| HS Code | 731006 |
| Productname | 3M 5491 PTFE Extruded Film Tape |
| Manufacturer | 3M |
| Producttype | PTFE extruded film tape |
| Backingmaterial | Extruded PTFE film |
| Adhesivetype | Silicone |
| Color | Gray |
| Totalthickness | 6.7 mil (0.17 mm) |
| Backingthickness | 5.0 mil (0.13 mm) |
| Adhesivethickness | 1.7 mil (0.04 mm) |
| Temperaturerange | -65°F to 500°F (-54°C to 260°C) |
| Tensilestrength | 32 lb/in (14 N/10 mm) |
| Elongationatbreak | 200% |
| Adhesiontosteel | 25 oz/in (2.7 N/10 mm) |
| Dielectricstrength | 7000 V |
| Coefficientoffriction | 0.05 |
| Chemicalresistance | Excellent to most chemicals |
| Widthsavailable | 1/4 in, 1/2 in, 3/4 in, 1 in, 2 in, and other slit widths |
| Length | 36 yd (32.9 m) |
| Coresize | 3 in (76.2 mm) |
| Shelflife | 24 months from date of manufacture |
| Ullisting | Yes |
| Rohscompliant | Yes |
As an accredited 3M 5491 PTFE Extruded Film Tape factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Each roll is individually boxed; 3M 5491 PTFE Extruded Film Tape, 1 inch x 36 yards, one roll per carton. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with 3M 5491 PTFE Extruded Film Tape, palletized, secured, and stowed for safe ocean freight transport. |
| Shipping | 3M 5491 PTFE Extruded Film Tape is not classified as hazardous for transport. It has no UN number, hazard class, or packing group. Ship in original sealed packaging, keep dry, avoid extreme heat and direct sunlight. Standard ground, air, or ocean freight is acceptable. No special documentation is typically required. |
| Storage | Store 3M 5491 PTFE Extruded Film Tape in a cool, dry, well-ventilated area, ideally at 20–25°C and 40–60% relative humidity. Keep sealed in original packaging, away from direct sunlight, heat, moisture, solvents, and strong oxidizers. Do not freeze. Rotate stock and allow to acclimate before use. Protect from dust and physical damage. |
| Shelf Life | Shelf life is 24 months from date of manufacture when stored at 21°C (70°F) and 50% relative humidity. |
In helicopter engine sensor harness assembly, 3M 5491 is applied as a helical overwrap to SCL or Spec 55 wire bundles that route between the core-mounted junction box and the fire-zone pylon connectors. The relevant installation standard is SAE AS50881C, which requires pressure-sensitive tape mechanicals to be verified under ASTM D3759/D3759M and electrical insulation resistance under ASTM D257; space-adjacent programs add outgassing screening per ASTM E595 with total mass loss and collected volatile condensable material thresholds of 1.0% and 0.1%, respectively. Tape is typically 25.4 mm wide, applied at 50% helical overlap, producing a nominal one-pass wall thickness of 0.132 mm and a reverse-wrap wall thickness of 0.264 mm. The resulting material usage ratio is 1.5 linear metres of 25.4 mm tape per linear metre of harness at 50% overlap, not including 5% tail loss. The tape is fed from a variable-tension winder set at 2.5–4.5 N; edge alignment is maintained within ±1.6 mm per 300 mm lay length, and the wrap is burnished with a pneumatic roller at 0.3–0.5 MPa to remove trapped air. On production lines, the dominant failure mode is silicone adhesive oozing from under the tape edges after prolonged exposure to service temperatures above 230°C, which deposits non-conductive residue on connector backshells and causes intermittent contact resistance during acceptance test. The tape must therefore not be specified as a sole wall insulator in fire-zone harness sections exceeding 230°C continuous; 260°C short-term excursions are possible but require inspection for adhesive migration at 250 h intervals. Terminal products include engine fuel pump harnesses, anti-ice controller cable assemblies, and landing gear brake temperature sensor leads.
For autoclave cure of epoxy/carbon prepreg laminates, 3M 5491 is used as a sacrificial release interface on aluminum or Invar tool surfaces to prevent resin adhesion and reduce tool cleaning between cycles. The process is controlled under AS9100D production planning, while tape tensile properties are qualified per ASTM D3759/D3759M and peel adhesion per ASTM D3330/D3330M. The release interface is applied as a single ply with butt joints not exceeding 0.8 mm gap; overlap is not permitted because the resulting step height telegraphs through to the first laminate ply and creates a resin-rich pocket. The tape-to-tool coverage ratio is 1.0 m² of tape per 0.97 ± 0.01 m² of tool surface after edge trimming; edges are held outside the net trim boundary by 12–15 mm. Cure is performed at 180°C with a ramp rate of 2–3°C/min, autoclave pressure of 0.6–0.7 MPa, and dwell of 120–180 min. At these conditions, the silicone adhesive remains below its 260°C continuous ceiling, but silicone migration into the bondline is documented after repetitive tooling re-use; users must wipe tool surfaces with methyl ethyl ketone and conduct a water-break test after each debulk. A process conflict occurs when tooling features deep recesses or double curvature radii below 50 mm; the tape cannot be applied without wrinkling, and localized release failure transfers tape fragments into the laminate. In those regions, a liquid release agent is substituted, but cross-contamination with the silicone adhesive must be avoided because it can suppress interlaminar shear strength. Terminal products include wing flap fairing panels, radome shells, and interior CFRP seat frame components.
