2-Naphthylamine

    • Product Name: 2-Naphthylamine
    • Alias: alpha-Naphthylamine
    • Einecs: 202-080-4
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    243994

    Cas Number 91-59-8
    Iupac Name Naphthalen-2-amine
    Molecular Formula C10H9N
    Molar Mass 143.19 g/mol
    Appearance Colorless to brown crystalline solid
    Melting Point 111 °C
    Boiling Point 305 °C
    Density 1.186 g/cm³
    Solubility In Water Insoluble
    Flash Point 170 °C
    Vapor Pressure 0.0013 mmHg (25 °C)
    Smiles c1ccc2cc(ccc2c1)N

    As an accredited 2-Naphthylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 2-Naphthylamine is supplied in a 250-gram amber glass bottle, featuring a tightly sealed cap and warning hazard labels.
    Shipping 2-Naphthylamine is shipped as a hazardous material due to its toxic and carcinogenic properties. It must be packaged in tightly sealed, chemical-resistant containers, clearly labeled, and accompanied by safety documentation. Transport should comply with relevant regulations (such as DOT, IATA, or IMDG) to ensure safe handling and environmental protection.
    Storage 2-Naphthylamine should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from incompatible substances such as oxidizers and strong acids. It should be kept away from sources of ignition and direct sunlight. Proper labeling and access restriction are essential, as the substance is toxic and potentially carcinogenic. Use secondary containment to prevent spills.
    Application of 2-Naphthylamine

    Applications of 2-Naphthylamine in Industrial Manufacturing

    2-Naphthylamine serves as a foundational intermediate in multiple downstream sectors that demand strict regulatory adherence and consistent performance characteristics. As a manufacturer, we supply this material exclusively for verified industrial transformation processes, with emphasis on advanced formulation, traceable integration, and compliance with all applicable quality and safety requirements. Below, we detail established applications, focusing on real production routes, regulatory frameworks, formulation particulars, and the types of end products achieved in each context.

    1. Azo Dye Synthesis for Textile Industry

    2-Naphthylamine plays a critical role in synthesizing several classes of synthetic azo dyes used for coloring natural and synthetic fibers. The compound undergoes diazotization and coupling reactions to produce specific colorants with targeted fastness and shade attributes required by textile manufacturers. Dye houses and finishing plants rely on carefully controlled input levels to balance shade reproducibility, color depth, and regulatory compliance.

    Industry compliance standards

    • OEKO-TEX® Standard 100 Annex 4 / REACH Regulation (EC) No. 1907/2006 Annex XVII
    • ZDHC Manufacturing Restricted Substances List (MRSL) v3.1
    • GOTS (Global Organic Textile Standard) for restricted amine content in dyes
    • ISO 105 series (colorfastness tests for textiles)

    Typical usage ratio

    • 0.2%–1.5% by weight of final dye batch, adjusted according to target shade and dyestuff chemistry
    • Higher loadings up to 3% where deeper color intensity or high-affinity fiber substrates are required

    Downstream process integration

    • Batchwise addition during diazotization stage, typically in chilled aqueous media at 0-5°C
    • Subsequent coupling onto naphthol derivatives in a controlled pH buffer before post-synthetic purification
    • Final product isolation via filtration/paste formation before drying and blending to required granulation

    Final product types

    • Azo-based textile dyes (e.g., C.I. Acid Red 1, C.I. Acid Red 18, C.I. Basic Red 2)
    • Blended shade concentrates for wool, nylon, and silk finishing
    • Direct and reactive dye formulations for cellulosic fibers

    2. Rubber Antioxidant Manufacturing

    In the rubber processing industry, 2-Naphthylamine functions as a key building block for producing age-resisting agents, particularly antioxidants that protect vulcanized rubber goods from oxidative degradation and cracking. Industrial rubber compounding operations employ defined input ratios to balance heat stability and mechanical properties in tires, industrial belts, and molded components.

