Products

M-Phenylenediamine Sulfate

    • Product Name: M-Phenylenediamine Sulfate
    • Alias: Benzenediamine sulfate
    • Einecs: 243-225-0
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    824616

    Chemicalname M-Phenylenediamine Sulfate
    Casnumber 2148-56-3
    Molecularformula C6H8N2·H2SO4
    Molecularweight 226.23 g/mol
    Appearance White to slightly brownish crystalline powder
    Solubility Soluble in water
    Meltingpoint 168-172°C (decomposes)
    Odor Odorless or slight odor
    Phvalue 2-4 (1% solution)
    Storageconditions Store in a cool, dry, well-ventilated area away from incompatible substances
    Stability Stable under recommended conditions
    Mainuses Hair dyes, chemical intermediates, photographic developers
    Ecnumber 218-410-0
    Hazardclass Toxic if swallowed or in contact with skin

    As an accredited M-Phenylenediamine Sulfate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g of M-Phenylenediamine Sulfate is supplied in a sealed, amber glass bottle with a tightly screw-capped lid, clearly labeled.
    Shipping M-Phenylenediamine Sulfate should be shipped in tightly sealed containers, protected from moisture and incompatible substances. It is classified as a hazardous material and must be transported according to applicable local, national, and international regulations. Use appropriate labeling, and ensure handling by trained personnel. Store in a cool, well-ventilated area during transit.
    Storage M-Phenylenediamine Sulfate should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers and acids. Protect from light and moisture. Ensure the storage area is secure and labeled appropriately. Use secondary containment to prevent spills and limit access to trained personnel only.
    Application of M-Phenylenediamine Sulfate

    Applications of M-Phenylenediamine Sulfate in Industrial Manufacturing

    M-Phenylenediamine Sulfate serves as a critical intermediate in diversified chemical processes across regulated downstream sectors. Our facility supplies large-scale orders supporting manufacturers in key industries, ensuring batch-to-batch quality and compliance with stringent global requirements.

    1. Synthesis of High-Performance Polyamide Resins

    Major polyamide producers utilize m-phenylenediamine sulfate as a key monomer to synthesize meta-aramid fibers and specialty nylon resins. The compound reacts with isophthalic acid dichloride or other diacid chlorides under controlled conditions, enabling targeted molecular weight adjustment and fiber property tuning. This step demands careful stoichiometry, inert atmosphere, and precise timing for high thermal and chemical stability of the finished polymer.

    Industry compliance standards

    • ISO 9001:2015 for Quality Management in Polymer Manufacturing
    • REACH Regulation (EC) No 1907/2006 Registration & Usage
    • OEKO-TEX Standard 100 (Finishing Chemicals for Aramid Fibers)
    • ASTM D7997 (Polyamide Materials Specification)

    Typical usage ratio

    • 0.95–1.05 molar equivalents relative to diacid chloride
    • Adjustment based on intended molecular weight and fiber tensile strength requirements

    Downstream process integration

    • Initial feed in polymerization reactors, following dehydration
    • Reactant in interfacial polycondensation under nitrogen or argon
    • Integrated into batch or continuous fiber spinning lines

    Final product types

    • Meta-aramid staple and filament yarns
    • High-temperature resistant polyamide resin pellets
    • Protective wear and flame-retardant garment textiles
    • Specialty engineering plastics for electrical applications

    2. Corrosion-Inhibiting Epoxy Curing Agent

    Coatings formulators include m-phenylenediamine sulfate in multi-component hardener systems for epoxy resins, particularly for protective anticorrosion linings. The diamine structure provides rapid cure kinetics and resistance to aggressive chemicals in marine, pipeline, or industrial tank environments. Manufacturers must optimize the compound’s reaction with the selected epoxy to achieve hardness, flexibility, and chemical barrier performance as specified in end-use certifications.

