Products

1,2,4-Trichlorobenzene

    • Product Name: 1,2,4-Trichlorobenzene
    • Alias: 1,2,4-Trichlorobenzol
    • Einecs: 204-429-6
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    931971

    Cas Number 120-82-1
    Molecular Formula C6H3Cl3
    Molar Mass 181.45 g/mol
    Appearance Colorless to pale yellow liquid
    Melting Point 17 °C
    Boiling Point 213 °C
    Density 1.45 g/cm3 (20 °C)
    Solubility In Water Insoluble
    Vapor Pressure 0.46 mmHg (25 °C)
    Flash Point 93 °C (closed cup)
    Odor Aromatic
    Autoignition Temperature 605 °C

    As an accredited 1,2,4-Trichlorobenzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,2,4-Trichlorobenzene is supplied in a 500 mL amber glass bottle with a secure screw cap, labeled with hazard warnings.
    Shipping **1,2,4-Trichlorobenzene** should be shipped in tightly sealed, corrosion-resistant containers. It must be labeled as a hazardous material and transported in accordance with local, national, and international regulations. Avoid exposure to heat and moisture. Ensure containers are upright and secure during transit to prevent leaks and spills.
    Storage 1,2,4-Trichlorobenzene should be stored in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and incompatible materials such as strong oxidizers. Keep the container tightly closed and properly labeled. Use corrosion-resistant containers and store away from food and drink. Avoid sources of ignition, as the chemical is flammable. Ensure appropriate spill containment measures are in place.
    Application of 1,2,4-Trichlorobenzene

    Applications of 1,2,4-Trichlorobenzene in Industrial Manufacturing

    1,2,4-Trichlorobenzene serves critical roles across select chemical production sectors, supporting process chemistry where specific halogenated aromatic intermediates are indispensable. As a direct manufacturer, we focus exclusively on established, verified downstream channels where this material is essential for product quality and operational throughput. The following sections detail key industrial scenarios based on actual end-use integration.

    1. Dye and Pigment Intermediate Synthesis

    In the dye and pigment industry, 1,2,4-Trichlorobenzene functions as a vital chlorination agent and as a solvent in the synthesis of various azo and anthraquinone dyes. Its specific reactivity profile allows downstream producers to achieve high purity levels in target chromophores, supporting vibrant color development and stability for textile and coatings applications. Its consistent composition helps manufacturers manage batch variability and avoid process disruptions during sulfonation and coupling reactions.

    Industry compliance standards

    • REACH Annex XVII (EU)
    • OEKO-TEX Standard 100 (for restricted substances in textile dyeing)
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • GB/T 23975-2009 (PRC: Testing Methods of Dyestuff Intermediates)

    Typical usage ratio

    • Acts as a chlorinating solvent or reaction medium at 8–20% w/w relative to target intermediate mass, adjusted for solubility and process temperature

    Downstream process integration

    • Charged directly to reaction vessel during initial coupling, halogenation, or condensation steps of dye precursor synthesis; subsequently removed by distillation

    Final product types

    • Reactive dyes for cotton fabrics
    • Disperse dyes for polyester
    • Pigment intermediates for coatings and printing ink formulations

    2. Agrochemical Synthesis (Herbicide and Pesticide Intermediates)

    Producers of phenoxy herbicides and certain insecticides rely on 1,2,4-Trichlorobenzene as a halogen-rich solvent and process medium for condensation and nucleophilic substitution reactions. Its ability to dissolve multiple aromatic and chlorine-containing substrates enables high-yield syntheses of key intermediates, such as dichlorophenol derivatives and triazole precursors, with minimal byproduct formation and supported downstream crystallization efficiency.

    Industry compliance standards

    • FAO/WHO JMPR (Joint Meeting on Pesticide Residues) guidance for technical grade material
    • ISO 9001:2015 for agrochemical manufacturing quality
    • EPA 40 CFR Part 158 (US, pesticide active ingredient registration requirements)
    • GB 33886-2017 (PRC: Maximum residue limits for pesticides in food)

    Typical usage ratio

    • Employed at 10–18% w/w as solvent or diluent relative to total batch mass, depending on solubility of target molecules and target reaction kinetics

    Downstream process integration

    • Added before reflux or controlled-temperature grinding to optimize solubility and reactivity, then recovered for recycling after crystallization of the desired active agrochemical ingredient

    Final product types

    • Phenoxy herbicide technical concentrates
    • Triazole and benzoylurea insecticide intermediates
    • Fungicide active substance intermediates

    3. Polymer Additive Manufacturing (Heat Transfer Media)

    Polymer process plants employ 1,2,4-Trichlorobenzene as a reference solvent for intrinsic viscosity measurement and molecular weight characterization of polyesters (such as PET), as well as a high-boiling heat transfer medium. Its thermal stability and solvency parameters ensure reproducible viscometric analysis under QC protocols, supporting consistent polymer property assessment leading to more reliable film, fiber, and resin production with tighter control over melt flow index and end-use mechanical strength.

