Products

2,2'-Azobisisobutyronitrile

    • Product Name: 2,2'-Azobisisobutyronitrile
    • Alias: AIBN
    • Einecs: 208-915-9
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications
    HS Code 134653
    Cas Number 78-67-1
    Molecular Formula C8H12N4
    Molecular Weight 164.21 g/mol
    Appearance White to pale yellow crystalline powder
    Melting Point 99-103 °C
    Boiling Point Decomposes before boiling
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in alcohol, acetone, ether, and chloroform
    Density 1.1 g/cm³
    Odor Odorless or faint
    Main Use Polymerization initiator

    As an accredited 2,2'-Azobisisobutyronitrile factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 500g amber glass bottle with a tightly sealed cap, labeled "2,2'-Azobisisobutyronitrile," hazard symbols, and handling instructions.
    Shipping 2,2'-Azobisisobutyronitrile (AIBN) should be shipped as a hazardous material due to its flammability and explosive properties. It must be packaged in tightly sealed containers, kept cool and dry, and away from sources of heat or ignition. Follow all relevant regulations for transport of dangerous goods, including proper labeling.
    Storage 2,2'-Azobisisobutyronitrile (AIBN) should be stored in a cool, dry, and well-ventilated area, away from heat, sparks, open flames, and incompatible substances such as acids and oxidizers. Store in a tightly closed container, protected from light. Refrigeration (2–8°C) is recommended to prevent decomposition, as AIBN is sensitive to heat and may explosively decompose upon warming.
    Application of 2,2'-Azobisisobutyronitrile

    Applications of 2,2'-Azobisisobutyronitrile in Industrial Manufacturing

    2,2'-Azobisisobutyronitrile (AIBN) serves as a critical initiator in several polymerization and specialty chemical processes. We supply AIBN in grades and packaging suitable for integration into regulated industrial environments, aligning with the requirements of manufacturers producing batch and continuous-process products worldwide. The following scenarios exemplify genuine, large-scale industrial uses focusing on essential compliance, process, and formulation details.

    1. Acrylic Polymer Resin Production

    Acrylic resin manufacturers rely on AIBN as a high-efficiency free-radical initiator during the polymerization of methyl methacrylate and related acrylate monomers. This allows precise control of polymer architecture, which is critical for downstream applications such as automotive coatings and adhesive binders. Integration occurs in strictly controlled environments, with dosing adjusted to meet specific chain length and molecular weight targets. Formulators must balance regulatory requirements with production efficiency, especially when manufacturing resins for demanding industrial and OEM end uses.

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    2. Polyvinyl Chloride (PVC) Suspension Polymerization

    PVC manufacturers use AIBN as an essential free-radical source in suspension polymerization, typically for specialty and heat-resistant PVC grades where peroxide initiators introduce unwanted impurities. The initiator enters the aqueous phase under rigid process monitoring, ensuring fast startup and narrow particle size distribution. Process engineers adjust the AIBN feed to reflect vinyl chloride conversion rates and plant capacity, with critical attention to compliance for pressure, emissions, and residual monomer levels.

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    3. Styrene-Based Copolymer Manufacturing

    Styrenic polymers, including ABS (acrylonitrile butadiene styrene), SAN (styrene acrylonitrile), and HIPS (high-impact polystyrene), integrate AIBN in both emulsion and mass polymerization routes, particularly when thermal stability and uniform initiator half-life are crucial. Operators add the initiator post-emulsification or continuously feed during polymer build-up phases to drive conversion and maintain gloss and physical properties demanded in appliance housings and consumer electronics. Plant QC teams closely monitor residuals and decomposition byproducts for final product certification.

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    4. Organic Synthesis – Foaming Agent in Polymer Production

    AIBN finds repeated use as a precision nitrogen-releasing blowing agent in closed-cell foam manufacture, particularly with PVC plastisols and unsaturated polyester/fiberglass composite panels. Here, decomposition delivers pores or microcellular structures, imparting low density, improved insulation, and surface finish. Process parameters and initiator quality directly affect bubble size and distribution, impacting end-user functionality such as flooring underlayments or specialty gasketing. Strict feeding controls and post-processing ensure compliance with safety and residual volatility controls.