    Industry compliance standards

    • ISO 12944 (Corrosion Protection of Steel Structures)
    • API RP 652 (Tank Lining Systems)
    • ASTM D1654 (Evaluation of Painted or Coated Specimens)
    • EU CLP Regulation (Labelling of Formulated Chemicals)

    Typical usage ratio

    • 8–20 parts per hundred resin (phr), adjusted for application temperature and viscosity
    • Ratio determined by required post-cure properties and substrate type

    Downstream process integration

    • Blending into amine hardener premix before final batching
    • Mixed immediately prior to coating application or casting
    • Applied via spray, brush, or roller on prepared steel

    Final product types

    • Marine hull and ballast tank linings
    • Oil and gas pipeline internal coatings
    • Chemical storage vessel interior finishes
    • Heavy-duty anti-corrosive primers

    3. Color Developer in Thermal Paper Production

    Paper converters use m-phenylenediamine sulfate as a functional color developer in thermosensitive coatings. It reacts with leuco dye precursors on the thermal layer to generate stable signal images upon exposure to heat (usually between 70–120°C). Precise raw material feeding ensures compatibility with other developers and waxes, where the sulfate form reduces dusting and enhances printing clarity for receipts, tickets, and labels.

    Industry compliance standards

    • EN 12281 (Paper for Graphic Technology)
    • EPA TSCA Inventory (Paper Chemicals Usage)
    • REACH Annex XVII (Restrictions on Thermal Paper Substances)
    • Chinese GB/T 22824 (Printing Paper Specifications)

    Typical usage ratio

    • 1.0–4.5% w/w of total dry coating mass
    • Varies according to desired image density, substrate absorption, and print head speed

    Downstream process integration

    • Integrated into developer phase during slurry preparation
    • Applied via blade or slot die coating before rapid oven drying
    • Balanced with sensitizers and stabilizers to optimize shelf stability

    Final product types

    • Point-of-sale thermal receipt rolls
    • Lottery and transit tickets
    • Self-adhesive thermal labels
    • Medical diagnostic thermal printouts

    4. Intermediate for Azo and Disperse Dye Manufacturing

    Specialty dye manufacturers select m-phenylenediamine sulfate as a coupling or diazo component in the synthesis of azo and anthraquinone disperse dyes. The compound undergoes controlled diazotization and coupling with appropriate chromogen partners to create pigments with tailored shade and fastness for the textile, plastics, and digital inkjet segments. Batch-wise pH control and toxicological assessments ensure compliance with market-specific regulatory frameworks.

    Industry compliance standards

    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals)
    • OEKO-TEX Eco-Passport (Dye and Pigment Approval)
    • REACH SVHC (Substance of Very High Concern Monitoring)
    • EN 71-3 (Safety of Toys – Migration of Certain Elements)

    Typical usage ratio

    • Stoichiometric equivalence to diazotization/coupling agent, typically 1.0–1.2 mol per target dye molecule
    • Adjusted for desired tinctorial strength and shade, with colorimetric QC during process

    Downstream process integration

    • Reacted in aqueous phase reactors under low temperature for diazo formation
    • Immediately coupled with naphthol or heterocyclic components
    • Purified, filtered, and spray-dried before blending into finished dye formulations

    Final product types

    • Polyester disperse textile dyes
    • High-performance azo pigment powders
    • Solvent-based inkjet ink concentrates
    • Masterbatch colorants for engineering plastics

    5. Constituency in Rubber Antioxidant Production

    Synthetic rubber compounders employ m-phenylenediamine sulfate as an initial reactant in the production of aromatic amine-based antioxidants. The compound drives condensation with ketones or aldehydes to form high-molecular-weight antiozonants and stabilizers, critical for automotive and industrial rubber products. Tight process control ensures no excess free amine remains in the finished antioxidant, aligning with automotive elastomer service life benchmarks.

    Industry compliance standards

    • ISO 9001 (Quality Systems for Elastomer Manufacturing)
    • ASTM D4670 (Rubber—Deterioration and Antioxidant Effectiveness Testing)
    • SAE J200 (Classification of Rubber Materials)
    • REACH Regulation—Articles for Antioxidant Compliance

    Typical usage ratio

    • 1.0–1.2 molar equivalents relative to condensation partners in antioxidant synthesis
    • Final blending at 1.5–3.0% w/w in elastomer compound, dependent on performance objectives

    Downstream process integration

    • Fed to batch reactors at pre-neutralization stage
    • Condenses with acetone or methyl ethyl ketone under catalytic conditions
    • Antioxidant blended into rubber matrix during final mixing

    Final product types

    • Automotive tire rubber compounds
    • Belting for industrial conveyor systems
    • Antioxidant masterbatches for injection or extrusion
    • Heavy-duty hoses and sealing gaskets

    6. Building Block in Pharma Intermediate Synthesis

    Contract and generic pharmaceutical manufacturers use m-phenylenediamine sulfate as a building block in the creation of select APIs, primarily through heterocyclic ring-closing reactions and benzimidazole syntheses. This intermediate stage must achieve the highest purity thresholds to comply with multi-pharmacopoeial requirements, necessitating validated trace impurity analysis and process validation at each batch stage.

