Naphthalene

    • Product Name: Naphthalene
    • Alias: NAFTALIN
    • Einecs: 202-049-5
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    941756

    Name Naphthalene
    Molecular Formula C10H8
    Molar Mass 128.17 g/mol
    Appearance White crystalline solid
    Melting Point 80.2 °C
    Boiling Point 218 °C
    Density 1.14 g/cm3 (at 20 °C)
    Solubility In Water 0.031 g/L (at 25 °C)
    Vapor Pressure 0.087 mmHg (at 25 °C)
    Odor Strong, mothball-like
    Cas Number 91-20-3
    Flammability Flammable
    Hazard Classification Harmful, suspected of causing cancer

    As an accredited Naphthalene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Naphthalene is packaged in a 25 kg tightly-sealed, white HDPE drum with hazard labeling, moisture protection, and clear product identification.
    Shipping Naphthalene should be shipped in tightly sealed containers, protected from heat, sparks, and open flames. It must be labeled as a hazardous material (flammable solid, UN 1334) and transported according to regulations (DOT, IATA, IMDG). Ensure proper ventilation, avoid contact with oxidizing agents, and include safety documentation and emergency procedures with the shipment.
    Storage Naphthalene should be stored in a cool, dry, well-ventilated area away from heat, sparks, open flames, and incompatible substances such as strong oxidizers. Keep it in tightly closed, properly labeled containers to prevent moisture absorption and vapor release. Store away from food and drink, and ensure that containers are protected from physical damage and direct sunlight. Use appropriate secondary containment if necessary.
    Application of Naphthalene

    Applications of Naphthalene in Industrial Manufacturing

    Naphthalene serves as a core petrochemical intermediate across several industries. Its unique aromatic structure enables the production of high-purity specialty chemicals and mass-market end products. As a direct manufacturer, we supply naphthalene with tight specification control for downstream processors requiring consistent feedstock quality, process reliability, and regulatory compliance.

    1. Phthalic Anhydride Production

    Major phthalic anhydride plants consume naphthalene as a principal aromatic hydrocarbon source through vapor-phase oxidation. Both catalysis efficiency and raw material composition directly impact conversion yield, impurity content, and loading onto vanadium pentoxide-titanium oxide catalyst beds. Our material supports continuous plants using process air or nitrogen, minimizing sulfur and ash content for extended catalyst life. Final phthalic anhydride is crucial for plasticizers, resins, and polyester manufacturing, which require strict quality control from upstream aromatic purity.

    Industry compliance standards

    • ISO 9001-certified production management for raw material traceability
    • REACH Annex XVII regulatory limits on impurities like polycyclic aromatic hydrocarbons (PAHs)
    • EU Commission Regulation (EU) 2018/2005 on the use of phthalates
    • Kosher/Halal declarations for pharmaceutical-grade output

    Typical usage ratio

    • Feed ratio of 0.55–0.6 kg naphthalene per kg phthalic anhydride, adjustable depending on air-to-hydrocarbon ratio and catalyst MBAs

    Downstream process integration

    • Introduced into the vapor-phase oxidation reactor intake system after filtration and melting
    • Direct metering to balance with air and recycle gas streams, with continuous monitoring of aromatic hydrocarbon input
    • Automatic feed adjustment based on catalyst activity and product colorimetric control

    Final product types

    • Phthalic anhydride flakes and molten formats
    • Plasticizers such as dioctyl phthalate (DOP) and diisononyl phthalate (DINP)
    • Polyester resins for coatings and fiberglass-reinforced plastics
    • Alkyd resin intermediates for paints and varnishes

    2. Sulfonated Naphthalene Formaldehyde (SNF) Concrete Admixtures

    The construction additive sector utilizes naphthalene as the main aromatic raw material in synthesis of SNF-based superplasticizers. Industrial polymerization with formaldehyde and subsequent sulfonation yields a dispersant critical for high-strength, low-water concrete formulations. Controlled conversion and degree of sulfonation are essential for consistent water reduction and slump retention in finished batches. Our low-residue grade allows predictable polymer properties for efficient admixture blending and dust-free powder handling.

