N-Hexyl Formate

    • Product Name: N-Hexyl Formate
    • Alias: formic acid n-hexyl ester
    • Einecs: 209-783-3
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    770507

    Cas Number 637-61-6
    Molecular Formula C7H14O2
    Molecular Weight 130.19 g/mol
    Appearance Colorless liquid
    Odor Fruity, apple-like
    Density 0.871 g/cm³ (at 20°C)
    Boiling Point 154-156°C
    Melting Point -66°C
    Flash Point 46°C (closed cup)
    Solubility In Water Poorly soluble
    Refractive Index 1.410 (at 20°C)
    Vapor Pressure 2 mmHg (at 25°C)

    As an accredited N-Hexyl Formate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing N-Hexyl Formate is packaged in a 200-liter HDPE drum, securely sealed, with clear hazard labels and product identification.
    Shipping N-Hexyl Formate should be shipped in tightly sealed, properly labeled containers, protected from moisture, heat, and direct sunlight. It is typically transported as a flammable liquid according to regulations (UN 1993). Ensure containers are upright and secure during transit, and handle with appropriate safety precautions to prevent spills or leaks.
    Storage N-Hexyl Formate should be stored in a cool, dry, well-ventilated area away from direct sunlight, heat, and sources of ignition. Keep the container tightly closed in a flammable liquids cabinet. Avoid contact with oxidizing agents, acids, and bases. Use only approved, clearly labeled containers to prevent leaks and contamination. Have proper spill containment and fire suppression equipment nearby.
    Application of N-Hexyl Formate

    Applications of N-Hexyl Formate in Industrial Manufacturing

    N-Hexyl Formate serves as an effective chemical intermediate and performance-enhancing agent in several specialized industrial sectors. Its unique ester properties enable efficient functionalization, aroma delivery, and solvent action in tightly regulated downstream markets. Below we outline specialized application scenarios based on real-world usage, production integration stages, industry standards, and resulting end products.

    1. Flavor and Fragrance Compounds Manufacturing

    N-Hexyl Formate plays a key role as a specialty ingredient in flavor and fragrance synthesis, valued for its distinctive fruity, apple-like aroma and volatile profile. Downstream manufacturers leverage it to fine-tune top notes and authentic nuances in both natural and artificial essence blends. Stringent purity and traceability requirements must be met, with the substance entering during the compounding stage to build target aroma profiles in compliance with food and personal care regulations.

    Industry compliance standards

    • IFRA Code of Practice for Fragrance Ingredients
    • EU Regulation (EC) No 1334/2008 on Flavourings
    • US FDA 21 CFR Part 172.515 (Flavouring Substances)
    • ISO 9235:2021 (Aromatic Natural Raw Materials/Isolates)

    Typical usage ratio

    • 0.01%–0.3% by weight in finished fragrance or flavor formula; level adjusted based on intensity target and any regional labeling restrictions.

    Downstream process integration

    • Added during the aroma compound blending phase, post-distillation quality check and prior to bottling or flavor base compounding.

    Final product types

    • Fine fragrances (eau de parfum, eau de toilette)
    • Flavored beverages (non-alcoholic, alcoholic cocktails)
    • Candy and confectionery flavorings
    • Baked goods flavor bases and industrial syrups

    2. Solvent for Industrial Coatings and Inks

    N-Hexyl Formate acts as a mid-boiling solvent in specialty surface coatings and high-performance printing inks, where its controlled volatility and minimal residue profile help optimize drying times and film formation. Downstream producers use it to enhance solvent balance, promote smooth application, and meet environmental and workplace safety regulations regarding VOC contents, integrating it into solvent blends during the mixing or thinning step immediately before dispersing pigments and binders.

    Industry compliance standards

    • EU VOC Directive 2004/42/EC (Decorative Paints and Varnishes)
    • ASTM D3960 (Determining Volatile Organic Compound Content of Paints and Coatings)
    • US EPA Method 24 (VOC Content in Coatings)
    • ISO 16000-6 (VOC in Indoor Air)

    Typical usage ratio

    • 2%–8% by weight in total solvent system, fine-tuned according to application viscosity, evaporation requirements, and pigment load.

    Downstream process integration

    • Introduced into solvent pre-mix tank prior to pigment dispersion or resin dissolution, blended under controlled agitation.

    Final product types

    • Industrial wood coatings (lacquers, enamels)
    • Flexographic and gravure printing inks
    • Plastic surface finishes and automotive interior paints
    • Metal packaging coatings

    3. Synthetic Lubricants and Functional Fluids Sector

    N-Hexyl Formate serves as a reactive intermediate and lubricity enhancer in the formulation of certain synthetic ester-based oils and hydraulic fluids. Formulators capitalize on its miscibility and chemical reactivity to achieve target viscosity and boundary lubrication properties required for advanced machinery. It is incorporated into esterification or transesterification reactors under precise conditions to ensure proper integration while observing lube oil and mechanical system safety standards.

