| HS Code | 465468 |
| Product Name | 3M 335 Polyester Protective Tape |
| Backing Material | Polyester |
| Adhesive Type | Acrylic |
| Color | Transparent |
| Backing Thickness | 2.0 mil |
| Adhesive Thickness | 0.8 mil |
| Total Thickness | 2.8 mil |
| Adhesion To Steel | 20 oz/in |
| Tensile Strength | 30 lb/in |
| Elongation At Break | 100% |
| Temperature Resistance | 250°F |
| Dielectric Strength | 5000 V |
| Core Diameter | 3 in |
| Standard Roll Length | 72 yd |
| Shelf Life | 18 months |
As an accredited 3M 335 Polyester Protective Tape factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | 3M 335 Polyester Protective Tape comes in 2 in × 72 yd rolls, packaged 24 rolls per case. |
| Container Loading (20′ FCL) | 20′ FCL loaded with palletized cartons of 3M 335 Polyester Protective Tape, securely braced and shrink-wrapped for safe ocean transport. |
| Shipping | 3M 335 Polyester Protective Tape is not regulated as a hazardous material for shipping. Transport in original packaging, keep dry, and protect from direct sunlight, moisture, and temperature extremes. No UN number, hazard class, placards, or special labeling required under DOT, IATA, or IMDG. Handle with normal care. |
| Storage | Store 3M 335 Polyester Protective Tape in its original packaging in a cool, dry, well-ventilated area. Keep away from direct sunlight, heat, moisture, dust, and ignition sources. Maintain moderate temperatures, ideally 15–30°C (59–86°F), avoiding freezing or excessive heat. Keep containers sealed and clearly labeled. Rotate stock and follow shelf-life guidelines. Consult the Safety Data Sheet for specific storage requirements. |
| Shelf Life | Shelf life is 24 months from manufacture when stored at 20°C (68°F) and 50% relative humidity in original packaging. |
On a production line fitted with a Gema OptiFlex Pro B corona gun and an 18 m infrared/convection hybrid cure tunnel, threaded holes, bearing journals, grounding pads, spline teeth, and machined mating surfaces are masked with a 0.05 mm polyester backing carrying a pressure-sensitive silicone adhesive. The tape is applied at 18–30 °C to solvent-wiped steel or aluminum substrates after degreasing; surface temperature below 10 °C reduces adhesive wet-out and increases edge-lift risk. The tape is burnished with a polyethylene hand roller at 2–4 kg linear pressure to eliminate entrapped air at the adhesive-substrate boundary. During electrostatic powder coating, corona guns operating at -60 to -100 kV and powder flow rates of 120–180 g/min deposit TGIC polyester or polyurethane powders across the exposed surface; the tape edge intercepts the powder cloud and prevents deposition onto the masked region. Cure is performed at a part metal temperature of 180–200 °C for 10–20 min, depending on powder chemistry and minimum cure specification. The polyester backing remains dimensionally stable under these conditions, but adhesive crosslinking increases during dwell and removal peel force rises if the part is cooled below 40 °C; hot removal at 50–70 °C is specified to minimize adhesive transfer. Silicone adhesive residue on Class A powder-coated surfaces is a known process conflict, and silicone contamination is controlled where subsequent liquid painting or adhesive bonding is planned. Adhesion of the cured coating is verified by cross-cut testing according to ASTM D3359-17 method B, with a minimum rating of 4B required by most architectural and general industrial specifications; cure completeness is assessed by solvent double rubs or differential scanning calorimetry for critical parts.
