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HS Code |
578278 |
| Name | 1,2-Phenylenediamine |
| Other Names | o-Phenylenediamine |
| Chemical Formula | C6H8N2 |
| Molecular Weight | 108.14 g/mol |
| Cas Number | 95-54-5 |
| Appearance | Grayish to purple crystalline solid |
| Melting Point | 102-104°C |
| Boiling Point | 256°C |
| Density | 1.209 g/cm³ |
| Solubility In Water | Soluble |
| Odor | Faint aromatic amine-like |
| Pka | 0.77 (first), 6.71 (second) |
| Flash Point | 150°C |
| Vapor Pressure | 0.016 mmHg (25°C) |
| Ec Number | 202-430-6 |
As an accredited 1,2-Phenylenediamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | 1,2-Phenylenediamine is packaged in a 500g amber glass bottle with a secure screw cap and clear hazard labeling. |
| Shipping | **1,2-Phenylenediamine** must be shipped as a hazardous material, following regulations for toxic substances. Packaging should be tightly sealed, clearly labeled, and compatible with the chemical. Transport in a cool, dry, well-ventilated environment. Comply with relevant international (UN 2239), local, and carrier-specific guidelines for safe handling and documentation. |
| Storage | 1,2-Phenylenediamine should be stored in a tightly closed container, in a cool, dry, and well-ventilated area, away from incompatibles such as strong oxidizers, acids, and bases. Protect it from light and moisture, and store away from sources of ignition. Ensure proper labeling and keep it in a designated hazardous chemicals storage area, following local regulations and safety guidelines. |
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Purity 99%: 1,2-Phenylenediamine with purity 99% is used in the synthesis of polymer stabilizers, where it provides enhanced antioxidative protection. Melting Point 104°C: 1,2-Phenylenediamine with a melting point of 104°C is used in dye manufacturing, where it offers precise color yield control. Particle Size ≤ 50 µm: 1,2-Phenylenediamine with particle size ≤ 50 µm is used in pharmaceutical intermediates production, where it ensures rapid and uniform reaction rates. Stability Temperature up to 120°C: 1,2-Phenylenediamine with stability temperature up to 120°C is used in rubber chemical synthesis, where it maintains reactivity under elevated processing conditions. Moisture Content ≤ 0.3%: 1,2-Phenylenediamine with moisture content ≤ 0.3% is used in the formulation of epoxy resin curing agents, where it improves cross-linking efficiency. Molecular Weight 108.14 g/mol: 1,2-Phenylenediamine with molecular weight 108.14 g/mol is used in agrochemical production, where it ensures predictable formulation performance. High Purity Grade: 1,2-Phenylenediamine high purity grade is used in electronics industry processes, where it reduces impurity-driven defects in conducting polymers. |
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Every year, we produce tons of 1,2-Phenylenediamine, a compound that has become essential in both specialty and bulk chemistry applications. Having worked hands-on in chemical manufacturing for decades, my team and I have witnessed the unique traits and challenges that this aromatic diamine brings to the table compared to related substances. We see it moving the wheels for dye synthesis, rubber chemical manufacturing, photography development, and organic intermediates. Even a modest improvement in quality parameters can shift outcomes for our clients downstream, which keeps us invested in high-precision processes and constant product feedback.
Structurally, 1,2-Phenylenediamine stands out as a benzene ring adorned with two amino groups in the ortho position. This seemingly simple arrangement is what sets it apart from para- or meta-phenylenediamines, as well as other aromatic amines. The proximity of the amino groups influences both the reactivity and the color characteristics when used in different synthetic routes. We manufacture it primarily as a technical grade crystalline powder with a purity that consistently hits targets above 99%. In our plant, we prevent common contaminants through multi-stage purification. Any deviation leaves a mark on color strength and consistency in clients’ end applications, from dyes to aerospace composites.
Many sources offer standard grades, but not all meet the demand for high consistency across timescales and lots. We don’t only control input materials with batch certificates; we regularly audit suppliers for aniline and ortho nitrochlorobenzene so that the precursor stream remains reliable. The final product’s pale rose crystals or tan crystals signal the degree of purity and trace impurities. We frequently get feedback from synthetic dye manufacturers: any stray trace of tar or residual solvents can cause color shifts. People rely on us to ensure every batch is visually and analytically consistent. Our internal batches usually yield a melting point of 102-104°C. Moisture, ash, and residue analysis get included in our outgoing reports because this data gives real assurance to formulators relying on repeat results without batch-to-batch recalibration.
