| HS Code | 973122 |
| Product Name | 3D Systems Fused Deposition Modeling Material ABS |
| Manufacturer | 3D Systems |
| Material Type | Acrylonitrile Butadiene Styrene (ABS) thermoplastic |
| Printing Technology | Fused Deposition Modeling (FDM) |
| Form | Filament |
| Rockwell Hardness | R105 |
| Available Colors | White, black, red, blue, yellow, green, gray |
| Support Material Compatibility | Soluble and breakaway support materials |
| Layer Thickness Range Mm | 0.178 to 0.330 |
As an accredited 3D Systems Fused Deposition Modeling Material ABS factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
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In automotive assembly cells, ABS FDM locating fixtures and go/no-go gauge bodies are produced when annual part volumes fall below the economic break-even for machined acetal or cast aluminum tooling. The feedstock is dried before printing to below 0.2 wt% moisture at 80 °C for 4 h in a desiccant dryer; ambient shop-floor RH exceeding 60% during machine loading can re-introduce enough surface moisture to create steam blisters and intermittent interlayer adhesion loss. Extruder setpoint is held between 240 °C and 250 °C, the build plate at 100–110 °C, and the chamber at 65–80 °C. Layer height is set to 0.178 mm for feature-rich gauge surfaces and 0.254 mm for slab-side fixture bodies. Infill ratio is configured at 45–60% for load-bearing bodies and raised to 100% for thin tongue sections that experience repeated go/no-go insertion. The heated chamber is the primary control for warp. Builds longer than 150 mm along any axis produced without a chamber typically show corner lift exceeding 0.5 mm at 0.7% linear shrinkage; with a chamber held at 70 °C, part-to-platform release occurs only after cooling below 55 °C. CMM inspection of fixture bores and slot widths is performed under ISO 2768-1 medium tolerance class; features below 100 mm are typically held to ±0.25 mm, and features above that length require scale-factor compensation of 0.15–0.30% applied separately to X and Y axes. Finished products include door hinge alignment pins, threaded clip locating blocks, sensor bracket drill guides, and handheld go/no-go gap gauges. The service boundary is 80 °C continuous; contact with engine compartment air above that temperature produces creep and bore ovality. No food-contact or skin-contact certification is required for these assembly aids, but REACH Article 33 SVHC communication and RoHS lead-mercury screening are applied where parts enter EU assembly sites.
Enclosure prototypes and low-volume covers are printed from ABS FDM material when flame rating, machinability, and solvent smoothing are required together. The as-printed surface has a measured Ra roughness commonly between 12 µm and 25 µm at 0.178 mm layer height. Vapor smoothing is performed in a sealed stainless-steel chamber with acetone concentration maintained between 5 vol% and 15 vol% in air at 50–65 °C. Exposure is 3–10 min, depending on shell thickness and embossed detail. Mass uptake greater than 5 wt% at the end of cycling produces a tacky surface, soft corners, and visible dimensional springback after cool-down. In industrial post-processing records, smoothing after sanding to 320 grit reduces Ra from above 12 µm to below 3 µm; without a sanding step, the process hides layer lines but does not remove large stair-step contour deviations. Mechanical property retention under ASTM D638-14 after moderate smoothing is generally within 90–95% of as-printed values; aggressive high-uptake cycles can reduce elongation at break by 30% due to solvent-induced crazing. Published data for this specific 3D Systems FDM ABS configuration under production vapor smoothing is limited; the parameter window above is derived from unfilled ABS FDM post-processing records and must be revalidated per batch and wall thickness.
Enclosure suppliers evaluate unfilled ABS FDM under UL 94 at the minimum final wall thickness. The material typically achieves HB at 3.0 mm; V-0 is not an inherent property. For equipment subject to IEC 62368-1, the housing may require an internal metal line or flame barrier if the end product uses an open-porting power supply. REACH Article 33 screening and RoHS XRF verification are performed on pigmented batches because low-level cadmium or lead may be introduced through recycled feedstock streams. The terminal parts include control-box shells, handheld test instrument enclosures, prototype laptop housings, and faceplates for rack-mounted equipment. Vapor-smoothed surfaces are not used for fine text below 1 mm stroke height because solvent redistribution erodes edge definition.
