Acetaldehyde

    • Product Name: Acetaldehyde
    • Alias: Ethanal
    • Einecs: 200-836-8
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    498958

    Chemical Name Acetaldehyde
    Iupac Name Ethanal
    Chemical Formula C2H4O
    Molar Mass 44.05 g/mol
    Cas Number 75-07-0
    Appearance Colorless liquid
    Odor Pungent, fruity
    Melting Point -123.5°C
    Boiling Point 20.2°C
    Density 0.783 g/cm³ (at 20°C)
    Solubility In Water Miscible
    Vapor Pressure 740 mmHg (at 20°C)
    Flash Point -39°C (closed cup)
    Autoignition Temperature 175°C
    Refractive Index 1.333 (at 20°C)

    As an accredited Acetaldehyde factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Acetaldehyde, 500 mL, is packaged in an amber glass bottle with a tight-sealed cap, featuring hazard and flammability labels.
    Shipping Acetaldehyde should be shipped in tightly sealed, approved containers, clearly labeled as flammable and hazardous. It must be transported in temperature-controlled, well-ventilated vehicles, away from heat, ignition sources, and incompatible substances. Compliance with relevant regulations (such as DOT, IATA, IMDG) is mandatory, and appropriate emergency procedures should be in place during transit.
    Storage Acetaldehyde should be stored in a tightly closed, cool, well-ventilated area away from heat, sparks, or open flames. Keep it in a flammable-liquid safety cabinet, separated from oxidizers, acids, alkalis, and amines. Use corrosion-resistant containers, preferably made of stainless steel or glass. Protect from direct sunlight, and always ground storage containers to prevent static discharge. Handle under an inert atmosphere if possible.
    Application of Acetaldehyde

    Applications of Acetaldehyde in Industrial Manufacturing

    We supply acetaldehyde as a core intermediate for multiple industrial sectors. Below we outline its verified use in each downstream field, highlighting regulatory standards, typical dosage ranges, stage of process addition, and types of finished items manufactured using our material.

    1. Pentaerythritol Production for Alkyd and Polyester Resin Industries

    Acetaldehyde serves as a critical raw material in the synthesis of pentaerythritol, which downstream users convert into alkyd paints and polyester resins. It reacts with formaldehyde through aldol condensation and subsequent processing, directly influencing product yield and purity. Our clients carefully balance feedstocks to adapt to production scale and reactor design, monitoring output parameters for compliance with paint and coating industry specifications.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems for chemical production
    • REACH Regulation (EC) No 1907/2006 for chemical substances
    • European Paint & Printing Ink Council (CEPE) guidelines for downstream resin manufacturing
    • US EPA regulations for VOC content in resins

    Typical usage ratio

    • 0.95 to 1.02 mole acetaldehyde per mole formaldehyde input, adjusted for catalyst and reaction path
    • Feedstock concentration typically maintained at 35%–40% wt. in aqueous solution

    Downstream process integration

    • Introduced in batch/continuous aldol condensation reactors with controlled temperature and pH
    • Immediately isolated upon conversion to minimize byproduct formation

    Final product types

    • Pentaerythritol-based alkyd resins for industrial protective coatings
    • Polyester resins for can coatings, automotive finishes
    • Pentaerythritol derivatives for fire-resistant plastics
    • Specialty polyols for UV-cured surface coatings

    2. Pyridine and Pyridine Derivative Synthesis

    This material is a principal feedstock in the production of pyridine and its derivatives. The downstream process employs the Chichibabin synthesis, combining acetaldehyde with ammonia and formaldehyde in the presence of catalysts, typically in fluidized-bed reactors. Product purity and consistent composition are closely linked to acetaldehyde grade and stoichiometric control during synthesis.

    Industry compliance standards

    • GMP guidelines for excipient and API-grade pyridine derivatives (ICH Q7)
    • Pharmacopoeias: USP/NF, EP for pharmaceutical intermediates
    • ISO 14001:2015 for environmental management in chemical manufacturing
    • Indian Standards IS 8058:1997 for pyridine quality

    Typical usage ratio

    • Acetaldehyde:Ammonia:Formaldehyde ratio maintained at 1:1:2 (molar basis) in standard commercial processes
    • Ranges between 17–22 wt% in total reactant mass, adjusted by end-product specification

    Downstream process integration

    • Charged to multi-stage catalytic reactors under 300–350°C with regulated ammonia flow
    • Effluent streams distilled to recover pyridine and side products

