| HS Code | 590217 |
| Product Name | 3D Systems VisiJet EBK-ENT-R36 Multi-Material Composites (VisiJet CE-BK + VisiJet CE-NT) |
| Material Type | Multi-material composite |
| Build Materials | VisiJet CE-BK and VisiJet CE-NT |
| Color | Black and natural/translucent |
| Tensile Strength | 42-48 MPa |
| Tensile Modulus | 2000-2200 MPa |
| Elongation At Break | 8-12% |
| Flexural Strength | 60-70 MPa |
| Flexural Modulus | 1900-2100 MPa |
| Hardness | 78-80 Shore D |
| Heat Deflection Temperature | 50-55 °C at 0.45 MPa |
| Density | 1.18-1.19 g/cm³ |
| Notched Izod Impact Strength | 20-25 J/m |
| Water Absorption | 0.4-0.5% |
| Layer Thickness | 32 µm |
| Print Technology | Multi-Jet Modeling (MJM) |
| Compatible Printer | 3D Systems ProJet 5000 |
As an accredited 3D Systems VisiJet EBK-ENT-R36 Multi-Material Composites (VisiJet CE-BK + VisiJet CE-NT) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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Patient-specific anatomical modelling imposes a dual requirement on printable elastomers: the bulk material must reproduce the nonlinear stress-strain response of soft tissue under uniaxial loading, while the interface between regions must resist delamination during repeated clamp and retraction cycles. The CE-NT phase is assigned to low-modulus parenchymal volumes; CE-BK is assigned to vessels, ducts, or tumour margins where higher tear resistance and visual contrast under surgical lighting are required. Compliance documentation for hospital-based training devices should include ISO 10993-5:2009 and ISO 10993-10:2010 panels when skin or mucosal contact exceeds 1 h; no claim of sterility is inferred from these designations. For European procurement, the build materials are assessed under REACH Regulation (EC) No 1907/2006 Annex XVII restrictions and RoHS Directive 2011/65/EU where embedded electronic components are used. Formulation addition ratio: no reactive diluent, filler, or plasticiser is compounded into the feedstock; the multi-material ratio is a digital volume distribution of 70:30 CE-NT:CE-BK as a starting point for solid-organ models, with CE-BK limited to 30% of build volume to avoid excessive stiffening of the palpation field. Exact voxel dithering is controlled by the MJP build processor, not by manual mixing. Downstream production process: parts are built at 32 µm layer thickness on MultiJet Printing platforms with wax-based support; support removal is carried out in an ultrasonic bath containing isopropyl alcohol or manufacturer-specified solvent at 20–25°C for 60–120 min, followed by forced-air drying at 40°C until mass change stabilises below 0.5%. A post-cure UV cycle of 20–40 min is applied only when the model must withstand repeated steam autoclave exposure. Terminal finished product types include patient-specific thyroidectomy trainers, cardiac septal defect replicas, vascular anastomosis task trainers, and CT-derived kidney models with embedded CE-BK tumour boundaries.
| Standard | Application condition | Test endpoint |
|---|---|---|
| ISO 10993-5:2009 | Direct cellular contact | Qualitative morphological grade |
| ISO 10993-10:2010 | Repeated skin contact | Delayed dermal sensitisation |
| ASTM D2240-15 | Shore A hardness | Durometer reading after 7-day conditioning at 23°C/50% RH |
Soft-robotic end-effectors fail primarily by crack initiation at the junction between the flexible bellows wall and the stiffer mounting flange. In CE-NT builds, a 45° fillet radius of at least 2.0 mm at this junction is required to keep the maximum principal strain below the tear-initiation threshold measured by ASTM D624-00(2020). CE-BK is used in the distal contact pads, where abrasion against corrugated cardboard, glass, and brushed aluminium occurs during pick-and-place cycles. Compliance standards: ASTM D412-16 for uniaxial tensile elongation, ASTM D624-00(2020) for die C tear propagation, ISO 37:2017 for stress-strain properties, and DIN EN ISO 527-2:2012 where rigid flanges are co-printed; SDS review under REACH Article 31 is required before air transport of uncured cartridges. Formulation addition ratio: the recommended build composition is 100% CE-NT for the pneumatic bladder and 100% CE-BK for contact pads; where a stiffness gradient between them is required, the digital voxel fraction of CE-BK is increased in 20–25% steps across 2.0 mm transition bands. No solvent blending is applied. The apparent hardness of the transition zone can be shifted between Shore A 27 and Shore A 35 by altering the voxel ratio; published data for the exact mechanical response of mixed voxel lattices is limited. Downstream production process: after building, the wax support is removed in a two-stage bath under agitation; residues inside pneumatic channels are cleared with a low-pressure solvent flush at 0.2–0.35 MPa until no paraffin film remains on infrared transmission. The assemblies are then dried for 12 h at 25°C and 50% RH before first actuation. Fatigue testing is conducted at 0.5 Hz for 10,000 cycles; samples with visible microcracks at the bellows root are rejected. Terminal finished product types include bellow-type soft grippers, vacuum suction cup end-effectors, soft finger actuators for logistics robots, and air-driven sorting heads for fresh produce handling.