    Industry compliance standards

    • EN 934-2: Admixtures for concrete, mortar and grout
    • ASTM C494/C494M – Standard Specification for Chemical Admixtures for Concrete (Type F & G)
    • ISO 14001 for environmentally-conscious production processes
    • GB 8076–2008 (China): Concrete admixture quality specifications

    Typical usage ratio

    • SNF production uses 0.2–0.25 kg naphthalene per kg superplasticizer, adjusted for molecular weight requirements and target sulfonation levels

    Downstream process integration

    • Naphthalene melted and charged to reaction kettle under controlled temperature prior to formaldehyde condensation
    • Sulfonation step follows pH and temperature-controlled addition of sulfuric acid
    • Finished SNF solution concentrated and spray-dried to powder or left as liquid admixture

    Final product types

    • Powdered SNF superplasticizers for bulk concrete plants
    • SNF aqueous solutions for ready-mix suppliers
    • PCE/SNF blend dispersants for cementitious dry-mix mortars
    • Flow enhancers for precast concrete, tunnels, and infrastructure projects

    3. Synthetic Dye Manufacturing

    The dye and pigment industry employs naphthalene as a vital aromatic nucleus for the preparation of azo and anthraquinone dyes. Reduced naphthol intermediates serve as coupling components to achieve bright shades and colorfastness in textile and leather coloration. Our material assures low trace metallics and consistent purity, supporting reproducible yields in multi-step dye synthesis, especially for disperse and vat dye families, where reaction kinetics demand high reactivity and controlled impurity levels.

    Industry compliance standards

    • OEKO-TEX Standard 100 for restricted substances in finished textile dyes
    • GHS classification with hazard communications labeling for transport and use
    • EU REACH Substances of Very High Concern (SVHC) compliance for PAH content
    • ZDHC (Zero Discharge of Hazardous Chemicals) Manufacturing Restricted Substances List (MRSL)

    Typical usage ratio

    • Consumption ranges from 0.9 to 1.2 kg naphthalene per kg finished dye intermediate, with specific ratio based on targeted molecular structure and auxiliary chemicals used

    Downstream process integration

    • Naphthalene transformed in reduction vessels to β-naphthol or α-naphthylamine for the diazotization step
    • Coupling with diazonium salts follows to build final dyestuff core
    • Purification steps and crystallization finalize dye quality before blending or formulation

    Final product types

    • Azo dyes for synthetic fiber and cotton coloration
    • Anionic disperse dyes for polyester yarn and filament
    • Vat dyes for denim and cellulose-based textiles
    • Naphthol AS-series pigment derivatives

    4. Insecticide and Moth Repellent Formulation

    Naphthalene acts as the primary active ingredient in manufacturing traditional solid and vapor-phase insect repellents. It is pelletized or pressed into branded consumer goods used for the protection of textiles and natural fibers from larvae infestation. Production batches require stable purity, controlled sublimation rate, and absolute absence of traced contaminants to meet strict safety and retail packaging regulations. End-users require consistent performance under varied storage and climate conditions.

    Industry compliance standards

    • US EPA CFR 40 Part 180—Tolerance exemptions for naphthalene as an active ingredient
    • European Union BPR Regulation (EU) No 528/2012 for biocidal products
    • Japan Household Goods Quality Labeling Act for labeling and ingredient declaration
    • National Institute for Occupational Safety and Health (NIOSH) exposure limits for factory operators

    Typical usage ratio

    • Formulated solid products contain 95–99% naphthalene by weight, diluted with minor inert carriers or anti-caking agents depending on final shape and market requirements

    Downstream process integration

    • Molten naphthalene is dosed into pelletizing or molding lines
    • Integrated flavor masking agents or color bosons are blended prior to cooling and solidification
    • Products pass vapor emission and size consistency checks before packaging

    Final product types

    • Moth repellent balls and cakes for household textile storage
    • Insecticidal pellets for warehouse and textile mill use
    • Coatings for packaging papers requiring mothproof properties
    • Agricultural repellents for stored seed, grain, or animal feed bags

    5. Synthetic Tanning Agents in Leather Industry

    The leather industry uses sulfonated derivatives of naphthalene as synthetic tanning agents, enhancing both the penetration of chrome tanning salts and the production of water-resistant leathers. These auxiliary tanning chemicals improve grain smoothness and color uniformity, demanded by automotive, shoe, and upholstery manufacturers. Stringent control over aromatic purity and sulfonation degree is necessary to ensure minimal residual odor and heavy metal carry-over in luxury end goods. We supply high-purity feedstock for sulfonation reactors used in continuous or batch tanning agent synthesis.

