| HS Code | 951473 |
| Material Type | Photopolymer |
| Color | Black |
| Tensile Strength | 48 MPa |
| Tensile Modulus | 1700 MPa |
| Elongation At Break | 8% |
| Flexural Strength | 70 MPa |
| Flexural Modulus | 1900 MPa |
| Hardness | 80 Shore D |
| Density | 1.12 g/cm³ |
| Heat Deflection Temperature At 0 45 Mpa | 60 °C |
| Heat Deflection Temperature At 1 82 Mpa | 50 °C |
| Notched Izod Impact Strength | 20 J/m |
| Water Absorption | 0.3% |
As an accredited 3D Systems VisiJet CE-BK Polymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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Pneumatic valve production at batch sizes between 50 and 2,000 units has adopted VisiJet CE-BK Polymer for gland seals where compression-molded nitrile rubber tooling cannot be justified by annual volume. In this application the seal lip is printed as a continuous circumferential profile with a 0.8 mm radial cross-section and a 1.5 mm axial sealing face, then interference-fitted into an anodized aluminum gland. Formulation addition ratio is 100% CE-BK as supplied. No reactive diluent, filler, or post-blended curative is added because any reduction in durometer must be achieved through a separate VisiJet grade, not through shop-floor mixing. Compliance baseline for compression set is ISO 815-1 Method A at 70°C for 22 h, with tensile and elongation values measured per ISO 37 on die-cut type 1 dumbbells. Tear resistance is characterized by ASTM D624 Die C. Downstream production occurs on a ProJet MJP 2500 Plus platform jetting at 800 x 900 dpi with 32 µm layer thickness. Printed green parts are transferred to a wax support removal oven at the manufacturer-specified temperature; residual wax is cleared in an ultrasonic bath containing non-aggressive cleaning fluid. Terminal product types are pneumatic poppet valve seals, cylinder cushion washers, air gripper gaskets, and pilot valve diaphragms. The limiting process condition is heat aging: if the compressed seal operates continuously above the material-specific temperature limit published on the batch certificate, permanent compression set will reduce contact force and allow air leakage. Published data for CE-BK under oil mist aging in pneumatic circuits is limited; a pre-production soak test is performed with the actual lubricating oil at 50°C, 60°C, and 70°C for 168 h to establish an internal acceptance baseline rather than relying on generic rubber aging curves.
The support removal step creates a process conflict that must be controlled. The wax support material must be heated sufficiently to melt and drain from deeply undercut seal profiles, but the oven set point must remain below the heat deflection limit of CE-BK to avoid local softening and section creep. If the oven temperature exceeds the manufacturer’s specified support removal window, thin lip sections below 1.0 mm can deform irreversibly before the wax fully clears, shifting the seal contact band and changing compression set performance. A staged soak profile is used for larger seal diameters above 40 mm, with a lower-temperature hold followed by a short finishing ramp, and dimensional verification performed after cooling against the CAD nominal. The acceptable variation for an industrial pneumatic seal lip is commonly limited to ±0.1 mm on the radial cross-section; this is checked with a non-contact optical comparator before installation into the gland housing.
Repeated bending of wearable medical device housings concentrates strain at snap-fit undercuts, display gasket grooves, and charging port apertures, where tear initiation becomes the dominant failure mode. VisiJet CE-BK Polymer is processed undiluted at 100% formulation addition ratio; no plasticizer is introduced because plasticizer migration would alter tear strength and potentially irritate skin in prolonged contact. The compliance pathway for a finished device incorporates ISO 10993-5 cytotoxicity testing and ISO 10993-10 sensitization and irritation testing, with the manufacturing file controlled under ISO 13485. Tear resistance is characterized by ASTM D624 Die C on specimens printed in the XY plane, while flex fatigue is screened by repeated extension to 50% strain for 10,000 cycles using a motorized linear stage. Downstream manufacturing uses MultiJet Printing at 32 µm layers, followed by wax support removal in a warm air oven and a two-stage isopropanol and deionized water rinse; no additional thermal cure is applied after the support removal cycle. Terminal product classes include continuous positive airway pressure mask cushions, wearable cardiac monitor housing gaskets, glucose sensor adhesive carriers, and hearing aid charging case seals.