In low-volume MJP gasket production, compression-set failure is driven by the elastomer losing recovery force after prolonged thermal load, resulting in flange relaxation and bypass leakage. For CE-NT gaskets conditioned at 70°C for 22 h under 25% deflection, the compression set is measured according to ASTM D395-18 Method B; the achievable value is batch-dependent and is strongly influenced by post-cure completeness and residual support solvent. Compliance anchors: ASTM D395-18 Method B for compression set, ASTM D2240-15 for Shore A hardness, ASTM F37-06(2013) for seal leakage rate on flat sheets, ISO 815-1:2019 for low-temperature compression set, and EN 13555:2014 for gasket creep/relaxation parameters used in flange design calculations. For EU industrial machinery, the article-level REACH SVHC communication obligation under Article 33 is applicable when cured parts are supplied above 0.1 wt% candidate-list substance threshold. Formulation addition ratio: the bulk seal body is built from 100% CE-NT; CE-BK is assigned only to the outer alignment ring at 15–20% of total part volume to provide visual identification and moderate abrasion resistance at the bolt-contact face. Because the two elastomers are not chemically co-cured, interfacial adhesion is mechanical and depends on layer-wise cure; a minimum interface overlap of 3.0 mm is specified. Downstream process: build orientation places the seal face perpendicular to the Z-axis to reduce staircase-induced leak channels. Support removal uses a two-stage isopropyl alcohol soak; parts are then vacuum-dried at 45°C and −0.08 MPa for 6 h to strip residual alcohol from the subsurface. A closed-loop UV curing cabinet with 365 nm LED arrays is used for 30–60 min; incomplete post-cure causes anomalously low durometer readings at the core. Terminal finished product types include flange gaskets for low-pressure chemical injection systems, manway cover seals for pilot-scale reactors, pneumatic cylinder end-cap seals, and leak-test fixtures.
Iterative shell modifications in orthotic fitting trials are conventionally performed on thermoplastic sheets at temperatures above their glass transition. Substituting multi-material printed elastomers requires matching the local stiffness of the anterior tibial strap and the cushioning of the plantar surface without delamination under sweating and repeated donning. Standards: ISO 22523:2006 for external limb prostheses and orthoses, ISO 13485:2016 for design-control documentation when the device remains in a clinical investigation, ISO 10993-1:2018 for skin-contacting categorisation, and REACH Annex XVII entries 51/52 for phthalate-restricted plasticisers if the material is used in child-specific orthoses. Formulation addition ratio: the CE-NT bulk phase accounts for 85–90% of build volume; CE-BK inserts are embedded in the heel counter and the proximal strap anchorage at 10–15% volume. No external plasticiser is added. The digital voxel boundary is stepped over 1.5–2.0 mm to reduce stress concentration. Published data for physiological loading of this exact CE-BK/CE-NT combination is limited. Downstream process: the initial limb scan is converted to a surface mesh and shelled at 2.0–4.0 mm wall thickness depending on body mass. After MJP at 32 µm layer thickness, wax support is removed with manufacturer-specified solvent at 20–25°C; the device is then placed in a circulating-air oven at 40°C for 8 h to bring residual extractables below the clinic's threshold. A final isopropyl alcohol wipe at 70 vol% is used before patient contact. Terminal finished parts include ankle-foot orthosis trial shells, custom insole prototypes with variable Shore A zones, below-knee socket liner check sockets, and off-loading heel wedges for diabetic foot trialling.
