2-Hexene

    • Product Name: 2-Hexene
    • Alias: cis-2-Hexene
    • Einecs: 211-133-1
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    731799

    Name 2-Hexene
    Iupac Name hex-2-ene
    Molecular Formula C6H12
    Molar Mass 84.16 g/mol
    Appearance Colorless liquid
    Density 0.676 g/mL at 20°C
    Boiling Point 63-64°C
    Melting Point -139°C
    Refractive Index 1.402 at 20°C
    Flash Point -16°C
    Structure Type alkene (contains a C=C double bond between C2 and C3)
    Isomerism Exists as cis- and trans- isomers
    Solubility In Water Insoluble
    Cas Number 592-45-0

    As an accredited 2-Hexene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle containing 500 mL of 2-Hexene, securely sealed with a plastic cap and labeled with hazard warnings and product details.
    Shipping **2-Hexene** is shipped in tightly sealed containers, typically drums or tanks, under cool, well-ventilated conditions. It is classified as a flammable liquid and must be kept away from heat, sparks, and incompatible materials. Proper labeling and documentation as per transportation regulations (UN No. 1208, Hazard Class 3) are mandatory.
    Storage 2-Hexene should be stored in a cool, dry, well-ventilated area away from heat, sparks, and open flames. Keep the container tightly closed and protected from physical damage. Store separately from oxidizing agents and acids. Use approved safety containers and grounding for bulk quantities. Label containers clearly and avoid prolonged exposure to air to minimize the risk of polymerization or hazardous reactions.
    Application of 2-Hexene

    Applications of 2-Hexene in Industrial Manufacturing

    2-Hexene serves as a critical intermediate in several chemical manufacturing processes, facilitating the synthesis of value-added chemicals for downstream industrial applications. As an experienced manufacturer, our knowledge supports end users in achieving precise integration of this raw material, ensuring regulatory adherence, consistent product quality, and efficient processing across tightly defined market sectors.

    1. Linear Low-Density Polyethylene (LLDPE) Copolymer Production

    Producers of LLDPE target very specific material performance by employing 2-hexene as a comonomer within the controlled environment of low-pressure polymerization reactors. The incorporation levels directly influence film toughness, clarity, and tear resistance. Integration into high-output plants requires strict feedstock quality control and precise ratio management for consistent polymer attributes. Our products align with these requirements for mass production of packaging films and other polyethylene-based materials.

    Industry compliance standards

    • ISO 1872-1 Plastics—Polyethylene (PE) Molding and Extrusion Materials—Part 1: Designation System and Basis for Specifications
    • U.S. FDA 21 CFR 177.1520 for Food Contact Polyolefins
    • EU Regulation (EU) No 10/2011 on Plastic Materials and Articles Intended to Come into Contact with Food
    • REACH Regulation (EC) No 1907/2006

    Typical usage ratio

    • Generally 1% to 12% by mol comonomer relative to ethylene feed, adjusted based on required density and mechanical strength of the final polymer. Higher comonomer concentrations result in softer, more flexible LLDPE grades.

    Downstream process integration

    • Continuous or batch-fed into gas-phase or solution-phase copolymerization reactors alongside ethylene monomer. The comonomer feed rate is programmed to vary with desired melt index and final resin grade.

    Final product types

    • Blown and cast film for agricultural, industrial, and consumer packaging
    • Stretch film and shrink wrap
    • Molded containers and lids
    • Extruded tubes and pipes

    2. Chemical Synthesis Intermediate for Aldehyde and Alcohol Manufacturing

    Our 2-hexene product provides olefin feedstock for manufacturers carrying out hydroformylation (oxo synthesis), targeting C7 aldehydes and subsequent alcohols. This route supports large-scale surfactant, plasticizer, and lubricant base stock synthesis, driving transformation processes within integrated chemical facilities. Reactant purity and isomeric ratio remain under strict monitoring to ensure reliable yield and reproducibility in sensitive downstream catalytic operations.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems for Fine Chemical Production
    • Chemical Manufacturing cGMP (21 CFR Parts 210 and 211 where applicable)
    • Responsible Care Management System (RCMS) adherence
    • REACH pre-registration and notification for intermediate use

    Typical usage ratio

    • Stoichiometric ratios vary between 1:1 and 1:1.2 (olefin:CO+H2) based on catalyst system and targeted conversion rates. Adjustments account for process temperature and downstream aldehyde chain-length requirements.