    Industry compliance standards

    • ASTM D4603 (Determination of Intrinsic Viscosity of PET by Solution Viscometry)
    • ISO 1628-5 (Plastics — Determination of viscosity number and limiting viscosity number)
    • FDA 21 CFR 177.1630 (Indirect food contact for PET)
    • ISO 9001 for laboratory quality management

    Typical usage ratio

    • Used at a solvent-to-polymer mass ratio of 30:1 to 40:1 for analytical dissolution; for heat transfer purposes, circulated neat or as a primary component in closed-loop systems

    Downstream process integration

    • Applied during laboratory or in-process QC viscometric analysis, with spent solvent reclaimed post-test; utilized in jacketed reactor systems during polymerization for uniform heat distribution

    Final product types

    • Polyethylene terephthalate (PET) resin for bottle and film production
    • Polyester fibers for textiles and industrial applications
    • High-strength engineering plastic feedstock

    4. Chemical Processing Solvent for Halogenated Aromatic Compounds

    Producers of specialty chlorinated aromatics use 1,2,4-Trichlorobenzene as a selective crystallization medium or reaction solvent in multi-stage halogenation, necessary for manufacturing compounds used in electronic, lubricant, and plasticizer industries. Its low water solubility, high boiling point, and chemical inertness under controlled conditions allow downstream operators to optimize isolation of products such as tetrachlorobenzenes and other high-purity chemical building blocks.

    Industry compliance standards

    • EN ISO 9001:2015 for chemical process management
    • Responsible Care standards (chemical industry code of practice)
    • TDS and MSDS verification per regional regulatory requirements (REACH, TSCA)
    • Specific internal SOPs for crystallization and purification

    Typical usage ratio

    • 1,2,4-Trichlorobenzene used as the principal solvent at 20–35% of total batch volume; ratio refined based on solubility data for individual downstream aromatic products

    Downstream process integration

    • Solvent charged at the crystallization or reflux stage to control nucleation, followed by solvent exchange or distillation; designed for closed-loop solvent recovery on plant scale

    Final product types

    • Tetrachlorobenzene for high-end lubricant additives
    • Specialty halogenated intermediates for electronic chemicals
    • Additives for high-temperature resins and adhesives

    Free Quote

    Competitive 1,2,4-Trichlorobenzene prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615365186327 or mail to admin@ascent-chem.com.

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    Email: admin@ascent-chem.com

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    Certification & Compliance
    More Introduction

    1,2,4-Trichlorobenzene: Manufacturer’s Perspective on Reliable Quality and Industry Value

    Our Story with 1,2,4-Trichlorobenzene

    In our plants, we have made and moved countless batches of 1,2,4-trichlorobenzene over the decades. Many customers still ask the same questions about why they should trust a local manufacturer over a trader, or what makes our process worth seeking out. Let’s talk about what sets this material apart and what that means for everyday operations, right on the factory floor and in application work.

    What Makes 1,2,4-Trichlorobenzene Tick?

    1,2,4-Trichlorobenzene is a clear, colorless liquid with a characteristic aromatic odor. On our lines, we have found the consistency of the material defines its quality—every batch must meet strict purity thresholds to deliver the performance that customers expect. We control for purity greater than 99.5% by gas chromatography, because trace impurities and residues don’t just look bad on a spec sheet; they can gum up catalysts, create off-odors, or in some reactions undermine results outright.

    Our model 1,2,4-TCB hits several quality benchmarks from the first drums out of the reactor. Water content always stays under 300 ppm because higher moisture slows down downstream production, especially for customers in the dye and pesticide industries. We learned long ago that many end users rely on consistency batch-to-batch, because changes, even subtle ones, can throw off polymer yields or dye shade uniformity.

    Usage Borne of Real Industry Experience

    Multi-ton quantities of 1,2,4-trichlorobenzene roll off our sites every year, headed for uses in agrochemical intermediates, dye manufacture, and as a specialty solvent for heat transfer and degreasing. Through trials with partners, we know both the appeal and the challenges of handling chlorinated aromatics in scale-up and continuous operation. Many facilities use this compound as a carrier or reaction medium for making herbicides such as MCPA esters, or for solvents when processing certain copper phthalocyanine pigments.

