| HS Code | 715736 |
| Density | 1.01 g/cm³ |
| Melting Point | 168 °C |
| Water Absorption 24 Hr | 0.5% |
| Tensile Strength At Yield | 36 MPa |
| Elongation At Break | 300% |
| Flexural Modulus | 700 MPa |
| Izod Impact Strength Notched 23 C | No Break |
| Shore D Hardness | 58 |
| Heat Deflection Temperature 0 45 Mpa | 85 °C |
| Glass Transition Temperature | -40 °C |
| Melt Volume Flow Rate 235 C 2 16 Kg | 10 cm³/10min |
| Mold Shrinkage | 1.0% |
As an accredited Arkema Rilsamid AMN BLACK P40 TLD PA12 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 20 kg sealed, moisture-proof polyethylene-lined bags, ensuring safe, dry storage and handling of Rilsamid AMN BLACK P40 TLD PA12 powder. |
| Container Loading (20′ FCL) | 20′ FCL: Palletized bags of Arkema Rilsamid AMN BLACK P40 TLD PA12, secured with bracing, moisture-protected, and properly labeled for safe transport. |
| Shipping | Arkema Rilsamid AMN BLACK P40 TLD PA12 is a polyamide 12 resin supplied as black pellets. Ship in sealed, moisture-proof bags or drums to prevent water absorption. Store in a cool, dry area away from direct sunlight and oxidizers. Non-hazardous for transport, but avoid dust generation and handle with standard industrial hygiene practices. |
| Storage | Store Arkema Rilsamid AMN BLACK P40 TLD PA12 in a cool, dry, well-ventilated area, tightly sealed in original packaging to prevent moisture absorption. Keep away from direct sunlight, heat sources, and ignition hazards. Avoid prolonged storage; use within recommended shelf life to maintain processing performance. |
| Shelf Life | Shelf life: 2 years from production date if stored in original, unopened packaging in a cool, dry place. |
Rilsamid AMN BLACK P40 TLD is a black-pigmented polyamide 12 compound supplied for injection moulding and, where part geometry permits, low-shear profile extrusion. The resin is fully compounded at the supplier. No downstream addition of impact modifier, carbon black, or UV stabiliser is required. Dry-as-moulded PA12 absorbs 0.7–0.9 wt% moisture at 23 °C, 50 % RH, while PA6 absorbs 2.5–3.0 wt% under the same condition. That difference directly affects snap-fit dimensions, clamp force relaxation, and connector back-off in humid service. The values in this applications section are representative processing and service boundaries for unfilled PA12 injection grades. Lot-certificate data for the specific P40 TLD variant should be referenced before setting production limits.
| Downstream segment | Reference standard | Controlled parameter | Process boundary |
|---|---|---|---|
| Fuel vapour quick connectors | SAE J2044; SAE J2260 | Residual moisture | 0.15 wt% maximum |
| Outdoor cable ties | IEC 62275; UL 94 HB | Regrind fraction | 15 wt% maximum |
| Air brake push-to-connect fittings | SAE J2494; ISO 179-1/1eA | Mould temperature | 70–80 °C for knit-line ductility |
| EV coolant quick connectors | ISO 527-2; coolant soak at 90 °C | Virgin material control | 100 % virgin |
| Dishwasher snap-fit brackets | IEC 60335-1 clause 30.2 | Insertion force | 25–35 N for 3.0 mm beam width |
| Dry-sliding conveyor guides | VDI 3400 texture 24–27 | Contact pressure | 1.5 MPa maximum |
In under-hood fuel vapour return systems, quick connectors are moulded to the SAE J2044 form factor and tested for leak closure after thermal cycling. For production lots drawn from Rilsamid AMN BLACK P40 TLD, the converter applies a 100 % virgin material rule on any cavity that enters the fuel-vapour wetted boundary. That rule is not driven by the base resin but by the absence of batch-level traceability for post-industrial regrind in fuel-contact lot release under IATF 16949 material change control. The compound is dried first. A desiccant-bed dryer with a dew point of −40 °C delivers 80 °C hopper air for 4–6 h. Residual moisture is checked by Karl Fischer titration or a halogen moisture analyser at 160 °C. Target is below 0.15 wt%. Injection is run on a conventional three-zone screw. Barrel settings from feed to nozzle are 210 °C, 230 °C, 245 °C, 250 °C. Mould temperature is held at 50–70 °C with a water unit. Injection speed is set to fill the land area in 0.4–0.8 s. Hold pressure is 60–80 MPa hydraulic. Gate location is placed off the sealing ring to prevent a weld line in the retention barb. Terminal components include ORVR canister purge connectors, vapour return line couplers, and fuel tank vent elbows. Compliance testing for fuel permeation is run per SAE J2260 or SAE J2658 depending on the line class. The grade is not a low-permeation fluoropolymer. A vapour line in a hybrid system may therefore use it only as a connector body, not as the primary barrier tube. Long-term exposure to methanol blends above 15 vol% should be qualified separately, because published data for this specific compound under aggressive alcohol fuels is limited.