The operational boundary in this downstream sector is not the printing step but the biological evaluation of the completed wearable. Under occlusive skin contact beyond 24 h, the finished device must be evaluated for extractables under ISO 10993-18, because the polymer’s residual low-molecular-weight species are not characterized in the standard mechanical datasheet. In addition, the black elastomeric surface should not be considered inherently biocompatible solely because the material is processed without fillers; batch-specific certificates of analysis must be reviewed alongside the final device cleaning and packaging process before clinical trial deployment. For devices that require repeated sterilization, the compatibility of CE-BK with autoclave, ethylene oxide, or gamma radiation is not assumed and should be confirmed on printed geometry identical to the production geometry to avoid misleading validation across different wall thicknesses.
Ingress protection in handheld industrial tablets and field instruments has driven the replacement of die-cut elastomer gaskets with directly printed VisiJet CE-BK Polymer seals in low-volume enclosures. Formulation addition ratio is kept at 100% CE-BK as supplied; any attempt to compound the resin with silicone oil or filler before jetting lowers the cure response and creates jet dropout on the ProJet MJP 2500 Plus printhead array. The process builds the gasket as a single continuous bead with a 0.6 mm minimum cross-section and a 25% target compression in the housing groove; printing at 800 x 900 dpi and 32 µm layers produces groove-conformal geometry that die-cutting cannot replicate. Compliance is assessed at the finished device level under IEC 60529 for ingress protection ratings, with material declarations meeting RoHS Directive 2011/65/EU and REACH Regulation (EC) No 1907/2006. After support removal and ultrasonic cleaning, the gasket is installed into an injection-molded polycarbonate groove. Terminal products are overmolded battery door gaskets, stylus port seals, side key switch mats, and docking station compression pads. The limiting boundary is groove tolerance: if the seal is compressed beyond 35% strain at elevated temperature, stress relaxation may drop the contact force below the specified IP rating threshold.
Low-volume automotive service parts and pre-production validation builds have used VisiJet CE-BK Polymer to replace compression-molded EPDM seals where a 12- to 16-week tooling lead time would halt vehicle prototype assembly. The resin is loaded at 100% formulation addition ratio, with no carbon black, sulfur, accelerator, or process oil added; this eliminates cure-rate variability associated with batch-to-batch curatives in rubber compounding. Downstream processing on the MultiJet Printing platform at 32 µm layer thickness allows undercuts and hollow cross-sections to be printed without draft angles, after which wax supports are removed in a heated chamber and the part is rinsed. Compliance documentation for automotive prototype use includes SAE J200 rubber classification for applicable elastomer suffix requirements, FMVSS 302 flammability screening at the composite component level, and REACH SVHC documentation. Terminal product types are body harness grommets, dust covers for shifters, stop lamp housing gaskets, and door check link bumpers.
The operational boundary is thermal and chemical. CE-BK should not be specified for continuous contact with engine oil above 80°C unless a long-term soak test under ISO 1817 in the actual fluid is performed, because published data for CE-BK in hot hydrocarbon oils is limited. In automotive assembly trials, the material is most reliable in passenger-compartment and exterior electrical sealing rather than underhood oil-contact environments. For any exterior seal exposed to road de-icing salts, cyclic weathering according to ISO 4892-2 or an internal OEM weathering standard should be run on a full assembly because the printed elastomer’s surface may respond differently than conditioned EPDM reference plaques.
