Products

Calcium Dithionite

    • Product Name: Calcium Dithionite
    • Alias: Calcium hydrosulfite
    • Einecs: 231-873-7
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    894138

    Chemical Name Calcium Dithionite
    Molecular Formula CaS2O4
    Molar Mass 184.22 g/mol
    Appearance white crystalline powder
    Solubility In Water soluble
    Density 2.62 g/cm3
    Melting Point decomposes before melting
    Odor slight sulfurous odor
    Cas Number 10102-18-8
    Stability unstable in moist air
    Primary Use reducing agent
    Synonyms calcium hydrosulfite
    Storage Conditions store in a cool, dry place
    Decomposition Products sulfur dioxide, calcium sulfate
    Hazard Statements may release toxic gases on decomposition

    As an accredited Calcium Dithionite factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Calcium Dithionite is packaged in a 25 kg white HDPE drum, featuring a secure lid and clearly labeled hazard warnings.
    Shipping Calcium Dithionite should be shipped in tightly sealed containers, protected from moisture and air, as it is sensitive to decomposition. It must be handled as a hazardous material, kept away from oxidizers and acids, and transported according to local and international regulations for chemical substances to ensure safety and compliance.
    Storage Calcium Dithionite should be stored in a cool, dry, and well-ventilated area, away from heat, moisture, and incompatible materials such as acids and oxidizers. Keep the container tightly closed and properly labeled. Protect from direct sunlight and sources of ignition. Use non-sparking tools and avoid friction or rough handling to prevent decomposition or fire hazards.
    Application of Calcium Dithionite

    Applications of Calcium Dithionite in Industrial Manufacturing

    Calcium dithionite is widely used as a specialized reducing agent across several industrial sectors, each with distinct integration methods, compliance frameworks, and formulation requirements. The following sections outline key downstream applications based on actual manufacturing processes, quality standards, and end product requirements as encountered in the chemical raw material supply chain.

    1. Textile Dyeing and Bleaching

    Textile processors deploy calcium dithionite as a strong reducing agent during vat dyeing and textile bleaching stages. Operators use it primarily for indigo dye reduction in denim, achieving controlled color depth and minimizing fiber damage. Its reactivity helps decolorize unwanted pigments from cotton, viscose, and other cellulosic materials. The chemical integrates into continuous dyeing ranges, where reaction time, pH, and temperature require careful monitoring to ensure uniform reduction without overbleaching.

    Industry compliance standards

    • OEKO-TEX® Standard 100
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals Manufacturing Restricted Substances List)
    • ISO 9001:2015 Quality Management in Dyehouses
    • REACH (EC No. 1907/2006)

    Typical usage ratio

    • 0.5–3.0% owf (on weight of fiber), adjusted by fabric load and dye depth

    Downstream process integration

    • Added directly to dyeing bath or bleaching vessel post-dispersion and before temperature ramp-up

    Final product types

    • Denim and workwear fabrics
    • Bleached cotton yarn
    • Dyed viscose textiles
    • Cellulosic fiber blends

    2. Pulp and Paper Bleaching

    Pulp mills incorporate calcium dithionite during the final stages of pulp bleaching, especially for high-yield pulps and mechanical pulps where lignin and chromophores cause unwanted coloration. The reducing action selectively decolorizes quinones and other colored residues that resist oxidative bleaching. Careful dosing prevents paper fiber degradation and achieves brightness improvements essential for newsprint, tissue, and specialty papers.

    Industry compliance standards

    • ISO 14001 Environmental Management (Pulp & Paper)
    • EN 646 Paper and Board—Color Stability Test
    • Food Contact Directive (for packaging grades)

    Typical usage ratio

    • 0.2–1.5% dry pulp weight, optimized by pulp type and target brightness

    Downstream process integration

    • Injected in final bleaching towers or mixing chests following primary oxidation steps

    Final product types

    • Newsprint and catalog paper
    • Tissue and napkin grades
    • Food contact papers
    • Bristol and coated boards

    3. Leather Processing and Tanning

    Within the leather industry, manufacturers use calcium dithionite in pickling, degreasing, and vat dye reduction steps. Its role as a controlled reducing agent allows tanners to modulate hide color and remove residual oxidized materials prior to tanning. Process managers calibrate addition based on hide load and water content to prevent over-reduction, which could affect subsequent tanning chemistry or physical leather properties.