| Downstream operation | Maximum interface temperature | Typical dwell at temperature | Removal specification | Governing test method |
|---|---|---|---|---|
| Powder coating cure | 200 °C | 10–20 min | Remove at 50–70 °C | ASTM D3359-17 |
| Sulfuric acid anodizing, Type II | 22 °C | 30–90 min | Remove before nickel acetate seal | ISO 2085:2018 |
| Hot air solder leveling | 265 °C | 2–6 s | Remove below 40 °C | IPC-TM-650 2.3.25 |
| Autoclave composite cure | 182 °C | 120–180 min | Remove at 60 °C after depressurization | ASTM D3330/D3330M |
| Plasma spray overspray | 150 °C intermittent | seconds to minutes | Remove after each torch pass | AMS 2437B |
On aluminum airframe components, selective anodizing of lap-joint faying surfaces is rejected where full corrosion resistance is not required, and polyester tape is applied to exclude chromic or sulfuric acid from precise zones. The tape is applied over degreased aluminum tooling holes after alkaline cleaning and nitric acid desmutting; edges are burnished with a rounded PTFE spatula to create a seal against acid ingress. In Type II sulfuric acid anodizing per MIL-A-8625F or ISO 2085:2018, the bath is maintained at 18–22 °C, current density is controlled at 1.2–1.8 A/dm², and dwell time is 30–90 min to produce an oxide thickness of 5–25 µm. Under these conditions, the polyester film resists swelling and the silicone adhesive provides a seal against the acidic electrolyte; however, bath circulation and hydrogen evolution at the masked boundary create micro-gaps at sharp transitions, and acid wicking beneath the tape leads to a ragged anodic edge after sealing. In hardcoat Type III anodizing at 0–5 °C with current densities of 2.4–3.6 A/dm² and voltage ramps to 60–120 V, the tape can be lifted by localized joule heating at high-current-density zones, and the polyester can embrittle over 90 min; published data for this specific configuration is limited, and a liquid mask or aluminum foil/lead tape is often substituted. Removal is performed before nickel acetate sealing at 96–100 °C to avoid trapping sealant under the tape edge. The surface is then hot water rinsed, and seal quality is assessed by coating weight per ASTM B137-95(2021) or impedance per ISO 2931:2017.
Gold finger protection prior to hot air solder leveling begins with the masking of chamfered edge connectors on FR-4 printed circuit boards after final gold plating. The tape is applied to cover the bevel and the first 2–5 mm of the board edge, then burnished with a soft silicone roller to eliminate bubbles. During HASL, the boards are fluxed and passed through molten SAC305 solder at 250–265 °C for 2–6 s vertical immersion. The tape must survive this thermal shock without lifting, curling, or allowing solder wicking into the gold finger area. After cooling to below 40 °C, the tape is removed; residue on gold fingers is measured by ion chromatography or resistivity of solvent extract according to IPC-TM-650 2.3.25, with an acceptance criterion of 1.56 µg NaCl/cm² equivalent for many aerospace and telecommunications assemblies. Where silicone-sensitive optical surfaces or wire-bond pads are adjacent, a polyimide or non-silicone adhesive tape is substituted because silicone transfer from the adhesive can impair subsequent gold ball bond strength. The finished board is inspected under 10×–30× magnification for tape adhesive transfer, fiber protrusion, or solder splash per IPC-A-600J, class 3.
During autoclave cure of carbon fiber/epoxy prepreg, the boundary between the bagged part and the tool flange is sealed with polyester flash tape to prevent resin bleed past the edge parallel and to provide a predictable edge break. The tape is applied to a clean steel or aluminum tool surface at 20–25 °C after application of release agent; it follows the net trim line and overlaps the prepreg edge by 10–15 mm. In a typical cure cycle, the sealed vacuum bag is evacuated to 0.8–0.9 bar vacuum, and the autoclave is pressurized to 6–7 bar at 177–182 °C for 120–180 min. The polyester backing does not flow, and the silicone adhesive remains in place on the tool edge, but entrapped volatiles can create small tunnels at the adhesive-tool interface if the bag is not debulked properly. After cure and cooling to 60 °C, the flash tape is removed with the bagging film; adhesive residue on the tool is unacceptable because it contaminates subsequent release agent coats and changes the surface energy of the tool flange. Vacuum bag integrity is checked by a pressure decay test before and after cure, with a maximum allowable vacuum loss of 0.14 bar in 5 min frequently applied in production. Laminate quality at the edge break is assessed by ultrasonic C-scan or cross-sectional microscopy, and ply wrinkling must not exceed 0.25 mm out-of-plane per internal aerospace limits.