| Standard / method | Condition | Published behavior for unfilled ABS FDM | Limitation |
|---|---|---|---|
| UL 94 | Vertical burn, 3.0 mm specimen | Unfilled ABS commonly rates HB; V-0 is not inherent | Requires flame-retardant additive or internal barrier |
| IEC 62368-1 | Fire enclosure | HB may be acceptable if internal shielding limits ignition source | Engineering evaluation required |
| RoHS 2011/65/EU | Homogeneous material | Unfilled ABS can comply when no restricted pigments are present | XRF screening per lot recommended |
| REACH 1907/2006 | SVHC disclosure | No SVHC expected in unmodified ABS feedstock; supplier declaration needed | Additives and masterbatch alter status |
| ASTM D257 | Surface resistivity | Typically >1012 Ω/sq | Not static dissipative; unsuitable for ESD-safe trays without additive |
Vacuum forming tools printed from ABS FDM are used for short-run trays, blisters, and equipment covers when machined aluminum tooling cannot be justified. The master is printed at 0.127–0.178 mm layer height with 100% infill; the upper surface is sanded to 240 grit and sealed with a two-part epoxy coating applied at 0.5–1.0 mm to prevent sheet-material marking. Vacuum channels are drilled after epoxy cure at 0.3–0.5 mm diameter spaced on a 25–40 mm grid over the forming area. The tool is mounted on a perforated zinc-aluminum plate and preheated to 50–70 °C before HIPS or ABS sheet is pulled. During sheet contact, tool-surface temperature must remain below 90 °C; otherwise the ABS tool face begins to soften and vacuum holes close. In low-run forming records, ABS tools of 2–3 mm skin thickness typically survive 100–500 cycles with HIPS at 2 mm sheet thickness, but crack initiation occurs at sharp internal corners after repeated thermal cycling. For polyurethane casting masters, the same printed ABS pattern is sealed with wax-free lacquer and molded in platinum-cure silicone; the silicone cavity then receives polyurethane resin. The sealer prevents styrene migration into the silicone and permits demolding from semi-mounted bosses. Products include packaging trays, concave equipment covers, and short-batch housing prototypes. Compliance for food-contact packaging is not claimed unless a functional barrier over the ABS tool is validated under FDA 21 CFR 177.1520 or equivalent; tooling used for industrial parts is screened for REACH SVHC and RoHS homogeneity.
ABS FDM is used for sacrificial investment casting patterns when low-volume castings require features that are difficult to machine into a wax injection die. The pattern is printed hollow with a 2–4 mm wall thickness and is fitted with a wax runner system; drain holes are placed in blind pockets to allow melt escape. Thermal expansion of ABS between room temperature and burnout is in the range 80–110 × 10-6 K-1, roughly two to three times that of typical investment wax. A rapid ramp from ambient to 600 °C produces shell cracking before the polymer can volatilize. Industrial practice inserts an intermediate plateau at 250–300 °C for 30–60 min to allow the pattern to soften and drain before shell temperatures exceed 400 °C. Burnout then proceeds in an oxygen-containing furnace to 650–700 °C; residual carbon is removed at the upper plateau. Ash content is tested per lot because filler or pigment variations in ABS feedstock alter shell residue. Published data for this specific 3D Systems FDM ABS configuration in investment casting is limited; foundries run trial pours with wall-thickness gradients to map shell cracking before production orders. Environmental controls are required at burnout: styrene and acrylonitrile decomposition products are captured by LEV and thermal oxidizer, and workplace exposure is assessed under EN 689 or local regulation. Parts produced through this route include low-volume stainless steel pump housings, aluminum linkage arms, and bronze valve bodies. Dimensional repeatability is lower than wax-injected patterns; linear contraction from printed pattern to final casting is typically 1.5–2.5% but varies with shell thickness and alloy.
Non-patient-contact ABS FDM housings, cable management brackets, and tray inserts are manufactured for diagnostic instrument development where the printed part must withstand repeated surface disinfection. The housings are printed at 0.127 mm layer height with 60–80% infill and annealed at 85–95 °C for 1–2 h in a forced-air oven before cleaning validation. Annealing reduces locked-in extrusion stress and lowers the probability of environmental stress cracking from 70% isopropanol wipes. Residual stress from a non-heated chamber manifests as white stress marks at boss roots after contact with alcohol. Vapor smoothing is avoided in cleanroom-adjacent builds because acetone residue can volatilize into optical benches. Published data for this specific 3D Systems FDM ABS configuration under repeated disinfection cycles is limited; the cleaning protocol is therefore validated on printed coupons before transfer to production. The material is not autoclaved; steam at 121 °C exceeds the heat deflection temperature and causes severe warpage. Immersion in isopropanol is avoided because surface softening and dimensional swelling of approximately 0.3–0.5% after 24 h can affect snap-fit retention. Products include pump housings, tray cassettes for reagent bottle handling, and cart bumpers. Biocompatibility testing under ISO 10993 is not required for no patient contact, but surface cleanability is documented under ISO 15883 or an internal SOP. REACH SVHC disclosure is maintained for EU installation. The operational boundary is 60 °C continuous and 70% isopropanol as a wipe, not immersion.