    Downstream process integration

    • Fed continuously into hydroformylation reactors with synthesis gas and catalyst solution (commonly rhodium or cobalt-based systems). Downstream steps include distillation and hydrogenation, where the derived aldehyde or alcohol is isolated and upgraded per final customer requirements.

    Final product types

    • Heptanal and heptanol for surfactant and plasticizer production
    • Base oils for synthetic lubricants
    • Intermediates for specialty chemical additives

    3. Alkylation Agent in Aromatic Hydrocarbon Processing

    Operators in the petrochemical sector utilize 2-hexene as an alkylating agent to introduce n-hexyl chains onto benzene, toluene, and xylenes, using catalytic Friedel–Crafts or zeolite-based processes. This step forms intermediates for high-value detergent range alkylbenzenes and functional specialty fluids. Exacting feed and catalyst conditions must be managed to avoid isomerization and maximize linearity, a key parameter for product applications.

    Industry compliance standards

    • API 685 Process Safety Standards for Alkylation Units
    • EU Directives on Industrial Emissions (IED, 2010/75/EU)
    • ASTM D3049 Standard for Alkylate Quality Assurance

    Typical usage ratio

    • N-hexene is dosed 1.0–1.5 equivalents per aromatic molecule, subject to activity of the alkylation catalyst and target monoalkylated product selectivity. Adjustments ensure the required linear-to-branched alkyl chain ratio.

    Downstream process integration

    • Introduced via controlled dosing pumps to continuous stirred-tank reactors (CSTR) or fixed-bed reactors. Following reaction, crude product undergoes neutralization, phase separation, and purification steps to produce detergent-range linear alkylbenzenes or specialty aromatics.

    Final product types

    • Linear alkylbenzene sulfonate (LAS) surfactant base
    • Alkylated aromatics for lubricant and solvent manufacture
    • Functional fluid additives

    4. Oligomerization Feed in Polyalphaolefin (PAO) Synthesis

    Leading synthetic lubricant manufacturers rely on 2-hexene as a controlled-feed oligomer precursor in the production of PAOs via cationic or Ziegler–Natta catalysis. The choice of oligomerization strategy and ratio of C6 feed directly determines the viscosity index and pour point of the resulting base oils, which are crucial for next-generation automotive and industrial lubricants. Traceable handling systems and targeted feed rates secure uniform chain-growth distribution, minimizing byproduct fraction.

    Industry compliance standards

    • ISO 21469: Safety of Machinery—Lubricants with Incidental Product Contact
    • API 1509 Engine Oil Licensing and Certification System (EOLCS)
    • ACEA European Engine Lubricant Specifications
    • ILMA GF-6/7 PAO Quality Protocols

    Typical usage ratio

    • Blend ratios range from 50% to 100% for pure C6-based oligomers; often combined with C8/C10 fractions to modulate viscosity. Ratio selected per target lubricant performance characteristics.

    Downstream process integration

    • 2-hexene charges directly to the oligomerization reactor with metered flows to control the degree of polymerization and molecular weight distribution. Product purification uses vacuum distillation and hydrogenation.

    Final product types

    • PAO base stocks for synthetic engine and transmission oils
    • Industrial gear oils and hydraulic fluids
    • Lubricant additives for high-temperature operation

    5. Intermediate for Agricultural Chemical Manufacturing

    Selected agricultural chemical formulators employ 2-hexene in the synthesis of specialty herbicide intermediates and specific plant protection co-formulants. These transformations rely on precise reaction timing and feedstock quality assurance, as downstream processes demand high-purity intermediates for further functionalization and formulation robustness, particularly in global regulated markets.

    Industry compliance standards

    • FAO/WHO Codex Alimentarius Pesticide Residue Limits
    • OECD Principles of Good Laboratory Practice (GLP)
    • China GB/T 31270 Safety Requirements for Chemical Pesticide Production
    • EU Regulation (EC) No 1107/2009 on Plant Protection Products

    Typical usage ratio

    • Usually 0.5–2.5 molar equivalents in initial synthetic steps versus secondary reactants depending on final active ingredient structure. Ratio adapted for each patented synthesis protocol.

    Downstream process integration

    • Incorporated during key alkylation or addition reactions carried out in batch or semi-batch reactors. Product streams then undergo extraction and further refinement or derivatization before final formulation.

