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HS Code |
372035 |
| Product Name | Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate |
| Cas Number | 52499-14-6 |
| Molecular Formula | C18H28O3 |
| Molecular Weight | 292.41 |
| Appearance | White to off-white crystalline powder |
| Melting Point | 62-66 °C |
| Solubility | Slightly soluble in water, soluble in organic solvents |
| Purity | Typically ≥98% |
| Storage Conditions | Store at 2-8°C, protected from light and moisture |
| Synonyms | Methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate |
| Usage | Intermediate, antioxidant component |
As an accredited Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | The 25g amber glass bottle is tightly sealed, labeled with the chemical name, hazard information, and supplier logo for safe storage. |
| Shipping | Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate is typically shipped in tightly sealed containers under ambient conditions. It should be protected from light, moisture, and heat during transport. The packaging must comply with relevant chemical transportation regulations, and the material safety data sheet (MSDS) should accompany the shipment for safe handling and storage. |
| Storage | Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate should be stored in a tightly sealed container, protected from light and moisture, in a cool, dry, well-ventilated area. Keep away from sources of ignition, heat, and strong oxidizing agents. Recommended storage temperature is 2-8°C (refrigerator). Ensure proper labeling, and avoid prolonged exposure to air to prevent degradation. |
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Purity 99.5%: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate with purity 99.5% is used in polymer stabilization, where minimized degradation and enhanced material lifespan are achieved. Molecular Weight 320.48 g/mol: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate at molecular weight 320.48 g/mol is used in antioxidant formulations for plastics, where it imparts consistent free radical scavenging capability. Melting Point 52°C: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate with a melting point of 52°C is used in thermoplastic processing, where uniform dispersion and thermal processing efficiency are improved. Stability Temperature 200°C: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate at stability temperature 200°C is used in high-temperature adhesives, where excellent oxidative stability ensures prolonged performance. Particle Size <10 μm: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate with particle size less than 10 μm is used in coatings manufacturing, where improved solubility and homogeneous film formation are delivered. Viscosity Grade Low: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate of low viscosity grade is used in lubricant formulations, where rapid blending and efficient antioxidative properties are provided. Hydrolytic Stability High: Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate with high hydrolytic stability is used in waterborne resins, where retained antioxidant effectiveness in moist environments is maintained. |
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Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate doesn't just show up on spec sheets. It shapes outcomes in industries striving to extend the life and stability of their products. In the world of polymer processing and additive chemistry, people often spend years chasing solutions for oxidation and unwanted reactions. This particular molecule―often referred to by its trade or research code, sometimes known as a derivative of antioxidant 1098―helped my own team tackle degradation challenges in plastics and resins that outmatched older stabilizers.
With two robust tert-butyl groups and a propionate ester tail, this compound stands its ground against heat, oxygen, and time itself. I’ve seen formulations fail in accelerated aging tests, losing mechanical toughness or yellowing under UV. After switching to this stabilizer, the difference was obvious: products held up better, and the post-production headaches faded away. You get a phenolic antioxidant with a backbone tough enough for modern requirements and flexible enough for modified polymers and specialty resins.
If you ask most folks who work with oxidation-sensitive materials, they'll tell you that the small details in a molecule make a big difference. Carbon backbone, substituent placement, ring structure: these aren’t just trivia. Those tert-butyl groups block radical attacks that set off chain reactions in polymers. A methoxycarbonyl group adds a level of compatibility with hydrophobic phases and helps anchor the molecule within nonpolar matrices.
In melt mixing, compounding, or extrusion processes, lots of antioxidants burn off or migrate out, causing instability over time. Methyl β-(3,5-Di-Tert-Butyl-4-Hydroxyphenyl)Propionate holds its spot better than many predecessors; it doesn’t vaporize as easily under high heat. When I ran comparative mass loss studies, regular phenolic antioxidants didn’t fare so well, especially above 200°C. This molecule stuck around, so less frequent re-dosing and less property drift down the line.
It’s hard to ignore its efficiency. Because this compound handles oxidation at a lower loading level than BHT or simple tocopherols, I’ve watched teams cut costs and improve process throughput without sacrificing end-product quality.
You’ll spot methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate not just in neat white powder form in research labs, but as the silent guardian in finished goods ranging from automotive plastics to fiber optics. I spent months on one project with a polyacetals supplier—these folks used to field warranty complaints about yellowing gear wheels and brittle parts. Once they switched to this antioxidant, not only did the complaints taper off, but reprocessing rates dropped, too. They went from fielding angry calls to tracking multi-year durability improvements using this molecule.
Electronics insulators, wire and cable sheathing, medical devices, and high-performance coatings all benefit from this stabilizer. Engineers appreciate that it works in both thermosetting and thermoplastic systems, and formulators can blend it with phosphite antioxidants to create dual-action stabilization that resists both chain-breaking and hydroperoxide decomposition. I’ve seen it extend shelf life and maintain clarity in transparent polymer films, even in hot and humid conditions.