A wearable electronic enclosure places a thin elastomeric gasket between the polycarbonate or ABS housing and the skin or textile layer. The sealing interface is subjected to cyclic shear from arm swing, partial pressure from sweat vapour, and repeated isopropanol disinfection. CE-NT is selected for the skin-contact seal; CE-BK is applied to the outer bezel lip where UV exposure and abrasion from clothing occur. Compliance standards: ISO 10993-5:2009 and ISO 10993-10:2010 for skin-contact materials, ISO 4628-2:2016 for blistering evaluation after accelerated vapour exposure, ASTM D1149-18 for ozone resistance of the outer bezel lip, and IEC 62321-5:2013 for phthalate content where child-worn products are under review; RoHS under Directive 2011/65/EU Annex II is referenced when the seal is integrated into an electrical assembly. Formulation addition ratio: the seal body is 100% CE-NT; the outer cosmetic lip contains a 50:50 voxel-dithered transition from CE-NT to CE-BK, yielding a dark outer edge without a chemical mixing step. Because the two phases are delivered as separate material cartridges and jetted independently, the ratio is set in the build processor rather than in liquid formulation. Downstream production process: parts are built at 32 µm layer thickness with the sealing face upward; support removal is carried out in isopropyl alcohol at 25°C for 45–60 min. After removal, parts are dried in a desiccator at 30°C and 10% RH for 6 h. A final UV post-cure at 365 nm for 20–30 min is used to drive conversion above 90% to reduce water-soluble extractables. Solvent exposure must not exceed 120 min because swelling above 5% by mass can reduce seal bead height below the housing compression specification. Terminal finished product types include wrist-worn device gaskets, ear-worn device tips, chest-strap electrode insulators, and head-mounted display facial seals.
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The product designation 3D Systems VisiJet EBK-ENT-R36 identifies a multi-material photopolymer kit containing two build material formulations: VisiJet CE-BK, a black opaque acrylate-based material, and VisiJet CE-NT, a natural translucent material. The EBK-ENT-R36 commercial SKU is supplied for MultiJet Printing platforms that operate with two heated build material bays and a wax-based support system. The materials are jetted through piezoelectric printheads, planarized by a recoater blade, and cured by UV exposure in the build chamber. The kit is not an adhesive, coating, or casting resin. The individual CE-BK and CE-NT cartridges are recognized by the printer software as separate build materials and must be assigned to discrete solid regions or shells in the CAD model.
Published documentation for the EBK-ENT-R36 kit as a separate datasheet is limited. The individual CE-BK and CE-NT datasheets list mechanical property measurements against ASTM D638-14, ASTM D790-17, ASTM D256-23, and ASTM D648-18. Users qualifying the paired set should not transfer single-material datasheet values to the multi-material transition zone without separate tensile bars or flexural coupons spanning the CE-BK/CE-NT interface. Test coupons should be printed in the same orientation, layer height, and post-cure sequence as production parts.
Parts produced with CE-BK and CE-NT are embedded in wax-based support material after the build. Support removal on MJP systems generally follows a two-stage process: a controlled oven melt-out phase followed by heated oil or proprietary solvent immersion. Because EBK-ENT-R36 contains two build materials with different optical density, process heating can be non-uniform if the black CE-BK regions absorb infrared energy more rapidly than natural CE-NT regions. The wax removal station should therefore be profiled with a weighted part load that includes both materials. Thin natural translucent walls should not bear the weight of black sections during melt-out. Published data for the EBK-ENT-R36-specific melt-out temperature and immersion time is limited, so the equipment manufacturer’s recommended range should be bracketed with sacrificial parts at the upper and lower limits.
