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HS Code |
858931 |
| Cas Number | 75-66-1 |
| Iupac Name | 2-Methyl-2-butanethiol |
| Molecular Formula | C5H12S |
| Molecular Weight | 104.21 g/mol |
| Appearance | Colorless to pale yellow liquid |
| Odor | Strong, disagreeable, skunk-like odor |
| Boiling Point | 98 °C |
| Melting Point | -112 °C |
| Density | 0.799 g/cm³ at 20 °C |
| Flash Point | 13 °C (closed cup) |
| Solubility In Water | Insoluble |
| Refractive Index | 1.440 at 20 °C |
| Vapor Pressure | 185 mmHg at 25 °C |
| Pubchem Cid | 11558 |
As an accredited 2-Methyl-2-Butanethiol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Amber glass bottle containing 100 mL of 2-Methyl-2-Butanethiol, tightly sealed with a screw cap and hazard labeling. |
| Shipping | 2-Methyl-2-butanethiol must be shipped as a hazardous material due to its flammability and strong, unpleasant odor. It should be packed in tightly sealed containers, compliant with DOT and IATA regulations, and clearly labeled. Transport in well-ventilated vehicles, away from heat, sparks, and incompatible substances is required. |
| Storage | 2-Methyl-2-butanethiol should be stored in a tightly closed, chemical-resistant container in a cool, dry, and well-ventilated area, away from sources of ignition, heat, and incompatible substances such as oxidizers and acids. Protect from direct sunlight and moisture. Ensure proper labeling and keep away from food and drink. Use appropriate secondary containment to prevent leaks or spills. |
Applications of 2-Methyl-2-Butanethiol in Industrial ManufacturingAs a direct manufacturer of 2-Methyl-2-Butanethiol, we continuously optimize quality consistency and traceability across diversified industrial supply chains. Below, we highlight proven application domains where this raw material integrates into key processing workflows, featuring compliance requirements, formulation advice, incorporation stages, and downstream product formats. 1. Odorant Additive for Natural Gas DistributionEnergy sector operators utilize 2-Methyl-2-Butanethiol as a pungent odorant to ensure leak detection in otherwise odorless natural gas—its strong, distinctive aroma enables rapid identification of system failures or unplanned releases. During odorization, precise injection equipment incorporates the material before pipe distribution or compression, safeguarding workplace and residential environments. Industry compliance standards
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2. Pesticide Intermediate in Agrochemical SynthesisDownstream agrochemical manufacturers deploy 2-Methyl-2-Butanethiol in thiol-functionalization reactions to construct selective herbicides and fungicide molecules. The compound enters batch reactors under controlled conditions to generate key intermediates, forming sulfur linkages necessary for bioactive crop protection formulations. Industry compliance standards
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3. Fragrance Ingredient in Food Flavor LogisticsFlavor and fragrance manufacturers blend 2-Methyl-2-Butanethiol at controlled ultralow dosages into synthetic flavor preparations, often as an impact modifier to simulate savory notes or reinforce meaty/brothy profiles. The compound is continuously metered into food-safe mixing tanks equipped with vapor containment, then further processed into customer-ready flavor compounds under stringent hygiene regimens. Industry compliance standards
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4. Polymerization Chain Modifier for Industrial RubberSpecialty rubber producers in the automotive and sealing industries use 2-Methyl-2-Butanethiol as a chain-transfer agent in emulsion or solution polymerization of styrenic and diene-based elastomers. The addition of thiol functionality during radical polymer growth stages enhances control over molecular weight and crosslinking density, improving both mechanical and chemical resistance in the final elastomer profiles. Industry compliance standards
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5. Sulfidation Agent in Petroleum Refining and Catalytic ProcessingRefinery operators employ 2-Methyl-2-Butanethiol during catalyst activation protocols within hydrotreating and hydrodesulfurization units, where it acts as a controlled sulfidation agent for transition metal catalysts. The compound is vaporized and mixed into reactor feeds under nitrogen purge or hydrogen flow, delivering sulfur atoms needed for catalyst surface passivation and extended operational stability. Industry compliance standards
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We have come up close to every batch and barrel passing through our production floors for years. There’s nothing theoretical about working with 2-Methyl-2-butanethiol — the muscle memory kicks in before sunrise. Our operators, solution chemists, and maintenance team all know the smell, the handling quirks, and where customers get the best use out of it. Let that paint an honest picture: this chemical’s story is written by people whose hands smell faintly sulfurous at the end of a shift.
