Products

5-Nitrobenzotriazole

    • Product Name: 5-Nitrobenzotriazole
    • Alias: 5-Nitro-1,2,3-benzotriazole
    • Einecs: 247-401-2
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    286555

    Chemical Name 5-Nitrobenzotriazole
    Cas Number 933-56-8
    Molecular Formula C6H3N4O2
    Molecular Weight 163.12 g/mol
    Appearance Light yellow to brown crystalline powder
    Melting Point 150-154°C
    Solubility Water Slightly soluble
    Density 1.65 g/cm³ (approximate)
    Purity Typically ≥98%
    Storage Condition Store in a cool, dry place
    Synonyms 5-Nitro-1,2,3-benzotriazole
    Inchi InChI=1S/C6H3N4O2/c11-10-7-5-3-1-2-4-6(5)9(10)8/h1-4H
    Pubchem Cid 13844
    Hazard Classification Irritant

    As an accredited 5-Nitrobenzotriazole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 5-Nitrobenzotriazole, 100g: Supplied in a sealed amber glass bottle with a secure screw cap, labeled with hazard information and chemical details.
    Shipping 5-Nitrobenzotriazole is shipped in tightly sealed containers, protected from heat, moisture, and incompatible substances. Transport complies with standard chemical regulations, and containers are properly labeled with hazard information. Shipping methods prioritize safety, often by ground or specialized courier, and packaging follows all local and international guidelines for hazardous chemicals.
    Storage **5-Nitrobenzotriazole** should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from heat sources, sparks, open flames, and incompatible materials such as strong oxidizers and reducing agents. Protect from moisture and direct sunlight. Label the container clearly, and store according to local regulations for hazardous chemicals to ensure safety and stability.
    Application of 5-Nitrobenzotriazole

    Applications of 5-Nitrobenzotriazole in Industrial Manufacturing

    As a direct manufacturer of 5-Nitrobenzotriazole, we focus on supporting only those sectors with technically validated, large-scale downstream adoption of this specialty raw material. Below, we outline the principal industrial integration scenarios, giving process-specific detail to help formulation and technical teams evaluate its differentiated contribution across several high-demand areas.

    1. Copper Electroplating Additives

    Experienced metal finishing formulators rely on 5-Nitrobenzotriazole as a controlled grain refiner and corrosion inhibitor during advanced copper electroplating processes. Its precise addition enhances deposit brightness, suppresses pitting, and stabilizes surface passivation, especially for PCBs and high-reliability components. Integrators optimize the dosage based on bath kinetics, current density, and targeted layer uniformity, providing manufacturers with reproducible improvements in deposit integrity while ensuring compliance and traceability through each production tank and plating run.

    Industry compliance standards

    • IPC-4556 (Electroless and electrolytic copper plating for printed boards)
    • RoHS Directive 2011/65/EU (European restriction of hazardous substances)
    • ISO 4527 (Electroplated coatings of copper and copper alloys)
    • EN 12540:2000 (Metallic coatings – Electroplated coatings of nickel, copper, and their alloys)

    Typical usage ratio

    • 0.02–0.1 g/L of bath solution; adjusted according to required deposit thickness and operational cycle length

    Downstream process integration

    • Direct metered dosing to the working electrolyte bath after system set-up and before current is applied; monitored continuously to ensure uniform distribution throughout large-scale tank circuits

    Final product types

    • Copper-plated PCBs (Printed Circuit Boards)
    • Connector pins and electronic contacts for automotive and telecom
    • High-durability copper-plated fasteners
    • Decorative and functional electroplated copper components

    2. Industrial Water Treatment Corrosion Inhibitors

    Plant engineers often specify 5-Nitrobenzotriazole in closed-loop and recirculating cooling water systems where mixed-metal piping and heat exchanger units require targeted corrosion management. The compound forms persistent, ultrathin coordination films that suppress corrosion, particularly of copper and copper alloy components, minimizing maintenance downtime. Operators calculate the treated system volume and adjust dosing to maintain persistent corrosion inhibition, especially under load fluctuations and variable water chemistries typically found in large industrial installations.

