Products

Methylarsonic Acid

    • Product Name: Methylarsonic Acid
    • Alias: MMA
    • Einecs: 221-657-2
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    486170

    Cas Number 124-58-3
    Iupac Name Methylarsonic acid
    Molecular Formula CH5AsO3
    Molecular Weight 140.97 g/mol
    Appearance White crystalline solid
    Melting Point 238 °C (decomposes)
    Solubility In Water Soluble
    Density 2.157 g/cm³
    Boiling Point Decomposes before boiling
    Pka 4.2
    Synonyms Monomethylarsonic acid, MMA
    Odor Odorless

    As an accredited Methylarsonic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Methylarsonic Acid is packaged in a 500g amber glass bottle with a chemical-resistant cap and hazard labeling for laboratory use.
    Shipping Methylarsonic Acid should be shipped in tightly sealed, corrosion-resistant containers, clearly labeled with appropriate hazard warnings. Transport must comply with local and international regulations for toxic chemicals. Ensure containers are secured to prevent leaks and handled with protective equipment. Keep away from incompatible substances and store in a cool, dry, well-ventilated area during shipment.
    Storage Methylarsonic acid should be stored in a cool, dry, well-ventilated area, away from incompatible substances such as strong oxidizers and bases. Keep the container tightly closed and properly labeled. Store away from direct sunlight and sources of heat or ignition. Use corrosion-resistant containers, and ensure access is restricted to trained personnel. Follow all local, state, and federal storage regulations.
    Application of Methylarsonic Acid

    Applications of Methylarsonic Acid in Industrial Manufacturing

    Methylarsonic acid supports several established industrial fields as a specialized arsenical intermediate. Its controlled use as a processing aid and precursor compound is subject to stringent regulation throughout the chemical supply chain. Below, we detail major downstream applications backed by mature processing experience, market standards, and integration practices.

    1. Synthesis of Organarsenical Herbicides

    Methylarsonic acid acts as a foundational intermediate for the manufacture of selective organoarsenical herbicides, including monosodium methanearsonate (MSMA), disodium methanearsonate (DSMA), and their associated salt forms. These herbicide formulations target annual and perennial grasses, sedges, and broadleaf weeds in non-food crop sites, cotton, golf course management, and railway rights-of-way. Compliance focuses on environmental, worker, and residue regulations throughout upstream formulation and downstream application. Manufacturers optimize dosage according to active arsenic content, regional weed spectrum, and final product strength requirements.

    Industry compliance standards

    • US EPA Registration (40 CFR Part 158, FIFRA requirements)
    • EU REACH Annex XVII and PPP Regulations (Regulation (EC) No 1107/2009)
    • OECD GLP for analytical methods
    • Japan Chemical Substances Control Law (CSCL)

    Typical usage ratio

    • 10–30% by weight in technical-grade formulations, with batch adjustment based on targeted arsenic concentration and formulation strength

    Downstream process integration

    • Addition to alkaline salt reaction vessels to produce MSMA and DSMA
    • Integration at pH adjustment stage and downstream purification (filtration, crystallization)
    • Final blending into commercial herbicide concentrates or granules

    Final product types

    • Technical MSMA for weed control
    • DSMA herbicidal salt
    • Pre-mixed herbicide formulations
    • Active ingredient for post-emergence weed management in regulated markets

    2. Arsenic-Based Semiconductor Precursors

    In advanced materials industries, methylarsonic acid contributes as a specialty precursor in fabricating certain III-V compound semiconductors. It serves as an arsenic source in the synthesis of materials used for optoelectronic devices, photodetectors, and high-frequency integrated circuits. Producers focus on traceability, controlled impurity profiles, and strict compliance with electronic-grade purity specifications, as well as emission controls for workplace safety.

    Industry compliance standards

    • SEMI C64, C75 standards for electronic chemical purity
    • ISO 9001 and ISO 14001 certified manufacturing
    • RoHS and REACH hazardous substance regulations (for downstream device export in EU)
    • US OSHA Permissible Exposure Limits (PEL) for arsenic compounds

    Typical usage ratio

    • Typically <0.1–2% by process total mass, with adjustment for desired doping concentrations and deposition rate

    Downstream process integration

    • Inclusion as arsenic precursor in thin-film or MOCVD reactors
    • Solution phase doping of epitaxial wafers prior to annealing
    • Controlled delivery to maintain stoichiometry and minimize side product formation

    Final product types

    • Gallium arsenide (GaAs) and indium gallium arsenide (InGaAs) wafers
    • Photodiode and phototransistor substrates
    • Terahertz imaging device bases
    • Integrated circuit (IC) die for RF and optical switches

    3. Organometallic Catalyst Production

    Methylarsonic acid functions as a reagent for the preparation of specialty organometallic catalysts, particularly for targeted polymerization reactions and materials modification. The controlled insertion of arsenic-containing ligands enables reaction specificity and influences molecular weight distribution in industrial-scale polymer applications. Careful handling maintains catalyst integrity and minimizes trace contamination risks, with full documentation for catalyst registration and process validation.