    Industry compliance standards

    • ISO 17075 (Leather—Determination of Chromium(VI) Content)
    • Leather Working Group (LWG) Environmental Protocol
    • REACH SVHC compliance for treated leathers

    Typical usage ratio

    • 0.1–0.7% by wet salted hide weight, varying by hide origin and dyeing target

    Downstream process integration

    • Introduced in rotating drums or open vats during pickling and pre-tanning stages

    Final product types

    • Boot upper leather
    • Automotive upholstery hides
    • Garment and bag leathers
    • Dyed split suede

    4. Chemical Synthesis: Reductive Transformations

    Intermediate and specialty chemical manufacturers incorporate calcium dithionite in multi-step organic synthesis, especially for reduction of nitro compounds, quinones, and azo intermediates. Lab managers prefer its relatively mild reducing conditions, allowing direct reactor feeding for controlled conversions while limiting undesired side reactions. Technical staff adjust pH, solvent ratio, and temperature to maximize selectivity for downstream pharmaceutical or pigment intermediates.

    Industry compliance standards

    • GMP (Good Manufacturing Practice) for pharmaceutical intermediates
    • ISO 9001:2015 (Chemical Manufacturing)
    • Responsible Care Management Systems (RCMS)

    Typical usage ratio

    • 0.8–5.0 molar equivalents, varied by molecular substrate and yield targets

    Downstream process integration

    • Added during reduction stages of batch or continuous flow processes prior to isolation of reduced intermediates

    Final product types

    • Pharmaceutical precursors
    • Organic pigments and dyes
    • Photographic chemicals
    • Pesticide intermediates

    5. Water Treatment and Dechlorination

    Industrial water treatment operators utilize calcium dithionite to remove residual free chlorine and chloramine from process water streams, especially in textile and paper plants where chlorine-based agents are used upstream. The reducing agent ensures process water meets downstream equipment requirements and environmental discharge limits by converting chlorine to chloride. Plant engineers monitor redox potential and adjust dosing in-line to match flow rate and contaminant load.

    Industry compliance standards

    • US EPA NPDES Permit Compliance (Clean Water Act)
    • ISO 14046 (Water Footprint Assessment)
    • Local environmental protection agency effluent standards

    Typical usage ratio

    • 2.0–5.0 ppm per ppm free chlorine present in water, dosage tuned by online monitoring

    Downstream process integration

    • Injected into water treatment lines prior to final filtration or discharge, often under PLC control

    Final product types

    • Treated process water for plant reuse
    • Compliant effluents for direct environmental release
    • Dechlorinated water for sensitive downstream manufacturing

    6. Mining and Mineral Processing

    In mineral beneficiation circuits, operators use calcium dithionite to reduce ferric iron and stabilize certain sulfide ores during flotation and leaching stages. Its selective reducing action aids in improving selectivity and metal recovery rates, especially in the recovery of precious metals from complex ores where oxidizing impurities suppress flotation. Site managers control addition based on ore characteristics and circuit performance data.

    Industry compliance standards

    • SME Mineral Processing Plant Design Practice
    • ISO 14001 (Environmental in Mining)
    • Mine discharge water quality standards (regional)

    Typical usage ratio

    • 0.05–0.3 kg per ton ore, dependent on ore oxidation state and process flow

    Downstream process integration

    • Added to conditioning tanks or flotation units during ore pre-treatment

    Final product types

    • Gold and silver concentrates
    • Refined base metal ores
    • Flotation tailings with lower oxidation content

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    Certification & Compliance
    More Introduction

    Calcium Dithionite: A Reliable Choice for Industry

    Insight from the Production Floor

    Our journey with calcium dithionite goes back almost two decades on the shop floor. Over the years, we've watched the chemical shift from a niche specialty into a staple across several sectors. Workers who have handled the yellowish, crystalline powder day-in and day-out discuss it with a rare sense of practicality. From the way it reacts in a mixing vat to its fast solubility in water, the compound brings its own quirks and advantages that shape real manufacturing outcomes, not just for us but for every end user who bets on consistency.

    Model Variants and Why They Matter

    We run three main model grades in our calcium dithionite line, each built around feedback from textile dye houses, water treatment plants, and pulp or paper mills. High-purity (98% min) stands as the reliable option where color consistency matters—think textile processing, where even a half-percent impurity can wreck a shirt batch. For less sensitive applications, like some grades of water dechlorination, a 90% grade delivers all the reductive power but with a nod to budget constraints.

    Throughout years of batches, we've learned that purity isn’t the only dividing line. Moisture content changes how the compound flows from the drum, and trace byproducts will influence reaction time. We standardized on a moisture cap at 1%, after facing trouble in a damp summer where a shipment caked up and blocked an automated feeder, stalling an entire bleaching line for two shifts. Continuous quality checks, both from our own labs and third-party verifiers, means operators spend less time fussing with fines or powder lumps and more time running clean, controllable processes.