Outdoor cable ties for PV combiner boxes and outdoor telecommunications cabinets are not specified by tensile strength alone. The acceptance test is clamp force retention after 1000 h of artificial weather exposure according to ISO 4892-2 method A. A black UV-stabilised PA12 grade resists surface crazing longer than natural PA6 under the same cycle because the carbon black loading is already dispersed during polymerisation. In thin wall sections of 1.5–2.5 mm, melt temperature is held at 230–250 °C. The mould is cooled to 40–60 °C to shorten cycle but not below 40 °C, because rapid skin freezing in the ratchet tooth creates a marked orientation zone that reduces flexural elongation. Hot-runner valve gates are preferred. A single sprue gate into a multi-cavity tie mould produces unequal packing. The resulting tie-to-tie clamp force standard deviation can exceed 3.5 % when cavity imbalance is greater than 5 %. Regrind from sprues and runners may be reintroduced at 15 wt%, not higher, because repeated shear on black PA12 lowers viscosity at high shear rate and shifts the ratchet tooth fill pattern. Reprocessed material is dried separately before blending. Terminal products include UV-stabilised cable ties to IEC 62275, mounting saddles, and edge clips. Flammability is not enhanced. The compound is typically rated UL 94 HB and is therefore used in enclosures where the fire protection strategy is containment rather than material self-extinguishment.
Push-to-connect fittings for air brake circuits are produced in multi-cavity tools with collapsible cores for the tube release sleeve. The governing performance standard is SAE J2494 for reusable push-to-connect tube fittings, with pressure cycling to 1.0 MPa and temperature exposure from −40 °C to 100 °C. The release button in PA12 must have a Charpy notched impact value above 8 kJ/m² at −40 °C when tested per ISO 179-1/1eA. Closed-loop rework from the same grade is limited to 20 wt%. The rework stream must be dried to 0.12 wt% moisture before blending, or the melt cushion becomes unstable due to steam voids at the nozzle. Mould temperature is the critical parameter for the knit line at the collet slots. At 50 °C mould, the knit-line elongation measured on a tensile bar per ISO 527-2 may fall to 20–30 % of the bulk value. Raising the tool to 70–80 °C restores ductility by letting the flow fronts interdiffuse before crystallisation freezes the interface. Barrel temperatures are set 10–15 °C above the mould feed throat, with a flat profile of 235–250 °C. Injection speed is reduced in the final 20 % of stroke to purge gas from the rib roots. Terminal components are body couplings, 90° elbows, and tube support collets in trucks, trailers, and bus air brake systems. Because the grade is black, customer-specific marking is made by laser engraving rather than inkjet. Surface temperature at the marking station must be below 70 °C to avoid melt-phase distortion of the engraved zone.
For glycol-water coolant loop quick connectors in hybrid and battery-electric thermal management circuits, the governing inputs are continuous exposure to 50:50 ethylene glycol–water at 85–90 °C and cold soak at −40 °C. The PA12 connector body is chosen for low moisture uptake and hydrolysis resistance relative to PA66 in warm coolant. The part is injection moulded under 100 % virgin material control. No PVDF cap layer and no glass fibre are used, because the connector must remain ductile when a service flush exposes it to a coolant pressure spike of 1.2 MPa. Mould temperature is set to 70–80 °C. This is above the standard semi-crystalline mould temperature and extends cycle time, but it reduces frozen-in stress at the hose-barb root. Long-term coolant exposure testing is run in pressure vessels at 90 °C for 1000 h using the production coolant mixture. Tensile strength retention and elongation at break are measured per ISO 527-2. The acceptance boundary is retention of at least 70 % elongation at break after exposure. The material is not qualified for continuous contact with hydrocarbon brake fluid or aggressive phosphate-ester hydraulic fluids. Terminal products include quick connectors, elbow manifolds, and temperature-sensor bungs in cooling loops. Because PA12 has a glass transition near 40–50 °C, the press-fit retention force drops as the coolant loop approaches 90 °C. The connector design therefore uses a retention collar or screwed retainer rather than a plain interference-fit barb alone.