    Industry compliance standards

    • ISO 15380 (Biodegradable Hydraulic Fluids)
    • DIN 51517-3 (Industrial Lubricants Standards)
    • REACH Regulation (EC) No 1907/2006 (Substance Registration)
    • ASTM D445 (Viscosity Testing of Oils)

    Typical usage ratio

    • 0.5%–4% of total ester base stock; dosage varies depending on required viscosity index and biodegradability profile.

    Downstream process integration

    • Charged as a feedstock during the initial esterification stage or as a co-reactant in targeted transesterification reactions within closed reaction vessels.

    Final product types

    • Fire-resistant hydraulic fluids
    • Biodegradable base oils for industrial gears
    • Compressor lubricants for precision machinery
    • Environmentally sensitive metalworking fluids

    4. Chemical Intermediate in Plasticizer Synthesis

    N-Hexyl Formate operates as a specialty building block for downstream plasticizer manufacturers, providing alkyl ester groups essential for flexibility and migration resistance in PVC and soft polymer compounds. Rigid traceability and batch testing align with international plastics safety and migration standards. This raw material usually enters at the esterification stage before downstream purification and finishing, ensuring critical properties in compliance with end-use safety expectations.

    Industry compliance standards

    • EU Regulation (EU) No 10/2011 on Plastic Materials and Articles Intended to Come into Contact with Food
    • US FDA 21 CFR 177.2600 (Rubber Articles Intended for Repeated Use)
    • REACH Annex XVII (Use Limitation of Certain Substances)
    • ISO 9001:2015 (Quality Management for Plastics Manufacturing)

    Typical usage ratio

    • 1%–5% of total raw material input; amount customized based on required flexibility, migration limits, and regulatory thresholds for end-use.

    Downstream process integration

    • Introduced into reactor vessel as part of alcohol feedstock during base-catalyzed esterification, followed by distillation and purification before compounding with polymer resins.

    Final product types

    • PVC-based children’s toys
    • Flexible tubing and gaskets for food processing equipment
    • Medical-grade PVC sheets
    • Environmental protective films and liners

    5. Fine Chemicals and Pharmaceutical Intermediates

    N-Hexyl Formate is incorporated as a reaction intermediate and protective group controller in the synthesis of active pharmaceutical ingredient (API) side chains and certain specialty fine chemicals. Production sites must document batch control, trace impurity profiles, and validate analytical specifications according to global pharmacopeial and GMP guides. This ester is charged during targeted alkylation or esterification stages under validated process conditions for downstream isolation and conversion.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for APIs)
    • European Pharmacopoeia (Ph. Eur.) quality standards
    • US Pharmacopeia (USP) monographs related to intermediates
    • ISO 17025 (Laboratory Competence for QC Testing)

    Typical usage ratio

    • 0.2–2 molar equivalents relative to target intermediate, adjusted by stoichiometry and yield optimization in specific reaction pathways.

    Downstream process integration

    • Charged in main reactor during selective alkylation or protection group insertion; reaction progress monitored via HPLC and GC, followed by purification prior to further transformations.

    Final product types

    • API side chain precursors
    • Specialty esters and ethers for fine chemical synthesis
    • Aroma actives for pharmaceutical flavor masking
    • Intermediate step reagents in custom pharma manufacturing

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    Certification & Compliance
    More Introduction

    N-Hexyl Formate – Precision from the Chemical Manufacturer’s Floor

    A Closer Look at N-Hexyl Formate

    Speaking directly from years of hands-on manufacturing, N-Hexyl Formate stands as one of those specialty esters that deliver distinct advantages in advanced chemical processes. Our production lines generate this compound with an emphasis on consistent quality, keeping up with strict analytical controls at every stage. Through esterification, we produce N-Hexyl Formate with a sharp focus on keeping moisture and aldehyde residues at a minimum. Our process ensures product purity that meets demanding standards, and most shipments reflect assay values above 98%.

    N-Hexyl Formate flows out as a clear, colorless liquid, bearing a fruity, slightly floral aroma. Boiling point emerges around 171°C, and a typical refractive index, measured using digital equipment that undergoes regular calibration, tracks closely to reported literature values. These features matter throughout its journey from the plant to its many destinations.

    Meeting Modern Industry Needs

    Leading perfumers and flavorists reach out for N-Hexyl Formate specifically when looking to weave unique, long-lasting top notes into formulations. Each drum and IBC container we deliver is locked for minimal contamination with inert gas, so product freshness remains at its peak for extended periods. On shop floors, regular tank sampling ensures no batch leaves without meeting all outlined physical and chemical parameters.