    Industry compliance standards

    • ASTM D1384 (Standard test method for corrosion test for engine coolants in glassware)
    • ISO 11885 (Water quality – Determination of selected elements by ICP-OES)
    • Regulation (EC) No 1907/2006 (REACH registration for water treatment chemicals)
    • ANSI/ASHRAE Standard 188-2018 (Legionellosis: Risk Management for Building Water Systems)

    Typical usage ratio

    • 1–4 ppm (mg/L) in circulating water circuits, calculated based on total copper content and system flow rates; periodic monitoring required

    Downstream process integration

    • Continuous injection via automated dosing pumps to recirculation line or holding tank following initial system flush; real-time corrosion monitoring supports dynamic adjustment

    Final product types

    • Corrosion-inhibited industrial water/coolant blends for HVAC installations
    • Power plant closed-loop cooling water
    • Chemical refinery process water
    • Chiller coolant solutions for high-capacity server rooms and data centers

    3. Anti-Tarnish Treatments for Metalware Manufacturing

    Manufacturers of precision brass and copperware select 5-Nitrobenzotriazole as a key anti-tarnish agent because it forms stable surface films that delay oxidation and color change after fabrication. Its predictable film-forming kinetics allow consistent, long-term tarnish resistance—key for consumer-facing metal goods and technical parts awaiting downstream assembly. Quality teams select the optimal bath concentration based on metal finish, exposure scenario, and storage profiles, integrating the treatment into line-side processes directly after final metal cleaning.

    Industry compliance standards

    • REACH Annex XVII (Substances of very high concern—limit compliance for end-product exports)
    • EN 1811:2011 (Reference test method for nickel release from all post-treated metalware)
    • ASTM B700 (Standard specification for electrodeposited coatings on metalware)
    • ISO 9227 (Corrosion tests in artificial atmospheres – Salt spray tests)

    Typical usage ratio

    • 0.1–0.5% w/v in aqueous anti-tarnish baths; varied according to required post-treatment durability and storage time

    Downstream process integration

    • Immersion treatment of degreased copper and brass components post-polishing; followed by rinsing and air drying before packaging or subsequent assembly

    Final product types

    • Tarnish-resistant hardware and utensils
    • Precision musical instrument components (such as mouthpieces, keys, valves)
    • Architectural fittings and plated fixtures
    • Consumer electronic device metal cases

    4. Additive for Silver Recovery in Photographic and X-ray Processing

    Operators of large-scale photographic and X-ray film development labs use 5-Nitrobenzotriazole as an additive in silver recovery electrolytes. This improves process selectivity by suppressing unwanted electrochemical side reactions and enables cleaner silver deposition on cathodes, meeting high-purity requirements necessary for recycling and reuse. Technicians optimize input levels depending on the silver throughput, solution pH, and recovery current, integrating quality control steps at each cycle.

    Industry compliance standards

    • DIN 1310-4 (Photographic grade silver recovery systems)
    • ISO 14001 (Environmental management for photo industry waste treatment)
    • Japanese Industrial Standard JIS Z 9110 (Silver recovery from used photographic solutions)
    • Occupational Safety and Health Administration (OSHA) workplace chemical handling guidelines

    Typical usage ratio

    • 0.02–0.08 g/L in recovery electrolytes; tuned for solution chemistry and anticipated batch volume

    Downstream process integration

    • Directly added to the silver recovery tank at the start or during bath refresh; monitored via online sensors for silver concentration and purity

    Final product types

    • Recovered silver cathodes for photochemical recycling
    • Pure silver ingots for industrial re-melting
    • Refined silver powders for electronics and brazing alloys
    • Waste minimization byproducts for responsible hazardous material disposal

    Free Quote

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    Certification & Compliance
    More Introduction

    5-Nitrobenzotriazole: A Manufacturer’s Perspective on This Versatile Chemical

    Our Commitment to Quality and Consistency

    Every batch of 5-Nitrobenzotriazole we produce reflects years of cumulative experience in fine chemical manufacturing. The compound’s unmistakable pale yellow powder appearance speaks to its reliable purity, which we check at multiple process stages using high-performance liquid chromatography. Our consistency stems not just from rigorous testing, but from hands-on familiarity with every challenge that can arise during synthesis. Having produced this molecule at both pilot and industrial scales, we know the intricacies: from solvent ratios during diazotization to drying cycles that deliver optimal flow for downstream applications.

    Understanding the Structure and Model

    5-Nitrobenzotriazole carries the benzotriazole core substituted at the 5-position with a nitro group, a structural modification that unlocks new chemical behaviors compared to unsubstituted analogs. This difference is not academic. Small tweaks in ring electronics lead to significant changes in reactivity, UV absorbance, and solubility. Every bottle that leaves our factory bears the precise isomer, specified by rigorous structural confirmation, ensuring customers receive exactly what their syntheses demand. Adhering to a minimum purity of 99% as standard, we see no shortcuts – trace impurities in specialty chemicals can derail entire reaction schemes.