2-Methyl-2-butanethiol, often called tert-Amyl mercaptan, brings certain undeniable qualities to the table. Its CAS number, 75-66-1, has become a fixture on our production sheets and labeling lines. Our product achieves a purity level above 98 percent, measured by GC, and we back that level using in-house testing with tried-and-true equipment. Color, odor, and specific gravity are not abstract numbers for us--we check, we test, we tweak processes to stay on target. There’s a body to this compound, a density and a volatility that command respect in the tank farm and in the lab alike.
We see most orders for 2-Methyl-2-butanethiol driven by odorant applications. Utilities and pipeline operators favor it for imparting a skunk-like warning scent to natural gas and LPG, which would otherwise remain undetectable. This job is safety-critical; the full stench becomes a powerful ally, alerting people of leaks before disaster hits. Our batches end up in canisters hauled cross-country or tank wagons refilling city stations, and there’s responsibility in that process from filling to delivery.
Beyond odorant use, the compound works as a building block in organic and pharmaceutical synthesis. Research teams experimenting with selective sulfonation, thiol-functionalized intermediates, and catalyst systems request this molecule because the branched structure of 2-Methyl-2-butanethiol gives unique performance compared to its straight-chain cousins. Certain agrochemical pathways, specialty polymer modifications, and sulfur-containing fine chemicals have all benefited from this feedstock. We are used to inquiries from R&D divisions running small lots, where they want a repeatable source for reproducible results.
The volatility and physical reactivity of this mercaptan demand safe, knowledgeable handling. We’ve designed protocols and trained staff for the acrid vapor, the stubborn residues, and the corrosion potential. Acid-washed stainless reacts less, and temperature control really matters in transit and blending. Customers who understand these requirements keep coming back, seeing that our real-world experience shows up in packaging, technical support, and reliability.
Our 2-Methyl-2-butanethiol comes out of reactors with the sort of consistency you only achieve by working through thousands of batches a year. Material is produced according to our regular batch schedules to fill both drum-scale and bulk-tank needs, kept in tightly sealed drums or ISO tanks to control both volatility and contamination.
We work to deliver a pale yellow to clear liquid, with a distinct and pungent mercaptan odor. Anyone who uncaps a drum knows it means business. The product sits well at room temperatures but doesn’t like exposure to the open air. The boiling point typically lines up near 98°C, and density remains between 0.83–0.85 g/cm³ at 20°C—figures familiar not just to our QA staff but to plant engineers and maintenance crews managing heat exchangers and pumps on a weekly basis.
Assay specs are not theoretical endpoints here. Each shipment goes out with GC analytics from our own labs. We run water content tests to keep levels far below 0.1%—the difference between a clean reaction and a frustrating one. Sulfur content, byproduct identity, and non-volatile matter checks all figure into our sign-off process. There’s a detail-oriented mentality fostered from years of production slips and upgrades; product release isn’t automatic, it’s signed by staff who know what a failed reaction or a leaky tank would cost.
You can engineer and automate, but in practice, the biggest difference-maker comes down to people: trained eyes, solid procedure, good equipment. We use UN-rated steel drums and pressure-tested tanks for transport, and bulk lines are regularly flushed with nitrogen to prevent oxidative tainting or vapor hazards.