    Final product types

    • Pyridine and alkyl pyridine bases for agrochemical synthesis
    • Nicotinic acid (vitamin B3) intermediates
    • Pyridinecarboxaldehyde for fine chemicals
    • Pyridine solvents used in API manufacturing

    3. Peracetic Acid Manufacturing for Disinfectants

    Acetaldehyde is widely applied in the oxidation route for peracetic acid production. The process reacts our product with acetic acid or hydrogen peroxide in specialized reactors, often supporting continuous in-line monitoring for concentration and impurity control. Manufacturers supplying the food safety, healthcare, and water treatment sectors rely on stringent batch records and validated cleaning protocols when handling this intermediate.

    Industry compliance standards

    • US FDA 21 CFR 173.315 for antimicrobial agents
    • ISO 13485 for medical device disinfectant manufacture
    • Food Chemicals Codex for food sanitation products
    • AOAC Official Method 991.21 for peracetic acid determination

    Typical usage ratio

    • 4–8% acetaldehyde relative to total reactants depending on target peracetic acid concentration
    • Process engineers select input levels based on reactor residence time and peroxide excess

    Downstream process integration

    • Metered addition to jacketed reaction vessels at 20–40°C, followed by oxidation and subsequent stabilization
    • Used as a limiting reagent to finely control peracetic acid output

    Final product types

    • Commercial peracetic acid solutions (5–15%) for medical sterilization
    • High-concentration peracetic acid for food plant equipment cleaning
    • Sanitizing agents for bottled water industry equipment
    • Biofilm control agents for industrial water treatment systems

    4. Acetic Acid Intermediate Route for Acetate Fiber Manufacturing

    Acetaldehyde is processed to acetic acid via selective oxidation, then integrated into esterification operations for cellulose acetate fiber production. The acetate textile sector depends on precise impurity profiles and stoichiometric control, particularly where environmental discharge and worker safety standards require careful handling of all intermediates. This downstream continuity ensures reliable fiber formation and dye uptake properties in the end-use chain.

    Industry compliance standards

    • OEKO-TEX® Standard 100 for finished fibers
    • ISO 9001 and 14001 for chemical and environmental management
    • China National Standard GB/T 3725-2009 for cellulose acetate fiber
    • Japan Industrial Standard JIS L1033 for acetate textiles

    Typical usage ratio

    • Oxidation employs 1 mole acetaldehyde per mole of intended acetic acid yield; actual throughput set at 90–98% conversion for downstream integration
    • Acetic acid content optimized based on degree of cellulose substitution needed in fiber grade

    Downstream process integration

    • Fed into continuous oxidation reactors with manganese or cobalt catalysts at 50–70°C
    • Resultant acetic acid proceeds to esterification after rigorous washing and impurity removal

    Final product types

    • Filament-grade cellulose acetate yarns for fashion textiles
    • Tow & staple fibers for cigarette filters
    • Acetate-based nonwovens
    • Print media substrates for specialty packaging

    5. Butyraldehyde Production for Plastics and Plasticizer Feedstocks

    Downstream manufacturers employ acetaldehyde in the oxo process, reacting it with propylene using catalysts to synthesize n-butyraldehyde—a precursor for the production of 2-ethylhexanol and various phthalate plasticizers. This integration stage demands precise temperature and pressure controls, high-throughput system monitoring, and ongoing feedstock purity checks to meet demanding requirements in the automotive, construction, and consumer goods plastic sectors.

    Industry compliance standards

    • EU Directive 2011/65/EU (RoHS) for plastic additives
    • ISO 50001 for energy-intensive plasticizer manufacturing
    • ASTM D1257-06(2014) for plasticizer performance evaluation
    • REACH registration for downstream phthalate and plasticizer products

    Typical usage ratio

    • 0.9–1.0 mole acetaldehyde per mole propylene input in the oxo process
    • Ratios adjusted seasonally based on plasticizer market grades

    Downstream process integration

    • Injected into high-pressure reactors with cobalt or rhodium catalysts at 100–150°C
    • Followed by aldehyde isolation and upgrading to alcohols and esters

    Final product types

    • n-Butyraldehyde for 2-ethylhexanol and phthalate plasticizer synthesis
    • Plasticizers incorporated into polyvinyl chloride cables and films
    • Solvents for flexible PVC manufacturing
    • Automotive and construction plastics

    6. Crotonaldehyde Synthesis for Agrochemical Intermediates

    Chemical plants utilize acetaldehyde in aldol condensation to prepare crotonaldehyde, which is then upgraded to n-butanol, sorbic acid, and crop protection intermediates. Manufacturers maintain rigid reaction conditions to control selectivity, minimizing impurity profiles essential for agrochemical and specialty food preservative applications. Traceability of input purity and batch-to-batch consistency remains a critical customer requirement.