    Production Challenges and Solutions

    Several years of experience have taught us to respect the complexity of nitration chemistry. Early on, we found that temperature spikes could lead to undesired side products or incomplete conversion. We fixed this by fine-tuning our mixing protocols, using state-of-the-art control systems, and training our technicians to respond immediately to subtle clues during each batch. In our process, each cooling curve is monitored in real time, and we never rely on automation alone; an experienced operator’s instinct often catches what a sensor might miss. These safeguards keep our product consistent whether orders run a few kilos or several tons.

    Application in Corrosion Inhibition

    Our 5-Nitrobenzotriazole enjoys a strong reputation in the metalworking industry, especially in copper and brass protection. Factories face mounting challenges with corrosion, particularly on intricate machine parts that see rough chemical environments. Many customers once relied on plain benzotriazole, but those who have shifted to the nitro derivative tell us of extended lifespans on their equipment and lower maintenance needs. The nitro group imparts stronger surface binding, a property verified both in our own lab’s QCM (Quartz Crystal Microbalance) tests and by end-user feedback. Users can run their systems for longer between cleaning cycles, translating to real reductions in downtime. This isn’t theoretical; it directly affects plant productivity.

    Photography and Imaging

    Photographic chemical manufacturers look for narrow windows of UV absorbance and electron transfer ability when choosing additives. Standard benzotriazole often falls short, especially under challenging lighting and contrast conditions. The electron-withdrawing nitro on our product’s ring structure improves performance in developer solutions, controlling fog and enhancing grain definition in black-and-white film processing. These are insights we have gathered from partnerships with darkroom specialists and field engineers who ran real-world comparative trials. Their verdicts informed refinements in our drying and milling steps to reduce particulate clumping, improving solubility and accuracy at micro-dosing scales.

    Fine-Tuning for Electronic Applications

    Demand from the electronics sector continues to push us toward even tighter impurity profiles. Printed circuit board manufacturers depend on additives that will not introduce ionic contamination – even at the parts per billion level. We responded by upgrading our filtration systems and introducing dedicated washing lines to eliminate cross-residue from other aromatic triazoles. Only with this extra work can we support clients who operate in the unforgiving world of microelectronics, where a single contamination incident can halt production for hours or days. Our regular back-and-forth with customer QA teams helps us drive down contamination risks to levels that routine bench chemistry might overlook.

    Pigment and Dye Intermediates

    In the pigment industry, having a robust intermediate that reacts cleanly under various conditions is crucial. 5-Nitrobenzotriazole behaves distinctively compared to its methyl or unmodified relatives. The nitro substituent steers coupling reactions and shapes the final chromophoric outcome. Pigment chemists we work with have shown us how the choice of triazole starting material can impact hue and fastness in the final product. Through small-scale pilot runs and full-scale production trials, we have fine-tuned our process to provide a product that matches these unique flow and solubility requirements. Years of dialogue with pigment and dye plants have enabled us to understand precisely what hinders or helps their formulations.

    Technical Specifications Reflecting Real-World Needs

    Through every phase of manufacturing, we keep close tabs on properties that our customers actually measure – melting point, particle size, and moisture content. Our product typically melts at 180-184°C, and we perform particle size distribution analyses by laser diffraction, since small variances can affect reactivity. Our most discerning customers require moisture levels below 0.2%, achievable only with gentle vacuum drying and careful packaging. Engineers from several plating and photo labs have told us that even small upticks in moisture content can induce unwanted side reactions. That feedback led us to invest in double-sealed antistatic bags and desiccant packs for every shipment.

    Packaging and Handling — Built on End-User Feedback

    From the outset, we realized good packaging goes beyond meeting shelf-life numbers. We worked with users in busy manufacturing environments who do not want to wrestle with clumsy closures or risk spills from fragile bags. Their direct input drove our transition to tough, resealable drums and custom polyethylene liners, which protect against both mechanical and chemical exposure. We heard from logistics colleagues about bulk shipping sensitivities to shock and vibration, so we adapted our drum packing to prevent caking during long hauls. Such hands-on collaboration, rather than generic answers, accounts for the trust customers now place in our hardware.

    Comparing 5-Nitrobenzotriazole with Other Options

    Not all benzotriazole derivatives perform equally, and side-by-side comparisons in our own applications lab support what customers see on their factory floors. Standard benzotriazole, while effective for corrosion inhibition under mild conditions, often loses effectiveness in particularly harsh acid or saltwater environments. The nitro-modified structure enhances surface affinity, confirmed by both electrochemical analysis and practical real-world testing. For plating and electronics users especially, this added robustness can mean the difference between ongoing maintenance headaches and a trouble-free system.