Appliance builders using Rilsamid AMN BLACK P40 TLD in dishwasher spray arm brackets and washing machine hose clamps are not primarily concerned with fuel certification. They are concerned with ejection speed and snap-fit insertion force after cleaning-agent exposure. The material is dried to 0.10 wt% before moulding. Melt temperature is kept at 230–245 °C to limit thermal history. Mould temperature is set at 60–70 °C, not 25–30 °C. At low tool temperature, a flexural hinge leaf may snap during first insertion because the oriented skin layer is too brittle. Snap-fit insertion force is measured on a tensile machine at 50 mm/min. The specification is 25–35 N for a 3.0 mm beam width. The compound is not flame-retarded, so the appliance enclosure position must keep the part away from the heater element sheath and from the fan motor insulation class boundary. Compliance is linked to IEC 60335-1 clause 30.2 only when the bracket is not enclosed. If enclosed, the appliance manufacturer retains responsibility for fire containment. Terminal products are spray arm clips, detergent drawer latches, and hose clamps. Regrind is allowed at 20 wt% for non-cosmetic, non-snap components but not for the hinge leaf. Post-moulding assembly is done within 72 h. Humid ageing increases insertion force and can shift a marginal hinge from pass to fail.
On dry-sliding guide rails running against polished 304 stainless steel, galling risk is controlled by limiting contact pressure below 1.5 MPa and speed below 0.6 m/s. Dry-sliding guide profiles for automated bottling lines and packaging lanes use this black PA12 as an injection-moulded replacement for shortened stainless steel wear strips. Published dry-sliding data for unfilled PA12 against steel generally cluster between 0.30 and 0.40 dynamic coefficient of friction. Grade-specific P40 TLD results should be requested from the supplier because internal lubricant content affects stick-slip. The part is moulded at a wall thickness of 6–10 mm to resist creep, which extends cycle time to 35–60 s. Mould temperature is held at 70–80 °C to reduce sink and constrain crystallisation shrinkage. Regrind use is restricted to 10 wt% for thick-section guides, because higher rework fractions increase post-moulding voids and alter the wear face flatness. The wear surface is textured with a mould-etch of VDI 3400 grade 24–27. A polished wear surface increases stick-slip at low speed. Terminal products include guide rails, chain return profiles, and wear pads. The operational limit is continuous dry running above 60 °C ambient. Above that boundary, the material softens and the wear rate rises. For wet lubrication with alkaline conveyor lubes at pH 9–10, PA12 is suitable for short contact cycles but not for continuous immersion at 80 °C, where hydrolysis of the amide bond accelerates. No food-contact claim is made unless a specific lot is qualified under EU 10/2011 or FDA 21 CFR 177.1500 by the converter, because the black pigment and internal additive package are not automatically compliant in all jurisdictions.
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Arkema Rilsamid AMN BLACK P40 TLD is a black, plasticized polyamide 12 (PA12) molding and extrusion compound. The material designation under ISO 1043-1:2011 identifies PA12 with carbon-black pigmentation; the P40 identifier denotes a low-modulus plasticized composition, and TLD denotes a combined thermal and light stabilization package for outdoor service. Density determined under ISO 1183-1:2019 is typically 1.01–1.03 g/cm³ at 23 °C, with lot-to-lot variation generally controlled within ±0.01 g/cm³. The melting peak measured by differential scanning calorimetry under ISO 11357-1:2020 and ISO 11357-3:2020 falls near 172–178 °C, and the crystallization temperature on cooling is typically 135–145 °C. Melt volume-flow rate under ISO 1133-1:2022, condition 235 °C/2.16 kg, is usually reported between 8 and 15 cm³/10 min, but the certified lot value is the control target. The pellets are supplied in moisture-barrier packaging and should be stored below 30 °C at less than 60 % relative humidity to preserve the as-packaged moisture level.