    The boiling point of 214°C puts it in a sweet spot for high temperature solvent work; it withstands heat without breaking down or losing effectiveness. Over the years, dyestuff manufacturers have trusted 1,2,4-TCB for processing vat and disperse dyes. Those who purify and recrystallize difficult compounds count on its stable behavior, because temperature swings don’t suddenly shift its solvent power the way lower-boiling solvents can. We’ve watched solvent recovery systems run more efficiently with our trichlorobenzene, thanks to its thermal resilience and low volatility loss.

    Healthy Respect for Safety and Handling

    Factory veterans know it’s not all about chemical performance. Compatibility with plant practice, risk management, and safe transport matter just as much. Our 1,2,4-trichlorobenzene ships in mild steel drums, ISO tanks, or IBCs prepared to handle its slight corrosivity to some plastics and most rubbers if spills occur. Proper ventilation, cold storage, and PPE keep workers safe during sampling and transfer; procedures that have become second nature for us after years on the job.

    Over time, we have invested in closed-system transfer lines, vapor scrubbing, and vapor recovery units that reduce environmental emissions. Regulations in many countries classify chlorinated aromatics as hazardous, so we track every barrel closely and assist customers with compliance paperwork. Effective communication channels with environmental regulators and logistics providers allow us to anticipate client questions around handling, exposure, and waste disposal.

    Grading and Specifications: Why Purity Drives Performance

    We manufacture several grades of 1,2,4-trichlorobenzene. High-purity solvent grades suit industries requiring minimal organic residues—especially pharmaceutical intermediates and dye formulators. Technical grade works well for less purity-sensitive applications, such as heat transfer fluids or additive carriers. The key factors influencing performance remain crystal clear content, low water, absence of sulfur contaminants, and minimal ortho- or meta-isomer content.

    On our plant floors, instruments monitor not only overall GC area purity but track specific trace impurities. Dechlorination can occur with sloppy production, so we physically check every batch for low monochlorobenzene and dichlorobenzene levels. The worst that can happen is a failed downstream lot because a supplier skimped on process control. After seeing how even a trace contaminant can foul up a long reaction or show up in final product analysis, we’ve doubled down on inline analytics, operator training, and process audits.

    Comparing 1,2,4-Trichlorobenzene and Its Cousins

    Some buyers still struggle to understand the distinction between the three main trichlorobenzene isomers: 1,2,3-, 1,2,4-, and 1,3,5-. We field questions every season about substitution on short notice, or why a single digit in a catalog means so much in industrial consequences. The answer comes down to structure, process history, and intended use.

    1,2,4-Trichlorobenzene carries chlorine atoms at positions 1, 2, and 4 on the ring. This orientation provides certain solubility and reactivity advantages in manufacturing. For example, its solubility profile makes it less likely than 1,2,3- or 1,3,5- isomers to precipitate unwanted solids when acting as a carrier solvent for dyes or pharmaceuticals.

    We’ve also seen, through customer compliance audits, that 1,2,4-TCB is favored in formulating certain crop protection intermediates because of its easier separation and less byproduct formation. Its melting and boiling points suit many high heat and condensation reactions better than the other isomers, reducing batch cycle times for clients aiming for tight schedules.

    In heat transfer applications, performance hinges on thermal stability. 1,2,4-Trichlorobenzene outperforms other isomers tipping toward residue build-up or thermal decomposition at high temperature. Customers notice longer bath lives and cleaner heat exchanger tubes when using this compound straight from the drum, undiluted.

    From Lab to Ton-Scale: Process Wisdom and Supply Confidence

    Chlorination is rarely straightforward—small impurities creep in, yield fluctuates, and equipment fouling must be managed. Over decades, we have tuned conditions to maximize the preferred 1,2,4-isomer, suppressing 1,2,3- and 1,3,5- formation. Shortcuts or old equipment will invite isomeric and color impurities, risking downstream process failure for customers. We take nothing for granted, checking not just the main peaks but also background colors and lingering off-odors—signs of a poorly managed batch.

    We train technicians in the quirks of this chlorination process, because the difference between a well-run and a poorly-run batch can mean hours of filter cleaning or, worse, product returned from a frustrated client. Our reactors, distillation columns, and separation systems all trace back to persistent process optimization—never simply ‘set and forget’ chemistry. This attention bleeds through, from raw material selection through to logistics scheduling.

    We’ve learned processes must adapt to market and regulatory demands. Today, more downstream factories demand documentation on impurity profiles, batch traceability, and sustainable sourcing. By holding every step of the process in-house—from chlorination to fractionation to loading—we protect customer lines from surprises. Repeat clients, from South Asia to Eastern Europe, have told us they stick with our supply because they see fewer batch failures and surprise shutdowns.