Production-scale experience on MJP hardware indicates that residual wax in blind channels below 1 mm diameter is the most frequent source of batch-to-batch rejection. Ultrasonic bath cleaning can reduce residual support but may induce cavitation damage on thin CE-NT sections if the part is not fixtured. A consistent post-cure UV dose is also required because incomplete acrylate conversion at the surface can leave a tacky residue and reduce hardness measured by ASTM D2240-15. The UV post-cure unit should be validated for timer or radiometer settings, and parts should be rotated to expose shaded internal surfaces. Operators should avoid stacking parts during post-cure, since contact points can block critical UV wavelengths and create localized under-cure.
The CE-BK and CE-NT formulations are rigid engineering photopolymers. The black and natural variants differ primarily in pigment package and optical transmission; the base monomer system is not disclosed in the public safety data sheets. Shrinkage in photopolymerization is a function of monomer conversion and cross-link density, not solely pigment loading. Users measuring dimensional stability should condition parts to equilibrium and record shrinkage against the CAD model using a calibrated optical comparator or CMM. Solvent uptake in CE-BK and CE-NT follows the behavior of cross-linked acrylate networks: short-term exposure to isopropanol is common for cleaning, but prolonged contact with ketones, chlorinated solvents, or aggressive automotive fluids can produce microcracking and loss of tensile elongation. Published chemical compatibility data for EBK-ENT-R36 is limited; immersion testing should follow ASTM D543-21 or equivalent.
Thermal expansion in CE-BK and CE-NT is not commonly disclosed in public literature. If the two materials are used in a housing that undergoes repeated thermal cycling, the assembly should be tested from the minimum to maximum service temperature. Differential expansion at the color transition can create tensile stress at the interface. A conservative measurement method is to precondition parts at 23 °C ± 2 °C and 50 % ± 5 % RH according to ISO 291:2008, then measure critical dimensions before and after the thermal cycle. Published data for the specific EBK-ENT-R36 configuration is limited, so internal CTE comparison should be performed with a thermomechanical analyzer or equivalent calibrated instrument.
The EBK-ENT-R36 kit differs from single-material VisiJet M2R and M2G offerings by supplying a black and natural material pair in one ordering SKU. M2R clear and gray materials are often used where a single neutral rigid material is acceptable. CE-BK provides opaque black identification surfaces; CE-NT provides a natural translucent appearance without post-process painting. The mechanical property overlap between CE-BK/CE-NT and other rigid VisiJet photopolymers has not been published as a single comparative table for the EBK-ENT-R36 configuration. A material substitution therefore requires side-by-side tensile testing according to ISO 527-2:2012 or ASTM D638-14 using the same MJP platform, layer height, and post-cure protocol. Substitution based solely on visual appearance or datasheet hardness is not technically sufficient.
Individual CE-BK and CE-NT documentation may report tensile strength, tensile modulus, elongation at break, flexural strength, flexural modulus, notched Izod impact, and heat deflection temperature. The test methods commonly referenced are ASTM D638-14, ASTM D790-17, ASTM D256-23, ASTM D648-18, and ISO 75-1/2:2020. A separate EBK-ENT-R36 combined datasheet that reports the interface properties of CE-BK and CE-NT printed in the same build is not always published. Where a value is not disclosed, the appropriate engineering response is to state that published data for the specific configuration is limited and to generate internal qualification data. Do not interpolate properties between the two materials across the transition boundary.
| Verification area | Reference method | CE-BK individual documentation | CE-NT individual documentation | EBK-ENT-R36 combined kit documentation |
|---|---|---|---|---|
| Tensile properties | ASTM D638-14 / ISO 527-2:2012 | Reported on individual datasheet where available | Reported on individual datasheet where available | No separate public combined datasheet located |
| Flexural properties | ASTM D790-17 / ISO 178:2019 | Reported on individual datasheet where available | Reported on individual datasheet where available | No separate public combined datasheet located |
| Heat deflection temperature | ASTM D648-18 / ISO 75-1/2:2020 | Reported on individual datasheet where available | Reported on individual datasheet where available | No separate public combined datasheet located |
| Impact resistance | ASTM D256-23 / ISO 180:2023 | Reported on individual datasheet where available | Reported on individual datasheet where available | No separate public combined datasheet located |
| Hardness | ASTM D2240-15 / ISO 868:2003 | Reported on individual datasheet where available | Reported on individual datasheet where available | No separate public combined datasheet located |
Because the EBK-ENT-R36 SKU is regionally coded, cartridge volumes and fill weights can vary by regional packaging. The operator should verify that the printer’s material bay mapping matches the cartridge RFID or barcode recognition. Mismatched insertion of CE-BK into the wrong bay can produce build aborts or contamination at the fluid couplings. The system software generally locks material selection to the assigned bay; production records should capture cartridge lot number, date of first use, and printer serial number to support traceability under ISO 9001:2015 or equivalent quality management requirements.