    Industry compliance standards

    • FAO/WHO Codex Alimentarius for food grade preservatives
    • ISO 9001 for batch consistency in fine chemical intermediates
    • EU Directive 91/414/EEC for active agrochemical substances
    • US EPA regulations on chemical intermediates for pesticide production

    Typical usage ratio

    • Typically 2 moles acetaldehyde per mole crotonaldehyde achieved in single or double-step condensation; adjusted based on scale-up yield and catalyst performance
    • Ratios modulated by end-use as food or technical grade products

    Downstream process integration

    • Loaded into continuous flow or batch reactors after pre-purification
    • Catalyst selection (solid base or acid) optimizes downstream conversion

    Final product types

    • Crotonaldehyde for sorbic acid food preservatives
    • Pesticide and herbicide intermediates
    • Synthetic flavors and fragrances (regulated)
    • n-Butanol for coating and solvent industries
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    Certification & Compliance
    More Introduction

    Acetaldehyde: A Chemical Manufacturer’s Actual Insights

    Understanding Acetaldehyde Beyond the Basics

    Working in the chemical industry means seeing thousands of tons of acetaldehyde move from reactors to tanker trucks and then on to countless users around the world. The average person may never stop to ask what this clear, flammable liquid does, but in production halls and lab benches, its usefulness shapes our daily work. As a manufacturer, we draw on decades of practical experience, not just textbook knowledge.

    Acetaldehyde, with its familiar sharp, fruity odor, touches more manufacturing processes than most realize. Years of hands-on handling have highlighted the challenges it brings: volatility, reactivity, a tendency to polymerize if left alone, and strong interaction with many organic compounds. Good reason so much engineering has gone into storage, transport, and quality control.

    Specification and Production Realities

    Our standard product grades follow industry accepted purity levels—between 99% and 99.5% for most uses. Higher grades exist for specialized fields, but the bulk of market demand lies here. Purity isn’t just a laboratory boast—impurities like crotonaldehyde and acetic acid change reaction outcomes, waste time on purification, and create reliability issues downstream. Day after day, we see how repeatable, on-spec batches reduce rework and downtime.

    Process routes also matter. We use ethylene oxidation, which gives fewer byproducts compared to legacy hydration of acetylene. This method, with selective catalysis, sharply lowers quantities of unwanted side products such as formaldehyde, ensuring consistency in large-scale operations. During audits, clients point out how process route affects their end product’s profile, odor, and even regulatory reporting. Industry-wide, acetaldehyde material made by the old acetylene route carries different impurities and a slightly harsher smell—important for food additives and flavors.

    Application Value Seen on Plant Floors

    No two batches of acetaldehyde end up with exactly the same user story, but most go toward model applications like the production of acetic acid, peracetic acid, pyridine, pentaerythritol, and synthetic resins. Our teams have visited resin makers who explain that slight off-purity in acetaldehyde causes foaming or unwanted color in their end products. Clients in the flavor and fragrance sectors demand consistent sensory profiles, and bulk storage near beverage plants often means stricter controls.

    Acetaldehyde’s quick reactivity—a trait that makes it a key building block—forces us to focus on how it’s handled. Open vessels lead to self-condensation or polymerization, so our operations crew trains new hires to keep lines airtight and urge customers to use nitrogen blanketing. The lesson got drilled in after a rushed loading sent a shipment with clouding due to trimer formation, which led to a full recall and days of customer support calls. Over years, each mistake teaches improvements in drum lining, venting, and additive use.

    Large-scale production links acetaldehyde to familiar and not-so-familiar chemicals. Vinyl acetate and acetic anhydride both trace their carbon chains back to this raw material. Downstream, you’ll also find it in solvents, dyes, explosives, and disinfectants. In pharma, its presence gets tightly regulated—only the purest content passes scrutiny, demanding special handling and batch documentation. Many plant operators have stories of how process upsets or delayed maintenance produced off-spec material, teaching costly but unforgettable lessons about operational discipline.