    We hear from many R&D teams in fragrance and flavor houses looking to achieve a soft, rounded green note, or a delicate fruit back. N-Hexyl Formate resists hydrolysis under neutral conditions, so compositions retain intensity across aging studies. Because of its manageable volatility, the compound behaves predictably when blended, giving formulation chemists practical room to tweak finished products without introducing instability.

    How Our Model Supports Stability and Innovation

    We have shaped our manufacturing protocols according to feedback from converters and formulators. With direct in-house control over raw material quality and reaction yields, we address issues like residual acid or alcohol content promptly. Our teams test every lot for common generator impurities using both GC-FID and HPLC, backed by certificates of analysis recognized across the industry. Product traceability forms an essential part of our lot management, something many downstream partners see as critical in risk-sensitive markets.

    Some customers in the solvents and fine chemical intermediates sector use N-Hexyl Formate as a building block thanks to its ready functional group, which participates in tailored esterification sequences. For those in specialty coatings, the compound brings low toxicity and predictable evaporation rates to custom blends. Our experience indicates a clear demand for consistent purity not only for flavor and fragrance, but also for downstream reactions.

    Distinct Product Value – Drawing from Daily Manufacturing Reality

    Our position as a direct producer—not a reseller or trader—lets us offer undiluted N-Hexyl Formate with reliable supply timelines. Through process optimization, we limit byproducts like hexanol and formic acid down to trace levels. All transfers and bottling go through antistatic, closed-loop systems. Workers on the plant floor have direct involvement in quality screening, setting us apart from enterprises that simply move packaged goods.

    During finished product audits, staff run batch samples through multi-point FT-IR scans. This uncovers even subtle batch-to-batch variances and provides fingerprints that are difficult to match through superficial repackaging or relabeling. It’s these checks and firsthand process engagement that anchor trust in the product. Our analytical team maintains shift logs and process deviations are reported in real time to production supervisors. This rapid feedback gives us agility to adapt when upstream materials shift, or customer requirements tighten.

    Direct Observations: Usage Trends and Field Examples

    Perfumery continues to drive strong demand, especially in Europe and parts of Asia, where stricter ingredient disclosures make batch quality indispensable. Several multinational flavor houses now specify minimum organoleptic standards for N-Hexyl Formate, which we meet using automated headspace sniffing as a routine part of quality release. End users in fine chemicals have recently moved to scale up processes involving aryl-hexyl intermediates, citing ease of purification and minimal side reactions with our supplied product.

    At our plant, operators have monitored changes in customer formulations that favor more natural-sourced raw materials. In our reactor systems, all lines are stainless to avoid trace metal contamination that could compromise performance in sensitive end uses. Project engineers have fielded requests to supply small pilot runs in addition to full-scale bulk, helping research labs push new concepts without over-committing resources.

    Contrasting with Other Esters – Where N-Hexyl Formate Finds Its Niche

    Compared to ethyl or butyl formate, the hexyl homolog shows greater tenacity in volatile mixes and lends well to specialty green fruit accords. While methyl formate finds its place mainly as a fast-evaporating solvent or refrigerant, N-Hexyl Formate’s larger molecular framework brings noticeably slower evaporation—useful in longer-lasting formulations for cosmetics or industrial scented products.

    One technical manager visiting our plant described how the higher boiling point helps dial in release profiles in encapsulated fragrances, an edge that lighter esters rarely offer. Teams working in specialty cleaning products find N-Hexyl Formate less aggressive than shorter-chain analogs, which translates to safer workplace exposure and smoother product handling. From our perspective, these nuanced distinctions play out on factory floors and in research briefs—not just on paper or in catalogs.

    Commitment to End-User Value, Not Just Commodity Supply

    We recognize that for end-users unlocking demanding formulations, minor batch variations or unexpected contaminants can ripple downstream and escalate costs. So our internal controls start with selection of formic acid and hexanol lots, logging COA cross-checks on each incoming tanker. Storage tanks remain nitrogen-blanketed to keep hydrolysis at bay, an approach that shows visible results in longer shelf stability for our outgoing material.

    Customer-facing teams maintain records of unique needs or historical complaints, driving improvements in cleaning protocols, sampling frequency, or documentation practices. Our approach outpaces that of firms working through trading intermediaries—our engineers, process supervisors, and lab techs deal directly with your requests and concerns, closing feedback loops in days, not weeks.

    Real-World Feedback from Formulators: Opportunities and Adjustments

    Professionals in aroma chemical synthesis often highlight the advantage of minimal “off” notes—delivering natural fruitiness without unwanted harshness. Through plant-floor upgrades, our distillation columns now push for narrower cut ranges, cutting out fractions rich in heavy byproducts or odor-active minor impurities.

    In conversations with technical buyers, a recurring theme surfaces: requests for increased batch consistency, especially as companies seek greater traceability and compliance with new national standards. Our analytical pipeline now includes periodic third-party lab confirmations alongside in-house analyses, adding extra assurance. Clients in Eastern European food ingredient manufacturing share positive outcomes when using our N-Hexyl Formate as a differentiator in apple and pear flavor bases.