    Industry compliance standards

    • ISO 9001 for catalyst production
    • ISO 17025 trace analysis methods
    • Responsible Care® Process Safety Management
    • National chemical registration where applicable (TCSA, TSCA, K-REACH)

    Typical usage ratio

    • 0.05–1% by mass, tailored by catalyst system design and reaction batch size

    Downstream process integration

    • Reaction with metal centers to generate organoarsenic catalyst complexes
    • Final blending as catalyst support or initiator for polymerization
    • Integration in polymer synthesis reactor after monomer charging

    Final product types

    • High-specification polymer resins with custom molecular architecture
    • Functional coatings for electronics, aerospace, and chemical processing
    • Research-grade catalyst systems for proprietary polymer development
    • Performance elastomers and copolymers with arsenic-based functional groups

    4. Analytical Reference Calibration and Trace Testing

    Laboratories utilize methylarsonic acid as a calibration standard for analytical methods that quantify arsenic species in water, soil, and biological samples. Its known stability supports the preparation of certified reference materials, proficiency testing samples, and matrix-matched controls for environmental, agricultural, and occupational arsenic monitoring. Rigorous metrological traceability, purity characterization, and compliance with laboratory accreditation requirements ensure data reliability for regulatory and research users.

    Industry compliance standards

    • ISO 17025 for analytical laboratories
    • US EPA SW-846 Method 7063 (Arsenic Speciation by HPLC-ICP-MS)
    • EN 15763 (Water Quality—Arsenic Measurement by HPLC/ICP-MS)
    • APHA Standard Methods 3120 B (Trace Elements by ICP-MS)

    Typical usage ratio

    • Preparation of 0.01–100 mg/L calibration solutions depending on matrix, detection limit, and method sensitivity requirements

    Downstream process integration

    • Dilution and stabilization into analytical standard solutions for instrument calibration
    • Inclusion in certified reference material (CRM) production for arsenic speciation studies
    • Proficiency test sample preparation for inter-laboratory comparison

    Final product types

    • Matrix-matched calibration standards for HPLC-ICP-MS analysis
    • Reference solutions supplied in sealed ampoules
    • Proficiency testing kits for regulatory compliance laboratories
    • Arsenic speciation CRM sets for environmental and food safety assessments

    Free Quote

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    Certification & Compliance
    More Introduction

    Methylarsonic Acid: Our Experience Manufacturing a Reliable Solution

    Understanding Methylarsonic Acid

    Methylarsonic acid stands as a testament to the value of precision in industrial chemistry. As a manufacturer, our team has handled every stage of its production — sourcing raw materials, maintaining exacting process parameters, and refining the compound’s purity to meet the demanding standards set by agriculture and industrial customers. This particular organoarsenic acid has found a home in a few specialized markets, where its properties bring a strong performance advantage.

    Our methylarsonic acid comes in the form of a crystalline powder, typically presenting as either white or pale off-white, and blends easily into aqueous solutions. The compound follows the structural formula CH3AsO3H2 and features a well-established molecular weight of 140.97 g/mol. These details matter less to end users than the compound’s function, but we focus on them in our plant for one reason: every specification influences how well methylarsonic acid integrates into real-world applications.

    Where Methylarsonic Acid Proves Its Value

    For most buyers, methylarsonic acid’s reputation was built on its long-standing use as a selective herbicide. Agricultural operators in particular have come to rely on the compound to control grass and broadleaf weeds in rice paddies and other specialized crop environments. We have spent years listening to feedback from field managers and chemists. They consistently report that our formulation allows precision weeding, protecting desirable crops while targeting the pests.

    Not every herbicide offers this selectivity. Nor do all synthesized arsenic products meet the level of control demanded by modern agricultural science and environmental regulations. Industrial labs and research bodies have also pointed out methylarsonic acid’s importance as a reference compound for analytical chemistry, especially in trace arsenic studies and toxicity tests. Our approach keeps impurities—such as inorganic arsenic species—very low, which matters in precision laboratory work and regulatory compliance.