Jetting reliability for CE-BK and CE-NT is governed by low-shear viscosity, surface tension, and pigment dispersion stability. The printhead firmware compensates for normal viscosity variation by adjusting piezoelectric drive voltage, but the factory acceptance band is not operator-adjustable. Cartridges stored below recommended room temperature can exhibit temporarily elevated viscosity; cartridges heated above the recommended range can age prematurely. EBK-ENT-R36-specific viscosity versus shear rate data is not published. On the production floor, missing jets, satellite droplets, or banding parallel to the recoater direction indicate that the material or printhead condition has shifted outside the control envelope. The response is not to modify the material but to replace the cartridge, clean the printhead, and verify the planarizer gap.
Do not dry CE-BK and CE-NT cartridges in a conventional desiccant dryer. The materials are supplied as sealed liquid photopolymers; heating under vacuum or air can polymerize the material prematurely or alter jetting viscosity. The cartridges should be stored away from UV sources and fluorescent light. If the material has been exposed to temperatures below 10 °C during transport, the cartridge should be conditioned at room temperature for a period specified by the manufacturer before insertion into the printer. These constraints are not unique to EBK-ENT-R36 but apply to jettable acrylate photopolymers generally.
For machined features, CE-BK and CE-NT can be drilled, reamed, and tapped after post-cure, but cutting speeds should be reduced compared with injection-molded ABS because thermoset photopolymers can chip or melt at high feed rates. Machined edges at the CE-BK/CE-NT transition may show material pull-out if the tool exits the black region and enters the natural region. Climb cutting and sharp tooling are preferred. The resulting surface should be inspected under 20× magnification for interface delamination. No published machinability data for EBK-ENT-R36 is available, so feed and speed parameters must be validated on sacrificial parts.
When a printed housing combines CE-BK and CE-NT regions under load, the failure path may localize at the interface rather than in either bulk material. Tensile bars printed with the interface perpendicular to the loading axis should be tested according to ASTM D638-14 and compared to single-material controls. If the interface strength is not published, a conservative design approach assumes the transition zone is a weld line. The designer should avoid placing the material boundary at a snap-fit root, living hinge, or sealing lip. For sealing applications, the CE-NT surface should be checked for flatness after post-cure because differential shrinkage can create step offsets at the color change. Measurement should be performed with a calibrated dial indicator or CMM, and the measured step height should not exceed the seal manufacturer’s specified gap tolerance.
| Regulatory or quality requirement | Reference | Verification practice |
|---|---|---|
| Heavy metals restriction | RoHS Directive 2011/65/EU | Request individual CE-BK and CE-NT declarations |
| SVHC reporting | REACH Regulation EC 1907/2006 | Check Article 33 candidate list disclosure for each cartridge |
| Material safety | GHS SDS | Review protective measures for uncured resin and support material |
| Dimensional measurement | ISO 1101:2017 | Set internal GD&T callouts for multi-material step offset |
Painting and coating adhesion tests should include cross-cut adhesion according to ISO 2409:2020 or ASTM D3359-23. Residual wax and under-cured acrylate are the two most common causes of coating failure. A solvent wipe alone is not sufficient; post-cure followed by light abrasive blasting or sanding of the surface improves mechanical anchoring. The black CE-BK surface may require different primer timing than the natural CE-NT surface because pigment can affect surface energy. Adhesion should be tested on both materials and on the transition line.
Material qualification for EBK-ENT-R36 should therefore proceed as a paired set, not as two independent materials. Physical performance tests across the transition boundary, support removal process capability, and document status should be recorded in the production batch record. Where public datasheet values are absent, the qualification record must state that published data for the specific EBK-ENT-R36 configuration is limited and that the internal test data supersedes marketing literature.