In industrial and specialty chemistry, it’s tempting to group all phenylenediamines together—after all, there’s 1,3-phenylenediamine (meta), and 1,4-phenylenediamine (para) sitting right beside our 1,2 isomer. Our experience challenges this shortcut. The ortho isomer behaves differently under oxidizing conditions, showing more rapid coupling reactions, which matters a lot if someone is synthesizing hair dyes, antioxidants, or certain heterocycles. Para-isomers are more commonly used in rubber antioxidants and cosmetics. Our customers often share that only the 1,2 compound gives the depth of hue or molecular branching they desire in triazole or benzotriazole intermediates. Structural nuances drive the outcome in azo dye development, affecting purity, persistence, and shelf life.
We’ve also found the smell and handling characteristics shift notably with the ortho compound. The amine “bite” and fugitive odor is more pungent, leading us to invest in local ventilation and handling controls on our own plant floor. Cross contamination across isomer lines can lead to unpredictable byproducts, so we keep dedicated lines and vessels for this stream. The ortho isomer also forms chelates and complexes more readily, which is both an advantage and a liability depending on the client’s needs. Our direct manufacturing experience is what lets us work with our customers to tune purity, particle size, and control metal traces when certain textile dyes or photographic developers need low background interference.
Dye and pigment companies take up the lion’s share of our output. Ortho-phenylenediamine forms the backbone of many blue and black dyes, especially where resistance to washing and fading is vital. Early feedback from the textile sector brought us to tune crystal size and check for residual solvents, as even small variances impact dye uptake and fastness. We’ve supplied product for ink manufacturers, who need a homogenous feedstock with stable shade intensity.
In the rubber industry, use patterns are different. Minor impurities alter the antioxidant profile, especially in high-performance or heat-cured elastomers. We keep a close watch over residual aldehydes and other byproducts, knowing that off-note chemistry can trigger premature aging in tires and belts. Photographic chemical producers have also come to rely on our 1,2-Phenylenediamine; this is due to its clean oxidative coupling behavior that brings out precise image tones and developing speeds. That feedback pushed our quality team to certify every batch on spectrophotometric endpoints before it heads out the door.
Outside those highlighted uses, we also ship to agencies and labs producing benzotriazole and similar specialty intermediates. The selectivity of 1,2-Phenylenediamine in these syntheses tracks with their need for purity, so we often collaborate directly with R&D teams on custom prep runs and unique lots. That’s an advantage direct production brings—any variation or unplanned impurity gets picked up immediately by our internal team, not left for resellers to puzzle over.
Direct manufacturing exposes us to the practical side of scale-up and regulatory shifts. Many clients navigating REACH or TSCA compliance ask for full traceability and impurity breakdowns. We document every major processing step, from aniline sourcing to drying protocol, and give clients thorough batch analytics. The majority of requests revolve around minimizing non-target isomers and tracking down residuals of o-chloroaniline or nitro species. This helps end users satisfy increasingly tough material disclosure regulations. We’ve learned not to treat these data requests as separate from the core offering but as integral to the value we can add as a direct producer.
Safety management and training reflect what’s needed for an aromatic diamine—exposure limits are stringent, and the compound’s toxicity means that plant floor procedures focus on physical containment and fast spill response. Long-term experience has taught us that hand-off with logistics and transport partners should include detailed site-specific training, as minor handling errors at a distribution point can lead to odors or unexpected reactivity. We still review and refresh safe-work protocols after visible lessons: one incident with moisture condensation inside a railcar spurred us to design drier handling bays and install vapor-recovery units outside our loading station.
Disposal and environmental emissions also continue to occupy us. Aromatic amines tend to persist in the environment, bioaccumulate, and show up in wastewater tests. Our direct control over waste streams lets us use multi-stage scrubbers, activated carbon beds, and quick pH neutralization, keeping us clear of local limits and audits. We’ve responded to community and regulatory pushback not with mere paperwork but by physically upgrading our water and air handling, cutting aromatic releases in both visible discharge and trace emissions. For customers downstream, this track record signals a reliability that’s not evident from generic spec sheets traded across online platforms.