ABS FDM production brackets and sensor mounts are reinforced with ultrasonic or heat-staked metal inserts where threaded fasteners must be removed repeatedly. Hole sizing is derived from insert supplier data for amorphous thermoplastics; for injection molded ABS the hole diameter is specified 0.3–0.5 mm below the insert outer diameter. In FDM parts, layer porosity at 60% or 100% infill changes local crush strength, so the lower end of the interference range is used first. Ultrasonic insertion is performed at 20 kHz and 0.3–0.8 s weld time; horn pressure and amplitude are set from the insert supplier’s ABS curve. Published data for this specific 3D Systems FDM ABS configuration under threaded insert installation is limited; the following starting parameters are drawn from insert manufacturer data for unfilled ABS injection-molding grades and must be revalidated on printed coupons. In field measurements on printed brackets, brass insert pull-out strength is commonly 30–50% lower than in injection molded ABS of equal wall thickness because tunnel voids adjacent to the shrink-compensated hole reduce stress transfer. Heat-staking is used where ultrasonic vibration would crack thin-section bosses; the tip temperature is set at 180–220 °C. Tightening torque for M3 brass inserts in 6 mm wall sections is derated to 0.2–0.3 N·m; M4 inserts are derated to 0.4–0.6 N·m. Products include LIDAR sensor brackets with M4 inserts, cable clamp plates, and replacement machine guards. The operational limitation is threaded fastener re-tightening without inserts; direct tapped ABS FDM threads lose preload after fewer than 5 insertion cycles under 0.3 N·m because material creep strips the flank surfaces.
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The 3D Systems Fused Deposition Modeling Material ABS is an unfilled acrylonitrile-butadiene-styrene copolymer filament supplied for material-extrusion additive manufacturing systems. The product is packaged as a vacuum-sealed spool with desiccant. Published literature for this specific 3D Systems cartridge does not currently list a single universal model number; the material is assigned platform-specific part numbers that appear on the batch label and certificate of conformity. The filament is offered in nominal diameters of 1.75 mm or 2.85 mm depending on the printer series. The batch certificate records average diameter, typically controlled to ±0.05 mm, and ovality to no more than 0.03 mm, measured on a two-axis laser micrometer after final spooling. Storage is recommended at 15–25 °C and <30 % RH. Unsealed ABS filament can reach an equilibrium moisture content of 0.2–0.4 wt% at 23 °C and 50 % RH. Before processing, material exposed to ambient air for more than 24 h is dried in a forced-air dryer at 80 °C for at least 4 h. Moisture above 0.05 wt% during extrusion produces surface blisters, irregular filament feed, and audible popping at the nozzle. The material is not shipped in a sterilized or food-contact-validated package unless explicitly stated by lot documentation.
The base chemistry is a styrene-acrylonitrile matrix with dispersed polybutadiene rubber particles. The glass-transition temperature of the styrene-acrylonitrile phase is 95–105 °C by dynamic mechanical analysis at 1 Hz; the rubber phase glass transition is below −60 °C. This two-phase structure provides higher impact resistance than polystyrene but lower continuous-use temperature than polycarbonate. Unlike ABS-like photopolymer resins, this product is a melt-processed thermoplastic and does not require UV post-curing. No stoichiometric formula applies because ABS is a copolymer with variable comonomer ratio; typical extrusion grades contain 15–30 wt% polybutadiene phase. Moisture content in incoming material is measured by Karl Fischer titration per ISO 15512 when lot-level verification is required.