    We have also trialed methyl and alkoxy derivatives; despite some advantages in solubility or volatility, they generally do not deliver the lasting protection or photochemical precision of the 5-nitro motif. Each substituent brings unique electronic effects. The nitro group draws electron density and fundamentally alters reactivity, opening the door to applications that rely on both stability and reactivity depending on the surrounding chemical matrix. This isn’t academic theorizing – it’s the result of iterative, real-world testing and customer partnership.

    Storage and Shelf Life Insights

    Experience tells us that longevity hinges not just on the molecule’s intrinsic stability, but also on how it is stored. We recommend dark, dry, cool storage because we’ve seen firsthand how heat or light accelerates color change and hydrolysis, especially in humid climates. We track product quality over time in real warehouses and real supply routes, not just in the lab. With this diligence, customers have successfully kept product integrity stable for over two years, far longer than official datasheets suggest, provided storage practices match our recommendations.

    Supporting Sustainability and Waste Minimization

    Manufacturers face steady pressure to cut waste and reduce energy input. We have reworked our nitration pathways to use solvent and reagent systems with improved recyclability. In earlier days, spent acids and wash waters posed disposal headaches; today, we collect, neutralize, and recover these streams responsibly, turning what was once a costly liability into a resource. Sharply reducing chemical waste wasn’t optional – regulators and conscientious customers demand it. Our willingness to modify old habits and invest in new equipment has lowered the total process footprint and sharpened our competitive edge.

    Health, Safety, and Regulatory Compliance in the Real World

    Worker safety sits front and center in any real manufacturing environment. Our teams have documented every lesson learned, from handling powders under negative air pressure to installing continuous dust monitoring in high-traffic areas. Training never stops; new operators shadow seasoned staff before working independently. We use glove boxes and sealed drums because our staff have learned through direct experience how even brief unprotected contact can pose risks. We comply with all relevant local and regional regulations because we want our teams to go home healthy every day – rules don’t cover every scenario, so we design our safeguards based on experience, not just minimum legal obligations.

    End-User Support Based on Real Experience

    Customers often encounter surprises in scale-up or in integrating a new batch into established processes. Our technical staff includes former production chemists who have run these molecules on the floor themselves. Their advice extends beyond shelf-level problems, covering everything from blending the powder into tough matrices to adjusting pH at the reactor. On several occasions, we have visited plants during transfer to diagnose and resolve plugging, clumping, or unexpected reactivity. This kind of help solves real problems quickly, based on the challenges only a chemical plant can throw at you.

    Balancing Supply Chain Reliability

    Running a chemical manufacturing operation provides a special vantage point on the pain points of the global supply chain. We have built multi-source networks for all key raw materials, maintaining buffer stocks not out of necessity, but as a result of lessons learned during trade interruptions. During shipping slowdowns or customs holdups, customers often contact us for early warning or alternatives. Because we keep direct visibility over our entire supply chain, we can respond quickly, swapping suppliers within prequalified lists to keep timetables on track. Having lived through these disruptions, we treat logistics as seriously as chemistry itself.

    Adapting to Shifting Market Needs

    Market expectations change, sometimes quickly. A few years ago, most requests centered on bulk supply for large-scale corrosion inhibition. In recent years, fields like high-end photochemistry, imaging, and printed electronics have begun to dominate. We follow this closely, staying in ongoing conversation with R&D teams and adjusting our process windows accordingly. For certain customers, we hold back higher-purity cuts from our core production runs or produce customized micronizations to meet precise specifications. This brings extra costs, and not all ask for it, but years of close working relationships allow us to anticipate and support long-term development programs. Such responsiveness only comes from holding control of both chemistry and logistics in-house.

    What Makes Our 5-Nitrobenzotriazole Stand Apart

    All the operational tweaks, equipment upgrades, and user dialogues ultimately serve a single goal: offering a product that performs without drama, batch after batch. Our focus rests on keeping impurity levels predictable, flows manageable, and every shipment matched to the real requirements of complex customer processes. This kind of reliability has to be earned; it comes from tracking user needs, responding to surprises, and treating every shipment as both a technical and personal commitment. Satisfying chemical specifications is the baseline – keeping our partners up and running through real-world challenges is what sets us apart in the specialty chemical sector.

    Building for the Long Term

    We see 5-Nitrobenzotriazole not just as a chemical, but as a bridge between decades of accumulated production know-how and the rapidly evolving demands of manufacturing worldwide. As chemistry advances, our unique vantage point as the manufacturer puts us close to the problems users face, from trace impurity troubleshooting to fine-tuning corrosion inhibitors and improving pigment durability. We listen attentively when plant managers, process engineers, or R&D chemists call with a pressing need. That readiness, built on hands-on production and deep-rooted experience, has formed the backbone of our ongoing partnerships and continued innovation, year after year.

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