    Safety and Responsibility in Production

    Manufacturing organoarsenic compounds brings responsibilities that never fade. We invest extensive time in worker safety training, equipment maintenance, and continuous evaluation of effluent streams. Years of audit experience have taught our operators how to react effectively to any abnormal process readings, reducing the risk of airborne exposure or unplanned emissions. Our waste management protocols separate and treat solvent residues and spent catalysts, minimizing the potential for any release into the wider environment. We continually engage with local authorities and environmental experts, making adjustments as new information on best practices becomes available.

    Our facility implements real-time monitoring of air and water parameters throughout the production process. We know from practical experience that small upsets can escalate without vigilant oversight—so we prioritize detection and rapid intervention over after-the-fact remediation. Dealing with arsenic-containing compounds is not a simple task, and awareness of both acute and chronic hazards stays central to our plant culture.

    Product Consistency and Real-World Use

    Farmers and research partners ask for reliability first. They want to be confident that each order delivers the same behavior in the field or laboratory as the one before it. To deliver this, we monitor every batch for purity and content—setting specifications based on consistent customer feedback. Typical qualities include a minimum assay of 98 percent (as CH3AsO3H2), a moisture content below 1 percent, and controlled limits for heavy metal contaminants such as lead, cadmium, and inorganic arsenic.

    Every year, we invest in updating our analytical equipment to stay ahead of new requirements. Our laboratories operate with high-performance liquid chromatography (HPLC), atomic absorption spectroscopy, and colorimetric assays. In practice, this commitment means our batches meet evolving regulatory standards in diverse markets, whether destined for use in Asian agriculture or heading to scientific institutions in the Americas.

    Differences Compared to Alternative Products

    Methylarsonic acid remains distinct from other arsenic-based herbicides and analytical standards. Compared with monosodium methanearsonate (MSMA) or disodium methanearsonate (DSMA), the acid form we manufacture contains no sodium. This difference shows up in product solubility, compatibility with formulants, and, in certain contexts, lower risks of metal salt buildup in soils. Our plant engineers often discuss that using the acid form enables manufacturers and researchers to choose their own neutralizing agents or carriers, opening opportunities for custom formulations that aren’t possible with pre-neutralized salts.

    For research purposes, methylarsonic acid’s defined structure and high purity let laboratories calibrate test equipment and model biological behavior with greater accuracy than with bulk arsenic oxides or mixed organoarsenic lines. Scientific users value precise, well-documented source material. From our side, offering a singular acid form lets customers design their protocols with full control over pH, ion strength, and companion reagents.

    Practical experience in large-scale agriculture has revealed that the performance of the acid form may shift slightly compared to MSMA or DSMA due to how the soil chemistry interacts with the base compounds. Methylarsonic acid on its own connects well with various adjuvants. Farmers or formulators often cite the benefit of building blends suited to their crops’ unique soil conditions, especially when sodium load or pH control are issues.

    Customer-Focused Development

    We’ve learned over the years that agricultural users expect more than just purity; they want insights and technical backup that make applying methylarsonic acid straightforward. Our support teams work directly with agronomists, helping them integrate new batches and validate product performance each growing season. We’ve participated in dozens of demonstration plots, adjusting application rates, spray timing, and mixture partners to help drive productivity while safeguarding crop safety.

    An open, two-way communication loop with users brings valuable information back into our facility, guiding small tweaks in our crystallization, packaging, or logistics. In our experience, even details like container type, seal design, and label clarity can alter how efficiently farm crews or lab staff deploy the product. Our plant managers read field reports, identify recurring issues, and test out refinements on our pilot lines before any full-scale change. This history of customer feedback results in fewer on-site mixing headaches and more predictable results in every context.

    Managing Regulatory Challenges

    The story of methylarsonic acid’s regulation winds through decades of environmental review. As public awareness grows about arsenic in soils and water, compliance targets shift. Lines between scientific guidance and operational law blur at times, especially as new data arrives. Our role involves keeping up with every change in accepted maximum residue levels, application restrictions, and reporting forms across jurisdictions.

    We subscribe to industry bulletins and government updates, but practical readiness depends on employee training and transparent documentation. Every production shift receives regulatory briefings. Paperwork connects every production lot with a chain of quality and compliance checks. We know from past audits that a missing signature or misplaced analysis sheet can trigger problems. So, our systems stress accuracy and redundancy, not just in measurements but across all recordkeeping.

    Several years ago, export customers faced new caps on arsenic per hectare and required guarantee letters to verify the source and specification of inputs. We collaborated with their technical teams, sending test data, production records, and certification documents. This responsive, hands-on approach avoided interruptions and helped both sides meet these adjusted legal standards. Having lived through these cycles, we appreciate the value of proactive compliance—regulatory foresight prevents shipments from stalling and avoids costly product rework.