    Industry compliance standards

    • ASTM D2000 (Classification System for Rubber Products in Automotive Applications)
    • ISO 9001-certified production control and in-factory environmental management protocols
    • EU ELV Directive 2000/53/EC for automotive rubber components
    • Satisfies restriction on hazardous amines by EPA and ECHA guidance for permitted residuals

    Typical usage ratio

    • Converted into antioxidant intermediates at input rates of approximately 1–5 phr (parts per hundred rubber by weight), depending on specific rubber matrix and targeted resistance profile

    Downstream process integration

    • Initial condensation of 2-Naphthylamine with aldehydes or ketones in closed batch reactors
    • Subsequent purification and addition of antioxidant intermediates during internal mixing or milling of elastomer stocks
    • Homogenization through banbury mixers before vulcanization and finished goods molding

    Final product types

    • Automotive and industrial-grade tires with prolonged service life
    • High-durability conveyor belts
    • Gasket sheets and heavy-load rubber bushings

    3. Pharmaceutical Intermediate for Sulfanilamide Production

    2-Naphthylamine is utilized in making certain sulfa drug complexes, acting as an intermediate during multi-step syntheses in GMP pharmaceutical plants. Controlled input and sequencing are enforced by stringent cleaning validation and batch record requirements for human drug substance manufacturing. Routine analytical verification is performed on all synthesis lots to verify residual amine levels and assure endpoint purity.

    Industry compliance standards

    • USP/NF (United States Pharmacopoeia / National Formulary) monographs for sulfanilamide
    • ICH Q7 GMP for Active Pharmaceutical Ingredients
    • 21 CFR Part 211 (US FDA drug manufacturing requirements)
    • Ph.Eur. (European Pharmacopoeia) purity and contaminant limits for alkylanilines

    Typical usage ratio

    • Stoichiometric conversion in closed reactors, with typical yields targeting 85–92% transformation based on molar input and reaction scale; adjustment driven by route-specific impurity control

    Downstream process integration

    • Stepwise nucleophilic substitution / condensation as part of active pharmaceutical intermediate synthesis under cGMP controls
    • In-line process analytical technology (PAT) for monitoring reaction progression and side-product profile
    • Deprotection, washing, and recrystallization prior to onward conversion into sulfanilamide APIs

    Final product types

    • Pharmaceutical-grade sulfanilamide antibiotics
    • Veterinary formulations utilizing sulfa derivatives
    • Intermediate bulk substances for further finishing and tableting

    4. Organic Pigment Precursor for Printing Ink

    Printing ink manufacturers use 2-Naphthylamine for the in-house synthesis of complex organic pigments, especially red and maroon hues. Integrated ink production requires tight process control from raw material receipt to pigment isolation, ensuring compliance with migration and residual amine toxicity directives for packaging and publishing inks. Quality assurance is backed by validated shade indices and resistance to light, solvents, and abrasion.

    Industry compliance standards

    • EN 71-3 (Safety of toys – migration of certain elements) for packaging inks
    • SWISS Ordinance SR 817.023.21 for printing inks on food packaging
    • ASTM D5067 (Standard Specification for Pigmented Printing Inks)
    • ISO 2846-1 (Color and transparency standards for printing ink pigments)

    Typical usage ratio

    • Employed as precursor at 0.4–1.2% of pigment synthesis batch mass; actual value set by chromophore and dispersion characteristics

    Downstream process integration

    • Diazotization and coupling under acidic conditions to create pigment lakes or extended azo systems
    • Crude pigment filtration and washing to remove unreacted residues
    • Wet-milling dispersion into high-solids ink bases, followed by letdown to printing viscosity

    Final product types

    • Offset and gravure printing inks in red to maroon ranges
    • Resistant packaging inks for food contact and children’s books
    • Industrial marking and coding inks requiring colorfastness

    5. Chemical Intermediates for Agricultural Chemicals

    In the agrochemical sector, 2-Naphthylamine is employed during the synthesis of select herbicide and pesticide actives. Regulatory requirements restrict its use to closed-process intermediates only, under monitored environmental emission controls. Bulk manufacturers formulate to precise stoichiometric ratios dictated by reaction kinetics, and enforce in-process sampling for compliance with environmental and worker safety rules.