    How Acetaldehyde Differs from Similar Products

    Some buyers new to the field confuse acetaldehyde with formaldehyde or propionaldehyde, perhaps since all three are short-chain aldehydes with some overlapping uses. Practical realities set them apart. Formaldehyde flows through plants as an aqueous solution—easier to store and less volatile, yet toxic and aggressive toward metals. Propionaldehyde, by comparison, has a higher boiling point and distinctive odor—a trait veteran operators detect instantly.

    Where acetaldehyde stands apart is in its reactivity and odor profile. It acts as an intermediate for so many synthesis pathways due to how easily it undergoes addition reactions. In polymer chemistry, it gives flexible starting points for both rigid and pliable materials. Workers in the field see the impact firsthand—storage rooms occasionally require ventilation upgrades and extra monitoring just for acetaldehyde, whereas similar spaces holding formaldehyde solution need more corrosion-resistant materials and more rigorous local exhaust around mixing stations.

    Many buyers ask if acetic acid could replace acetaldehyde for some syntheses. The chemistry says otherwise. As carboxylic acids, acetic acid and propionic acid show different reactivity than aldehydes. The ability to condense with amines, react with alcohols, or undergo aldol reactions drives acetaldehyde’s special role. Our troubleshooting team has helped customers rework their feedstocks after attempts to substitute acids for aldehyde failed, costing both material and time.

    Points of Focus: Safety and Environmental Responsibility

    Few chemicals demand the level of vigilance required by acetaldehyde. Years of onsite experience have shown how leaks, spills, or overheating create both safety and compliance issues. Being lighter than air, its vapors escape quickly and form explosive mixtures. We’ve refined monitoring, venting, and automated shutdown systems across our manufacturing lines, learning from smaller incidents in the past.

    At our plant, anyone tasked with handling acetaldehyde wears full PPE, including goggles and proper respirators. The liquid irritates skin and eyes on contact, and old-timers recall the days before stricter regulations, when repeated exposure left workers with sinus problems. Each improvement—ventilated filling cabinets, transfer lines with backflow prevention, vapor recovery units—has followed real world events, not just regulatory checklists.

    Since environmental regulations tighten each year, we keep pace with new air emissions rules and discharge limits. Acetaldehyde breaks down in air fairly quickly, but even minor fugitive emissions add up. We invested in destructive oxidizer units for exhaust air and solvent recovery systems for process streams. Wastewater from cleaning or run-off goes through careful neutralization to limit biological oxygen demand. Urban customers, especially, have asked about total life-cycle impact—which pushed us to develop contained transfer, returnable tanks, and improved emission reporting. None of these current best practices existed decades ago; they grew out of both compliance needs and public health incidents in the mid-20th century.

    Insight Into Supply Chain and Customer Experience

    If you work in chemical manufacturing long enough, you come to rely less on abstract supply/demand charts and more on listening to what actual users face. Acetaldehyde tends to fluctuate as oil and ethanol prices shift. Our purchasing managers watch upstream cost fluctuations in ethylene and oxygen, then forecast effects on delivered price. When crop failures hit ethanol feedstock, acetaldehyde prices usually climb—painful for both us and downstream clients.

    In real life, delivery reliability overshadows lab specs. Several years ago, a cold snap delayed rail shipments and froze pumps, causing ripple effects along the supply chain. Our operations team had to improvise with extended loading hours, heated vehicles, and closer customer calls. The lesson stuck: storage capacity onsite and nearer to customers makes all the difference in supply crunches.

    Bulk users—those in resin manufacturing or intermediates—measure success by feedstock timing and quality. Small-scale users, such as fine chemicals or pharmaceutical ingredient producers, pay even closer attention to packaging, handling, and proof of batch consistency. Over time, we found that working with customers to train their own operators on safe handling, ventilation, and trouble-shooting cut down on incidents and improved satisfaction. Exchanging “war stories” and best practices builds the kind of partnership that outlasts any contract or bulk price offer.

    Emerging Trends: Innovation From Ground Level

    The fundamentals of acetaldehyde haven’t changed in decades, but customer requirements evolve. EU and North American standards have gradually driven innovation in packaging, vapor containment, and impurity limits. A few years ago, flavor and fragrance users began asking about trace VOCs not specified by previous regulations—demanding improvements in cleaning, filling, and real-time testing.

    From a production standpoint, real-world feedback directs where investments get made. Food additive and pharmaceutical sectors have pushed for upgrades in trace analysis, moving from routine titration to high-resolution chromatography for every outbound batch. This pressure has meant more automation, better sample tracking, and faster response times, which suit specialized applications best but slowly filter down to bulk production.