    Commitment to Environmental Responsibility

    Working with a substance as sensitive as methylarsonic acid means we constantly assess the lifecycle impacts of our process. Our operations integrate solvent-recapture systems and energy management steps that shrink our carbon footprint. Effluent treatment protocols undergo annual review and external audits. Whenever new technologies emerge, such as enhanced scrubbers or improved crystallization techniques, we weigh investment against both regulatory risk and sustainability gains.

    Our manufacturing staff take part in regular training, focused on not just how to handle the product, but also why it matters. Experienced operators understand the importance of correct transfer points, secondary containment, and the discipline of triple-washing empty vessels. Spill drills are routine, but the goal is prevention—real safety lies in attention to detail, not just emergency response. Waste generated from the operation passes through multi-stage treatment, with solid residues safely packaged and sent for high-temperature destruction.

    Years of feedback from environmental scientists have shaped policies beyond the letter of the law. Where regional regulations allow for disposal via landfill, we often pursue safer incineration or advanced chemical fixation. We also take an active role in local community education. Site tours for students, partnerships with environmental monitoring groups, and community hotlines all play a part in keeping trust strong between the plant and its neighbors.

    Continuous Process Improvement

    Each production lot tells a story of incremental gains. Operators, engineers, and labs work in succession to push quality just a bit higher each quarter. That could mean switching from batch to continuous crystallization, which has delivered tighter particle-size control and higher yield. Sometimes it’s as simple as modifying a pump seal or changing filtration media, both of which have reduced downtime and contamination risk.

    Rarely do improvements appear overnight, but by testing changes on pilot lines, we examine real-world effects before committing to scale. This method saves resources and prevents disruption. Recent years have seen our teams blend traditional batch chemistry with automation-driven process control. We monitor critical pressures, temperatures, and pH in real time and use the data to fine-tune upstream and downstream settings. As experience builds, these changes stack up to more consistent product performance and increased operator confidence on the shop floor.

    Packaging and Product Integrity

    Customers have taught us that packaging needs to survive more than just the trip from our plant to a regional storage site. We select multi-layered, moisture-resistant bags for the bulk powder, with vacuum-sealed liners and tamper-evident closures for more sensitive applications. Each shipment includes detailed labels covering batch numbers, assay results, and expiration dates, always traceable back to production records and archived analytical reports.

    Temperature swings, rough handling, and unpredictable delays can affect the final utility for farmers or lab staff. So we test container response to both summer heat and cold storage. If a specific market asks for smaller pack sizes for controlled lab usage, we oblige and recalibrate sealing equipment as needed. International customers sometimes require added language or transportation labeling — we lean on experience from customs paperwork and supply chain discussions to anticipate these needs.

    Troubleshooting and Customer Support

    No manufactured product escapes the occasional challenge. We have seen early clumping issues due to humidity, or difficulties in dissolving the acid in certain hard-water regions. Having in-house chemists and field technical staff means the time from report to remedy stays short. We dispatch fresh sample packets, work through joint testing protocols, and adjust guidance in technical sheets as new patterns emerge.

    Sometimes the solution lies in a processing tweak—slightly extended drying steps or tighter particle-size fractioning. Sometimes it means improving warehouse humidity control, not just in our facility but in customer storage. Working directly with agricultural extension officers, we have piloted adjustments to spray equipment, solution pH, and nozzle selection, clearing up compatibility or application issues faster than blanket troubleshooting. These ongoing dialogues ultimately smooth field operations, helping to ensure farmers get reliable, repeatable results every season.

    Looking at Research and Future Applications

    Trends in chemical research often prompt questions about the scope of methylarsonic acid’s use beyond herbicides and reference standards. Recent years have seen academic and industrial labs pursue possible medical studies or biochemical tracing. Where our customers approach us for high-purity, accurately weighed microbatches, we scale down production and process with analytical calibration in mind.

    Our plant’s flexibility delivers batches for next-generation research, without compromising the workflow needed for larger, agricultural-scale orders. Lab teams communicate directly with our quality control counterparts to tweak purification or packaging needs for these smaller, highly specific orders. This responsiveness creates a pathway for new ideas, helping researchers test possibilities while ensuring every gram tracks back to clear, reproducible methods.

    Conclusion: Meeting Today’s Standards and Tomorrow’s Challenges

    Building a dependable supply of methylarsonic acid has brought us face-to-face with technical, environmental, and practical demands. Every order reflects accumulated experience in process design, user support, regulatory diligence, and a willingness to aim higher with every batch. Transparent communication—inside our facility and outward to the global community—drives our decisions, from raw material selection to finished goods delivery. As agricultural and scientific needs change, we continue adapting, drawing on what we have learned and what our partners have shared, to keep this specialized product reliable and responsive to its users’ evolving needs.

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