    Industry compliance standards

    • ISO 9001 Quality Management System for process traceability
    • ZDHC Leather Manufacturing Restricted Substances List (MRSL)
    • OEKO-TEX Leather Standard for harmful substance testing
    • European Directive 2002/61/EC on dangerous substances in leather processing

    Typical usage ratio

    • 0.18–0.22 kg naphthalene per kg synthetic tanning agent, tuned for molecular weight distribution and degree of sulfonation

    Downstream process integration

    • Charged as molten naphthalene to sulfonation reactor with acid metering and temperature control
    • Product isolated and neutralized for direct use in pickle or chrome tanning baths
    • Finished leather product subjected to repeated washing and neutralization cycles to remove residuals

    Final product types

    • Water-resistant finished leathers for automotive and marine upholstery
    • Shoe upper leathers with enhanced dye uptake
    • Handbag and garment leathers with smoother grain
    • Specialty technical leathers for performance applications

    Free Quote

    Competitive Naphthalene prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615365186327 or mail to admin@ascent-chem.com.

    We will respond to you as soon as possible.

    Tel: +8615365186327

    Email: admin@ascent-chem.com

    Get Free Quote of Ascent Petrochem Holdings Co., Limited

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Naphthalene: Product Introduction and Manufacturer’s Perspective

    Rooted in Chemical Tradition

    Working in chemical production every day, we become familiar with the real backbone materials that keep major industries running. Naphthalene, with its unmistakeable pungent odor and unique crystalline structure, stands among the oldest and most approachable aromatic hydrocarbons. Historically, chemists recognized its signature melting at about 80°C and a boiling point just below 220°C, using this knowledge for decades to segment and purify product in practical, scalable ways. Our work with naphthalene has provided consistent results over years, even as other substances have shifted in and out of the market with changing demands or regulations.

    We produce naphthalene in refined, high-purity forms and make the material available in industry-standard flake or lump models, catering to various end-user preferences. Managing purity, moisture, and mesh size has always been central to our efforts because it directly impacts how naphthalene behaves, especially in applications requiring high reactivity or clean-burning characteristics. Most of our supply centers around a purity of 99% or higher, since technical or industrial users depend on clean feedstock for downstream synthesis or formulations.

    Process Control and Specification Insights

    Securing consistent naphthalene quality requires a tight process chain rooted in either coal tar distillation or petroleum-derived feedstock. We monitor feed purity, fee handling, and all distillation stages since every variable leaves its mark—too much phenolic residue can ruin an entire batch for dye intermediates or pharmaceutical use. Experience shows the best naphthalene for agricultural wetting agents often needs exceptionally low oil content, otherwise it leaves traces in the end-use formulation.

    Our own product range covers the full sweep of technical, commercial, and high-purity grades. Granular or pelletized models end up in moth repellents or deodorant balls, while technical flakes go to dyestuff and surfactant factories. Regulatory bodies generally demand that impurity profiles, such as the degree of sulfur or phenol contamination, stay within strict thresholds, especially if users will be making dispersants or chemical intermediates. These are not arbitrary—the presence of less pure material unleashes trace contamination in colorants, surfactants, or resins, damaging product performance and sometimes even plant equipment. Our production control systems devote entire stages to contaminant stripping, and over years we have seen clear reductions in customer troubleshooting calls as product gets cleaner.