Markets keep shifting. Increasing demand for specialty colorants in electronics, LEDs, and high-performance plastics has led to more scrutiny from tech sector buyers. Quality For lower impurity requirements, our team uses additional chromatographic and spectrographic analysis for contaminant tracking. Sometimes, end users need a slightly altered form: large granular lots for automated feeding systems, or ultra-fine powder for rapid solubility. As a direct manufacturer, we cut lag time and guesswork by handling these modifications ourselves, with plant engineers and QA specialists signing off before each custom lot enters full production.
In closer engagement with customers aiming for “green” dyes, we receive requests for “traceable-synthesis” batches, where every input, energy-wash step, and transport node must have a documented environmental impact score. In recent years, we’ve shifted to more energy-efficient reactors and solvent recycle protocols, and these changes show in both our safety profile and downstream cost structure. Customers want assurance that the same lot they qualify today will match a repeat order for years, and this stability only comes from manufacturing with in-plant oversight. Without direct control, minor deviations in drum headspace, crystallization rates, or filter type may slip in, affecting reactivity and purity.
One unique value in modern markets is the technical assistance we provide after delivery. Because we know all processing conditions and compositional subtleties, we can trace any odd reaction or color behavior back to the production choices made two or three months prior. Customers experimenting with niche polymers or next-generation dyes often reach out for root-cause troubleshooting. That level of responsiveness and transparency is only possible with direct manufacturing context—third-party traders usually lack records or firsthand access to production history.
We never consider transport and storage logistics an afterthought. 1,2-Phenylenediamine is sensitive to moisture, high heat, and oxygen, making long-haul shipping a logistical balancing act. Our loading crew uses lined drums and inert gas purging to keep product quality stable during movement, reducing oxygen pickup and humidity adsorption. Field reports from downstream distributors back up our real-world experience: simple packaging choices—such as switching from fiber drums to steel containers with gasketed liners—can drastically improve shelf life and prevent off-odor or caking.
Recent global volatility in transportation has hammered home how just-in-time delivery models work better for smaller volume chemicals but expose bulk shipments to delay risk. Some clients still gamble on offshore resins or intermediates, only to come back to local direct manufacturers with demands for fast turnaround and high lot integrity. For us, strategic inventory and controlled lot segregation is not just risk mitigation—it’s product stewardship. During congested port scenarios, we’ve flown in replacement material at cost to keep customers’ synthesis schedules rolling, reinforcing our long-term partnerships.
Every shift in formulation or regulatory climate brings new requests. Sometimes, the need is high-percentage purity; other times, low-dust granules for automated handling minimize operator exposure on the customer’s side. Our plant runs pilot batches tailored to those asks, and we adjust crystallization or drying parameters based on actual process feedback from end users, not hypothetical “industry standards.” We see competitors who focus on cutting corners—diluted input streams, lighter regulatory coverage, warehouse reblending—lose credibility when customers face discordant performance between orders. Direct manufacturing accountability lets us guarantee traceability, batch reliability, and quick problem resolution.
Longtime clients appreciate the continuity our direct production enables. They know the faces in our quality lab and have direct channels into technical support. New challenges, such as legislative changes around aromatic amines or shifting workplace exposure limits, don’t catch us flat-footed. Instead, we initiate process changes right away, update our safety data, and communicate those changes directly to the supply chain. Open collaboration on formulation changes and proactive documentation satisfy the rising bar regulators and multinationals demand for transparency across supply chains.
Supply chains change, customer expectations rise, and compliance rules get more demanding every year. Having direct manufacturing control over 1,2-Phenylenediamine means everything from purity to technical assistance stays in our hands, not lost across layers of intermediaries. Every day our operations shape and are shaped by those working on the frontlines of pigment, additives, and polymer innovation. This creates advantages for our customers, from clear batch records to tailored process tweaks that only a fully integrated producer can provide.
Feedback drives our plant upgrades, and transparent communication with clients pushes us to higher standards—whether for environmental compliance, technical support, or custom product specs. The reliability, flexibility, and partnership that direct production allows are the foundation for long-term supply and cooperative problem-solving. For those choosing a source for 1,2-Phenylenediamine, it helps to know not just what the product is, but how and where it’s made, and the mindset holding the production line together.