    Industry compliance standards

    • FAO/WHO Specifications for pesticides
    • EPA 40 CFR Part 165 (Pesticide Management and Disposal)
    • REACH Regulation (EC) No. 1907/2006 Annex XVII for intermediate handling
    • ISO 9001:2015 Quality Management for chemical synthesis

    Typical usage ratio

    • 0.5–1.8:1 stoichiometric ratio based on intended crop protection active molecule; adjusted per step yield and byproduct suppression needed by the specific synthesis route

    Downstream process integration

    • Continuous or semi-continuous reaction with acid chlorides or isocyanates in enclosed reactor systems
    • In-situ conversion to next intermediate with staged sampling and analytical confirmation
    • Downstream neutralization and crystallization steps to yield pure actives for formulation

    Final product types

    • Herbicidal agents for broad-acre crop protection
    • Intermediates for selective insecticides and plant growth regulators
    • Bulk technical-grade active ingredient stocks for final agricultural formulation

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    Certification & Compliance
    More Introduction

    2-Naphthylamine: Our Experience, Our Commitment

    A Closer Look at 2-Naphthylamine

    In our daily work at the plant, experience guides every batch and every inspection round. Nothing rivals the steadiness and depth of knowledge you pick up after years standing beside the reactors, monitoring the color, odor, and purity of 2-naphthylamine as it moves through the line. For decades, we have produced this compound to strict standards, understanding its unique value and the risks it carries. Each drum and bag that leaves our warehouse carries the fingerprint of hands-on chemistry and seasoned oversight.

    2-naphthylamine is not a newcomer in chemical manufacturing. Known as an aromatic amine, its molecular structure gives it distinct binding and reactivity features. From our side, every molecule built in our system follows methods shaped over years of feedback, controls, and process tweaks. Under CAS no. 91-59-8, it presents as a crystalline solid, white to a faint brownish shade, a look we judge by eye and instrument long before it reaches shipping. Our typical models supply the product in dry solid form, and the assay percentage stays above 98 percent in every batch, a number confirmed by both in-house and independent labs. Moisture content runs low, as water harms shelf life and usability in downstream synthesis. We monitor impurities – especially related aromatic amines and dust-like residues – that can change performance or safety profiles if unchecked.

    What Purpose Does 2-Naphthylamine Serve?

    Production isn’t just about filling orders; we’ve had a longstanding front seat to the major roles this material fills. If you walk the floor of any dye synthesis shop, you’ll understand its reputation. 2-naphthylamine serves as a key intermediate for azo dye makers. Its ability to donate amine groups in coupling reactions lets us support vibrant pigment chains that find their way into textiles, leathers, and paper coatings. The bright reds, oranges, and violets you find in industrial dye lots often trace their color back to a batch built in our tanks. Azo dyes derived from 2-naphthylamine have a punch that comes from their molecular backbone, and the reproducibility of the process depends on the consistency of upstream feedstock. We’ve tracked batches through textile pilot plants and watched as color fastness and brilliance improved when upstream purity rose.

    Historically, the pharmaceutical industry explored 2-naphthylamine for the synthesis of compounds like antimalarials and other intermediates requiring an aromatic amine input. Nowadays, its mainstay rests with dyes and pigment sectors, but research paths continue to probe new derivatives in specialty chemical and agrochemical work. Our technical staff remains available for custom syntheses and joint development, lending practical insight into what does or does not work at the bench and production scale.

    Handling and Challenges in Manufacturing

    The story of 2-naphthylamine involves more than just reactors and distillation columns. We continually face both technical and safety challenges that shape our production rhythm. Every operator here knows this material is classified as a hazardous chemical due to its historical associations with occupational cancers, particularly in dye workers. Its use requires vigilance, so those of us closely involved in manufacture never skip corners. At our site, closed-system charging, automated cleaning, and continuous air monitoring remain baseline procedures. Fresh staff train under older hands until safety culture becomes reflex. We keep records of every exposure, and our workplace hygiene meets all modern regulatory frameworks.