Filling valves, vapor recovery nozzles, and emergency containment setups all reflect things we learned the hard way. No textbook solution matches the discipline of double-glove checks during loading or catching a faulty gasket at 5:30 am. In summer, ambient heat spikes demand more than just shade cloths; we implement extra tank monitoring, and product inspections speed up. Every label warning points to specific incidents on our floor—this isn't language from a template, but direct adaptation to risks taken seriously enough to change how we work.
Tradespeople and chemical buyers often ask about the difference between 2-Methyl-2-butanethiol and its more common relatives, such as ethyl mercaptan, n-propyl mercaptan, or tert-butyl mercaptan. Beyond structure and volatility, the nose knows. This compound's odor has a uniquely sharp, layered profile, more pronounced at low concentrations, which has changed how utilities calibrate their detectors and thresholds.
Functionally, the higher boiling point and branched steric hindrance influence reactivity: in synthesis, this means less unwanted side reactions and greater selectivity in thiolation or alkylation steps. Not all mercaptans behave the same under catalyst environments, and decades of plant experience have shown that certain intermediates only work out with a tertiary-substituted backbone. In gas odorizing, 2-Methyl-2-butanethiol persists better through compression and pipeline processes; it doesn’t evaporate out as quickly as lighter analogues, making it especially suited for long-haul transmission.
We field regular requests to swap product lines, but not all molecules are a plug-and-play proposition. Odor linger, compatibility with odorant injection systems, and even customer complaints about “off-smells” tend to trace back to overlooking subtle differences in molecular branching or vapor pressure. Including technical feedback from the field, we publish short notes and bulletins—all based on plant findings rather than broad-market summaries. These come not from marketers, but from the people troubleshooting pumps and swapping filters onsite.
It’s easy to underestimate how much discipline goes into keeping a thiol operation safe, reliable, and clean. Over the years, odorous releases, valve leaks, and temperature excursions taught hard lessons—you solve these by steady refinement, new gaskets, better seals, and aggressive preventative maintenance. No shortcut exists. We introduced periodic retraining for all dock and plant employees before it was standard industry guidance because critical eyes catch the sort of small changes that prevent downtime or incidents.
Routine communication with transportation contractors, end users, and municipal safety officials keeps everyone aware of what’s coming off the truck or going into storage tanks. If a safety officer calls with a question, it goes directly to someone with front-line experience—not a call center or generic helpdesk. Shared knowledge on storage limits, detection threshold adjustments for new projects, and choices about which mercaptan to use flows both ways.
Effective odorant delivery means learning from on-the-ground incidents. Schedule delays, acted-on odor reports, and system malfunctions all lead to tweaks in supply chain management, labeling, site-specific packaging changes, and documentation. Over time, our warehouse workflows, drum tracking, and shipping choices all adapted to suit high-turnover and process-dependent requirements. The end goal stays constant: rapid, accurate delivery of uncompromised material so teams can keep their processes moving.
Sulfur compounds catch regulatory attention for obvious reasons. We have learned to navigate shifting environmental standards, town by town, state by state. Waste treatment systems and emissions scrubbers play non-negotiable roles; these aren’t afterthoughts, but core features required for our particular production lines. Inspections are accepted as routine, with documentation and logbooks always up to date. Our plant’s environmental team walks the floor as often as management, and both have experience addressing community odor reports or questions from local emergency authorities.
There’s no universal standard for how long-term sulfur emissions affect every community, so we set targets tighter than what law demands, based on incident analysis and feedback from those living and working nearby. Spill prevention is not just a slogan, but built into physical plant layout, from sealed transfer zones to sloped flooring, secondary containment, and dedicated response kits distributed around the tank farm.
Working with a volatile thiol means stepping up lifecycle tracking—every drum, tote, and batch receives a record attached from synthesis to loading dock. Waste disposal procedures reflect not just legal mandates but practical realities: thiol residues carry strong, lingering odor signatures that simple washing does not erase. We treat all effluent and washwater before release, and regularly tune scrubber operation as concentrations shift with each shift’s throughput.