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    5. Radical Initiation in Polymer Bead Manufacturing (Expandable Polystyrene)

    Producers of expandable polystyrene (EPS) beads incorporate AIBN into suspension polymerization to favor a uniform cell structure and high expandability, critical for thermal insulation and packaging foam markets. The initiator’s thermal profile enables sharp control of bead expansion rates during both polymerization and downstream pre-expansion processes. Monitoring of dosing and initiator decomposition supports plant safety protocols and prevents off-spec batches, which are crucial factors for large-volume EPS molders.

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    6. Synthesis of Specialty Acrylonitrile Copolymers

    Manufacturers of nitrile-based specialty copolymers, such as nitrile rubber (NBR) and high-barrier packaging materials, use AIBN to initiate solution or emulsion polymerization with tight control over molecular microstructure. Accurate initiator metering and process sequencing enable formulators to fine-tune chemical resistance, flexibility, and barrier properties for performance in automotive, gaskets, and FDA-approved food packaging. Comprehensive compliance and analytical monitoring backstop each production lot shipped.

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    Certification & Compliance
    More Introduction

    Introducing 2,2'-Azobisisobutyronitrile: A Reliable Choice from Our Production Lines

    What 2,2'-Azobisisobutyronitrile Means to Chemical Manufacturing

    In our plant, 2,2'-Azobisisobutyronitrile—often called AIBN—ranks among the most dependable initiators for free-radical polymerization processes. Over decades, our engineers and quality teams have seen AIBN stand up to the daily challenges of making everything from acrylic resins to specialty plastics. Its model—sometimes referred to in short as AIBN or by its CAS number 78-67-1—represents much more than a line item on a data sheet. Each batch produced requires control, knowledge, and an unwavering attention to purity.

    When we talk about specifications, we mean real performance, not paperwork. Anyone placing demands on the consistency of a product like this knows that a slight impurity or moisture content can skew an entire day’s work in the polymerization reactor. Typical material from our lines consistently achieves purities above 99%, with water content below 0.2%. In real-world terms, this means smoother operations, reduced risk of runaway reactions, and far less downtime due to quality issues in the downstream process.

    The Role of AIBN in Polymerization

    Large-scale polymer manufacturing runs on dependable reaction starters. AIBN has established itself as a backbone product in this field. It’s no secret why—our own operators have worked side-by-side with AIBN for years when producing acrylic fibers, PVC, and ABS plastics. The decomposition temperature of AIBN may seem like a minor technical detail for outsiders, but for the people on the floor, it’s central. At 64°C, it begins releasing nitrogen and generating free radicals at a predictable rate, which is exactly what’s needed for controlled polymerization.

    The way AIBN decomposes avoids some of the sensitivity problems that come with other initiators. Benzoyl peroxide, for instance, can pose hazards from its higher sensitivity to mechanical impact. Compared to that, AIBN offers our team a measure of safety and confidence during weighing, mixing, and feeding. It also emits virtually no offensive odors, making life easier for those in the production hall.

    What Makes Our AIBN Stand Out

    Experience has taught us time and time again that manufacturers care about two things: a product that works exactly as expected, and a partner who recognizes the cost of downtime and batch losses. The process we’ve refined over years does not stop at making a molecule—it’s about delivering real, tangible trust in each drum or bag we send out.

    We don’t cut corners. Every shipment of AIBN out of our facility has met strict impurity profiles confirmed by chromatography and wet chemistry. It’s an approach shaped by listening to feedback from polymer producers, paint manufacturers, and researchers in advanced coating labs. They look closely at decomposition rate data, solubility in various monomers, and fine margins in particle size when working with dispersions. We tailor our process around this real-world input, not just industry norms.

    Everyday Applications: From Labs to Large-Scale Plants

    Acrylic sheets, nitrile rubber gaskets, synthetic adhesives, emulsion polymers—these everyday products all trace back to AIBN-initiated reactions at some stage. Most people only see the end product, but anyone involved in the supply side knows that a steady, clean, and consistent feed of AIBN keeps a long chain of manufacturing ticking.