Orthotic cushioning and footwear prototyping require a stiffness gradient across a single part that cannot be obtained from a uniform Shore hardness sheet material. In this application CE-BK Polymer is consumed at 100% resin solids as the sole build material, while the effective local stiffness is varied by adjusting internal lattice volume fraction between 25% and 55% in the CAD file rather than by changing material formulation. MultiJet Printing at 32 µm layers produces unsupported lattice struts down to 0.8 mm diameter, and the wax support removal cycle is followed by forced air drying to eliminate residual solvent before skin-contact trials. Compliance for orthotic devices references ISO 10993-5 and ISO 10993-10 where classified as medical devices, while footwear prototyping falls under REACH Annex XVII restricted substances and brand-specific restricted substance lists. Terminal product types are diabetic insole arch plugs, heel cup prototypes, metatarsal pad prototypes, and midsole flex-zone demonstrators.
The limiting material behavior in orthotic applications is cyclic compression set. The printed lattice should be tested to ASTM D395 Method B at 23°C and 40°C for 24 h before design freeze, because lattice orientation relative to the Z axis changes the measured set and may create premature softening in high-cycle walking simulations. Published data for CE-BK in full-scale footwear abrasion tests such as ASTM D1052 Ross flex is limited; therefore, structural prototypes should not be treated as production insoles or midsoles without a separate upper-bonding and flex-cycling validation program.
End-of-arm tooling in collaborative robot stations now uses VisiJet CE-BK Polymer for gripper pads that must conform to variable part geometry without marring aluminum or polished steel surfaces. The formulation addition ratio is 100% CE-BK; no tackifier, colorant, or conductivity additive is blended because inkjet jetting windows are tight and reactive diluents alter the molecular weight between crosslinks, reducing tear strength measured by ASTM D624. The downstream production sequence begins with MultiJet Printing at 32 µm layer thickness and 800 x 900 dpi resolution, followed by support wax removal in a heated oven and ultrasonic cleaning in deionized water. A conformal gripper pad is typically printed as a 2.0 mm outer skin with an internal lattice core at 40% volume fraction, then mounted onto a machined aluminum jaw plate with M3 fasteners in countersunk pockets. Compliance baseline includes ISO 10218-1 for collaborative robot safety validation and RoHS Directive 2011/65/EU for the CE-BK resin declaration. Terminal product classes are cobot gripper fingers, suction cup adapter lips, pick-and-place pads, and bin-picking jaw faces.
The critical process boundary is interlayer adhesion. Tear initiation at the Z-plane interface can occur if the printer’s planarizer or printhead temperature falls outside the manufacturer’s specified window; parts must be visually inspected for delamination after 1,000 flex cycles using a servo-controlled gripper test rig. In deep-dive evaluations, specimens printed with a vertical Z orientation show lower tear strength than XY specimens under ASTM D624, so the part orientation should be rotated to place the highest tensile stress along the XY plane rather than across the layer boundaries. For gripper pads operating in cold-chain environments below 5°C, the dynamic stiffening behavior of CE-BK is not fully characterized in public literature; a cold-room flex test is required before deployment in refrigerated picking cells.
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3D Systems VisiJet CE-BK is a rigid, opaque, high-contrast black UV-curable photopolymer formulated for the ProJet MJP 2500 series MultiJet Printing platforms. The material is processed with co-deposited VisiJet S300 wax support material within a build envelope of 294 × 211 × 144 mm and a native layer thickness of 32 µm. CE-BK is part of the VisiJet CE material family intended for consumer electronics enclosure prototypes, dark bezels, black functional covers, and appearance-critical parts requiring reduced post-print color finishing. Published mechanical values are typically generated on Type I tensile specimens according to ASTM D638-14 and flexural specimens according to ASTM D790-17. The polymer is not a translucent optical material and is not intended as an investment-casting pattern. The dark surface reduces visual contrast during dimensional inspection under structured-light scanning, but the same low reflectivity can mask wax-support residue in blind recesses. Process controls therefore require validated support-removal inspection under low-angle illumination rather than reliance on visible color contrast alone.