Where air plasma spray booths produce a plasma jet at 8,000–15,000 K and particle velocities of 200–400 m/s, polyester protective tape is restricted to overspray shielding on adjacent surfaces rather than direct grit blast impingement. The tape is applied to mating flanges, cooling holes, and bearing bores before the part is mounted on a turntable or robot manipulator. Direct grit blasting with 24–60 mesh alumina or silicon carbide at 40–60 psi perforates and removes the polyester backing; therefore the tape is installed after preparation and only receives low-angle overspray and ricochet particles. During air plasma spraying of yttria-stabilized zirconia thermal barrier coatings, the surface temperature of the masked zone can rise to 100–150 °C due to plasma plume proximity; the tape may shrink and lift if the torch dwells for more than a few seconds on a single location. After coating, the tape is removed before coating buildup bridges the edge and causes edge chipping. Coating bond strength is evaluated per ASTM C633-13(2020) or AMS 2437B for aerospace thermal spray, and overspray-masked zones are inspected for discoloration or adhesive residue with ultraviolet light or wipe tests.
Chemical paint stripping of aerospace aluminum skins exposes surrounding areas to aggressive stripper formulations, and polyester tape is applied over antennas, pitot-static ports, and lap-joint seams to prevent stripper ingress. The tape is installed after solvent cleaning and before the stripper gel is applied; edges are pressed firmly because stripper penetration at the tape edge is the primary failure mode. Benzyl alcohol/hydrogen peroxide or benzyl alcohol/formic acid gels operate at 20–35 °C for 15–45 min; the polyester backing resists swelling, but methylene chloride-based strippers are largely phased out under REACH restrictions. After the dwell period, the tape is removed before high-pressure water rinsing at 10,000–15,000 psi to prevent stripper residue from being trapped between the tape and the substrate. The stripped surface is then inspected for corrosion pitting, adhesive residue, and surface profile change according to ASTM D4417-21 or ISO 8501-1.
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3M 335 Polyester Protective Tape is a transparent polyester carrier coated with a silicone pressure-sensitive adhesive. The product is supplied in roll form and is used as a temporary masking medium on metal and composite surfaces during high-temperature or chemically aggressive processing. Manufacturer-published typical values place total tape thickness at 0.051 mm (2.0 mil) when measured under ASTM D3652/D3652M. Peel adhesion to steel is listed at 5.5 N/100 mm (20 oz/in) when tested under ASTM D3330/D3330M. Tensile strength at break is listed at 385 N/100 mm (22 lb/in) and elongation at break at 90 % under ASTM D3759/D3759M. Continuous operating temperature is limited to 177 °C; short excursions to 204 °C require process validation. The silicone adhesive provides clean release after thermal cycling, but silicone transfer is a contamination risk for subsequent liquid painting or bonding operations. The product is differentiated from general-purpose acrylic polyester tapes by higher thermal stability and from polyimide tapes by a lower continuous-temperature limit and greater transparency at typical roll widths.
| Property | Test method | Typical published value |
|---|---|---|
| Total thickness | ASTM D3652/D3652M | 0.051 mm (2.0 mil) |
| Backing thickness | ASTM D3652/D3652M | 0.025 mm (1.0 mil) |
| Adhesion to steel | ASTM D3330/D3330M | 5.5 N/100 mm (20 oz/in) |
| Tensile strength at break | ASTM D3759/D3759M | 385 N/100 mm (22 lb/in) |
| Elongation at break | ASTM D3759/D3759M | 90 % |
| Continuous operating temperature | Manufacturer rating | 177 °C |
| Intermittent operating temperature | Manufacturer rating | 204 °C |
The polyester film is oriented poly(ethylene terephthalate) and provides the mechanical backbone of the tape. The silicone pressure-sensitive adhesive is cast onto the film and covered by a release liner. The adhesive does not require heat activation and forms bonds by pressure at ambient temperature. Because the adhesive is silicone, initial adhesion to low-surface-energy substrates is moderate; maximum adhesion is developed after a dwell time of approximately 24 h. On steel, peel adhesion values are recorded at a 180° peel angle under ASTM D3330/D3330M. The tape is translucent enough for visual alignment but is not intended for optical applications requiring high light transmittance.