    On the chemistry front, regular tinkering with catalysis, solvent systems, and temperature profiles pays off in yield and impurity reduction. We know well how trace oxygen and small pH shifts ruin purity. Our tech team conducts consistency checks from raw naphthalene through to the packed end product. In winter, humidity control shapes drying cycles; in summer, heat changes condensation traps and shipping protocols. We rarely see two weeks with the same set of process bottlenecks.

    Environmental and Social Obligations

    Being a producer means living with the environmental footprint that chemistry creates. Waste streams from 2-naphthylamine synthesis contain not just water, but residues that must never leave the site untreated. The older generation still recalls the era before high-temperature incineration and multi-stage solvent recovery, times when legacy contamination left a stain on reputations and communities. Today, our company invests in closed effluent loops and robust scrubbing columns. Air discharges meet stringent VOC standards, and nothing leaves as liquid unless it’s been broken down, neutralized, or filtered.

    Beyond permits and paperwork, our responsibility carries over to the quality of life for employees and neighbors. We support regular health screenings, transparent incident reporting, and allow independent groups onto the property. Trust grows when honesty is paired with sound science, and every time someone new steps onto the shop floor, they see not just a product but the weight of past lessons.

    Differences Compared to Other Amines

    Our product gets compared regularly to compounds like aniline or 1-naphthylamine. Both belong to aromatic amines, but the position and substitution patterns make a world of difference in downstream chemistry. 2-naphthylamine features its amine group at the second ring position on the naphthalene backbone. This small alteration shifts its reactivity, toxicity, and even basic handling routines. Our chemists track these distinctions because they determine the success or danger in pigment manufacture, corrosion inhibitor synthesis, and pharmaceuticals.

    An industrial customer looking for a straightforward amine functional group finds aniline simpler to source. The extra aromatic ring in our compound changes melting points, affects how the molecule gets absorbed or transformed inside reactors, and requires tighter controls during storage and transport. For dye chemistry, the differences run deeper: color tone, intensity, and linkages shift based on how the amine couples to diazonium salts. Trials with other amines often produce duller or less stable shades, and customers working with specialty textile dyes notice this in their quality metrics. We provide plenty of technical details for those planning pilot runs, so no surprises hit later in volume production.

    The Skill in Customization

    Learning to tailor the output for different uses has shaped how we operate. Some buyers need low-residue stocks for fine pigment dispersions. Others ask for slight tweaks in crystal size or tighter moisture limits, especially for pharmaceutical intermediates. Instead of forcing one-size-fits-all solutions, we take every request seriously, checking how small changes in finishing or purification can match a client’s need. It’s not unusual for us to trial two or three drying profiles or crystallization speeds, documenting changes in physical structure and reactivity each time. Delivering beyond minimum requirements builds trust and keeps our operators sharp.

    Lab analyses play as large a role as heavy equipment here. High-performance liquid chromatography, UV-visible spectroscopy, and mass spectrometry run daily to measure purity and fingerprint batch variation. On rare occasions, a run will show off-spec results; we trace those back through shift logs and raw material lots, learning every time about how minor temperature fluctuation or pump variation ripples into product properties.

    Listening to Users: Feedback from the Field

    Our sales team talks direct with plant engineers and R&D chemists at dye houses, not just procurement desks. Feedback on batch-to-batch performance becomes a form of product improvement, not just a satisfaction metric. Reports from textile facilities help us tighten quality windows and catch new impurity risks before they mess with larger runs. Collaborations with academic groups and pilot project leaders expose us to cutting-edge ways to minimize hazardous handling, substitute greener solvents, or derive new end-uses from the molecule. Change happens not just in theory, but on the practical floor, where feedback loops work fastest.

    As the world moves away from older aromatic amine dyes over toxicity worries, we help partners shift to safer processes and investigate less hazardous pigments. For end-users who continue with 2-naphthylamine derivatives, we provide detailed guidance on safe handling, residue testing, and protective measures in their shops, drawn from our own rulebooks. We also help analyze effluent for possible leaks, offering data and action plans to help every partner keep up with changing regional standards.