    What Sets Calcium Dithionite Apart

    In its heart, calcium dithionite is a strong reducing agent. Compared to sodium dithionite, it doesn’t carry quite the same punch, but the trade-off lies in stability and shelf life. We've seen customers stick with us after batch tests showed calcium dithionite held up better in humid storerooms, giving them more flexibility on logistics and storage. Unlike the sodium cousin, calcium dithionite tends to produce less dust and offers a lower solubility in water, so operators get fewer plumes of airborne residues—a frequent source of complaints from both plant staff and safety inspectors.

    A common question revolves around why someone should pick the calcium salt over the sodium or zinc versions. Our technical feedback boils it down to three points: calcium dithionite causes less corrosion in processing equipment, leaves behind calcium-based residues that are easier to handle than their sodium counterparts, and meets the regulatory bars for certain eco-friendly production lines. The experience of one textile mill illustrates this: after switching to our 98% grade from a sodium product, they reported a marked drop in maintenance downtime due to scale. Alkalinity in the calcium-based residue softened the water outflow, helping downstream processes run without the hidden costs often buried in the balance sheet under ‘unexpected maintenance’.

    Applications: From Fabric Dye to Pollution Control

    If you walk across our warehouse during shipping season, the destination labels read like a cross-section of industrial manufacturing. Textiles consume a good chunk, drawn by the predictable performance of calcium dithionite during vat dye reduction. Operators in the dye house rely on fast, complete reduction to achieve those deep, uniform shades on cotton and rayon. If you cut corners on reductant, streaks start to show in the finished batch. Our experience backs this up: sample runs done in partnership with major dye houses show a solution prepared with our calcium dithionite achieves full reduction within the first cycle, sending less oxidized dye down the drain and more onto the fabric.

    Water treatment uses also stand out for the compound. Municipal plants reach for our mid-grade product during dechlorination, knocking out chlorine residues before water returns to rivers or goes into the supply grid. The same reactivity that strips color in textile vats scrubs out harmful ions without piling up corrosive byproducts. We field technical calls from engineers fine-tuning their dosing protocols, and real-world feedback led us to tweak grain size distribution so that calcium dithionite dissolves rapidly without flash clumping in automated feeders.

    Pulp and paper production forms the third major leg. Here, calcium dithionite shines as a selective bleaching agent, removing colored impurities from recycled pulp while preserving cellulose strength. Sodium-based alternatives can sometimes attack the cellulose backbone, leading to weaker paper and more breakage during conversion. We tracked several pilot runs where calcium dithionite produced a finished, high-brightness pulp at lower usage rates compared to sodium dithionite, compensating for its less aggressive reduction with gentler chemistry. The sustainability side also weighs in. Plant managers often ask for residue data and discharge testing: calcium-based sludges settle more effectively than sodium, making waste handling less of a headache.

    Quality Management from Manufacturing to Delivery

    Few things cause more frustration than a delivery that arrives out of spec. We learned the hard way that simply relying on batch certificates doesn’t cut it. Every lot of calcium dithionite clears sampling by both instruments and trained operators. During peak summer, we ramp up cold storage for certain lots, as high temperatures accelerate decomposition. Even on the plant floor, workers keep drums sealed tight and away from sunlight. Years ago, a well-meaning new hire stacked a shipment beside a window: two days of added UV ruined more than a ton of product, which ended up in hazardous disposal, not in the hands of a customer.

    We issue clear instructions on in-plant storage and handling, developed together with our own warehouse managers and chemistry teams. There’s no substitute for experience. A simple tweak—lining bins with food-grade liners to prevent tiny leaks—came after a customer flagged residue buildup on their conveyor belts. Now, every drum leaves the plant with updated liners, saving clients unexpected cleaning costs.

    Direct Conversations Shape Our Progress

    As a manufacturer, we talk regularly with the chemists and engineers who use our products daily. It’s not rare for feedback sessions to turn up things no amount of textbook knowledge would reveal—clumping issues at a specific humidity, or residue buildup at a certain pH range. Input from one water treatment specialist resulted in us re-testing particle sizes across different dissolving tanks, highlighting the need for different grain profiles depending on batch size and local water conditions.

    We also field plenty of technical support questions. Many involve troubleshooting a problematic batch, especially if switching from a sodium or zinc reductant. The most common issues tend to relate to mixing procedures and dosing rates, so we've developed quick start guides and hosted plant site visits for new customers. In one notable case, a minor dosing error produced unexpected byproducts; our team worked with the site chemist to zero in on procedural differences, adjusting the order of chemical addition in their sequence. Yields rose, and the customer later shared the fix with their wider corporate team.