Extrusion temperature is normally set between 230 °C and 250 °C. At 230 °C, melt viscosity is high enough to produce visible road edges; at 250 °C, thermal yellowing of the butadiene phase can begin during dwell times above 30 min. The build plate is held at 90–110 °C for the first layer and 80–110 °C for subsequent layers. A heated chamber or enclosure maintained at 45–60 °C is required for parts with an XY dimension greater than approximately 80 mm. Without a chamber, convective cooling at ambient 20 °C produces stress gradients that delaminate corners. Layer height with a 0.4 mm nozzle is typically 0.15–0.25 mm. Linear print speed is 40–60 mm/s. The interlayer tensile strength, measured on printed tensile bars per ASTM D638-14, is generally 55–65 % of the XY value when the chamber is held at 50 °C. At chamber temperatures below 35 °C, interlayer strength falls below 50 % of the XY value because the previous layer cannot be re-melted deeply enough for polymer chain diffusion. Retraction distance for direct-drive systems is 0.8–1.5 mm at 25–40 mm/s; Bowden systems require higher retraction, but values above 2.0 mm can draw molten material into the cold zone and produce feed failures. Print-cooling fans are disabled or limited to 0–20 % duty cycle. First-layer adhesion is achieved on polyimide tape, PET film, or an acrylonitrile-styrene-based slurry. On an extrusion line with a single-screw extruder at L/D ratio 24:1 and barrel zones set to 210/220/230/240 °C, moisture above 0.08 wt% caused filament diameter deviations visible at the laser gauge and increased melt-fracture during spooling. Batch-to-batch shifts in butadiene content can move the melt flow index by approximately ±2 g/10 min without altering printer diameter.
For unfilled ABS, solid infill above 80 % produces high cumulative shrinkage and can pull large parts off the bed. Hexagonal infill at 40–60 % reduces residual stress while retaining tooling stiffness. Use 3–4 perimeter shells; more than 5 perimeters can build high skin stress and increase corner curl. Alternate infill angle at 45°/−45° relative to the build axis rather than 0°/90° to avoid aligned contraction. Support structures are printed from the same ABS unless a soluble support filament is available on the machine. ABS supports require mechanical removal and leave witness marks. For breakaway supports, separation distance of 0.2–0.35 mm is typical. The material is not compatible with polyvinyl alcohol support filaments because PVA degrades above 60 °C and the required bed temperatures differ.
Because published data for the specific 3D Systems FDM ABS formulation is limited, the following ranges are representative of unfilled ABS extrusion grades and should be checked against the lot certificate. Values are derived from dried, injection-moulded or printed coupons using the stated methods.
| Property | Reference range | Test method |
|---|---|---|
| Density | 1.03–1.07 g/cm³ | ASTM D792 |
| Tensile strength at yield | 33–46 MPa | ASTM D638-14 |
| Tensile modulus | 1.9–2.5 GPa | ASTM D638-14 |
| Elongation at break | 3–10 % | ASTM D638-14 |
| Flexural modulus | 2.0–2.7 GPa | ASTM D790-17 |
| Notched Izod impact | 150–300 J/m | ASTM D256-10 |
| Heat deflection temperature at 0.455 MPa | 90–100 °C | ASTM D648 |
| Vicat softening temperature | 95–105 °C | ISO 306/A50 |
| Melt flow index | 5–15 g/10 min at 220 °C/10 kg | ASTM D1238 |
| Print shrinkage | 0.4–0.9 % | Two-axis caliper measurement |
| Coefficient of linear thermal expansion | 80–110 ×10⁻⁶/°C | ASTM E831 |
| Flammability at 3.0 mm thickness | UL 94 HB | UL 94 |
Melt flow index measured at 220 °C and 10 kg is typically 5–15 g/10 min for extrusion-grade ABS; values above 15 g/10 min improve flow but reduce melt strength and increase stringing. Capillary rheometry at 230 °C and 100 s⁻¹ shows apparent viscosity in the region of 400–900 Pa·s for general-purpose grades. These values are not a substitute for product-specific batch data.
Shrinkage and residual stress in printed geometries are governed by the difference between deposition temperature and the glass-transition temperature. As deposition roads cool, a constrained skin forms and tensile stress accumulates. Warpage is most severe in large solid sections. On open-frame FDM machines without heated enclosures, corner lift of a 100 mm × 100 mm × 10 mm coupon has been measured at 0.3–0.7 mm using a feeler gauge at the bed surface. With the chamber held at 55 °C, lift remained below 0.1 mm. A brim of 8–15 mm and corner tabs reduce, but do not eliminate, the stress state. Dimensional shrinkage is anisotropic; longitudinal shrinkage is lower than transverse shrinkage because adjacent roads constrain contraction. The shrinkage range is typically 0.4–0.9 % under uncontrolled cooling. Annealing at 90 °C for 2 h reduces internal stress but produces additional dimensional change of 0.3–0.6 % along the longest axis. Printed ABS is not recommended for continuous structural loads above 50 °C without annealing; unannealed parts can relax and lose clamp load.