Manufacturer-published nominal property values for CE-BK are reproduced below as typical values, not as specification limits. The values correspond to ProJet MJP 2500 Plus builds using default orientation and post-process parameters. Orientation-specific qualification coupons remain necessary for structural applications because layer-boundary effects alter mechanical response along the z-axis.
| Property | Published nominal value | Test method |
|---|---|---|
| Tensile strength | 34 MPa | ASTM D638-14 |
| Tensile modulus | 1,500 MPa | ASTM D638-14 |
| Elongation at break | 8 % | ASTM D638-14 |
| Flexural strength | 49 MPa | ASTM D790-17 |
| Flexural modulus | 1,300 MPa | ASTM D790-17 |
| Notched Izod impact | 24 J/m | ASTM D256-10 |
| Heat deflection temperature at 0.455 MPa | 52 °C | ASTM D648-18 |
| Heat deflection temperature at 1.82 MPa | 44 °C | ASTM D648-18 |
| Hardness | 78 D | ASTM D2240-15 |
| Density | 1.04 g/cm³ | ASTM D792-20 |
The tabulated values place CE-BK in the rigid, low-ductility photopolymer class. Tensile modulus of 1,500 MPa and flexural modulus of 1,300 MPa provide structural stiffness suitable for small enclosure covers and non-load-bearing black prototypes. Elongation at break of 8 % is lower than many tough stereolithography resins, so interference snaps and clip features require strain-limited design. The notched Izod value of 24 J/m indicates low energy absorption compared with semi-crystalline thermoplastics such as unfilled polyamide 6. Impact-sensitive components should use ribbing, thickened bosses, and generous fillet radii rather than relying on the polymer to absorb drop impact. Heat deflection temperatures of 52 °C and 44 °C under the respective stress levels restrict CE-BK to low-temperature consumer appliance and indoor electronics environments.
Native processing on the ProJet MJP 2500 Plus uses a fixed MultiJet print head array, and the printer software applies a material-specific UV dose per voxel rather than selecting an independent layer height for each job. CE-BK is dispensed alongside VisiJet S300 support wax, and the two-phase build requires that support material remain in place until the as-built part is transferred to the post-processing station. The as-built part stays on the build tray until wax removal, and the build should be oriented so that drainage channels avoid retained wax in closed cavities. In high-definition mode the nominal z-step is 32 µm, while xy-resolution is governed by the MultiJet print head array rather than selected per material. Fine text or knife-edge features are typically oriented with critical surfaces in the xy-plane because layer-stepping on shallow angles below 10° produces visible banding that is only partially mitigated by post-print smoothing. CE-BK does not require a thermal post-cure step, but residual support wax must be fully removed before any UV clear coat, primer, or adhesive bonding application.
MultiJet Printing with CE-BK differs from stereolithography and fused deposition post-processing because the wax support is removed by heat and subsequent rinsing rather than by mechanical breakaway or solvent dissolution in an aggressive solvent. The support wax allows internal channels and undercuts to be generated without pips or witness marks, but cleaning access must be verified. Long, narrow channels with diameters below approximately 2 mm can retain wax because ultrasonic cleaning fluid does not circulate effectively in blind features. Production-scale MultiJet lines therefore add extended cleaning cycles only for geometries with demonstrated wax retention. CE-BK’s black surface increases the difficulty of detecting thin wax films, so visual inspection requires oblique lighting or ultrasonic imaging for critical channels.