The packaging line for retort pouches uses 19 mm wide 3M 5491 on resistively heated seal jaws to prevent molten polyethylene from building up on plated steel tooling. Compliance for indirect food contact is typically governed by FDA 21 CFR 177.1550 for perfluorocarbon resins and, where European Union requirements apply, Commission Regulation (EU) No 10/2011; peel adhesion of the silicone adhesive to stainless steel is monitored under ASTM D3330/D3330M. The tape is installed as one continuous strip covering 100% of the jaw contact face; the splice is placed at a jaw end so that it falls outside the product seal area. The tape introduces a thermal gradient of approximately 0.7–1.0°C between the heater surface and the sealant interface, requiring setpoint compensation for LLDPE sealant operation at 165–190°C with dwell times of 0.5–1.2 s and jaw pressure of 0.28–0.45 MPa. Material consumption is 1.2 m of tape per 300 mm jaw face, and replacement cycles in continuous operation are typically 6 months at 2,000 cycles/day. The main production failure is adhesion loss in the first 100 cycles due to plasticizer migration from the pouch film; wiping the tape surface with isopropanol between shifts stabilizes peel and reduces seal bar contamination. The tape should not be used in direct contact with food or for sealing at temperatures above 260°C, because decomposition products are hazardous. Terminal products include stand-up retort pouches for pet food and medical device barrier packaging.
Automotive exterior trim coating operations employ 3M 5491 as a die-cut masking layer on aluminum heatsink extrusions before electrostatic powder deposition. The finish is validated under ASTM D3359 for dry film adhesion and ISO 2409 for cross-cut classification, while tape removal characteristics are quantified by ASTM D3330/D3330M with a minimum peel of 4.0 N/10 mm to stainless steel. Die-cut pads with M5 through-hole geometry are supplied on a release liner and applied at a taping area ratio of 23–28% relative to the part surface; the application ratio is adjusted so that the mask remains outside the grounding contact areas used for electrostatic deposition. Following powder application, parts traverse a convection cure oven at 190°C for 20 min; the silicone adhesive retains peel-removal capability without adhesive residue transfer onto the cured powder. The process boundary appears when liner removal is performed at relative humidity 25–30%; static charge on the tape edges attracts overspray and creates a fuzzy mask edge after cure. Operators therefore apply the mask in a controlled environment at 40–60% RH and use an ionizing air knife immediately before powder application. This use case is limited to cure schedules below 260°C; higher temperatures risk adhesive carbonization and mask embrittlement during removal. Terminal products include powder-coated roof rack brackets, motor housing end caps, and extruded heat sink side plates.
Chlor-alkali electrolyser maintenance schedules specify 3M 5491 as a dry anti-stick interlayer between EPDM gaskets and monel or titanium raised-face flanges in sodium hypochlorite and brine transfer lines. The flange geometry is defined by ASME B16.5, and gasket stress distribution is evaluated under EN 1591-1; chemical resistance of the PTFE backing in acidic chloride service is assessed per ASTM D543. The tape is applied in 20 mm wide strips along the flange sealing face with a 10% overlap at each segment, providing a compressible release layer of 0.13 mm. Because the tape occupies compressible volume, bolt torque is increased by 0.5–1.0 N·m relative to the unlined gasket joint to maintain seating stress. The assembly sequence is a three-pass cross-pattern torque sequence to 60%, 85%, and 100% of the target torque, with a minimum 15 min wait between passes for creep accommodation. The operational boundary is severe: PTFE should not be used with molten alkali metals or elemental fluorine at elevated temperature, and decomposition begins above 260°C, releasing toxic fluorine-containing vapours. In service, flange pairs with tape interlayers show reduced gasket adhesion but require re-torque after the first thermal cycle because the tape compresses 0.02–0.04 mm under load. Terminal products include cell room flange pairs, brine line gasket joints, and sodium hypochlorite transfer connections.
