| HS Code | 661050 |
| Material Type | Thermoplastic polyurethane (TPU) elastomer |
| Color | White |
| Density | 1.10 g/cm³ |
| Shore A Hardness | 80-90 |
| Tensile Strength | 4.8-6.0 MPa |
| Tensile Modulus | 10-20 MPa |
| Elongation At Break | 250-300% |
| Flexural Modulus | 25-40 MPa |
| Tear Strength | 20-30 kN/m |
| Rebound Resilience | 40-50% |
| Compression Set | 20-25% |
| Operating Temperature Range | -30°C to 80°C |
| Layer Thickness | 0.10 mm |
| Particle Size | 50 µm |
| Biocompatibility | ISO 10993-1 |
As an accredited 3D Systems DuraForm TPU Elastomer Thermoplastic Elastomer for SLS Systems factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | 3D Systems DuraForm TPU Elastomer is supplied in a sealed, durable, moisture-resistant 10 kg container for SLS systems. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): palletized DuraForm TPU Elastomer Thermoplastic Elastomer powder for SLS systems, shrink-wrapped, secured in dry container. |
| Shipping | DuraForm TPU Elastomer for SLS is not classified as dangerous goods for transport under DOT, IATA, IMDG, or ADR. No UN number, hazard class, or packing group is assigned. Ship in original sealed containers, keep dry, avoid dust generation and ignition sources. Follow SDS, use appropriate PPE, and prevent static discharge. |
| Storage | Store in a cool, dry, well-ventilated area in original, tightly sealed containers. Protect from moisture, heat, direct sunlight, and ignition sources. Keep away from strong oxidizers. Minimize dust generation and static discharge; use grounding/bonding when handling powders. Do not store near food, drink, or incompatible materials. Follow the manufacturer’s SDS and local regulations. |
| Shelf Life | Shelf life is typically 12 months when stored unopened in a cool, dry place away from moisture and direct sunlight. |
DuraForm TPU Elastomer is a selectively laser sintered thermoplastic polyurethane powder whose processability is governed by the melt window between the onset of polymer flow and the point of thermo-oxidative breakdown. Published independent data for this specific formulation are limited beyond the supplier’s technical data sheet; the application-specific processing windows described below represent industry practice for TPU SLS powder classes and must be validated on the target SLS system. The material cannot be equated with injection-moulded TPU grades or filament-extruded TPU because the powder retains a solid-bed thermal history that changes the crystallisation behaviour of the soft segment after the first fusion cycle. Before any transferred application is qualified, lot-specific variables are measured: residual moisture after hopper storage, particle size distribution after recovery sieving, and melt flow index retention under ISO 1133-1:2022 at the supplier’s designated temperature and load. The powder is hygroscopic; open exposure at relative humidity above 60% ordinarily requires preconditioning in a dry-air or desiccant vessel, and failure to do so produces entrapped steam porosity and anisotropic elongation at break. The standard grade is supplied without a food-contact or potable-water migration certification, and contact with amine-based chemical agents should be avoided because the polyurethane hard domains undergo progressive solvolysis at the interface. The downstream segments are therefore separated by their regulatory termination points, mechanical thermal history, and surface-finish requirements rather than by generic descriptions of elastomer flexibility.
Within low-volume athletic and orthopaedic footwear, DuraForm TPU Elastomer is used to build lattice-structured midsoles, heel wedges, and pressure-relief inserts in which stiffness is controlled by cell topology rather than by plasticiser addition. The fresh-to-recovered powder blend for footbed parts is normally constrained to a higher virgin fraction than that used for visual models because reclaimed powder containing incipient melt agglomerates creates surface pinholes that reduce crack-initiation resistance. A practical control point used in production service is to limit recovered powder to 20–30% by mass after the fraction has passed a particle-size screen of 125 µm and after bulk density has been confirmed within the supplier’s specified tolerance; parts intended for prolonged plantar skin contact are frequently built from 100% virgin powder to simplify chemical traceability. The laser energy density is adjusted for a layer thickness of 0.1 mm, and wall sections below 1.2 mm are processed with reduced contour energy to prevent over-sintering of adjacent lattice nodes. After fusion, the parts are de-powdered with low-pressure air jets and glass-bead finishing; the soft surface cannot withstand aggressive tumbling with ceramic media because edge loss and cell fracture occur. Conditioning at 21–23 °C and 50% RH for 24 h prior to durometer measurement under ASTM D2240-15 or ISO 48-4 is needed to avoid transient hardness shifts. Tensile verification on printed coupons is performed under ASTM D638-14 using Type IV specimens cut in the XY plane; Z-direction tensile values are typically lower and must be reported for multiaxial stress regions. Regulatory documentation for consumer footwear normally includes REACH Annex XVII phthalate restrictions, CPSIA Section 108 phthalate screening, and, for medical orthoses that contact intact skin for more than 30 days, a biocompatibility file under ISO 10993-1:2018 supported by ISO 10993-5 and ISO 10993-10 data. Terminal products include custom running insoles with gyroid heel pads, diabetic offloading orthoses, and post-operative shoe stiffeners.