Published mechanical values for CE-BK are not sufficient for structural design unless the test coupon orientation matches the printed part orientation. In MultiJet Printing, droplet coalescence and UV cure generate layer boundaries with lower cross-link density than the bulk xy-plane. This can reduce z-direction tensile elongation and impact resistance relative to in-plane values. The manufacturer-published property table does not provide a full z-axis tensile dataset for every distributor batch; published data for this specific configuration is limited. For snap-fit covers and latching features, production groups print flexural elements in the xy-plane and apply a strain ceiling below the 8 % nominal elongation at break. Notched Izod values of 24 J/m reflect xy-plane coupon response and should not be extrapolated to z-loaded bosses or unsupported tab geometries. Build orientation also influences surface stair-stepping and support contact artifacts. Features with shallow angles below 10° to the build plane are oriented steeper to reduce banding unless a machined surface is acceptable.
For dark appearance parts that require metrology, the black surface of CE-BK can reduce optical artifacts in structured-light scanning, but the same dark color can hide crack initiation in thin flexural elements. Thin walls below 1.0 mm are sensitive to distortion during support removal because the flexural modulus of 1,300 MPa allows creep at moderately elevated oven temperatures. Field data from MultiJet Printing service bureaus indicate that CE-BK part distortion is most commonly observed in long, flat covers oriented parallel to the build plane when support removal temperatures approach the 0.455 MPa heat deflection temperature. Supporting the part during wax removal or choosing a steeper build angle reduces the bending moment caused by residual wax mass.
Parts printed in CE-BK are cleaned in two stages: heated support removal followed by ultrasonic cleaning in VisiJet EZ Rinse-C or a compatible low-alkaline cleaning agent. Because CE-BK exhibits an HDT of 52 °C at 0.455 MPa and 44 °C at 1.82 MPa, the wax-removal temperature must remain below the lower deflection threshold when parts carry residual wax mass or support anchors. Cleaning baths are typically maintained at 35 °C or below to avoid edge softening in thin sections. After cleaning, parts are air-dried under ambient conditions. No thermal post-cure is specified, but direct sunlight or high-intensity UV exposure can drive additional surface polymerization and produce minor color shift. The dark CE-BK surface complicates detection of residual support wax in blind holes; inspection under low-angle illumination or ultrasonic imaging is used on production lines. Published data for long-term solvent exposure of CE-BK is limited; wipe cleaning with isopropyl alcohol should be terminated immediately after residue removal because retained alcohol can promote surface microcracking in thin sections.
Adhesion of paints, primers, and coatings to CE-BK after support removal should be verified by cross-cut adhesion testing according to ASTM D3359. The black photopolymer can be coated with UV-curable topcoats, but solvent-based primers containing ketones, esters, or chlorinated solvents should be screened before production use. Because the material is a thermoset, it does not melt during drying or coating cure cycles; however, exposure above the heat deflection temperature under load can cause dimensional change. CE-BK’s dark color after cleaning is uniform enough for appearance prototypes but is not supplied with a certified color value such as a CIELAB target. If lot-to-lot color consistency is required, incoming material should be verified with a colorimetric instrument using a standard illuminate such as D65.
CE-BK differs from VisiJet M2R-BK in intended use. CE-BK is formulated for high-contrast black appearance and color stability in consumer electronics prototypes, whereas M2R-BK is positioned as a general-purpose black rigid resin. Published property tables for the two materials are not identical; CE-BK’s tensile modulus is lower than several general-purpose VisiJet rigid resins, and its dark opaque color eliminates the need for post-print dyeing of natural or clear resins. Unlike VisiJet M2R-CL, CE-BK is not suitable for light piping, light-transmission fixtures, or flow visualization. Unlike VisiJet M2 CAST, CE-BK is not suitable for investment-casting burnout patterns because the photopolymer does not melt cleanly in dewax furnaces. Transitioning from fused deposition of black ABS to MJP CE-BK also requires changing post-processing assumptions: CE-BK is a thermoset photopolymer, so ultrasonic welding and thermal staking used with ABS are not applicable. Adhesive bonding and mechanical fastening remain viable, but insert installation should use machined or printed pilot bores with low-interference thread designs.
