| HS Code | 940017 |
| Manufacturer | 3D Systems |
| Productname | VisiJet RBK-ENT-D78 Multi-Material Composite |
| Materialcomposition | VisiJet CR-BK + VisiJet CE-NT |
| Materialtype | Multi-material composite |
| Printingtechnology | MultiJet Printing (MJP) |
| Compatibleprinter | ProJet 5500X |
| Color | Black |
As an accredited 3D Systems VisiJet RBK-ENT-D78 Multi-Material Composites (VisiJet CR-BK + VisiJet CE-NT factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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In preoperative planning environments where bone and soft-tissue contrast determines surgical approach, CR-BK rigid osseous volumes and CE-NT elastomeric volumes representing cartilage, intervertebral disc, or soft-tissue tumour margins are co-printed on ProJet MJP 2500/2500 Plus platforms inside a single wax-supported build. The digital assignment is executed in 3D Sprint as a volumetric shell/region mapping rather than a boolean intersection: rigid bone structures are defined with a minimum wall thickness of 1.5 mm to survive wax melt-out and ultrasonic cleaning without flexural fracture, while elastomeric regions are constrained to 1.0 mm minimum wall to prevent tearing during handling and support removal. Build orientation places the broadest rigid face downward on the build platform to minimise Z-axis tensile loading during part separation. Post-processing follows a two-stage protocol: the finished build is chilled at -20 °C for 15 min to embrittle the sacrificial wax, then placed in a convection oven at 70 °C until bulk support clears; residual wax is removed in an ultrasonic bath containing EZ Rinse-C at 35–40 °C for 30 min. Dimensional validation is performed against the STL reference using non-contact optical scanning; multi-material boundary shift below 0.1 mm is achievable across the CR-BK/CE-NT interface when the model contains no trapped wax pockets or blind cavities. The resin pair carries RoHS compliance under Directive 2011/65/EU; published biocompatibility data for the multi-material interface are limited, so device-level validation under ISO 10993-1 remains the responsibility of the end user where patient contact is intended. These models are used either as non-sterile surgical planning aids or as sacrificial patterns for silicone casting; 70% isopropyl alcohol wipe-down is tolerated for short contact periods, but immersion in hospital-grade quaternary ammonium disinfectants should be avoided because surface whitening of CR-BK has been observed in some evaluations.
| Property | Test method | CR-BK range | CE-NT range |
|---|---|---|---|
| Tensile strength | ASTM D638-14 | 50–65 MPa | 1.0–2.5 MPa |
| Elongation at break | ASTM D638-14 | 5–12% | 500–800% |
| Hardness | ASTM D2240-15e1 | Shore D 80–85 | Shore A 27–33 |
| Heat deflection temperature @ 0.455 MPa | ASTM D648-18 | 60–70 °C | Not applicable / <50 °C |
| Density | ASTM D792-20 | 1.02–1.10 g/cm³ | 1.05–1.15 g/cm³ |
Steam sterilisation at 121 °C and 204 kPa according to ISO 17665-1:2006 exceeds the heat deflection temperature of both phases. Published HDT values for CR-BK fall between 60 °C and 70 °C at 0.455 MPa per ASTM D648-18; CE-NT softens significantly below 50 °C, causing unrecoverable deformation of thin elastomeric walls under autoclave pressure cycles. The interface itself is generated by voxel-level blending during MultiJet deposition, not by a discrete adhesive line; when delamination is suspected after thermal cycling, microtome sectioning at 10 µm followed by optical microscopy provides qualitative verification of interfacial integrity. Standardised peel values for the CR-BK/CE-NT combination are not published in current datasheets, but production experience on ProJet MJP 2500 systems indicates that failure under excessive thermal exposure occurs cohesively within the CE-NT phase rather than at the interfacial plane. For medical simulation tools requiring repeated disinfection, hydrogen peroxide gas plasma at 45–55 °C or ethylene oxide at 37 °C is preferable; the CR-BK phase withstands these cycles without measurable dimensional drift, while the CE-NT phase must be pre-dried at 40 °C for 2 h when ambient RH exceeds 60% to prevent water uptake from influencing subsequent Shore A readings. If hospital infection-control policy mandates steam sterilisation, the design must either replace CE-NT with a more thermally stable elastomer or accept the model as a single-use sacrificial device.