In sulfuric acid anodizing lines operated within MIL-A-8625F Type II parameters, the bath is commonly held at 18–22 °C with 150–200 g/L sulfuric acid and a current density of 1.0–1.5 A/dm² for 30–45 min. Acrylic pressure-sensitive adhesives lose shear holding capacity in this environment because ester linkages are susceptible to hydrolysis. Silicone adhesives resist hydrolysis under these conditions, and the polyester carrier is not significantly swollen by dilute sulfuric acid at ambient temperature. The primary failure mode on production racks is not adhesive dissolution but edge lifting. Edge lifting is observed when the tape is stretched during application or when it is applied over sharp machined corners without burnishing. Operators reduce edge lifting by pressing the tape with a hard rubber roller and by applying a second layer over critical edges. Removal is performed after rinsing and drying at ambient temperature; warm removal above 60 °C increases the probability of adhesive splitting, particularly on low-energy substrates.
Masking in powder coating cells is performed before electrostatic spray. The tape is applied to bearing seats, threaded bosses, grounding pads, and mating surfaces that must remain free of cured powder. Electrostatic guns operate at 60–90 kV, and powder cure ovens typically hold workpieces at 180–200 °C for 10–20 min. Under these conditions, the silicone adhesive releases cleanly from grit-blasted steel after cooling to 60 °C or lower. Removal above 80 °C can produce adhesive transfer on abraded substrates. The tape is not a substitute for high-temperature masking when the same surface will receive a liquid topcoat without an intermediate cleaning step; residual silicone from the adhesive can produce cratering. If a liquid topcoat is required, cleaning followed by wetting tension measurement under ASTM D2578 is used to verify the surface.
The 0.025 mm polyester carrier permits flat-bed and rotary die-cutting of small masking dots and irregular profiles. The tape is converted on servo-driven rotary die presses with typical cutting tolerances of ±0.1 mm. The silicone adhesive is supplied on a release liner; liner tension during unwinding is held below 10 N/100 mm width to prevent tunnel formation. On automated applicators, roll unwind tension is controlled below 15 N/100 mm width. Because the tape is transparent, optical registration sensors may require printed contrast features on the liner. Storage at 21 °C and 50 % relative humidity is recommended; exposure to relative humidity above 70 % can cause liner curl and reduce die-cutting consistency. The thin carrier improves conformance on radii and concave milled features but reduces resistance to puncture in blast or mechanical abrasion operations.
Alkaline etch and chemical milling operations expose masking tape to sodium hydroxide solutions at 40–60 °C for 10–30 min. The silicone adhesive maintains adhesion to degreased aluminum and titanium, but surfaces must be free of loose oxide and lubricant. A solvent wipe with isopropyl alcohol followed by a dry wipe reduces oil-induced adhesion loss. Edge curl is the dominant defect when the carrier is stretched during application; stretched polyester retracts in heated baths and exposes edges to etchant attack. For long immersion in concentrated alkaline etchants, heavier glass cloth tape is often required. Published data for continuous immersion of 3M 335 in concentrated hot sodium hydroxide is limited; therefore, process validation is required before full-scale use.
Polyimide masking tapes generally carry continuous temperature ratings of 260 °C and above, which exceed the 177 °C continuous limit of 3M 335. Polyimide is selected when the process includes solder reflow, autoclave cure, or prolonged exposure above 200 °C. Glass cloth tapes provide higher puncture resistance and abrasion resistance but are thicker and opaque. 3M 335 is used where thinness, transparency, and clean silicone release are more important than extreme thermal or mechanical resistance. Compared with acrylic polyester protective tapes, 3M 335 exhibits lower adhesive build on steel after short thermal exposure and better release from alkaline-cleaned surfaces. Compared with 3M 336, which employs a heavier polyester carrier, 3M 335 is more conformable and less resistant to puncture. The difference is most relevant when masking complex milled surfaces; the thinner carrier allows 3M 335 to follow tight radii without bridging, whereas the heavier carrier may bridge concave features and require additional scoring.
Because the silicone adhesive can transfer trace siloxane species, surfaces intended for subsequent coating or bonding must be inspected with a method sensitive to nonpolar contamination. A water break test may not detect low-level silicone transfer. Contact-angle goniometry or X-ray photoelectron spectroscopy is more sensitive, though not always practical on the production floor. A production protocol can specify solvent wiping followed by wetting tension measurement under ASTM D2578. The tape is intended for temporary masking only and is not a substitute for permanent sealing. Maximum storage is typically 18 months from date of manufacture when the product is stored in original packaging at 21 °C and 50 % relative humidity. Rolls should be kept away from direct sunlight and from temperatures above 30 °C.