    Green chemistry is no longer a buzzword but a primary motivator in process reviews. Process engineers monitor utility usage and waste generation with every shift, documenting each effort to improve efficiency. Our innovation team regularly reviews new catalysts meant to drive down both raw material input and waste. Recently, a pilot project cut minor byproduct formation, which trimmed post-process waste disposal costs for one of our largest customers.

    The Human Factor: What Experience Teaches

    Some insights only come from making the same material week in and week out. Take the example of pump maintenance: acetaldehyde’s tendency to attack seals left unchecked leads to minute leaks and vapor escapes—easily caught by old hands trained to notice a sweet, sharp odor at low levels. Quick intervention forestalls both safety events and environmental reporting headaches.

    On shifts, operators rotate jobs so that fresh eyes spot developing issues and old hands pass on lessons—such as double-checking valve orders before a batch changeover, watching condensation in sample lines, and adjusting heat tracing during seasonal transitions. Only in practice do you see how a chilly warehouse or hot afternoon affects vapor volumes, flash points, and tank pressure.

    Every transition or shutdown demands focus. Once, unexpected polymer buildup in a distillation column forced days of cleaning and rework. Lab staff later highlighted a raw material change and elevated storage temps overnight. Downstream customers with disrupted deliveries remembered the event for years. From each such episode, renewed standard operating procedures and checklists get written.

    Looking Ahead—Meeting Current and Future Challenges

    Maintaining reliable acetaldehyde quality in a tightening regulatory landscape means constant adaptation. Global moves to cap VOC emissions, cut greenhouse gases, and trace chemicals in consumer products raise the bar year by year. Teams now track not just output volume and purity but also environmental performance, customer claims, and operational hazards.

    Our facility meets with community safety groups twice annually to go over emergency plans and field questions about long-term pollution, health studies, and accident records. True risk management means more than keeping material within tank walls; it means building trust with both neighbors and end users. Open tours, safety demonstrations, and complaint hotlines have led to smarter controls and faster responses whenever something does go wrong.

    As major sectors look to “green” their supply chains, more customers ask for life-cycle impact data on every upstream chemical. We share firsthand what it takes to track raw ethanol sources, record ozone and particulate impacts from plant operations, and operate closed-loop solvent recovery. These investments often cost more than business managers predict, but the strategic gain comes in fewer disruptions, better brand reputation, and customer loyalty built on transparency.

    Supporting Facts and Practical Wisdom

    Both the World Health Organization and the U.S. National Toxicology Program have studied acetaldehyde’s role as a common air pollutant and as a metabolic product in humans. These reports prompted new guidelines, affecting how plant managers design containment. Our team learned that local regulators sometimes adopt stricter air emission limits than national ones, forcing reviews of every pressure relief valve and vapor tight seal on site.

    On a global scale, the market for acetaldehyde has shifted as more biologically-derived chemicals enter the scene. Industrial scale microbial fermentations, for example, compete with petrochemical methods. Our experience proves that chemical consistency, batch-to-batch document controls, and readiness for tracing origin remain critical—whether the upstream source is renewable or fossil-based.

    Anecdotes from users echo through industry events. A pigment manufacturer described an entire shift lost to a drum with high moisture content, which altered color development. Flavor mixers once rejected material due to off-notes traced back to small, previously ignored impurities in a “commodity” grade shipment. These stories reinforce why manufacturers focus so deeply on details in process, packaging, and logistics.

    Closing Thoughts From the Factory Floor

    Acetaldehyde comes with few easy shortcuts. Every improvement in safety, consistency, or cost follows real setbacks, sharp lessons, or ongoing customer requirements. Manufacturing this material at scale means knowing it from reaction vessel to tanker truck—and all the lab work, paperwork, and late hours in between.

    We keep learning, adapting old systems to new uses, investing in training, automation, and smarter environmental controls. The final word comes not from a textbook or regulation but from what works—avoiding trouble where possible, fixing mistakes quickly, and choosing reliability and safety over cutting corners. In today’s world, that blend of practicality and adaptability counts for more than theory alone.

    Those of us who manufacture acetaldehyde do so with a sturdy respect for its importance and a clear view of its risks and possibilities. We work side by side with those who use it, listening, adjusting, and learning every day. That’s the true foundation for quality chemical manufacturing—one batch, one customer, one shift at a time.

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