Flexible ducts, convolute bellows and air-management sleeves are converted from transfer-moulded EPDM to DuraForm TPU when the annual volume per geometry is below 5,000 units, because the elimination of steel tooling offsets the higher per-part powder cost. The SLS process for thin-wall ducting uses a layer thickness of 0.10 mm and a dual-mode scan strategy in which the contour beam is run at higher energy density to create a dense outer skin while the interior vector scan is de-rated to retain ductility. Part orientation is not arbitrary: convolute folds and unsupported overhangs exceeding 45° from the vertical generate stair-step stress concentrations that become micro-crack initiation sites during dynamic flexural fatigue at 2–3 Hz. The powder blend for production automotive ducting is more restrictive than prototype work; if the recovered fraction exceeds 15% by mass, the lot is typically segregated for non-safety validation parts unless lot-specific melt-flow retention and zero-agglomerate checks are passed. Nitrogen inerting is required during cooling to control oxidative degradation in the powder bed, and compressed-air blow-out through the duct bore is insufficient for fully enclosed bellows; a controlled vacuum and air-pulse sequence is specified to remove partially sintered powder from convolute roots. Minimum wall thickness for production bellows is held at 0.8 mm; lower values produce process-dependent tear strength and can collapse under negative-pressure cycles. Tensile and ageing reference values are obtained under ISO 37 and ISO 188 using die-cut specimens from flat build tabs. Flammability of cabin-adjacent ducts is evaluated under FMVSS 302 or ISO 3795, and interior emissions are screened against the OEM volatile organic compound limit for polyurethane materials. Terminal components include rear cabin air ducts, battery-pack pressure-equalisation bellows, and wire-routing sleeves; each geometry requires leak-decay testing and a minimum 10,000-cycle flexural endurance demonstration before production sign-off.
| Application domain | Primary compliance anchor | Test method designation |
|---|---|---|
| Footwear and skin-contact orthotic devices | REACH Annex XVII, CPSIA Section 108, ISO 10993-1:2018 | ASTM D2240-15, ISO 48-4, ISO 10993-5 |
| Automotive flexible ducts and bellows | FMVSS 302, ISO 3795, OEM VOC protocol | ISO 37, ISO 188, leak-decay protocol |
| Industrial low-pressure seals and gaskets | REACH Annex XVII, RoHS 2011/65/EU | ISO 48-4, ISO 815-1, pressure-decay test |
| Protective sports equipment | EU 2016/425, REACH Annex XVII | EN 1621-1:2012, EN 1621-3:2018 |
Because patient-specific orthotic shells require zero tooling and variable wall thickness, DuraForm TPU powder is routinely evaluated as a custom ankle-foot orthosis shell, spinal brace liner, or prosthetic socket interface where the prescribed skin-contact duration exceeds 30 days but does not involve mucosal contact or open-wound exposure. The design-to-part route replaces manual draping of thermoplastic sheet over a plaster cast: the practitioner’s three-dimensional scan is converted into a lattice-reinforced shell in which strut diameter and cell density are modified locally to control flexural stiffness without altering material hardness. The fresh-powder fraction for medical orthoses is normally 100% virgin material, and the build is discharged from a cleaned, validation-controlled SLS system because recovered powder cannot be used in a patient-contact device without candidate-specific cytotoxicity and sensitisation data under ISO 10993-5 and ISO 10993-10. Layer thickness is held at 0.1 mm, but the more demanding requirement is powder removal from blind lattice pockets; cell openings below 2.0 mm trap partially sintered powder that cannot be fully evacuated by air-jet cleaning, leading to mass variation and potential skin irritation from loose particulates. Post-build conditioning at 60 °C for 24 h may be used to drive off residual processing odour, but higher thermal ageing must be validated because the TPU soft segment can undergo irreversible hardening if polyurethane hard-domain ordering is shifted. Mechanical acceptance for orthotic shells is drawn from a protocol derived from ISO 10328 for lower-limb prosthetic loading, but the exact fatigue threshold is set by the treating clinician and the patient’s body mass. The manufacturing operation is maintained in alignment with 21 CFR Part 820 when the device is sold into the United States. The completed device file includes lot traceability from powder to part, a visual inspection for surface cracks around ventilation holes, and durometer verification under ISO 48-4. Terminal devices include bilateral ankle-foot orthosis shells with local flex zones, post-operative arm-sling frames, and prosthetic check-socket liners used before carbon-fibre definitive sockets are manufactured.