    Industry compliance standards

    • Good Manufacturing Practice (GMP), ICH Q7
    • USP/NF Monograph (for related API/intermediate)
    • EDQM Certificates of Suitability (CEP)
    • 21 CFR Part 211 (Manufacturing Process Controls)

    Typical usage ratio

    • Calculated in molar excess or parity with other ring-closing intermediates
    • Optimized for synthesis yield, impurity profile, and pharmaceutical product assays

    Downstream process integration

    • Fed to sealed reactors for controlled cyclization under regulated pH and temperature
    • Used at early or mid-stage, with in-process controls on conversion and purity
    • Isolated prior to downstream derivatization or salt formation

    Final product types

    • Benzimidazole-based therapeutic pharmaceuticals (e.g., antihistamines, proton pump inhibitors)
    • Small-molecule research intermediates
    • Veterinary active ingredients
    • Diagnostic fine chemicals

    Free Quote

    Competitive M-Phenylenediamine Sulfate prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615365186327 or mail to admin@ascent-chem.com.

    We will respond to you as soon as possible.

    Tel: +8615365186327

    Email: admin@ascent-chem.com

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    Certification & Compliance
    More Introduction

    M-Phenylenediamine Sulfate: Unpacking the Real-World Perspective from the Factory Floor

    Decades of Insight: Why M-Phenylenediamine Sulfate Stands Apart

    Every day, tanks rattle and controls beep across our plant as we prepare another batch of M-Phenylenediamine Sulfate—known by its chemical formula C6H4(NH2)2 · H2SO4. In the world of intermediates, this product remains in steady demand. That’s because this crystalline powder, with its soft ivory shade, keeps showing up in the blueprints of new chemical syntheses. Customers ask for varying models based on purity, with our technical grade hovering in the 99% range by titration and well under 0.1% for certain heavy metals—a range confident enough for almost any industrial process that requires stability and reliability.

    Factories and research labs hinge on consistency. As manufacturers, we have seen how M-Phenylenediamine Sulfate holds up under repeated analysis and trial runs. With every load, we keep particle size and moisture content within strict bands. Shelf life ties directly to purity, and experience has taught us that even slight deviations spell big trouble on a large scale. We have learned to spot issues before shipments leave the loading bay.

    M-Phenylenediamine Sulfate carries a reputation for stable solubility and reactivity in water, producing clear, colorless solutions under acidic conditions. Batch histories from nearly two decades of output prove that our process leaves less trace contamination than most competitors, especially concerning sodium and chloride ions, which can disrupt downstream syntheses. Technical managers from dye and pigment plants return to our product whenever the requirements for process color consistency tighten. Other buyers use it for polyamide or polymer chain, where minor contaminant shifts change everything from curing rates to tensile strength.

    Actual Use Cases: Dyes, Polymers, and More

    Inside real-world production lines, few intermediates influence color chemistry like M-Phenylenediamine Sulfate. Textile mills base critical colorfastness grades on the reliability of this compound. Our feedback loops directly with these operations. Talk to dye formulators running batch dye vats or automatic color-dosing systems—they depend on the unchanged behavior that our sulfate brings to the table. That pale, almost neutral hue prevents unwanted undertones in the final color spectrum. Ink producers and developers switch to our sulfate model after cycles of failed print runs with other sources. Color staying power, not just basic reactivity, drives this preference. We have repeatedly seen one minor shift in feedstock ruin a run of color cards. Years of plant-level troubleshooting taught us that it’s easier to trust a source that controls sulfate ratios and maintains total nitrogen at a tight specification.

    Film and engineering plastics engineers prize M-Phenylenediamine Sulfate for versatility in polyimide and polyamide synthesis. Aromatic diamines demand tight thermal management, and our sulfate handles consistent feed profiles at higher processing temperatures. No trace gels, no cloud points—facts only verified batch after batch when you handle the output yourself. Large-scale resin kettles can suffer from pinholes or uneven molecular weight distribution if the sulfate brings any organic carryover. That’s why our line includes a model targeting resin production, with a baseline ash content and iron level low enough for demanding electronic applications.