    Final product types

    • Precursor molecules for selective pre-emergence herbicides
    • Intermediate linkers for custom plant growth regulators
    • Co-formulants for controlled-release agrochemical delivery systems

    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 2-Hexene: A Closer Look from the Manufacturer’s View

    Our Journey with 2-Hexene

    For years, manufacturers who value reliable performance have depended on building blocks like 2-Hexene. The compound, with its molecular formula C6H12, stands out in our catalog due to its straightforward structure, consistent reactivity, and versatility. Producing this material demands close monitoring of process variables, as its double bond configuration defines not just its chemical behavior, but also its application window. Direct contact with the precursor stream and the exact refining steps leads to an end product that our teams can stand behind — a product clear in color, with high purity, and essentially free from unwanted isomers or oligomers.

    Operators running downstream processes count on that consistency. Each batch we craft undergoes rigorous GC testing to check for minimal impurity, ensuring users avoid batch-to-batch headaches. Customers who speak to our technical support aren’t strangers to questions regarding Z (cis) or E (trans) isomers. Our teams clarify that, while both exist, most industrial conversions lean on the E form, as its geometry favors catalyst selectivity for more predictable outputs. We take pride in keeping that isomer ratio tight so that project managers don’t face unplanned variables after the drum opens.

    Specifications that Matter on the Factory Floor

    Product managers talk about specifications, but upstream, to us in the plant, they aren’t just numbers on a spec sheet. They’re targets set every shift, measured at multiple points, and double-checked before the finished material ships. For 2-Hexene, purity measures regularly above 98% with traditional distillation and advanced polishing. That kind of threshold calls for reliable sourcing of raw butenes, as less refined stocks introduce trace contaminants that sneak into finished goods. During busy quarters, we run extra spot checks since minor contaminants present trouble on catalyst beds downstream, especially for users in polymer synthesis.

    A detail often overlooked outside our walls: the boiling point for 2-Hexene — hovering around 68°C — sits in the right neighborhood for solvent recovery without excessive heat. That translates to less energy spent during distillation, and lower turnaround time for operators running solvent recycle. Unlike bulkier alkenes, 2-Hexene vaporizes smoothly without leaving the residue that gums up heat exchangers. Our maintenance team appreciates that, because it means fewer shutdowns, and operators spend less time cleaning fouled lines.

    Usage: Beyond the Textbook

    Chemistry textbooks present 2-Hexene as an alpha-olefin, but on-site we’ve learned its role stretches far wider than that label suggests. Polyethylene and polyolefin producers rely on it to fine-tune copolymer density. When a process engineer wants flexibility or impact modification, a defined dose of 2-Hexene lets ethylene copolymer chains branch in a controlled way. In markets where end-user packaging demands ever-leaner films or softer material, this branching helps processors get both processability and product resilience.

    Surfactant manufacturers see something different. For them, the compound heads into sulfonation or hydroformylation steps. The double bond’s position in the chain responds rapidly to catalysts, accelerating batch throughput and cutting cycle times. Technicians who supply flavors or fragrances, especially on the greener chemistry side, use 2-Hexene as a synthetic intermediate when purity control is non-negotiable. Compared with some higher alkenes, the handling profile of 2-Hexene cuts down on harsh odor and minimizes labor spent on containment protocols.

    Comparing 2-Hexene Against Other Hydrocarbons

    Some buyers ask about the difference between 2-Hexene and 1-Hexene, expecting a minor distinction. In reality, from a synthetic perspective the location of the double bond changes reactivity profiles in a significant way. With 2-Hexene, the internal bond sits between the second and third carbon in the chain, instead of at the chain end. This makes its addition reactions and polymerization rates notably different. For polymer chemists seeking chain branching without excessive comonomer migration, the internal alkene wins. In our reactors, we see that 2-Hexene’s more stable configuration results in less undesired crosslinking during pressure swings.

    1-Hexene, by contrast, often serves as a starter for longer-chain linear low-density polyethylene (LLDPE), but some grades of film and piping become too rigid. 2-Hexene-paired copolymer allows for greater freedom in structure modification, lowering crystalline regions and widening the process window. The physical properties of these end products—impact-resistance and durability—depend strongly on comonomer architecture. As a supplier who directly observes batch outcomes, we work with R&D teams to select exactly which hexene fits their bespoke profile, steering them towards the internal alkene where performance advantages show up in finished resin.