Rotating machine winding repair records show that 3M 5491 can serve as interlayer insulation between magnet wire turns in random-wound stator coils where the available slot depth dictates an insulation build below 0.15 mm per layer. The electrical tape classification is evaluated under IEC 60454-2:2017, with dielectric breakdown tested per ASTM D149 and insulation resistance per ASTM D257 after 96 h at 23°C/50% RH. The tape is applied half-lapped at 55% overlap using 12.7 mm width, resulting in material consumption of 1.8 m of tape per linear metre of coil slot. Because the adhesive system is silicone-based, migration under thermal cycling limits the application to Class H (180°C) or lower hot-spot temperatures, although the PTFE backing tolerates 260°C short-term excursions. Vacuum-pressure impregnation with polyester or epoxy varnish requires a solventless varnish with viscosity below 400 mPa·s to penetrate tape edges at 0.1 mbar; otherwise, air pockets form at the overlap boundaries and partial discharge inception voltage drops. The critical process conflict is that silicone contamination in the varnish bath will cause fisheyes in the final impregnation, so the tape must be used in a segregated impregnation line and the bath filtered with 10 µm mesh after each campaign. Terminal products include mining shovel traction motor field coils and hydro generator exciter armature coils.
| Application | Cited standard / method | Processing boundary | Terminal product |
|---|---|---|---|
| Aerospace wire harness overwrap | SAE AS50881C, ASTM D3759/D3759M, ASTM E595 | 50% overlap, 2.5–4.5 N winder tension | Engine fuel pump harness, landing gear sensor lead |
| Autoclave composite cure tool release | AS9100D, ASTM D3759/D3759M, ASTM D3330/D3330M | 180°C cure, butt joint ≤ 0.8 mm, no overlap | Wing flap fairing panels, radome shells |
| Heat seal jaw release | FDA 21 CFR 177.1550, EU 10/2011, ASTM D3330/D3330M | 165–190°C, 0.28–0.45 MPa, 0.5–1.2 s | Retort pouches, medical barrier packaging |
| Powder coating mask | ASTM D3359, ISO 2409, ASTM D3330/D3330M | 190°C cure, 40–60% RH application | Roof rack brackets, motor housing end caps |
| Chlor-alkali flange anti-stick | ASME B16.5, EN 1591-1, ASTM D543 | 10% strip overlap, bolt torque offset 0.5–1.0 N·m | Cell room flange pairs, brine line joints |
| Medium-voltage coil interlayer insulation | IEC 60454-2:2017, ASTM D149, ASTM D257 | 55% overlap, Class H ≤ 180°C, varnish viscosity 400 mPa·s | Traction motor field coils, hydro exciter armatures |
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3M 5491 PTFE Extruded Film Tape is a pressure-sensitive composite whose nominal construction consists of 0.20 mm (0.008 in) extruded polytetrafluoroethylene backing and 0.05 mm (0.002 in) silicone adhesive, giving a total thickness of 0.25 mm (0.010 in). Standard rolls are furnished in 36 yd (33 m) lengths with widths from 12.7 mm (0.5 in) to 101.6 mm (4 in). The product is specified for dry-interface release, heat-sealing jaw covers, roller wraps on printing and laminating lines, and dielectric isolation where the exposed PTFE backing is the primary functional surface. Manufacturer-reported typical values in Table 1 are obtained under ASTM D3652, ASTM D3759, ASTM D3330, and ASTM D149; current 3M technical data sheet values control lot-specific acceptance. Unlike skived PTFE tapes, the extruded film is formed by continuous melt-phase processing, which reduces internal striation and improves thickness uniformity.
| Property | Typical value | Test method |
|---|---|---|
| Total tape thickness | 0.25 mm (0.010 in) | ASTM D3652 |
| Backing thickness | 0.20 mm (0.008 in) | ASTM D3652 |
| Adhesive thickness | 0.05 mm (0.002 in) | ASTM D3652 |
| Peel adhesion to stainless steel | 25 oz/in (6.8 N/25 mm) | ASTM D3330 |
| Tensile strength at break | 35 lb/in (153 N/25 mm) | ASTM D3759 |
| Elongation at break | 200% | ASTM D3759 |
| Dielectric breakdown voltage | 10 kV | ASTM D149 |
| Operating temperature range | -73 °C to 260 °C (-100 °F to 500 °F) | Manufacturer qualification |
The tape is installed on hot jaws and rotary sealing elements in packaging lines operating between 150 °C and 220 °C. The PTFE surface prevents molten film or coating transfer at the seal interface, while the silicone adhesive remains below the jaw surface temperature because of the thermal resistance of the backing. Intermittent excursions to 260 °C are specified; continuous operation above 204 °C is not recommended for load-bearing bonds because silicone pressure-sensitive adhesives lose shear holding capacity at elevated temperature. In L-bar sealers, the tape is typically applied to chromed steel platens with a butt joint or 5 mm to 8 mm overlap; the overlap is positioned outside the seal zone to avoid adhesive contamination. On rotary sealers with 300 mm-diameter steel rollers, tape tension is maintained below 5% strain to control edge lifting. Qualification is performed using ASTM D3330 peel adhesion after 24 h dwell at 23 °C and 50% RH, followed by 200 °C oven aging for 7 days to detect adhesive discoloration or backing delamination. Dwell times in typical polyethylene heat-seal operations are 0.5 s to 3.0 s at jaw pressures of 0.2 MPa to 0.7 MPa; these conditions do not normally exceed the adhesive thermal limit when the PTFE backing remains intact.
