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HS Code |
879135 |
| Chemical Name | Sodium Phenoxide |
| Chemical Formula | C6H5ONa |
| Molar Mass | 116.09 g/mol |
| Appearance | White to off-white crystalline powder |
| Solubility In Water | Freely soluble |
| Boiling Point | Decomposes before boiling |
| Density | 1.5 g/cm³ (approximate) |
| Cas Number | 139-02-6 |
| Odor | Characteristic phenolic odor |
| Ph Of Aqueous Solution | Strongly basic |
| Hazard Classification | Corrosive |
| Stability | Stable under recommended storage conditions |
| Storage Condition | Keep container tightly closed, store in a cool, dry place |
| Ec Number | 205-348-0 |
As an accredited Sodium Phenoxide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Sodium Phenoxide is packaged in a 500 g HDPE bottle with a secure screw cap, labeled with hazard warnings and product details. |
| Shipping | Sodium phenoxide should be shipped in tightly sealed containers, protected from moisture and incompatible substances such as acids and oxidizers. Transport in compliance with local, national, and international regulations for hazardous materials. Ensure labeling indicates its corrosive nature. Store in a cool, dry, well-ventilated area during transit to prevent decomposition. |
| Storage | Sodium phenoxide should be stored in a tightly sealed container, away from moisture and acids, as it is hygroscopic and reacts with acids to form phenol. Store in a cool, dry, well-ventilated area, protected from light and incompatible substances like oxidizing agents. Use containers made of materials compatible with strong bases, such as glass or specific plastics. |
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Purity 99%: Sodium Phenoxide of 99% purity is used in pharmaceutical intermediate synthesis, where it ensures high product yield and minimal by-product formation. Melting Point 95°C: Sodium Phenoxide with a melting point of 95°C is utilized in dye manufacturing, where it provides consistent reactivity for uniform coloration. Particle Size <100 µm: Sodium Phenoxide with particle size less than 100 µm is applied in fine chemical processes, where it enables rapid dissolution and improved process efficiency. Moisture Content <0.5%: Sodium Phenoxide with moisture content below 0.5% is used in organic synthesis, where it prevents hydrolysis and ensures product stability. Stability Temperature 120°C: Sodium Phenoxide stable up to 120°C is employed in polymer production, where it maintains catalytic activity without decomposition. Assay ≥98%: Sodium Phenoxide with assay of at least 98% is used in agrochemical formulation, where it guarantees consistent end-product quality. Bulk Density 0.8 g/cm³: Sodium Phenoxide with a bulk density of 0.8 g/cm³ is used in compounding processes, where it allows accurate dosing and homogeneous mixing. Iron Content <20 ppm: Sodium Phenoxide with iron content below 20 ppm is used in high-purity electronics applications, where it minimizes contamination and defect rates. Free Alkali <1%: Sodium Phenoxide with free alkali below 1% is employed in fragrance synthesis, where it reduces side reactions and ensures batch reproducibility. Molecular Weight 116.09 g/mol: Sodium Phenoxide with molecular weight of 116.09 g/mol is used in laboratory research, where it provides reliable stoichiometric calculations. |
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Sodium phenoxide, also known as sodium phenate, belongs to the class of aromatic sodium compounds produced through direct reaction between phenol and caustic soda. In our facility, work on this material demands close control over raw input quality, temperature, and reactive byproducts. We manufacture sodium phenoxide in the form of finely milled white-to-off-white powder, achieving a consistent phenol sodium salt content of 99% or higher. Residual moisture stays well below 1%, thanks to efficient filtration and oven-drying stages. The material dissolves in water to form an alkaline solution, and retains high purity for downstream reactions.
In our plant, sodium phenoxide synthesis takes place in lined stainless-steel reactors, where molten phenol and high-purity sodium hydroxide are combined under tightly controlled pH and temperature conditions. Instead of letting the mix sit, we keep the blend moving with paddle stirrers, preventing caking and uneven reaction. Minor changes in feeding rates, mixing duration, or temperature can affect particle granularity and sodium residue levels. Years of hands-on production have taught us the value of continuous monitoring and early adjustment. Air filtration removes even fine dust, reducing product loss and keeping our workers safe.