CE-BK is also different from elastomeric or tough MJP materials because it is stiff and relatively brittle at low strain. For consumer electronics applications, the material is used for stationary wearable housing prototypes, small appliance control-panel components, bezels, and optical inspection fixtures where black surfaces reduce stray light reflections. The nominal tensile elongation at break of 8 % limits snap-fit insertion strain. Tapered snap arms with a practical strain ceiling below 5 % are specified unless orientation-specific testing demonstrates otherwise. Thread-forming screws in printed bosses should use pilot holes and low-engagement thread designs. Printed vertical bores can exhibit radial variation at layer boundaries, and critical holes are machined to maintain roundness below 0.1 mm. CE-BK is not used for living hinges, high-impact tool housings, or continuous service above the 0.455 MPa heat deflection temperature.
Dimensional accuracy for CE-BK parts depends on geometry, orientation, and the support-removal thermal cycle. Published datasheets do not provide a single isotropic shrinkage factor for all features; compensation factors are applied in the printer software and validated by first-article inspection on a feature-specific basis. Thin walls below 1.0 mm are more sensitive to curling during heated wax removal than thick sections because low flexural modulus permits gravity-induced creep. Features below 0.5 mm may be limited by support-wax retention and cleaning access rather than native print resolution. For small reference features, unloaded geometric tolerances are often held within ±0.1 mm, but this is not a supplier guarantee for every material lot or geometry. Moisture uptake in high-humidity storage above 60 % RH can affect check-fixture dimensional stability; desiccant storage is specified for metrology reference assemblies. CE-BK should not be exposed to continuous service above its heat deflection temperature, and creep under load should be evaluated using ASTM D2990 or an equivalent long-term creep method for loaded enclosure clips.
The black surface of CE-BK can be marked, machined, or engraved after cleaning. Machining should use low cutting speeds and adequate dust extraction because the thermoset photopolymer does not produce continuous thermoplastic chips. Holes and slots intended for pressed inserts are often machined after printing rather than printed because as-printed vertical bores can exhibit layer-boundary porosity or radial variation. If inserts are installed with heat-staking methods used for thermoplastic resins, the process is not applicable to CE-BK because the material will not melt and may degrade locally. Press-fit inserts with low interference are preferred, and adhesive bonding with cyanoacrylate or structural acrylic adhesives can be used after surface preparation with isopropyl alcohol wipes followed by immediate drying.
Supplier documentation for CE-BK does not establish medical, food-contact, or high-temperature regulatory status. The dark pigment and UV-curable chemistry are intended for industrial prototyping and non-regulated consumer goods development, not for implantables or prolonged food-contact applications. Downstream manufacturers must request lot-specific compliance documents before using CE-BK in products subject to electrical and electronic equipment regulations.
| Regulation or standard | Documented status | Verification requirement |
|---|---|---|
| REACH Regulation (EC) No 1907/2006 | SVHC declaration required for each lot | Supplier safety data sheet |
| RoHS Directive 2011/65/EU | No intentionally added Pb, Cd, Hg, Cr(VI), PBB, or PBDE | Supplier certificate |
| ISO 10993-1 | No biocompatibility claim in typical datasheets | Not applicable |
| FDA 21 CFR Part 177 | No food-contact claim | Not applicable |
| UL 94 | Flammability class not always listed; request Yellow Card | Supplier test data |
Operational boundaries follow directly from the thermoset photopolymer chemistry. CE-BK should not be autoclaved, solvent-welded, or exposed to continuous service above the 0.455 MPa heat deflection temperature. Aggressive cleaners containing ketones, esters, or chlorinated solvents are avoided. Isopropyl alcohol used for short-duration wipe cleaning is removed immediately to reduce the risk of surface microcracking. No thermal post-cure is required, but subsequent UV exposure shifts surface color and should be controlled if appearance-matching is critical. Sections thinner than 0.5 mm are not recommended for load-bearing features because support-removal stresses and cleaning bath exposure can generate edge cracks that are difficult to detect on the black surface.