    Real-World Uses: A Manufacturer’s Experience

    While most people vaguely connect naphthalene with mothballs, its contribution reaches deep into construction, plastics, and chemical intermediate manufacture. Personally, we’ve shipped tankers of molten naphthalene to plasticizer makers who need it as a precursor for phthalic anhydride, a cornerstone of the plastic materials sector. Some partners expect granulated naphthalene to blend more effectively with base resins or dispersants, speeding their process and reducing site emissions. Here, material flow property is key, so we check friability, dust content, and melting-point homogeneity.

    The construction field has emerged as a particularly strong user. High-range water reducers (like naphthalene sulfonate formaldehyde condensate) rely heavily on our product. These additives give concrete mixes extended fluidity and strength while keeping water addition low—essential for modern, high-performance concrete. Producers of these additives often share that quality shifts in naphthalene show up in delayed set times or unwanted color changes in concrete. Our tighter batch tracking and adjustment of feedstock have cut these complaints by more than half for our largest customers in Asia and the Middle East.

    Within the dye and pigment field, manufacturers still source naphthalene due to its clean ring structure that serves as an easy precursor to naphthols and naphthylamines. Trace impurities in low-grade naphthalene cause shifts in dye shade or reactivity, so we see strong demand from this segment for higher specifications and for shipment in lined drums. At the solvent blending stage, users report that even tiny moisture differences can alter their downstream crystallization. Because of this feedback, our packing and drying lines were upgraded to reduce water traces to well below one-tenth of a percent for specified lots.

    In agriculture, formulation of wetting agents and plasticizers relies on naphthalene as an intermediate. It is not just about the chemical structure, but also the absence of ‘background’ contaminants that interfere with active ingredient performance. In-house testing has demonstrated that pure, dry naphthalene reduces problems with particle size drift and unexpected sediment in formulations—directly impacting yield and spray uniformity on the fields. The most successful agricultural product developers we supply insist on tightly packed, dust-minimized crystals for ease in their blending lines.

    Comparing With Other Aromatics and Alternatives

    There’s often confusion between naphthalene and alternative aromatics—benzene, anthracene, or camphor, for instance—especially for new users or those looking to switch raw materials. Naphthalene features a more complex, fused-ring structure than benzene, delivering higher efficacy in processes that rely on aromatic substitution or ring closure steps. For certain dye intermediates, users value naphthalene's double-benzene structure, which offers better progression toward target molecules during sulfonation, amidation, or oxidation.

    We also find distinctions in safety and environmental handling. While naphthalene is classified as a hazardous substance, it generally demonstrates lower acute volatility than pure benzene at ambient temperatures, which influences equipment selection for vapor management. Our plant safety teams constantly measure workplace air for naphthalene dust and vapor, calibrating control systems to local regulations and historical worker health data. In factory settings, worker exposure limits often drive the choice between naphthalene, anthracene, or phenanthrene. Our own results show naphthalene's physical characteristics, particularly its low water solubility and controlled vapor phase, enable safer manipulation in closed systems compared to more volatile or slippery aromatics.

    Refiners or preservative users sometimes investigate camphor or natural extracts. Most eventually grapple with cost, volatility, or inconsistent purity. Naphthalene’s source in steel industry byproducts and its huge established supply chain makes large scale, price-stable contracts possible, which we see as a constant advantage. In every case where substitution is considered, naphthalene typically retains a substantial edge due to predictability of performance in harsh chemical environments and the established safety procedures in the plants using the material.

    Handling Challenges and Customer Feedback

    Processing and shipping naphthalene involves its own set of hurdles, from temperature management to regulation changes. The solid form can sublimate at room temperatures, creating build-up and vapor in storage, so we invested in improved drum and bag lining. Users in warmer countries frequently demand metal-barrel packaging with vapor barriers. There are, on occasion, seasonal issues with caking or bridging, especially in damp climates. In response, our logistics teams introduced smaller, segmented drums for certain geographies, reducing the risk and waste at the customer’s site.

    Burning or accidental heating of naphthalene releases unmistakable fumes, and waste regulations prevent simple landfill disposal. We’ve dedicated significant time to helping partners set up controlled incineration and spent drum recycling programs, as naphthalene falls under several national hazardous waste codes. In many cases, on-site waste minimization audits with large buyers (including dye houses and agricultural blenders) have halved their disposal rates over two years. These changes usually link back to cleaner handling and smaller package size, with the added benefit of better compliance at inspection time.

