nominal elongation at breakISO 527-2/1A3.0–5.0 %5.0–8.0 %
    Flexural modulusISO 1785800–6500 MPa
    Charpy notched impact, 23 °CISO 179-1/1eA8–14 kJ/m²12–18 kJ/m²
    Heat deflection temperature, 1.8 MPaISO 75-2/Af155–165 °C
    Melting temperatureISO 11357-3176–180 °C
    Water absorption, saturation in water at 23 °CISO 621.5–2.0 %

    When PA12-GF30 Replaces PA66-GF30 in Dimensional-Stability-Critical Components

    In humid service conditions, PA12-GF30 offers a narrower dimensional change envelope than PA66-GF30. Under ISO 62, saturation water uptake of 1.5–2.0% for PA12-GF30 is roughly one-fourth the uptake of PA66-GF30. For a component with a 2 mm wall thickness, the resulting swelling-induced linear expansion is lower, reducing thread relaxation in threaded connectors and helping to maintain seal compression in fluid-handling systems. The trade-off appears in heat deflection temperature: PA12-GF30 exhibits HDT values of 155–165°C at 1.8 MPa under ISO 75-2/Af, while PA66-GF30 can exceed 245°C. Components exposed to continuous temperatures above 110–120°C are therefore generally outside the design envelope for PA12-GF30 without a validated thermal ageing programme.

    For snap-fit geometries, the lower flexural modulus of PA12-GF30 relative to PA66-GF30, approximately 5.8–6.5 GPa versus 8.5–10.5 GPa under ISO 178, reduces snap force for a given deflection but may require a longer arm or reduced strain to avoid plastic deformation. The notched Charpy impact values are more similar across the three 30% glass-filled polyamide families, but PA12-GF30 retains a greater proportion of impact resistance at low temperatures because of the lower glass transition of the PA12 matrix. Density is also lower: 1.24–1.26 g/cm³ for PA12-GF30 compared with 1.37–1.39 g/cm³ for typical PA66-GF30.

    Pneumatic quick-connect couplings and compressed-air fittings are produced from glass-filled PA12 where tolerance to oil mist, vibration, and ambient humidity is required. The material’s low moisture uptake measured under ISO 62 supports stable dimensions in unheated and under-bonnet areas. In fuel vapour management components, the PA12 matrix provides resistance to aliphatic hydrocarbons; however, exposure to sour gas or aggressive fuel blends containing high levels of aromatic solvents should be validated against the specific fluid formulation at the service temperature. Black connector housings, cable tie bases, and sensor retainers are additional industrial applications when UL 94 HB or specific electrical tracking resistance is not the primary requirement. Comparative tracking index and UL 94 classification should be confirmed from the supplier’s UL Yellow Card because published data for this exact grade can vary with pigmentation and wall thickness.

    Chemical compatibility for PA12-GF30 is generally favourable with hydraulic oils, diesel fuel, aliphatic hydrocarbons, greases, and salt solutions at ambient temperature. The material is not recommended for continuous exposure to strong mineral acids, phenols, cresols, formic acid, or oxidising agents at elevated concentration. Stress cracking under chemical load is a function of moulded-in stress, fibre orientation, and fluid temperature; published data for this specific grade under all chemical environments is limited. Components exposed to calcium chloride solutions or zinc chloride solutions, which are known stress-cracking agents for some polyamides, should be tested at the maximum service temperature and maximum allowable strain.

    Thermal ageing in air should not exceed the limits applicable to PA12. Continuous use at 100°C may be acceptable for short-term exposure, but long-term oxidative ageing can cause embrittlement and surface discolouration. An Arrhenius study or UL 746B long-term thermal ageing programme should be used to define the service life at a specific temperature. No UL relative thermal index for this exact grade should be assumed from generic PA12-GF30 literature. Under European Union Regulation (EC) No 1907/2006, the grade is subject to polymer registration requirements; under Directive 2011/65/EU, RoHS conformity must be assessed at the homogeneous-material level for the finished article.

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