    Compared to 2-Butene or 2-Octene, 2-Hexene offers a balanced mid-chain length that supports flexibility while maintaining volatility control. In alkylation and oligomerization processes, those working on-site appreciate how the intermediate volatility of 2-Hexene provides manageable vapor pressure and easier separator operation when contrasted with the more volatile butenes, and more sluggish separation of octenes.

    Real-World Challenges with Sourcing and Production

    Producing quality 2-Hexene at industrial volumes involves more than distillation. Sourcing comes first. Reliable feedstock, often derived from catalytic cracking of naphtha or direct extraction from mixed olefin streams, sets the tone for downstream work. Our technicians run feed analyses right at the tank farm to spot possible impurities, since anything carried through from upstream creates a headache later—subtle sulfur or residue levels can poison catalysts or cause unexpected side reactions.

    Downstream of the extraction units, we use stringent fractionation windows to capture the right boiling range and minimize co-elution of similar molecules. Operators watch for signs of isomerization under heat; gentle handling and rapid quenching are required so we keep the desirable trans/cis ratio stable—a factor that matters for buyers who know their catalyst beds are isomer sensitive. Production teams know that fluctuating utilities or plant upsets impact purity, so we maintain process excursions at a minimum by controlling column pressure, reflux rates, and temperature distribution to a tight margin.

    Supply chain disruptions add another layer of volatility. During transportation, 2-Hexene’s low viscosity and sensitivity to atmospheric oxidation mean tanks and containers need tight seals and minimal headspace. Our logistics staff tracks shipment tank cleanliness to avoid prior cargo residues that could degrade the current load. No process works in a vacuum. We work closely with hauliers and storage operators to document chain of custody—from the initial fill right through to the end user—so users know the 2-Hexene they receive has stayed within the specs checked at the plant.

    End-User Feedback Turns into Manufacturing Improvements

    Some of the best adjustments we’ve made on the production line come directly from users in the field. Downstream producers who reported minor polymer color shifts traced those issues to trace oxygen or water ingress in our bulk tanks, prompting us to overhaul nitrogen blanketing systems. The benefits rolled back to users, with brighter polymer output and fewer costly resin regrades. Others asked about drum residue after long storage. After identifying a relationship between storage temperature and evaporation loss, we now keep finished stock at lower temperature during warehousing. These improvements didn’t happen in a vacuum—they came from regular, boots-on-the-ground conversations with plant managers, not just buyers in an office.

    Further feedback highlighted the need for tamper-evident seals and tighter drum filling tolerances. In response, our packaging crew switched to full-drain drums with pressure venting to prevent swelling or denting in warm weather. Such tweaks seem small, but for downstream processors running tight, just-in-time schedules, a small leak or contents loss means a line-standstill.

    A Link in Green Chemistry and Responsible Practices

    Process sustainability is a real discussion inside our plant. Regulations restricting emissions from fugitive organic compounds drive us to capture vented vapors and scrub them before releasing to the environment. Control of 2-Hexene emissions during transfer and distillation means we actively seek out improved sealing technology for gaskets and pumps. Recovered vapors get recycled directly, displacing virgin stock and cutting waste.

    Many of our customers now base purchasing decisions on the overall environmental profile of their suppliers. Because 2-Hexene is a C6 alkene, it features moderately low carbon content compared to longer-chain or aromatic analogs. Lower boiling temperature translates into reduced process energy loads for recovery compared to heavier alkenes. We believe in transparency, so we share both energy usage data and total annual emissions reductions with end-customers who wish to document their own product lifecycle analyses.

    Driving towards a more responsible future, we continue to explore bio-based feedstock options for alkene production, although bio-derived C6 streams remain in their early days. These challenges don’t have simple answers, but we’re committed to evaluating each possible pathway on a technical and economic basis. Every gain we achieve—down to recycling process water, reducing purge losses, and tuning solvent recovery—directly improves the environmental impact of both our own operation and those who build with our 2-Hexene further down the chain.

    Solving Common User Problems with Application Support

    Support doesn’t stop at shipment. Our technical team spends time troubleshooting real-world problems reported by client process engineers. Some resin manufacturers come to us with gelling issues that were traced back to minor impurities in their 2-Hexene stream. By jointly reviewing their process data, we adjusted both our distillation cut points and sampling frequency for that contract, cutting down their off-spec incidents. Other users, especially in high-purity applications like laboratory syntheses, require documentation for every batch—chromatograms, impurity breakdowns, and trace metal analyses—so that regulatory filings go smoothly. We built out a dedicated product data portal for such users, making compliance less burdensome.