    Chemical process partners often face scaling issues, especially with pilot batches that behave unpredictably versus full-load campaigns. Drawing from our scale-up history, we offer pilot-scale drums filled off main line reactors, so new processes can test with material matching commercial purity, not batch-made proxies. This kind of real-world, hands-on supply reduces the risk of late-stage surprises and helps customers lock in specifications early.

    Supporting Next-Generation Demands: Flexibility and Reliability

    In the current climate, traceability and sustainability both play far bigger roles in chemical selection than ever before. Although N-Hexyl Formate remains a minor volume product compared to broader solvents, it draws attention for its safer profile and reduced regulatory headaches compared to phenol or glycol-based alternatives. As a manufacturer, we regularly review national and international inventory lists to preempt any compliance complications.

    Production means facing issues at every imaginable scale: interruptions in raw material supply, sudden shifts in product demand, freight challenges from new trade policies, or just the day-to-day tasks of preventing cross-contamination. On many days, our teams step in to reroute process streams, set up emergency cleanout routines, or field crews to collect rush lab results late at night. These experiences give texture and reality to the products we ship. Each improvement in our process comes from lessons learned during real operations—not management slideshows or best-practices templates.

    Market feedback helps us anticipate opportunities. In the last year, we have talked directly with R&D chemists testing novel green apple notes, or with safety compliance teams building cleaner workplace formulas for consumer products. Shifts in packaging also draw from feedback—many of our customers now favor steel drums with vapor-tight seals over open-head containers, so our filling lines handle both formats.

    Investments in Plant and Process: Raising the Quality Bar

    Just as stricter standards keep rolling out across regions and markets, so we have kept reinvesting in our chemical plant infrastructure. Utilities upgrades, modernized reactors, and automated control systems all signal commitment to producing N-Hexyl Formate that measures up beyond old-school commodity standards. With on-site calibrated titrators, digital pH meters, and gas-tight transfer hoses, plant operators actively reduce sources of error or product loss that can complicate downstream processing.

    We keep chemical compatibility top-of-mind—avoiding any chance of N-Hexyl Formate cross-contaminating other products in multipurpose facilities. Scheduled maintenance windows mean process lines get full cleanouts, not just water flushing. These adjustments take time and effort but provide visible payoffs in higher product recovery, happier downstream customers, and a reputation for reliability in specialty ingredient circles.

    Environmental and Safety Observations: Product Stewardship in Practice

    Safety reviews influence every plant process, from raw material offloading through batch quenching, to the layout of our tank farms. As a manufacturer with boots on the ground, minimizing VOC emissions and safe waste disposal guide operational choices. By using closed reactions and vapor recovery, we not only protect workers but reduce byproduct exposure above the reactor decks.

    Waste formates and excess hexanol are recaptured and recycled where feasible. Regular investment in extraction and distillation yields less waste ending up in effluent streams. In the past, these changes came in response to specific incidents where off-spec byproducts raised concern from plant neighbors—leading us to develop more robust containment and monitoring programs.

    Troubleshooting: Real Challenges and Real Solutions

    A few production cycles ago, a runoff from a hexanol drum arrival contained a higher-than-usual water content. Lab teams caught the anomaly on the first batch, so operations went into a controlled hold. Operators recalibrated water removal in the downstream distillation phase, kept additional sampling in play, and no out-of-spec material left the site. That experience, and similar daily lessons, reinforce why hands-on manufacturing oversight matters—especially with a specialty ester like N-Hexyl Formate, where end-use demands keep rising.

    Customers can sometimes face unexpected problems if blenders or tank farms become contaminated with offcuts from previous runs of heavier or lighter esters. Because we know each step in the production chain, and because plant staff follow a clear master cleaning schedule, our product avoids these pitfalls—leading to purer, more predictable results in every shipment.

    Looking Ahead: Meeting Tomorrow’s Chemical Needs

    We take pride in driving improvements rooted in genuine experience—not just spec sheets or sales literature. N-Hexyl Formate may sit in the background for most industrial or consumer applications, but getting its supply right underpins many high-value output streams, from signature scents and armoatic blends to specialty coatings.

    Trends in regulatory policy, shifting consumer preferences, and advances in formulation science call for strong links between chemical manufacture and end-product creators. Through direct collaboration, our teams adapt processes, troubleshoot faster, and build mutual understanding of where incremental improvements pay off.

    This approach keeps every drum of N-Hexyl Formate not just fit-for-purpose but uniquely reliable in ways that downstream customers count on. Each step, each hourly process check, and each piece of hard-won knowledge shows in the product we offer—and reminds us why manufacturing skill remains central to specialty chemical supply.

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