Industrial low-pressure pneumatic seals, flange gaskets and protective sleeves manufactured from DuraForm TPU are limited to dry gas, water-glycol coolant, and light mineral-oil exposure; continuous service above the supplier’s stated softening point or prolonged immersion in strong polar solvents produces dimensional stress relaxation at the sealing lip. Unlike a compression-moulded seal, the SLS part carries anisotropic mechanical response: tensile elongation is usually higher in the XY build plane than in the Z direction, so face-sealing and radial-sealing lips are oriented with their compression axis in the XY plane to maintain contact-line geometry under assembly load. The blend ratio for seal applications is governed by the recovered powder’s fines distribution and bulk density; reclaimed particles below 20 µm degrade recoating uniformity and create local void lines at the sealing surface. A production seal run typically restricts reclaimed powder to 10–20% by mass unless the recovery stream has been sieved and conditioned under nitrogen. After fusion, seal lips are not trimmed with rotary blades because the low tear-initiation strength of TPU produces micro-tearing at the cut edge; water-assisted de-powdering and cold trimming are preferred. Because the TPU achieves mechanical strength from reversible hard-domain ordering rather than vulcanisation kinetics, compression-set testing under ISO 815-1 is used to detect sealing-lip relaxation. Conditioning at 23 °C and 50% RH for 48 h before leak testing stabilises Shore hardness readings under ISO 48-4 and compression-set behaviour under ISO 815-1. A frequently applied pressure-decay screen for compressed-air seals is 0.5 bar/min on a 25 mm bore at 6 bar line pressure, but the acceptance value is set by the end-use assembly and the safety factor required by the machine builder. Industrial sealing products are documented against REACH Annex XVII and the RoHS Directive 2011/65/EU; food-contact seals or potable-water gaskets require additional migration testing beyond the standard grade. Terminal parts include pneumatic cylinder lip seals with lattice-compliant backbones, inspection-machine gaskets, and dry-air line sleeves for automated assembly cells.
Fused, impact-attenuating protective elements such as lacrosse shoulder caps, mountain-bike elbow pads, and chest-protector core inserts are produced by SLS when the part count per size and season remains below 1,000 per geometry and when the design calls for a variable-density cellular core that is not demouldable by conventional injection-mould tooling. The energy-dissipating behaviour of the structure is controlled by cell type, strut cross-section, and local relative density, not by foam-blowing agents; this eliminates the storage and mixing hazards associated with chemical foaming at the press and avoids the cell-collapse variability of gas-assisted injection moulding. The principal production bottleneck is de-powdering: lattice cells with openings below 2.0 mm retain unsintered powder, increasing part mass and shifting impact response because the residual powder dampens cell-wall flexure. Batch-to-batch control therefore requires mass comparison against the CAD target; if measured part mass exceeds the nominal design value by more than 5%, the recovered-powder fraction is reduced or the de-powdering air-pulse sequence is extended until the residual mass falls within tolerance. Tear initiation is screened under ASTM D624 on the fused TPU sheet because tear propagation at lattice junctions is the dominant failure mode in thin protective cores. Impact-protective categories are validated against EN 1621-1:2012 for limb protectors and EN 1621-3:2018 for chest protectors when the parts are placed on the market as personal protective equipment under EU 2016/425. Chemical compliance for sports equipment requires REACH Annex XVII screening for restricted phthalates and candidate-list substances; no substance declaration is complete without the powder lot’s safety data sheet and traceability to the final manufactured component. Terminal products include lacrosse rib protectors with tuned-density foam-free cores, MTB knee-pad shells, and motor-style chest-guard liners assembled inside a hard outer shell.
Thermally isolated wearable electronics enclosures and augmented-reality headset interfaces are evaluated with DuraForm TPU because the sintered surface provides a low-slip, soft contact face without a secondary overmoulding step. Electronic housing applications impose a different constraint set from orthoses or seals: the part must survive repeated manual flexure during device assembly and disassembly, must not shed particulate into optics, and must remain dimensionally stable at the heat rise generated by the electronics package. The powder blend for consumer electronic protective cases and headset interfaces often permits up to 30% recovered powder after dry-air storage and sieving, but the supplier’s melt-flow retention data controls acceptance for thin snap-fit walls. A wall thickness of 1.0 mm is considered a practical lower limit for demountable snap features; below this value, tear propagation at the snap root during repeated disassembly becomes lot-dependent and introduces unacceptable field-failure risk. The SLS process for such parts is run at 0.1 mm layer thickness with double contour passes on the engraved or snap-fit edges to reduce surface-linked crack initiation; interior hatches are de-rated to preserve bulk elongation. After fusion, optical-contact interface surfaces are cleaned with filtered ionised air to remove particulate contamination, and parts are bagged in dry packaging to prevent moisture uptake before insertion into the device. Compliance documents for electronic wearables include the RoHS Directive 2011/65/EU and REACH SVHC screening; if the TPU housing forms part of operator-handled electrical equipment, the finished assembly is assessed under IEC 62368-1, with the polymer’s flammability classification coming from the supplier’s UL 94 file or from end-product testing. Terminal components include head-strap conformal pads, controller grip sleeves, and protective hip-clip housings for body-worn data terminals.
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| Property | Test standard | Reported value |
|---|---|---|
| Hardness | ASTM D2240 | 65 Shore A |
| Tensile strength at break | ASTM D638-14 Type IV | 6.0 MPa |
| Elongation at break | ASTM D638-14 Type IV | 300% |
| Tear strength | ASTM D624-00 Die C | 30 kN/m |
| Density | ASTM D792 | 1.08 g/cm³ |
| Compression set | ASTM D395-03 Method B | 15% after 22 h/23 °C |