    End-Use Applications and Practical Handling Insights

    Open communication with our regular buyers has taught us that plant shutdowns trace back more often to variable intermediate quality than to flashed equipment or power outages. 1,2,4-Trichlorobenzene’s uses remain concentrated in a handful of major industry segments: dye and pigment synthesis, certain herbicide and pesticide intermediates, and as a heat transfer agent in specialty situations.

    Dyestuff production workers tell us that our consistent solvent quality saves them from having to stop the process to skim off tarry residues or filter particulates. Copper phthalocyanine pigment producers benefit from our tight purity and low-ash process, avoiding color unevenness. One printing ink manufacturer shared how adopting a consistent grade from our line cut process waste by more than 10% over a year.

    For pesticide and agrochemical synthesis, knowing the precise isomer content means the difference between a workable intermediate and a batch that runs short on conversion or clogs glass-lined reactors. Several multinational agrochemical companies request compliance documents that detail this, and we provide those certificates batch-by-batch, not as an afterthought but as a routine in our quality process.

    Heat transfer system operators have praised our high-temperature stability when using 1,2,4-trichlorobenzene as a heat medium fluid. During regular summer load spikes, customers have reported fewer unplanned cleaning shutdowns and more stable fluid performance. These tangible outcomes grow from dozens of technical discussions, site visits, and a habit of listening to pain points from the floor rather than the front office.

    Environmental and Compliance Commitments Shaping Production

    Creating a trusted supply of 1,2,4-trichlorobenzene doesn’t end at the reactor. As governments tighten controls on emissions, process water, and chemical transport, our job shifts too. For years, our engineers have developed closed reactor systems that reduce fugitive emissions, while waste material flows toward on-site incineration and solvent recovery units instead of open dumping.

    International standards for hazardous goods have shaped our packaging, labeling, and transportation practices. Transporting chlorinated aromatics across borders brings extra scrutiny, so every outgoing lot matches the paperwork—from UN classification to MSDS on every shipment. We work with logistics contractors trained in the quirks of chlorinated solvents, and each batch is logged for traceability, often down to the hour and shift.

    Modern clients request documentation on environmental performance and residual toxicity. Our laboratories track and report not only on conventional purity and water, but also on dioxin and furan traces, VOC profiles, and residual heavy metal presence. If company labs or external auditors flag an issue, we proactively adjust upstream process controls. Experience has made us nimble, because regulatory shifts can come with little warning. Our philosophy: control every known variable, and document everything that could affect client safety or regulatory inquiries.

    Supporting Customers: Beyond Generic Product Delivery

    We don’t see ourselves as selling a simple chemical. Our technical teams field regular queries about process adaption, compatibility with other solvents, and responding to process upsets involving trichlorobenzene. Over time, we’ve built a technical support structure able to provide batch-level analytical data, troubleshooting input, and practical advice for new clients who move their first load of chlorinated benzene through unfamiliar reactors.

    Sometimes, a user reports color drift in a cyan pigment lot or a reduced reaction yield in a pesticide intermediate. Investigation usually traces back to process design or insufficiently pure feed solvents, not always the trichlorobenzene itself. Our support teams often hop on a call with plant floor operators, talking directly to the chemists—the ones in the field, not behind a desk—about stirring rates, filtration, and post-run recovery. This on-the-ground help wins trust faster than a thousand sales pitches.

    We’ve also learned that logistics reliability is as crucial as chemical quality. A shipment delayed at port or rejected on inspection can ripple through a client’s quarterly results. By working directly with freight partners and monitoring every batch up to final delivery, we help clients sidestep costly delays and keep their own lines moving.

    Our Experience, Your Assurance

    Experience has built our understanding of what makes 1,2,4-trichlorobenzene deliver value—and what can go wrong without careful control. We produce in-house, under the eyes of technicians and supervisors familiar with every nuance of our reactors. Hundreds of plant hours and dozens of product audits later, every drum of our material carries not just a barcode, but a set of lessons learned, improvements made, and customer feedback folded into the next batch.

    We keep improving, not out of habit, but out of necessity. The next regulation, the next efficiency push, or the next client’s request forces process upgrades. The chemical industry never really sits still, and neither do expectations for 1,2,4-trichlorobenzene. In labs, on plant floors, and in shipping yards, the real test comes from the hands that use our product every day.

    Our doors stay open to plant trials, audits, and customer visits for a simple reason: insight grows best from real discussion, not from generic claims. We have confidence in how we produce and support 1,2,4-trichlorobenzene, but we learn most from hearing your real-world feedback—so every batch that ships is not the end of the story, but the next step in refining our partnership.

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