Product stewardship extends out to the customer. Technical data sheets get updated after regular review, and site audits occasionally prompt tailored solutions for specific storage or dispensing scenarios. End-user feedback informs our next moves—years of experience shaped new drum venting valves, liner options, and even packaging graphics to better communicate hazards in a way operators actually use on the ground.
Most of the new uses for 2-Methyl-2-butanethiol come from customers trying out novel reaction schemes or performance targets. Our track record supporting those pilots means more than just samples—it’s practical troubleshooting. If bench chemistry calls for scaled-up delivery, we work through custom blending, pre-weighed aliquots, and even on-site technical discussion. Innovation often runs fastest with a supplier willing to answer hands-on questions and deliver direct advice, not just catalog numbers.
Collaboration goes both ways. Customer labs working on pharmaceutical intermediates or new catalysts routinely check with us about specific lot history, contamination potential, or batch-to-batch variation. The cumulative know-how we’ve amassed—documented bottlenecks, temperature-sensitive reactions, or what drum size works best for a particular pilot line—sped up plenty of scale-ups and reduced missteps.
Over the past decade, specialty polymer makers, technical services contractors, and utility managers often cite our technical recommendations as decisive in selecting 2-Methyl-2-butanethiol over other candidates. Whether tuning injection rates for pipeline odorizing or exploring new synthesis vectors in the specialty chemical space, users depend on information rooted in operational perspective, not just spec sheets.
Our plant infrastructure never stays static. Investment in new pumps, higher capacity vapor recovery, and expanded QC lab space all reflect learning by doing. Frequent process audits turn up equipment with better corrosion resistance, or automation upgrades that keep exposures down and quality up. We push for real upgrades that translate to tangible customer gains—a philosophy judged not by abstract ROI but by fewer complaints, higher on-time shipping rates, and cleaner analytical results.
Long-term thinking guides raw material sourcing and energy management, too. With sulfur supply chains challenged in different ways over the years, resilience comes from maintaining alternative sources and stockpiling key raw materials ahead of seasonal demand spikes. Our energy team keeps a sharp eye on utility use, working to dial down peak draws and integrate new monitoring tools that reduce waste and manage costs more predictably across fiscal cycles.
Looking ahead, the regulatory climate and public scrutiny over sulfur organics push us to expand emissions treatment capacity and add scrubber redundancy. The only way to keep up with changing industry expectations is by adopting future-facing operational philosophies—staying flexible, staying alert, and maintaining a working partnership with all end users.
We know how it feels to take a call from a utility engineer at 2 a.m. dealing with a stubborn odorizer system. Our frontline support is not a call sheet; it’s years of in-house and field experience ready to jump in and troubleshoot. Lessons learned get written into operating procedures, safety checklists, and future plant expansions.
We run technical working groups drawing participants from customer engineering, plant management, and shipping coordinators. These sessions generate the changes that matter most—whether swapping out valve types, changing tank insulation patterns, or developing quick reference guides for hazmat incidents. All of it builds a foundation for mutual success down the supply chain: less delay, higher trust in product uniformity, and lower risk in daily operations.
No sales pitch replaces the certainty that comes from tested systems and open communication lines. Everyone involved, from raw material handling to delivery crews, knows their role in the web of safety, compliance, and quality that keeps this molecule moving where it’s supposed to go and out of where it shouldn’t be found.
Real-world chemical manufacturing means facing daily challenges—volatile odors, demanding specs, the pressure of customer deadlines, tough audits, and the occasional process surprise. Every bottle and drum reflects both technological investment and the accumulated experience of many hands. Our approach to 2-Methyl-2-butanethiol draws on hundreds of technical, logistical, and safety lessons learned—the unvarnished kind that only comes from being on the ground, batch after batch, year after year.
From our plant floor to your end use, our commitment stays the same: honest communication, dependable supply, and a determination to solve problems collaboratively. Each transfer, each drum, each reaction benefits from a body of hard-won chemical knowledge and a belief in raising the standard for everyone involved along the way.