We offer two primary models for customers: standard sodium phenoxide and a high-purity variant designed for demanding synthesis routes. Production batches are internally labeled by date codes and reactor source, not by arbitrary grade numbers. Battery manufacturers and dye makers often order the high-purity type, seeking trace metal levels below 10 ppm. In our experience, low sodium carbonate content makes a visible difference to downstream clarity in dye intermediates, especially when sulfonation or chlorination steps follow. The same cannot be said for grades sourced from plants still using open-vat batch techniques, where airborne contamination and caustic splashing leave behind hard-to-purify residues.
The customers who buy our sodium phenoxide come from diverse sectors: dye synthesis, pharmaceutical intermediates, pesticides, resin manufacturing, and photographic development. Over the years, we've seen sodium phenoxide form the backbone of azo dye formation, acting as a nucleophile and base in diazo coupling. Drug manufacturers use it in etherification reactions, enabling substitution at the para-position without introducing side products. The sodium salt also speeds up Williamson synthesis of phenyl ethers—resins and high-performance polymers made this way withstand more stress and chemical exposure than those built from less pure raw materials.
For pesticide synthesis, this compound is a go-to starter for making phenoxyacetic acid derivatives, which then transform into herbicides covering many staple row crops. In the film photography world, gallic acid and various developing agents rely on sodium phenoxide’s clean reactivity profile. The difference in yield and color clarity shows itself most dramatically in side-by-side tests: products made from our ultra-dry sodium phenoxide always provide deeper blues and less haze compared to those built on grades with higher moisture or caked lumps.
In aromatic chemistry, sodium phenoxide stands apart from potassium phenoxide and phenolates derived from weaker bases. Potassium analogues dissolve slightly more in water, but their higher price and variable supply chain make them less attractive for bulk users. Using sodium phenoxide rather than direct phenol plus caustic solution removes a production variable—site managers know what goes into the reactor, and less time is lost adjusting for titration errors.
Laboratory operators often ask whether bulk sodium hydroxide and phenol would suffice in place of a ready-made sodium phenoxide. Chemically, making sodium phenoxide in situ during each batch might sound cheaper, but the additional filtration, longer settling times, and unpredictable carbonation from ambient air introduce more room for inconsistency. During our years of process audits, industries switching away from pre-made sodium phenoxide almost always returned after noticing drops in output and purity.
Compared to sodium methoxide or sodium ethoxide, phenoxide brings aromatic stability and resonance not possible with aliphatic bases. In Williamson ether synthesis involving activated halides and heat-sensitive functional groups, only sodium phenoxide matches the selectivity needed for complex molecules. In some cases, potassium and lithium analogues change the solvent profile or attack weaker bonds, increasing unwanted by-products or making downstream purification more difficult.
Producing sodium phenoxide at scale brings a unique set of challenges. High-purity phenol (greater than 99.8%) is non-negotiable—trace sulfur, iron, or organic impurities in the feedstock show up in every subsequent reaction. Visual inspection during unloading, continuous monitoring of water and air systems, and tight protocols for cleaning blending tanks all contribute to batch reliability. Over the years, replacing aging seals and gaskets with PTFE alternatives lowered the incidence of black specks and stringy residue, problems that crop up quickly when caustic meets substandard hardware.
We adopted dedicated transfer lines and isolated storage tanks to avoid cross-contamination with chloride or carbonate byproducts. Each production run gets a unique identifier and certificate. A few early batches sailed through spot testing but revealed high sodium carbonate on full assay. We learned to track dissolved CO2 at every step—exposed surfaces even for a few hours pick up enough carbon dioxide to shift the specification. This real-world experience means that every delivery is backed by test records and strict documentation of operator actions.
Sodium phenoxide loves nothing better than to grab moisture and CO2 from the air, so we store drums in climate-controlled rooms and fill large polypropylene bags under nitrogen. During hot, humid months, we move more product in lined steel drums lined up for direct shipment, skipping warehouse stops. Freight handlers prefer bag sizes under 25 kg, cutting down on compression-related caking. For bulk orders, lined FIBCs protect against leaks and dust generation; one year, a leaking PVC liner led to a batch cross-contaminated with warehouse dust that failed to meet our specifications.
Most of our regular buyers run two-stage inbound inspection: a rapid color-moisture check on the dock, then a formal titration and sodium check in the lab. In the past, missed moisture pickups in drums sitting too long at ports led to visible clumping; after that, every drum is date-tracked and shipped within days of production end.