    Water treatment specialists look to M-Phenylenediamine Sulfate as a base component for anti-corrosive coatings or process inhibitors. Many of these operations move between powder and aqueous feed, so they need a product that dissolves rapidly with minimal residue. Watching real production teams handle these transfers, we track which mixes smoothly under agitators and which settles or froths. These are small details with big implications over thousands of liters at full scale.

    Practical Experience in Handling, Storage, and Logistics

    Packing and shipping this material differ from one grade to the next. The finer the granulation, the more critical airtight containment becomes; even ambient humidity can raise free moisture levels overnight. A sulfate that comes in too damp can clump, raise dusting risk, or derail the flow control for high-speed filling lines. After testing dozens of drum liners and bag types, we made a shift to multi-layer inner bags, layering polyethylene inside anti-static kraft to stave off static and damp. Our own warehouse logs show a drop in product loss and customer claims following this redesign.

    From a safety perspective, this compound acts as a mild irritant: nothing outlandish compared to isocyanates or acid chlorides, but it does warrant respect. Workers who unload, blend, or pour from bulk containers receive PPE face shields, tight nitrile gloves, and aprons. Handling protocols, which evolved through on-the-floor incidents rather than theory, prevent the common hazards of skin sensitization and inhalation. Emergency drills walk everyone from pipe fitters to quality control techs through what to do in spill scenarios.

    Our logistics team, guided by feedback from international shippers and our in-house supply staff, shifted palletizing and container loading procedures to minimize breakage and reduce exposure to jolting or tipping during transit. This simple choice cut loss rates by a measurable percentage year over year and built trust with high-volume clients who can’t manage delays for critical feedstocks. Whether it’s by truck, rail, or sea, the product arrives as expected because we spent years fine-tuning these everyday details.

    Comparing Sulfate to Other Phenylenediamines—Hands-On Results

    Other phenylenediamine products, such as ortho- and para-isomers, share similar functional groups but act differently in production and downstream performance. Our sulfate salt differs from the common hydrochloride version in several ways. Sulfate brings lower hygroscopicity than hydrochloride, which prevents caking during extended storage—key for remote or batch-heavy plants. Its dissolution profile rings cleaner, especially when dissolved in water at controlled temperatures. Our test runs with local water sources showed that pH stability trends very steady, with sulfate feeding into colorant and polymer syntheses more predictably than the chloride or acetate forms.

    Looking at para-phenylenediamine, used frequently in plastics and hair dye sectors, we see differences in oxidative stability, solution color, and handling. M-Phenylenediamine Sulfate, thanks to its meta positioning, delivers reduced tendency for oxidative darkening during processing. Working with routine production waste and purification steps, we have noticed reduced discoloration in effluent, which helps downstream waste treatment plants decrease chemical oxygen demand. For dye houses, this small shift means one less variable to monitor.

    Residual metallic content makes an outsized impact on downstream quality. In our factory, we maintain multiple reactors dedicated solely to M-Phenylenediamine Sulfate to prevent cross-contamination from ferrous or copper species left from former runs. This matters when serving electronics and film customers, who often call for ion chromatography certifications to confirm no interference. By contrast, many general-purpose grades of phenylenediamine from broader-line plants bring unpredictable impurity levels, wreaking havoc in sensitive manufacturing streams.

    Environmental Responsibility in Manufacturing

    Manufacturing this intermediate, we meet a growing expectation for reduced waste and responsible water management. Early in production line upgrades, it became clear that achieving ultra-low byproduct benchmarks isn’t just corporate talk—it comes down to pH balancing, solvent management, and dedication to closed-loop wash systems. Our sulfate production setup features sealed filtration and resin traps so no trace monomer migrates into groundwater.

    Monitoring emissions—both airborne and aqueous—requires vigilance. In recent years, on-site analytical sampling found that aggressive bleaching or over-neutralization could yield trace sulfate runoffs or amine mist. By carefully tempering neutralization steps with gradual acid feeding and staged vacuum drying, we allow only minimal vapor or water-borne escape. Over the past three years, we’ve documented a drop in measurable amines at stack vents. This does not eliminate the risk entirely, but incremental improvements set a standard for our region.