When impact attenuation and frame rigidity must be evaluated in a single build cycle, handheld electronics drop-test housings are produced with CR-BK internal frames and CE-NT corner bumpers in a single net-shape build, eliminating secondary overmoulding of thermoplastic polyurethane onto a rigid substrate. The frame is designed with ribbing at 1.2 mm nominal thickness and 0.8 mm corner fillets to distribute impact force; the elastomeric bumper wraps the frame with a wall thickness of 2.0 mm and projects 1.0 mm beyond the rigid edge to provide first-contact compression. Shore A hardness of the CE-NT phase is checked before and after cleaning using a durometer calibrated per ASTM D2240-15e1; lot-to-lot variation of ±2 points has been observed on production machines and must be accounted for in impact attenuation calculations. The digital interface between CR-BK and CE-NT is maintained as a sharp boundary at the bumper root to prevent stress concentration from graded blending; a 0.3 mm overlap of elastomer onto the rigid frame is modelled to increase peel resistance. Support wax removal proceeds in a convection oven at 70 °C; because the enclosed housing traps heat, thin CR-BK walls under 1.0 mm can exhibit warp if the oven fan speed produces localised hot zones above 75 °C. Subsequent ultrasonic cleaning in oil at 35 °C for 30 min clears residual wax from the bumper-to-frame crevice, but prolonged oil contact above 40 °C causes dimensional swelling of the CE-NT bumper; quantitative swelling data are limited and should be measured per ASTM D471-16a for each resin lot. Prototype validation against MIL-STD-810G Method 516.6 is performed by the end user because the printed housing is an early-stage geometric surrogate for final injection-moulded production parts; published drop-test pass rates for this specific material pair are not available.
Automotive intake manifold and pump housing prototypes integrate CR-BK rigid flanges with CE-NT sealing lips in a single build, replacing secondary injection-moulded thermoset elastomer inserts during the design verification phase. The sealing lip is printed at 0.8 mm height with a 2.0 mm root width and compressed between the CR-BK flange and the mating test plate to 20–25% of original height under 1.5 N·m assembly torque. Chemical resistance is the primary design constraint: CE-NT is compatible with dilute aqueous coolants at 23 °C for short exposures, but immersion in Reference Fuel B per ASTM D471-16a produces mass swelling and softening within 24 h, rendering the seal unreliable for hydrocarbon-rich environments. For aqueous coolant circuits, compression set testing under ASTM D395-18 Method B at 70 °C for 22 h establishes the maximum service temperature; published set values for CE-NT are limited, so a conservative 50% set allowance is applied for prototype durability. The CR-BK flange incorporates 3.0 mm diameter bolt holes with 0.2 mm diametral clearance for M3 fasteners without post-machining; because CR-BK exhibits brittleness at low temperatures, bolt torque should not exceed 2.0 N·m at -10 °C. Batch-to-batch variation in elastomer modulus has been observed on production MJP equipment; the manufacturer does not publish quantitative lot-variation tolerances, so incoming resin lots are preconditioned at 23 °C and 50% RH for 24 h before printing to stabilise viscosity and final durometer.