Chemistry is not all about what the textbooks say. A material may look identical on paper, but performance can vary from batch to batch, depending on upstream process discipline. While some importers use recycled phenol, producing a greyish, funky-smelling solid that dissolves slower and leaves behind colored sludge, our operation relies strictly on pharma- or electronic-grade feedstocks. Clean sodium hydroxide—flake, not recovered scrap—reduces iron, chloride, and potassium impurities to single-digit ppm levels.
We keep non-conforming product out of inventory and document all deviations in electronic logs. Customers count on this transparency; they can ask for the original test results from any lot. A decade ago, we suffered a recall due to poorly differentiated batch labeling; the lesson: tie every lot code back to a physical reactor, shift, and lab notebook. This level of traceability does not come from brokers, who often relabel and blend multiple sources.
Waste sodium salts and phenolic residues receive careful neutralization before leaving the plant. High-strength caustic and phenol vapors would quickly build up in an open system, so each reaction vessel has dedicated venting and fume extraction. Leaks and spills are rare but not unknown; we train everyone from the top down in the right way to clean, trap, and segregate anything that escapes. The sodium phenoxide process builds valuable skills in handling reactive sodium salts—not all shops spend the extra hours and dollars to ensure that their operators can spot trouble early.
As transport rules tighten and more customers focus on chemical stewardship, our investments in double-walled storage, better emission controls, and rapid incident reporting pay off season after season. We work closely with local regulators to make sure secondary containment and emissions stay within limits, even during high-volume months.
Pressure from both government and downstream customers has driven several rounds of upgrades at our site. Air scrubbers and water treatment units keep measurable emissions well below regional limits. We’ve swapped older mercury cell caustic with membrane-grade sodium hydroxide, reducing hazardous byproducts and lessening the regulatory burden on our warehouse teams. Recovered water and steam heat now pre-treat the raw phenol, improving process efficiency.
Our waste minimization efforts also focus on offspec or expired lot returns, which are processed in house rather than shipped off as waste. A few years back, product from a rain-damaged shipment was blended into a low-grade resin production stream—avoiding disposal and cutting raw material costs. Such closed-loop thinking means our process leaves a smaller footprint, while giving buyers assurance we take cradle-to-grave responsibility.
Customers in electronics and fine chemical spaces are beginning to demand sodium phenoxide with even lower trace metals, including arsenic, lead, and mercury. We are investing in inline monitoring to push detectable thresholds lower and strengthen internal controls. As stricter environmental rules phase in globally, clean effluent and closed-reactor handling protocols will grow in importance. Partnerships with logistics providers help us ship material safely, even over long distances under varying climate conditions.
Material innovation grows from responding to new application fields. Biodegradable plastics, novel UV absorbers, and advanced epoxy systems all rely on aromatic sodium salts for synthesis. Learning from feedback, we continue to focus on lowering impurity profiles and extending storage life. Trends toward just-in-time production and traceable logistics encourage us to refine safety, stewardship, and digital traceability.
Feedback from application chemists, supply chain managers, and maintenance technicians guides our product improvements. Rather than chasing every new trend, we focus on deep, detailed knowledge gained over years of production. Staff training helps every team member understand not just the what, but also the why of our process—leading to fewer breakdowns, less waste, and more confidence in the material’s fit for high-stakes applications.
Starting with careful selection of reactants and strict production controls, our sodium phenoxide gives users the reliability to focus on final product performance, not endless raw material troubleshooting. Open dialogue with downstream partners and constant review of batch data help us close the gap between lab-scale promise and full-scale delivery.
Manufacturing sodium phenoxide is about more than just meeting a specification: it means anticipating production challenges, collaborating closely with customers, and never settling for minimum compliance. The choice of input material and attention to each process detail play out in real-world results, whether in an efficient dye coupling, a faster developing chemical, or a clearer polymer intermediate.
Just as each batch number in our logbook tells a story—of seasonal temperature changes, operator vigilance, or an equipment upgrade—our ongoing refinement assures the reliability and reactivity that industry needs. Direct, proven experience guides improvements, future-proofs our process, and builds customer trust. We keep these lessons close as we keep pushing sodium phenoxide quality to new heights.