    For decades, odors connected with naphthalene have worried end-users, particularly when used indoors. From our side, reducing residual oil and improving packaging seal considerably dropped ‘bleed through’ into warehouses and production floors. We pioneered new liners that cut leakage rates nearly by half, based on odor testing in customer plants. Many health authorities and certification schemes have started expecting evidence that such efforts are in place. Our quality and compliance records allow us to share data directly with downstream manufacturers during audits, demonstrating actual emission and exposure reductions.

    Regulatory Awareness and Health Concerns

    Working with naphthalene over the years means staying on top of changing safety and environmental rules. We had to adapt as REACH in Europe and TSCA in the United States updated categories for persistent and bioaccumulative chemicals. In practice, that meant new documentation, special worker training sessions, and targeted environmental controls for production and transport sites. These moves ensured our products stayed available in all main markets and reduced audit failures among our largest buyers.

    Worker exposure and end-product residue get more scrutiny every year. Many plant managers seek alternatives because of growing concern around respiratory and possible carcinogenic effects. We’ve responded by investing in improved air-extraction, mandatory rotating-crew assignments, and continuous on-site monitoring for several process areas. In our experience, these steps reduce risk and costs tied to compensation or lost shifts. Direct talks with health professionals showed that personal protective equipment, combined with high ventilation rates, all but eliminate acute symptoms in production workers—these practical controls matter more than simply changing the chemical.

    End-users increasingly ask to review regulatory filings and research on downstream residue, especially in coloring agents, agricultural compounds, and plasticizers. As a manufacturer, we developed detailed impurity and residual reports, routinely providing them with every truck or container of naphthalene. These efforts matched stricter legal requirements, and, more importantly, built trust with users facing audits or regulatory reviews. Over the last few years, some global buyers even made ‘sustainability score’ part of purchasing, demanding data on environmental impact and workplace health controls as part of the supply contract. Our regulatory and technical teams regularly update those reports and make them available for customer references.

    Innovation and Industry Transitions

    Naphthalene’s place in chemical manufacturing is anchored by its reliability and value, yet we constantly scan the horizon for alternatives and new process improvements. Bio-based aromatics and specialty hydrocarbons appear in industry presentations every quarter, but few have yet matched naphthalene’s cost, process familiarity, or large-scale supply. Green chemistry is pulling some interest, especially from multinational buyers prioritizing environmental targets. Even so, naphthalene remains their fallback while newer solutions develop.

    Several of our customers have asked about renewable alternatives and special low-emission grades. In response, we collaborated with process engineers to test upstream adsorbents and downstream purification, resulting in a cleaner naphthalene that meets tougher import standards. We’ve piloted carbon-reduction reports, showing buyers how our plant process improvements reduce overall emissions per ton shipped. Adoption of real-time monitoring and digital tracking gives actionable data for us and the customers, directly linking factory adjustments to finished product delivered. Feedback shows this transparency improves buyer confidence and helps our partners meet their own ESG targets.

    The most innovative projects have emerged from close collaboration with downstream firms. One example involved joint research into residue-free naphthalene for high-grade concrete water reducers. Together, we proved that precise temperature and drying controls reduced not only water content but also led to higher performance in complex construction pours, cutting set times and improving durability. Experiences like this underscore the critical role of hands-on, continuous process feedback. Building this direct link between our plant and customer production lines builds lasting advantage—not just for us, but also for the industries we serve.

    A Manufacturer’s Commitment to Quality

    From the start, our role with naphthalene revolves around process quality, openness with partners, and investment in better outcomes for every industry we serve. Generating high-purity batches is about more than hitting a spec on a document; it means tracking each segment from raw feedstock acceptance, through fractional distillation and finishing, all the way to shipped product on a scale sizeable enough to back order volumes. Our testing labs, overseen by experienced chemists, monitor critical values—moisture levels below one-tenth of a percent, specific melting and boiling points, and routine GC-MS scans for trace aromatic impurities. Such controls only developed from years of customer feedback and field troubleshooting, not from static datasheets or textbooks.