Installation surface preparation involves removal of light oils and condensation from chromium, stainless steel, or cured-composite rolls. The surface is wiped with anhydrous isopropanol and allowed to dry before tape application. Full adhesion to stainless steel develops after 24 h contact under pressure at 21 °C to 25 °C; peel values stabilize after 72 h. Because the exposed PTFE surface has low surface energy, secondary bonding or adhesive tie-coating to that surface requires corona, plasma, or sodium-ammonia pretreatment. Untreated PTFE typically exhibits surface energy of 18 mN/m to 20 mN/m; adhesion of inks, resins, or secondary tapes generally requires surface energy above 38 mN/m after treatment. The tape is not specified for continuous immersion in ketones, esters, or aromatic hydrocarbons, because silicone adhesive swelling at the bond line may occur even when the PTFE backing remains unaffected.
PTFE exhibits time-dependent creep under compressive stress. In roll-wrap service, the tape is used under tension and moderate nip pressure; it is not specified as a bearing pad where compressive stress exceeds approximately 1 MPa to 2 MPa at 100 °C. For applications requiring higher load, equipment qualification should include compressive creep testing under ASTM D621 or equivalent. The extruded backing has elongation at break near 200% under ASTM D3759; installation tension on small rollers should remain below 10% strain to avoid residual stress that causes end-lifting. The silicone adhesive layer is applied at 0.05 mm, which limits gap-filling capacity; substrate roughness should not exceed 1.5 μm Ra for continuous adhesive contact. On aluminum or etched steel rolls, the adhesive bond survives intermittent temperatures up to 260 °C, but sustained shear load at that temperature is not covered by standard pressure-sensitive tape acceptance tests. Cold-temperature performance is bounded by the silicone adhesive, which remains flexible to -73 °C; below that threshold, handling damage from embrittlement may occur.
Skived PTFE film is produced by machining from compression-molded billets; the cutting process creates anisotropic tensile properties and occasional thickness striations. Extruded PTFE film used in 3M 5491 is produced by melt-phase extrusion, resulting in lower fibrillation tendency, improved thickness uniformity, and higher elongation before break. Glass-filled PTFE tapes provide higher wear resistance and dimensional stability under compressive load, but are stiffer and more abrasive to mating surfaces. 3M 5491 is therefore selected in dielectric and release applications where conformability, non-stick behaviour, and electrical insulation are controlling. It is not a direct replacement for glass-filled PTFE in high-wear chute liners or for skived PTFE in applications requiring the highest tensile anisotropy. The extruded backing can be cut with less particulate generation than skived PTFE, making it suitable for cleanroom masking in printed-circuit solder wave and conformal coating processes where loose fibre or nonvolatile residue is unacceptable. The non-porous extruded surface has dielectric breakdown of 10 kV under ASTM D149, but printed-circuit applications must verify compliance with insulation resistance after reflow and cleaning under the customer-specified standard.
| Standard or regulation | Relevance |
|---|---|
| ASTM D3652 | Pressure-sensitive tape thickness measurement |
| ASTM D3759 | Tensile strength and elongation at break |
| ASTM D3330 | Peel adhesion to stainless steel |
| ASTM D149 | Dielectric breakdown voltage |
| ASTM D3654 | Sustained shear holding power at elevated temperature |
| ASTM D621 | Compressive creep reference for PTFE bearing-like service |
| RoHS Directive 2011/65/EU | Restriction of hazardous substances in electrical and electronic equipment |
| REACH Regulation (EC) No 1907/2006 | SVHC communication and registration obligations in the European Union |
During autoclave cure of epoxy/carbon-fibre laminates, 3M 5491 is used as a release interface on caul plates or tool faces. The silicone adhesive is stable to 260 °C, but contact pressure above 2 bar autoclave pressure may cause adhesive flow and edge contamination. If the tape is used as a release ply, its PTFE backing prevents resin adhesion; however, silicone adhesive transfer to the laminate surface can impair subsequent bonding or coating. Surface-sensitive bonding after cure requires solvent wipe and plasma treatment to remove any residual silicone. Published data for this specific configuration is limited; qualification panels are required before production use.