Acetone vapour is a solvent-based finishing agent for ABS. The process typically exposes the part to acetone at 40–50 °C for 10–30 min in a closed vapour chamber. The resulting surface roughness can be reduced to approximately 1–3 μm Ra, measured with a contact profilometer per ISO 4287, but the process consumes dimensional material. Thin walls of 1.0 mm may lose 0.05–0.15 mm thickness, and sharp corners become rounded. If vapour smoothing is specified, clearance holes and snap features are printed with a positive allowance of 0.1–0.3 mm. The treatment is not recommended for thin-walled pressure-containing parts or internal cavities because retained solvent can produce delayed stress cracking. After smoothing, residual acetone must be removed by evaporation at 23 °C for 24–48 h before mechanical loading. Published data for the exact surface finish achieved with the 3D Systems product is limited; the values above are representative of printed general-purpose ABS.
Chlorinated and aromatic solvents attack ABS more aggressively than ketones. A 24 h immersion in acetone at 23 °C dissolves the surface; ethyl acetate can produce crazing within 1 h. Printed parts should not be exposed to gasoline, brake fluid, or solvent-based paints without a barrier coating. Dilute aqueous acids and bases are tolerated at room temperature.
Relative to polylactic acid, the ABS product has higher heat deflection temperature under 0.455 MPa load: 90–100 °C versus 50–55 °C for PLA per ASTM D648. PLA prints with lower warpage and can be run on open-frame systems at lower bed temperatures of 40–60 °C, but it lacks the impact resistance and acetone smoothability of ABS. Against polyethylene terephthalate glycol, ABS has lower as-printed surface gloss and higher resistance to acetone, but PETG typically shows elongation at break of 15–25 % compared with 3–10 % for ABS per ASTM D638. PETG also exhibits lower warpage and may be printed without a heated chamber. Compared with ASA, ABS has equivalent heat resistance but inferior ultraviolet stability. The polybutadiene phase in ABS is susceptible to photo-oxidation and embrittlement, whereas ASA uses an acrylate rubber phase and is specified for outdoor applications. PC-ABS blends raise the heat deflection temperature to approximately 105–125 °C and notched Izod impact to 400–600 J/m, but they require extrusion temperatures of 260–280 °C and chamber temperatures of 70–80 °C, which are not available on all platforms.
| Property | ABS | PLA | PETG | ASA | PC-ABS |
|---|---|---|---|---|---|
| Heat deflection temperature at 0.455 MPa | 90–100 °C | 50–55 °C | 70–75 °C | 90–100 °C | 105–125 °C |
| Tensile strength | 33–46 MPa | 40–60 MPa | 45–55 MPa | 35–45 MPa | 40–55 MPa |
| Elongation at break | 3–10 % | 5–15 % | 15–25 % | 5–15 % | 5–15 % |
| Notched Izod impact | 150–300 J/m | 20–40 J/m | 70–100 J/m | 150–300 J/m | 400–600 J/m |
| Acetone vapour smoothing | Compatible | Not applicable | Not applicable | Limited | Partial |
| Warp tendency on open-frame systems | High | Low | Low | High | Moderate–high |
Because printed ABS retains layer porosity, chemical resistance is governed not only by bulk polymer resistance but also by accessible internal surface area. The material is attacked by ketones, esters, aromatic hydrocarbons, and chlorinated solvents. It is not suitable for continuous contact with gasoline, brake fluid, or strong oxidizing acids. Under 24 h immersion at 23 °C, acetone causes surface dissolution and ethyl acetate produces crazing within 1 h. The unmodified grade is typically rated UL 94 HB at 3.0 mm thickness. FDA 21 CFR 177.1020 provides a food-contact listing for ABS as a polymer, but a printed part with layer porosity and process residues is not automatically compliant. The material is not recommended for outdoor service unless painted or coated, because unmodified ABS undergoes UV embrittlement after 6–12 months of natural weathering. The practical continuous-use temperature for unstressed parts is −20 °C to 80 °C in air. Below −20 °C, impact strength drops sharply. Processing at recommended temperatures emits low levels of volatile organics, including styrene and ethylbenzene; the printing area should be ventilated to maintain airborne concentrations below national occupational exposure limits. REACH and RoHS declarations for the specific lot should be requested from the supplier when regulatory documentation is required.