Dry-as-molded specimens exhibit ductile tearing rather than brittle fracture at temperatures above -30 °C because the plasticized amorphous phase retains segmental mobility and the crystalline fraction acts as a crack-arresting boundary. The glass transition temperature determined by dynamic mechanical analysis under ISO 6721-1:2019 at 1 Hz lies between 35 °C and 50 °C; below this transition the amorphous fraction stiffens, but the low amide concentration in PA12 limits secondary hydrogen-bonded clusters that contribute to embrittlement in PA6 or PA66. Charpy notched impact strength tested under ISO 179-1:2020 on type 1 edgewise specimens at -30 °C remains above 10 kJ/m² in properly dried moldings, while unnotched specimens generally do not fully break. Water absorption at saturation under ISO 62:2008 is 1.5–2.0 %, substantially below PA6 saturation, and limits humidity-dependent property drift. However, hygrothermal conditioning at 70 °C/85 % RH for 500 h can reduce tensile modulus by 10–20 % and increase elongation; the effect is beneficial for flexibility but adverse for snap-fit retention if latch geometry was not pre-compensated. The practical operational limit in cold impact is not a single temperature; it is controlled by notch radius, part thickness, weld-line position, and moisture history. Molding with sharp internal radii below 0.25 mm or with excessive packing pressure can lock in tensile skin stress and shift the ductile-to-brittle transition upward by 10–15 °C.
In cable-harness clips, spring retainers, and conduit fasteners produced on injection molding machines with clamp forces from 80 to 160 t, the grade is processed with melt temperatures of 230–260 °C and mold temperatures of 40–70 °C. Flexural modulus determined under ISO 178:2019 at 23 °C is typically in the 250–500 MPa range; the resulting low insertion force permits snap-fit assembly against PA66 brackets without separate live hinges. Retention force at elevated temperature is derived from tensile stress-strain data obtained per ISO 527-1:2019 and ISO 527-2:2019 on type 1A specimens; yield strength typically falls between 15 MPa and 25 MPa, imposing a derating of load-bearing clips above 80 °C. Carbon-black pigmentation provides an opaque black finish, and the TLD stabilization package is intended for under-hood sunlight exposure through cowl-screen gaps. For applications with continuous operating temperature above 100 °C, unplasticized or glass-reinforced PA12 grades are used instead because the plasticizer reduces heat deflection temperature measured under ISO 75-1:2020 and ISO 75-2:2020 method A at 1.8 MPa to roughly 40–55 °C.
Moisture concentration above 0.10 % by weight at the feed throat leads to hydrolytic chain scission, surface splay, and reduced weld-line strength. A desiccant dryer with closed-loop dew point at or below -30 °C is specified; pre-drying from sealed bags for 4–8 h at 80 °C is the standard starting condition, with the shorter time applying to thin-layer drying trays and the longer time to full hopper contents. Melt temperature is maintained from 230 °C to 270 °C; at 280 °C and residence time beyond 10 min, thermo-oxidative chain scission increases melt volume-flow rate by more than 20 % compared with the virgin pellet value, changing cavity filling and reducing impact strength at knit lines. On a single-screw extruder with L/D 24 and a three-zone screw having a compression ratio of 2.5:1, melt temperature is measured at the die with an immersion probe and controlled to 240–260 °C; die pressure is geometry-dependent and often remains below 150 bar. Hot-runner manifolds should be temperature-controlled at 230–250 °C; gate diameters below 0.8 mm generate excessive shear heating and may locally overheat the plasticizer at the gate. The plasticizer component can slowly deposit on screw and die surfaces after campaigns longer than 72 h; purging with a commercial polyamide purging compound is recommended before shutdown to prevent black specks in subsequent light-colored runs.
For pneumatic tubing, spiral wrap, and low-pressure fuel-vapor conduit, the PA12 backbone provides lower equilibrium moisture uptake than PA6 and good resistance to zinc chloride, common automotive greases, and aliphatic hydrocarbons. Carbon-black dispersion in thin-wall tube must be verified microscopically; agglomerates larger than 15 µm are unacceptable for wall thickness below 1.0 mm because they act as leak-path defects. Burst pressure in unreinforced tube is calculated from the hoop stress using tensile strength measured per ISO 527-2:2019; a typical yield strength of 15–25 MPa for plasticized PA12 produces lower hoop stress capacity than unplasticized PA12, so the P40 variant is normally restricted to conduit, corrugated tube, or return lines rather than high-pressure fuel rail lines. Abrasion resistance evaluated by ISO 4649:2020 method A is adequate for harness chafe protection but below glass-fiber-reinforced PA12; published data for this specific configuration remains limited for long-term dynamic wear against stainless-steel braid beyond 100,000 cycles.