    A common sight at our facility is technicians loading AIBN into a slurry reactor, carefully weighing the dose to match a new batch order. In emulsion polymerization, small deviations in initiation rates ripple down to product performance—be it tackiness of a pressure-sensitive adhesive or flexibility in a weather-sealing strip. Our own direct customer feedback says that smoother polymer chains, higher yields, and fewer complications with chain transfer agents all result from predictable, pure AIBN.

    Sometimes labs need only a few grams for a pilot test. We have research teams from universities and specialty plastics firms nearby, and their requirements shape a part of our process too. They look for a fine, free-flowing powder that dissolves rapidly, and our formulation team has perfected the conditions to deliver that in both small and bulk quantities. No excess dust, no clumping—even after weeks in our standard industrial packaging.

    How Our Teams Address Industry Challenges

    Polymer plants face growing demands for greener processes and safer chemicals. Our developers pay attention to solvent compatibility and residuals. AIBN leaves no heavy metal contamination, no significant side products—a key difference from redox initiators or other organic peroxides. Many polymerization plants face mounting scrutiny over possible contaminants carried by their starter chemicals. With AIBN, the byproducts break down mainly to nitrogen and small organic fragments, making waste handling easier.

    We see environmental and regulatory pressures up close. For instance, the push to remove hazardous substances from PVC production has made AIBN’s reliable and non-chlorinated formula even more attractive to many long-time partners. The simplicity and relative cleanliness of its decomposition profile reduce worries in countries with tight VOC or emission controls.

    On the occupational safety front, our line leads never forget the hazards of finely powdered chemicals. Each AIBN lot passes through anti-static handling areas and is packed under controlled dust conditions. Training for our operators focuses on safe storage, avoiding temperature spikes, and clear labeling—not just to comply with global standards, but because safety incidents cost time, money, and trust. We set up every corner of our plant so accidental mixing with incompatible organics remains a remote possibility.

    Strength in Consistency, Season by Season

    Chemical manufacturing isn’t just about molecules—it’s about delivering the same standard time after time, year in and year out. Some polymerization processes switch monomers as needs change. Reliability in initiator quality keeps processes nimble and on schedule. Our own production planners talk with customer counterparts, comparing results from winter to summer, before and after a humidity spike, checking for unexpected delays or trouble in polymer growth rates. This feedback cycle keeps us improving, batch after batch.

    The practical differences between AIBN and alternative initiators play out every day. Peroxides like methyl ethyl ketone peroxide or dicumyl peroxide often need much more careful temperature management. They also bring unpleasant odors and greater storage limitations. From our plant’s perspective, moving to AIBN means less risk and greater flexibility for customers, especially in settings short on space or advanced safety infrastructure. We routinely hear from customers switching away from peroxides simply to minimize irritation for line workers or to avoid compliance headaches with flammable storage restrictions.

    Practical Specification Matters

    We make our AIBN powder with particle sizes optimized for even distribution in solvent and aqueous systems. Anyone running a large reactor knows the pain points: clumping powders that create hot spots, or fine dusts that mess with feeding rates. Sticking close to a consistent mesh size in production prevents dosing fluctuations and improves polymer chain length control. Feedback from adhesive and resin makers led us to refine our drying steps to minimize agglomeration, so feeding into high-throughput lines goes as smoothly as possible.

    Moisture sensitivity stands out as a real-world issue. Any water in the batch can trigger premature decomposition—an expensive mistake for any operator. Our storage and packing always keep ambient moisture below the limit. We use sealed, inert-lined bags or drums and tightly monitor warehouse climate through both sensors and routine physical checks. Our teams accept no shortcuts, because a single compromised lot can ruin days of finished product and trust built up over years.

    Quality Assurance as a Built-in Value, Not Just a Promise

    QA isn’t a last-minute hurdle for us. Every operator and technician from our lines upholds a culture that started with our earliest batches. Each shipment gets tracked from raw material acceptance through every key stage—nitrile feedstock supplies, temperature charts for critical crystallization points, final batch testing via rapid microanalysis. We record and review these numbers because it’s what lets us see, almost at a glance, if a deviation is present. We don’t just sign off on specs; we act on critical trends before a batch ever leaves the floor.

    Batch-to-batch consistency defines our working relationships with customers. Adjusting polymer recipes is a costly process; keeping AIBN predictable removes unnecessary variables and lets process engineers focus on improvements rather than firefighting. We view ourselves as part of the supply chain, not just the origin of raw chemistry, and we hear the difference it makes when fewer surprises crop up during continuous or semi-batch runs.