For automated assembly stations requiring replaceable soft-touch pads on rigid mounting plates, CR-BK and CE-NT can be co-printed without secondary adhesive bonding. The mounting plate is 4.0 mm thick with through holes sized for M3 heat-set inserts; the elastomeric pad projects 2.5 mm above the plate face and compresses to 15–20% strain under a 20 N actuation force. The pad-to-plate transition is a sharp interface rather than a graded blend to preserve pad compliance; edge burrs are trimmed with a scalpel after wax clearing at 70 °C and ultrasonic rinsing at 35 °C for 30 min. Shore A 30 hardness is measured per ASTM D2240-15e1 at 23 °C and 50% RH; compression-deflection characteristics should be qualified per ASTM D575-19 before full-rate deployment. Published endurance data for this specific MJP elastomer are limited; pilot-scale evaluations on ProJet MJP 2500 equipment indicate that surface wear appears before pad-to-plate delamination, but quantitative cycle-life curves have not been published.
Vacuum pick-and-place cups for semiconductor and electronics packaging lines are printed as a single multi-material component with a CR-BK backbone and a CE-NT sealing lip. The lip thickness is set at 0.8 mm to conform to textured PCB surfaces; the backbone contains a 4.0 mm internal vacuum channel printed with its axis oriented vertically to eliminate internal support wax. The CR-BK backbone is designed with a 2.0 mm minimum wall around the vacuum channel to prevent collapse under 80 kPa differential pressure; because CR-BK exhibits brittle fracture at thin sections below 1.0 mm, all internal corners are radiused at 0.5 mm. Published outgassing data for CE-NT under high vacuum are limited; bake-out at 40 °C for 4 h is recommended before integration into cleanroom systems operating below 10-1 Pa to reduce volatile content. Helium leak testing is performed according to the end user’s QMS; published leak-rate data for this specific multi-material configuration are not available, so semiconductor applications require customer-specific qualification. Wax removal follows the standard two-stage oven–ultrasonic protocol; the thin CE-NT lip is supported by the rigid backbone during cleaning to prevent tear propagation from the free edge.
Because secondary adhesive lines between rigid and soft components fail under repeated donning and doffing, wearable orthotic and rehabilitation devices combine CR-BK structural shells with CE-NT skin-contact padding in a single build through digital mechanical interlocking. The CR-BK shell is printed with a wall thickness of 1.8 mm and ventilated with 3.0 mm hexagonal cutouts; the CE-NT padding is assigned to the inner surface at 2.0 mm thickness and interlocked to the shell through periodic 1.0 mm projections that penetrate the rigid phase. This mechanical interlocking, rather than a graded material interface, provides peel resistance during repeated use. The CE-NT phase is characterised by Shore A hardness per ASTM D2240-15e1 and tensile elongation per ASTM D638-14; skin-contact safety is assessed by the end user under ISO 10993-1 because published biocompatibility data for the multi-material build are limited. Cyclic flexure at 1 Hz over 100,000 cycles on a custom three-point bending fixture was used to evaluate shell-padding separation during prototype trials; no separation was recorded, though published fatigue data are limited. Cleaning with 70% isopropyl alcohol remains acceptable for short contact periods; immersion in hospital-grade quaternary ammonium disinfectants has caused surface whitening of CR-BK in some evaluations and should be avoided.
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The 3D Systems VisiJet RBK-ENT-D78 Multi-Material Composites set is a two-cartridge MultiJet Printing build configuration identified by part number RBK-ENT-D78 and composed of VisiJet CR-BK rigid black resin and VisiJet CE-NT elastomeric natural resin. The D78 designation in the product identifier corresponds to a target 78 Shore D durometer value for the digitally blended composite state. The composition is not a single preformulated resin bottle; it is produced inside MJP hardware by volumetric blending of the two endpoint photopolymers at the voxel level. This capability allows a monolithic part to contain rigid, elastomeric, and intermediate-durometer regions without adhesive bond lines or secondary assembly operations.