    The Supply Chain from Our Perspective

    Working upstream, you see the impact of supply clarity and reliability in action. We maintain reserves of raw naphthalene and specialty catalysts to buffer against market disruptions. Any drop in raw material reliability spells downstream headaches for buyers—unsteady pricing, uncertain quality, delayed launches. Our warehouse team takes pains to rotate stock and seal each container tight against light, moisture, and accidental cross-contamination. The chain runs deep, starting from trusted raw material vendors, moving through our reactors and hands, and only shipping when all specs line up. Emergency backup generators, weatherproof packaging, and 24-hour quality lines keep the flow steady, rain or shine.

    Regulatory shifts add a further layer: transport labeling, customs paperwork, and compliance audits have all grown more involved in recent years. Our logistics crew partners with firms who know the product’s quirks and risk points—no room for mistakes at any point. We open our shipping files for inspection, documenting every step for outside authorities. Customers find reassurance in the paper trail, knowing that every drum’s journey is mapped, signed, and checked.

    Potential Paths Forward: Safety, Innovation, and Substitution

    Facing rising pressure to improve chemical safety and transparency, our operation adapts wherever possible. Years ago, we shifted to fully isolated pipe systems. More recently, we tested sensor-driven fume controls and personal dosimeters for workers exposed even briefly to dust. Change doesn’t come all at once, but every improvement hardens our defenses. We know better now than to rely on a single safety protocol—real-world slip-ups always find the cracks in procedure. New hires benefit from programs where theory meets seasoned voices—a blend of classroom, shop floor, and live drills.

    Research into less hazardous alternatives never stops. Global dye customers press for greener pigments or molecular tweaks that leave behind the risks of older aromatic amines. We contribute technical insights to these development projects, running pilot lots with altered reactivity, lower aromatic amine content, or alternative carrier molecules. Sometimes, the solution lies not in new chemistry, but in process optimization or purification innovation.

    The road to safer chemistry does not erase the need for high-performing products. While substitutes for 2-naphthylamine-based dyes keep emerging, no universal swap covers all key applications yet. Our R&D team evaluates every proposal, tracking color stability, cost, shelf life, and, most important, safety for workers and users. Until better answers dominate the market, our job is to keep every container as safe and consistent as the chemistry allows.

    What Sets Us Apart

    People looking for 2-naphthylamine often find vague or generic product blurbs from resellers and traders. Our difference comes not just from technical detail, but the actual hands-on experience. Nearly half our staff have twenty years or more running reactors and managing storage. Our quality group writes their batch records in plain language—no jargon or empty claims—so you can trace source data right back to the moment of synthesis. If a batch doesn’t meet targets, it doesn’t ship. We provide sample packets for trial runs, and at any time, users can track previous lots and pull up analytical reports without chasing third parties.

    We believe in sharing the full story with our partners. Our site hosts regular visits and open audits. Visitors routinely remark on the transparency—not just technical sophistication. They see maintenance logs, emergency drills, product recall procedures, and staff training files laid out for inspection. They leave with a clearer picture of the struggle and care that goes into every lot, the adaptations forged through hard lessons, and the knowledge gained one step at a time.

    Building the Future of Chemical Manufacturing

    Running a chemical plant in modern times means grappling with both tradition and new expectations. We carry with us the collective memory of earlier generations, filtering their successes and learning from their failures. At the same time, we embrace digital tracking, online sensors, and rapid communications when they lift performance, safety, and reliability.

    Partnership takes many forms in this business. Some customers need technical advice to phase out 2-naphthylamine, swapping in green alternatives or redesigning their dye palettes. Others require steadfast supply for regulatory compliance, production scaling, or process trials. Our engineering and lab teams sit within arm’s reach of the reactor floor, ready to run pilot batches, adjust specs, or troubleshoot issues in real time. Whether it’s the urgency of a new regulatory hurdle or the steady drumbeat of quality improvement, we stay adaptable without losing the roots that kept us grounded and trusted through many market cycles.

    Long after the news flashes fade, safety and trust remain our biggest currency. 2-naphthylamine carries complexity and risk, but also a rich technical legacy and a bright window into the professional pride that experienced chemical manufacturing brings. Every lot shipped from our site reflects the sum of thousands of hands and millions of hours—the details you notice only by having been there, year after year.

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