    What Sets AIBN Apart from Other Initiators

    Many initiators have their moment—dilauroyl peroxide, potassium persulfate, tert-butyl peroctoate—but AIBN’s profile strikes a balance between performance, longevity, and shelf stability. Customers mention that after long transportation or storage, AIBN rarely degrades or becomes less effective, unlike some liquid peroxides that deteriorate if left in poorly controlled conditions. Our QA team inspects every incoming review or incident report for signs of caking, dusting, or off-odor. Any flagged batch is rechecked, no exceptions.

    Downstream users working with latex, acrylonitrile-butadiene copolymers, or special effect coatings often demand strict reactivity profiles. The relatively sharp initiation temperature and low residue formation make AIBN a pragmatic default for many. Certain peroxides, as our customers have reminded us during technical visits, can introduce side-chain end groups leading to product yellowing or inconsistent curing. We’ve watched how switching to AIBN cleans up the end result, particularly in transparent or color-sensitive compounds.

    Ongoing Improvements: Driven by Real-World Needs

    Technical support means honest dialogue. Our R&D group regularly reviews both long-term trends and sudden process interruptions on the customer side. Adjustments—like tweaking crystallization rates to cut fines and dust, or reviewing anti-static packaging performance—often begin as issues in the field. Years of blending production knowledge, customer input, and root-cause investigations have gradually pushed the reliability and usability of our AIBN forward.

    Recently, some high-throughput elastomer facilities asked us to develop a lower-dust AIBN for automated dispensing. Our engineers built new procedures focusing on grain structure and packing density. The challenge reminded us that real improvement comes from listening and adapting. Today, we ship both standard and specialty grades based on these lessons, and we always keep an ear out for more.

    At the same time, regulatory demands never stand still. Our compliance team constantly evaluates updates in workplace exposure limits, chemical transport rules, and product stewardship issues. Rather than react late, we build monitoring into our lot release process. As restrictions tighten, especially in European and North American markets, having clear, documented impurity profiles lets our customers avoid last-minute compliance headaches. We use this data to make decisions, not just fill out paperwork.

    Supporting Innovation and Reliable Production

    Aviation resins, medical plastics, UV-curable inks—these are markets where every technical detail counts. Research teams tell us that volatile, unpredictable initiator quality slows down new product launches. Our AIBN has been part of countless scaling projects, moving lab concepts to commercial runs. The goal remains the same: keep confidence high and troubleshooting to a minimum.

    Some startups and specialty producers experiment with blends of AIBN and other initiators to fine-tune reaction rates. Our technical partners ask for data—on heat evolution, pressure spikes, even long-term color retention. We provide full background analytics, not just certificates, to speed up troubleshooting. By staying in direct conversation with end users, and in some cases, running custom reactions in our pilot facility, we gain insights that feed back into every step of our larger-scale process.

    We make it policy to remain open to joint trials, confidential feedback, and collaborative process improvements. Many of our best process improvements started as off-the-record comments from teams facing production bottlenecks halfway across the world. We share lessons as freely as logistics allow, always working to keep materials, technical resources, and people moving in sync.

    Looking Forward: Purpose Beyond Production

    Our reputation relies on every shipment meeting safe handling, long shelf life, and minimal disruption. Modern supply chains cross borders and time zones. As a chemical manufacturer, we see our work as foundational—every particle of AIBN that leaves our site carries this expectation. Our teams feel the weight of that responsibility with every order filled. People trust us for more than a specification; they trust us not to set back their own production, reputation, or safety records.

    Continuous process review, worker safety, compliance vigilance, and open partnerships with customers keep us ahead of changes in both industry trends and regulatory requirements. Consistency, rigor, and humility in the face of everyday challenges drive our improvements and motivate our team to keep pushing standards higher, one batch at a time.

    Ultimately, AIBN stands as more than just a chemical initiator for free-radical polymerization. For us, it’s a benchmark of reliability—a product shaped not only by chemistry, but by decades of trust, collaborative improvement, and a culture that values every feedback, every lesson learned, and every relationship built along the way.

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