| Property | Test standard | Typical range / value |
|---|---|---|
| Density at 23 °C | ISO 1183-1:2019 | 1.01–1.03 g/cm³ |
| Melt peak temperature | ISO 11357-1:2020 / ISO 11357-3:2020 | 172–178 °C |
| Melt volume-flow rate, 235 °C/2.16 kg | ISO 1133-1:2022 | 8–15 cm³/10 min |
| Tensile modulus, 1 mm/min | ISO 527-1:2019 / ISO 527-2:2019 type 1A | 250–450 MPa |
| Tensile strength at yield | ISO 527-1:2019 / ISO 527-2:2019 | 15–25 MPa |
| Nominal strain at break | ISO 527-1:2019 / ISO 527-2:2019 | >150 % |
| Flexural modulus | ISO 178:2019 | 250–500 MPa |
| Charpy notched impact, -30 °C | ISO 179-1:2020 type 1 | 10–20 kJ/m² |
| Water absorption at saturation, 23 °C | ISO 62:2008 | 1.5–2.0 % |
The ranges are engineering reference values for plasticized PA12 black compounds and do not replace the Arkema lot certificate or current technical data sheet. Batch-to-batch variation in carbon black masterbatch and plasticizer feed may move melt viscosity and low-modulus behavior within the window; incoming inspection by ISO 1133-1:2022 and ISO 527-1:2019 / ISO 527-2:2019 is recommended for critical dimensions.
Selection depends on the design trade-off between flexibility, chemical resistance, moisture uptake, and load-bearing retention. Against unplasticized PA12, the P40 modification reduces flexural modulus by roughly 40–60 % and tensile yield stress by a similar margin, while increasing nominal strain at break and reducing brittle failure in thin living hinges or snap arms. Against PA11, the PA12 chain contains one additional methylene unit per repeating unit, lowering amide density and reducing saturation water uptake; both materials show low moisture absorption, but PA12 offers a slightly lower melting point and generally lower density, while PA11 may offer higher elongation in some grades. Against PA6, the difference is larger: PA6 reaches saturation water uptake of 9–10 % under ISO 62:2008, whereas PA12 remains below 2 %, giving the latter superior dimensional stability and lower humidity-dependent modulus drift. The plasticized PA12 grade is not suitable where creep modulus controls the design; sustained stress above 5 MPa at 60–80 °C requires unplasticized PA12 or glass-fiber-reinforced PA12 because plasticizer migration and creep under ISO 899-1:2017 will progressively increase deflection. The TLD stabilization is a differentiator for black outdoor components, but carbon-black pigmentation alone is insufficient without the hindered-amine and UV absorber system implied by the TLD designation.
Mold shrinkage in flow direction is typically 0.5–1.2 % depending on wall thickness and gate geometry; transverse shrinkage is slightly lower. Because plasticized PA12 crystallizes slowly, packing pressure must be held until the gate freezes, and mold temperature uniformity within ±5 °C is required to avoid dimensionally unstable areas. Post-molding annealing at 80–100 °C for 2–4 h in an air oven reduces molded-in stress and slightly increases crystallinity; this step is recommended before exposure to fuels or aggressive fluids. Weld-line strength in injection-molded cable clips is evaluated by tensile testing per ISO 527-2:2019 on double-gated plaques; weld-line efficiency typically remains above 60 % of the un-welded value when melt temperature is above 250 °C and packing pressure is sufficient to avoid hesitation marks.
Chemical compatibility in automotive fuel environments is a primary reason for specifying PA12 compounds. The plasticized grade withstands continuous exposure to diesel, gasoline, and zinc chloride salt spray when molded parts are annealed and low in internal stress. Environmental stress-cracking resistance under ISO 22088-2:2020 method A should be validated for each fluid; plasticizer extraction by hot biodiesel or aggressive methyl ester fractions can increase stiffness and reduce flexibility after long-term exposure. Immersion in ASTM D975 diesel at 60 °C for 1000 h may shift tensile modulus upward by 10–30 % if plasticizer migration occurs, so fuel-contact seals and clips require fluid-specific approval. Strong mineral acids, phenols, chlorinated solvents, and formic acid are incompatible at elevated temperature. The product complies with general REACH Regulation (EC) No 1907/2006 and RoHS Directive 2011/65/EU obligations when supplied by Arkema, but application-specific food-contact or medical certification is not implied by the TLD grade designation; regulatory confirmation under EU 10/2011 or USP Class VI, if required, must be obtained separately.