    Trust is earned through repeated performance when it comes to on-spec supply and ongoing responsiveness. Plant managers depend on shipments that do not delay their own lines or put their brands at risk with regulatory challenges. We build that stability into every batch, holding backlots and providing detailed test certificates for each container. Our logistics teams work with customers facing climate or storage challenges, offering flexible packaging or scheduled shipment solutions. The foundation for this partnership comes from shared problem-solving—when customers bring us new blending issues or storage hardships, we collaborate closely to pinpoint the cause and deliver better results, often updating our processes along the way.

    Observations From the Everyday Use of Naphthalene

    Real-world experience shapes every step of naphthalene production and use. Delivering shipments to varied clients—from the operator running a concrete mixing plant to the technician formulating next-generation dyes—demonstrates the unique, practical value of the material to modern industry. Operators prefer reliable flow of flakes or pellets, while plant chemists chase purity, fast melting, and minimal dust. For regulatory staff, tracking each batch with full documentation sets minds at ease. End users, especially in manufacturing, respond quickly to supply changes—positive or negative—so each minor process tweak at our plant reverberates across many downstream lines.

    Every problem our product solves has a direct effect on quality and productivity in other sectors. Good naphthalene turns up as slip-resistant additives in plastics, cost-effective moth protection, consistent pigment bases, and as components in chemical blenders for agriculture. The lessons from decades of production—including complications tied to raw material shifts or transport variations—have taught us to stay responsive and keep improving. Diagnostic skills sharpen when the market tightens or regulations change; being able to quickly adjust product flow, impurity level, or packaging makes all the difference.

    It’s easy for those outside the industry to underestimate the importance of raw material consistency, but for anyone making fine chemicals or concrete superplasticizers, drift in naphthalene parameters means time lost and resources wasted. Some of our earliest batch records remain in use today as benchmarks for troubleshooting and refining our procedures for greater control.

    Supporting Better Industry Practices and Future-Proofing

    As chemical producers, our responsibility reaches beyond batch quality. Coaching end users through new challenges—changing legislation, safety protocol updates, or market-driven specification changes—keeps us directly engaged with the broader industry ecosystem. Over the years, we have set up pilot trials at customer sites, adapted handling recommendations, and even shifted supply to meet urgent needs in cases of market disruption. Sometimes innovation emerges from these situations, including new packaging, optimized delivery scheduling, or upstream process enhancements that ultimately benefit a wide circle of industries.

    Naphthalene production at scale leaves a broad environmental footprint, and over time, energy efficiency, emission reduction, and waste minimization have replaced older practices. Investing in waste heat recovery units or vapor condensers yields both financial and regulatory benefits. Upgrades to drum cleaning and recycling at our own distribution yard created measurable reductions in hazardous waste. Active engagement with local communities and regulatory agencies reinforces our commitment and ensures smoother operational continuity. The broader lesson is to stay ahead of regulatory changes, not just react to them.

    Taking into account thousands of tons of annual production, our teams work with logistics, customer service, and technical support to spot problems early. Changes in weather patterns, shifts in regional market demand, or political volatility all impact real-world shipments. Direct customer conversations and close tracking of supply chain dynamics inform every operational decision, from scaling up special grades to shifting regional stocks. Being able to adjust rapidly and keep customers informed often means the difference between a lasting partnership and a lost account.

    Conclusion: Why It Matters From a Manufacturer’s View

    Looking at naphthalene from the perspective of long-standing producers, the material offers a rare blend of practicality, economic stability, and reliability for users across core industries. The challenges connected to health, odor, and environmental impact are real, and they require constant diligence, testing, and process adaptation. Drawing on our field experience, a plant focus sharpens the ability to keep product quality high, address the dynamic needs of buyers, and navigate the complex web of regulation and safe use. Quality, traceability, and responsive support form the backbone of our approach. By keeping our ears open to partners’ day-to-day realities and maintaining flexibility in our operations, we help maintain the steady flow of materials that keep a dizzying variety of essential products in motion—all starting from a few simple white crystals.

    Top