    Almost all customers benefit from clear safe handling advice, too. 2-Hexene’s volatility makes it handy during stripping and recovery but calls for proper venting and flame-proof gear during transfer. Plant operators on our end complete safety walkthroughs with the user’s own team before a contract is finalized, ensuring local standard operating practices sync up with our own emergency plans. If an incident happens, we keep response resources available for quick intervention, whether the cause is container rupture during summer transit or an unexpected line rupture.

    Continuous Improvement: Batch Consistency as a Core Value

    Consistency is not guaranteed by automation alone—it’s the people in control rooms and at sampling stations who make sure every shift delivers material that matches what left the plant last month or last year. Lab techs on our team note even slight changes in GC peak heights or trace sulfur levels. When we see a shift, operators dig into raw material lots, maintenance records, and process logs to head off a problem before it lands with the user.

    Our approach to process troubleshooting is rooted in years of direct feedback and hands-on troubleshooting. If a downstream process shifts—maybe a batch stalling earlier than before or product color not matching the target—we don’t hand off a canned answer. Instead our teams either schedule a site visit, or at minimum arrange process data sharing so origin and effect line up. Problems identified get documented and adjustments made for all customers, not just the one who flagged an issue. We document all process changes and communicate them directly to technical buyers for transparency.

    Regulatory Factors and Emerging Market Demands

    Over time, expectations for traceability and regulatory conformance have only grown stricter. In North America, REACH and TSCA registration shape shipment eligibility, while certain grades demand kosher or halal certification for export users. Every delivery batch carries explicit documentation on composition, as more regulators and end-users insist on audited supply chains. Smaller users, especially in academic and research settings, want reassurance that the 2-Hexene in their project matches both purity and regulatory paperwork, so our sales and compliance units continually update product disclosures as laws shift.

    Another emerging conversation points to the future: customers increasingly ask about circular economy or post-use recovery of their hexene-containing products. Although mechanical recycling currently dominates polyolefin markets, ongoing R&D efforts inside our own labs look for chemical recycling approaches that break down polymer waste back into C6 streams—offering a possible closed loop. In these collaborative projects, our role as the original manufacturer means we can vouch for the absence of persistent contaminants in virgin 2-Hexene, preparing current users for future recycling standards.

    Why 2-Hexene Remains Relevant

    Every team in the chemical sector knows trends can come and go, but certain building blocks continue to anchor new processes and new products. 2-Hexene's predictable chemistry and physical uncomplicatedness mean there’s always a new use case emerging. Industries dealing with adhesives, sealants, or flexible foams call on our support for specialized grades, each with controlled volatility or minimized trace impurities. Investments in process automation, deeper analytics, and supply chain resilience highlight a commitment to keeping this product available—even through swings in feedstock pricing or regulatory pressures.

    The difference between success and struggle in end-use applications comes down to detail: not just in purity, but in isomer control, handling safety, and responsible sourcing. As the manufacturer behind each drum of 2-Hexene, we judge our performance not by volume, but by the lack of complaints or surprises the moment a user drops our alkene into their system. Transparency, adaptability, and open dialogue with every customer drive our own journey toward better chemistry and better business.

    Pushing Forward: Outlook for 2-Hexene Applications

    Markets adapt. Copolymer resin properties evolve to meet changing bag, film, and packaging demands. Appliance makers want lighter housings with cleaner environmental footprints. The trend in surfactant chemistry heads toward greener, less persistent options. Through each of these developments, manufacturers like us keep refining process controls and logistics workflows to supply high-quality 2-Hexene—never seeing it as a commodity, but as a key ingredient requiring diligence.

    Looking ahead, the integration of digital process controls will further tighten production specs, supporting those users who run ever more sensitive processes. Research efforts into renewable feedstocks and advanced catalytic routes promise greater sustainability. As a manufacturer crossing decades of hands-on expertise, we understand that every new breakthrough relies on trust—trust in material purity, consistency, and openness. That trust is built one shipment, one batch, and one partnership at a time.

    If your process or product design explores new uses for C6 intermediates, our production and technical teams are always prepared to discuss challenges and support your next project. From our vantage point, making 2-Hexene is about more than supply—it's about production knowledge, responsibility, and a commitment to improving each part of the value chain it touches.
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