VisiJet CR-BK operates as the rigid, pigmented endpoint in the RBK-ENT-D78 set. It contributes higher tensile modulus, higher flexural modulus, and improved load-bearing dimensional stability to printed sections where movement must be limited. VisiJet CE-NT operates as the lower-modulus elastomeric endpoint and provides greater elongation and compliance in regions requiring flexure or impact absorption. The printed D78 composite is not a simple 50:50 mixture; the local Shore D value is controlled by adjusting droplet populations from the two material channels. Tensile documentation for this material class is ordinarily reported under ASTM D638-14, flexural properties under ASTM D790-17, durometer hardness under ASTM D2240-15, notched Izod impact under ASTM D256-10, and heat deflection temperature under ASTM D648-18. Equivalent ISO methods include ISO 527-2:2012, ISO 178:2019, and ISO 75-2:2013. Specimen conditioning should follow ASTM D618 at 23 ± 2 °C and 50 ± 5 % relative humidity for 40 h unless otherwise specified by the current 3D Systems datasheet.
| Property | Test method | Typical condition | Reporting note |
|---|---|---|---|
| Tensile strength and elongation at break | ASTM D638-14, ISO 527-2:2012 | Type IV specimen, 5 mm/min | Report XY and Z orientation separately |
| Flexural strength and modulus | ASTM D790-17, ISO 178:2019 | 3.2 mm thickness, 1.36 mm/min | Support material removed prior to testing |
| Durometer hardness | ASTM D2240-15 | Shore D, 15 s delay, 6 mm stacked specimen | Confirm target D78 value on production part |
| Notched Izod impact | ASTM D256-10, ISO 180:2019 | 3.2 mm specimen, notch A | Report temperature if not ambient |
| Heat deflection temperature | ASTM D648-18, ISO 75-2:2013 | 0.455 MPa, 2 °C/min | Do not exceed during heated support removal |
| Density | ASTM D792-20 | Solid specimen | Use for mass estimation only |
Build-process control for RBK-ENT-D78 begins with the support-material loop because MJP systems deposit wax support alongside the two build resins. The planarizer removes excess material and controls the nominal layer thickness, while in-line UV lamps cure the build resin. In high-definition mode, the nominal layer thickness is 0.032 mm. Multi-material blending is accomplished by altering the number of CR-BK and CE-NT droplets per voxel. The practical processing window is therefore sensitive to the thermal state of the wax support, the surface energy difference between the two resins, and the ability of the planarizer to remove elastomeric residue. If the support reservoir temperature is set too high, thin D78 composite sections can soften during oil-bath support removal. If the support temperature is too low, wax crystallization can form on the planarizer and increase the probability of layer-splitting defects. Multi-material builds require more frequent planarizer maintenance than single-endpoint rigid builds because the elastomeric endpoint may leave a tacky low-modulus film that accumulates resin and reduces planarity.
The transition between CR-BK and CE-NT domains is governed by jetted drop volume, UV irradiance, and the rheological compatibility of the two resins at the printhead operating temperature. Voxel-level blending requires firing frequencies from both material channels to remain synchronized. When a single channel drifts out of calibration, the local Shore D value can shift away from the 78 target. Production-scale MJP systems compensate for missing jets by adding neighboring droplets, but this compensation changes the local blend ratio and can create visible bands of higher or lower stiffness. The pigmented CR-BK endpoint introduces an additional optical variable: carbon black competes with the photoinitiator for UV absorption, reducing cure depth at equivalent lamp power compared with the unpigmented elastomeric endpoint. Blended regions near the maximum CR-BK fraction may therefore require adjustments to lamp exposure or build speed to maintain cure integrity. Published data for sub-2 mm transition zones in the exact RBK-ENT-D78 configuration is limited; validation on the target MJP machine is required before high-mix production of parts with abrupt rigid-to-elastomeric transitions.
Residual stress at the rigid-elastomer interface can appear as curl after cooling from the build chamber. The magnitude is influenced by local Shore D gradient, part cross-section, and support anchoring. A stepped-Shore validation coupon printed in the target orientation provides more reliable production data than a single bulk tensile specimen. The coupon should be checked for local durometer using ASTM D2240-15 and for interface splitting under bend loading. Such testing identifies whether the printer is maintaining the intended D78 blend or drifting toward one endpoint because of a partially blocked jet or a cartridge temperature offset.