    Comparing with Alternatives: What Experience Teaches

    Competitors often position sodium dithionite as the go-to for high potency. While its higher reduction potential works in some tough jobs, it brings headaches in others. Sodium dithionite can release sulfur fumes, especially if overheated in shipment or storage. We’ve had reports from customers who transitioned from sodium to calcium, relieved to see a drop in respiratory complaints and fewer calls to local environmental regulators about odors.

    Zinc dithionite also draws its supporters in specialty textile or chemical synthesis, but the higher costs and added metals in effluent force many operators to weigh the environmental compliance risk. Zinc residues build up in downstream waste treatment, adding costs for separation and disposal—costs that can shift a tight-margin operation into the red. We’ve helped operators evaluate process samples to show where the switch to calcium dithionite lowered both regulatory exposure and ongoing operating expenses.

    Another question we get, especially from global buyers, revolves around adulterants and quality drift over time. Adulteration—a persistent industry problem—can hit sodium products sourced from resellers that lack tight controls. Our internal process maintains traceability on every drum, logs each lot, and holds backup samples for a year. When a batch fails downstream, we can trace every component right back to the raw feedstock supplier, ensuring accountability. This approach brings confidence to procurement teams, and reduces the frequency of disruptions that flare up with inconsistent bulk shipments.

    Environmental and Regulatory Context

    Changes in environmental rules shape our manufacturing every year. Textile plants in regions pushing for zero-liquid discharge rely on chemical selections that lighten their burden downstream. Calcium dithionite plays a strong role here—its breakdown byproducts are easier to handle under modern waste water codes compared to sodium or zinc-based chemicals. As we adapt to lower emission targets, demand for the calcium salt has grown, especially where process engineers appreciate both safety and flexibility.

    Safe production runs through every stage. Early in our operations, an incident with a leaky valve led to a containment review and new drum testing protocols. Simple design updates, like tamper-seal caps and revised label adhesives for hot climates, kept regulatory audits smooth even in the busiest export seasons. Certain regions demand heavy-metal content certification; since calcium dithionite offers cleaner residue, we see quick approvals where rivals must take more time with paperwork and extra testing.

    Troubleshooting and Real-World Problem Solving

    Anyone who’s ever taken a call from an upset plant supervisor knows troubleshooting isn’t about pointing fingers—it’s about seeing the process through their eyes. We share real test data and walk customers step-by-step through fixes, from drum opening to batch mixing. In one pulp mill, workers noticed slower bleaching, traced back to an air leak in their dosing line that oxidized part of the powder. Fixing a $20 gasket restored output rates and avoided a costly chemical switch.

    Another recurring issue arises from bulk storage in humid climates. Calcium dithionite can break down if left exposed to air, so we ship with oxygen barriers and recommend rotating stocks. This lesson, learned from a warehouse in coastal Southeast Asia that suffered a complete product loss due to slow seeping in a rusty container, now shapes every bulk contract we sign. Adding silica gel packets and double-layer liners is a simple answer that prevents complex losses down the line.

    Supporting Product Life Cycle—Not Just the Sale

    We don’t just deliver drums. Our technical teams help set up dosing pumps and advise on discharge permits. This close support traces back to conversations with staff running dye houses at 2 a.m. or maintenance leads managing pulp lines. Speed and simplicity matter, so the guidance never stays buried in long emails or technical jargon.

    As markets change, we invest in upgrades that boost efficiency. We swapped older, open-feed filling hoppers for sealed conveyors after one too many dust incidents—protecting both staff and product, as every lost gram under the conveyor used to add up to real costs over time. These investments pay off with better working conditions, safer storage, and less waste all around.

    Conclusions Drawn from Experience

    Every facility, every shift, teaches something new about calcium dithionite. Its applications run deep, from textile dyeing to water treatment, and every customer weighs trade-offs between purity, cost, environmental impact, and operational ease. Our first-hand results, matched with open feedback from end users, pushed us to develop and refine three distinct grades, all with clear strengths for different industries.

    Reliability really comes down to trust: the trust that what’s loaded off the truck matches lab reports, that the process will repeat as expected, and that someone picks up the phone when a process question or problem crops up. Our continued focus on hands-on quality control, responsive technical support, and clear customer feedback loops builds that trust batch after batch. Whether it means tailoring a grain size for a new application or swapping out packaging to tackle tough storage environments, our approach makes calcium dithionite a dependable solution, built on real-world experience from the shop floor all the way to the finished product.

    Looking Ahead: Our Commitment

    As industry shifts toward greater traceability, tighter environmental controls, and rising labor standards, our approach stays rooted in what works: listening, adapting, and never losing touch with practical operations. Each drum reflects lessons learned from decades in the field, feedback taken directly from users, and a drive to meet tomorrow’s demands. Our investment in calcium dithionite keeps us at the forefront as technology—and the world—moves forward.

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