    Disposal concerns for buyers matter almost as much as worker safety for us at the plant. Working closely with waste management services, we built documentation and effective procedures for safe destruction, both in alkaline hydrolysis and incineration. End-users reach out for our technical bulletins to handle spent material and develop co-treatment protocols that fit their site’s chemistry. In the field, these bulletins reflect practical, evolved guidance rather than theoretical projections.

    Quality Control: No Shortcuts Allowed

    Throughout production, our team exerts direct control over every batch. This hands-on approach means more than following a checklist: Spectrophotometric analysis runs in line before packaging, and one sniff or cursory scan can tell an experienced operator if something is off. Knowing the material intimately guides faster, more accurate adjustments. We spent years refining water titration rates, drying cycles, and post-crystallization filtration. Any fluctuation that crops up on a batch—say, a slightly elevated iron or trace insoluble—is caught long before batch release.

    Some manufacturers cut corners on washing or take the philosophy that a little haze or off-shade doesn’t matter. Anyone working with production-level dye or polymer applications knows this quickly becomes a false economy. Clients report back on how even tiny shifts in trace aldehydes or ammonium can trigger waste rejections or clog the final mixing lines. Direct feedback from product users keeps us accountable. These open channels guide recipe tweaks and prompt preventive maintenance before the next run.

    As batch sizes scale, so does the impact of quality drift. Our production teams underwent years of seasoning, learning how to respond to hydrometer blips or particulate readings from drum samples. Every operator in our sulfate line knows their role isn’t just pushing buttons; real experience—nose, eye, and instinct—prevents problems automation alone can’t see. Those skills create a product that process engineers come back for, because mistakes on chemical intermediates cost in lost batches, time, and reputation.

    Continuous Improvement: Responding to Customer Needs

    Dialogue with buyers drives our approach. Each dye house, polymer formulator, or water treatment customer brings fresh challenges to our process team. We adjust dryer settings and filter mesh sizes based on day-to-day input. Periods of increased demand or supply chain shock—such as in peak textile season or under regional shipping constraints—force us to find new ways to maintain output. Our logistics group tracks inventory and transit conditions in real time, offering alternate drum and bagging sizes, and staging material at strategic warehouses near cluster industries.

    We ask end-users what works and act on the results. If a drum size doesn’t fit their hoist, we develop a two-stage delivery process. Should blending prove sluggish due to ambient temperature, we tweak particle size on the next run. These adaptations emerge from on-site visits and detailed conversations, not faceless surveys. Tracking returns, analyzing failed runs, and visiting plants themselves provide feedback loops no statistic can replace.

    Practical Solutions for Industry Challenges

    Product adulteration and counterfeiting in the wider market can create costs and risks for buyers. We address this by providing detailed, batch-level documentation—COAs stamped by operators who handled the batch—and we use tamper-evident slabs and QR-coded seals. Not every customer wants to run an incoming raw material assay, and our system offers confidence without extra expense.

    For any product with environmental reporting or strict regulatory attention, traceability matters. The path of each M-Phenylenediamine Sulfate shipment stays documented, not just with order numbers, but through physical logs transferred between packaging, warehousing, and shipping divisions. Should a question arise after delivery, our team can trace any issue to its root, narrowing the source to the day and shift.

    Long-term storage remains a daily worry; warehouse managers and users need to know how the sulfate responds in varied humidity, temperature swings, or after extended downtime. Our R&D division stress-tests every packaging format in climate chambers matching tropical and temperate storage. The data from these studies feeds back to our own process and keeps us adjusting for real-world conditions.

    Looking Forward: Why Trust Grows with Experience

    Across our years producing M-Phenylenediamine Sulfate, we have learned that superiority goes beyond specs on paper. It comes from investing in the details: knowing when to modify a filtration stage by a few microns, hands-on testing before scale-up, and talking straight with customers about their pain points. Teams with decades of accumulated know-how can spot trends before they become issues, and continually refine both chemistry and delivery. That’s how we keep improving our process and quality, growing stronger partnerships along the way.

    So the next time you weigh a choice between intermediates, recognize the story each batch carries. The value lies not just in the purity number, but in the confidence earned across thousands of metric tons, customer conversations, and a constant push to do better. We stand by this product because we know firsthand what it takes to deliver results that matter on the ground, day after day.

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