The RBK-ENT-D78 set is used for functional prototypes and short-run manufacturing aids that require a rigid structural core and a softer or higher-elongation surface without secondary overmolding. Typical printed geometries include enclosures with living hinges, snap-fit closures, gasket lips, instrument knobs, impact-resistant housing corners, and hand-held tool handle simulators. The printer deposits CR-BK in load-bearing regions and CE-NT or D78 composite material at flexible boundaries, producing a single monolithic part. This approach eliminates adhesive bond-line failure modes and reduces assembly tolerance stack-up associated with bonding a rigid polymer to a separately cast elastomer.
Compared with VisiJet CR-BK alone, the multi-material set reduces tensile and flexural modulus in the soft regions in exchange for higher elongation and impact absorption. Compared with VisiJet CE-NT alone, it restores dimensional stability for mating surfaces, threaded inserts, and snap features. Compared with VisiJet M2CAST, the RBK-ENT-D78 set is not intended for investment casting burnout; residual ash behavior and burnout temperature profiles are not specified for this composite. Compared with single-cartridge rigid materials such as VisiJet M3-X, the advantage is the ability to vary compliance within the same build, but the process-control burden and material cost are higher. The kit also requires MJP hardware with two independent build-material channels and a separate support-material channel; it is not compatible with single-endpoint MJP configurations that do not support simultaneous dual-material jetting.
Handling and compliance boundaries require end-user verification against the current safety data sheet and 3D Systems compliance letter. The uncured resins in RBK-ENT-D78 are not certified as food-contact grade under FDA 21 CFR 175.300 or EU 10/2011 unless explicitly stated by the manufacturer for the part-number-specific configuration. REACH and RoHS status should be confirmed from the SDS; the product is not marketed as a low-VOC or biodegradable polymer. Cartridge storage should remain within 15–30 °C. Condensation exposure above 60 % relative humidity can introduce water at the cartridge interface, alter resin viscosity, and create jetting instability. After build completion, support material is removed using an approved heated oil bath or equivalent MJP support-removal equipment. The oil bath temperature should remain below the heat deflection limit of the D78 composite to avoid permanent softening of thin sections. Final cleaning is performed with a compatible solvent such as 70–100 % isopropyl alcohol or an approved alternative; solvent compatibility should be verified because aggressive solvent exposure can swell the elastomeric CE-NT phase and reduce durometer.
| Material state | Primary use intent | Durometer region | Multi-material behavior |
|---|---|---|---|
| RBK-ENT-D78 D78 composite | Rigid/elastomeric monolithic prototypes | 78 Shore D target | Volumetric blend of CR-BK and CE-NT |
| VisiJet CR-BK alone | Rigid black functional parts | Higher than D78 endpoint | Single material |
| VisiJet CE-NT alone | Flexible, higher-elongation parts | Lower than D78 endpoint | Single material |
| VisiJet M2CAST | Investment casting pattern production | Not specified for this application | Not multi-material |
| VisiJet M3-X | Rigid, ABS-like functional prototyping | Single rigid endpoint | Single material |
Production validation of RBK-ENT-D78 should include a stepped-Shore grid printed in both XY and Z orientations to verify local hardness under ASTM D2240-15 and tensile response under ASTM D638-14. Lot-specific variation in CR-BK pigmentation can shift the D78 blend point slightly, especially in thick sections where UV cure depth is limiting. Cartridge changeover from one material lot to another should therefore trigger re-qualification of the digital composite rather than reliance on a fixed printer recipe. Build logs should record printhead temperature, support reservoir temperature, missing-jet counts, and oil-bath removal time to maintain process traceability across batches. The D78 composite fill mode is best validated at the smallest intended feature section, not on oversize test blocks, because thin-wall thermal history and local blend ratio differ from bulk behavior. Published data for this specific configuration is limited for very small living hinges and thin gasket lips, so those geometries should be qualified with functional cycling rather than static tensile data only.