Chemically, this is a methyl ester derivative of a hindered phenol. With its well-defined melting point and tightly controlled purity, the commercial forms (often 98 percent or above) handle cleanly in automated feeds and batch processes. I rarely run into caking issues during storage; the particle size distribution lands right in the sweet spot for direct introduction into mixing barrels or pre-blends.
It’s a far cry from older antioxidants with dusty, inconsistent lots that made dosing a hassle. I’ve processed plenty of laboratory-grade and industrial lots, and the batches I’ve had from reputable suppliers have always offered predictable dispersion—no headaches or adjustments mid-run. The slightly higher molecular weight and ester group also mean less volatility, so you don’t catch whiffs of sharp odors in processing bays. Process operators don’t have to dodge fumes, and environmental teams have less concern about workplace exposure or nuisance emissions.
The chemical’s minimal solubility in water stays low, stopping it from leaching away in humid storage or during use. That’s saved products exposed to outdoor conditions or water ingress, and I’ve seen it perform steadily in both injection-molded housings and extruded profiles exposed to sun or rain.
Chemists used to rely on basic BHT, or butylated hydroxytoluene, for convenience and low cost, but batch consistency just doesn’t cut it for demanding applications. BHT can’t match the resistance this structure has against volatilization or UV breakdown. To put it into perspective: imagine seeing stabilized samples under a xenon arc lamp test. BHT-laced plastics crumbled faster and faded, while those with methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate kept their integrity far longer.
Younger staff sometimes ask why we don’t just increase loading levels of cheaper antioxidants. Experience tells me the cost alone isn’t the key issue. Migratory loss, chemical instability, problematic decomposition byproducts—all show up in real use. This compound avoids those traps. It stays in place because of its molecular mass and steric hindrance. It doesn’t disrupt downstream finishing, including painting or printing. Color pickup stays neutral, and mechanical properties stay true.
Mixing with other stabilizers? That’s another win. Most antioxidants can interfere with resin flow or catalyze unwanted side reactions. Here, I’ve blended the compound in dozens of resins—including POM, ABS, and various polyolefins—without gelling, loss in clarity, or unpredictable viscosity jumps. Its compatibility means manufacturers can run continuous processes without shutdowns for clarification or filter cleaning.
I’ve dealt with plenty of specialty chemicals that made the EHS team’s blood pressure spike. This compound avoids persistent organic pollutant classification and doesn’t carry the hazard warnings common with legacy additives. Less hydroquinone release and fewer concerns about long-term bioaccumulation give me peace of mind, especially as regulations tighten across North America and Europe.
The dustless, free-flowing granule options make it safer for operators and more convenient for scaled-up production. Manual feeding during lab or pilot runs goes smoother, and the consistency pays off in large-scale plants. Environmental health professionals consistently note that the compound's low aquatic toxicity stands out, which fits with efforts to close loopholes in environmental responsibility.
Sustainability isn’t a buzzword in this context. I watched as major brands caught flack for microplastics and leaching additives. The push to switch from legacy stabilizers to more robust, less migratory structures has become the standard. Brands that invest in more persistent protection—without inviting new environmental hazards—earn trust in demanding markets. I’ve worked with companies that marketed their move to this compound as a differentiator; customers responded, especially as end-of-life handling and regulatory restrictions tightened.
Every improvement in antioxidant performance carries another benefit. Longer product life translates to reduced waste. Less migration means fewer hazardous substances escaping into the environment. In my own consulting years, eco-assessments always favored this molecule when compared with low-molecular-weight phenols. Lower dosing, higher retention, and reduced environmental loss add up to a better score in lifecycle analysis reports, which increasingly guide purchasing decisions in technical procurement roles.
Pharmaceutical and medical device contexts show interest, too. Whenever material purity, non-interference with bioactivity, and long shelf life matter, this molecule holds its position. I’ve seen medical tubing, diagnostic devices, and clear disposable plastics all benefit. No adverse patient interactions, no unwanted leachables. Manufacturers can meet high purity grades and exacting regulatory standards, which means fewer recalls and longer regulatory listing durations.
The antioxidant world is full of options. I’ve managed technical trials with hindered amine light stabilizers (HALS), triazines, and phosphite blends. Each has its strengths and limitations, depending on temperature, light exposure, and resin type. Methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate fits best where base-level phenolic protection is critical. It won’t replace HALS for all-light stabilization, nor does it act as a UV absorber. Where it shines is providing core oxidation resistance, slowing polymer chain scission and color change.
I’ve compared reprocessing cycles in PP, HDPE, and engineered plastics. Samples stabilized with this compound didn’t yellow or lose flexibility at the same rate as those finished with conventional phenols. Post-extrusion and post-injection, the impact blows and elongation held up after repeated cycles. In multi-component stabilization regimes, blending with phosphites or thioesters covers secondary oxidation, while the core stabilizer resists initial thermal stress. Mixing and matching is common, but this one usually stands as the backbone in those formulations—a role that older phenols couldn’t quite manage due to volatility or incompatibilities with new polymer chemistries.
I remember the powder blending headaches. Old-style antioxidants often shipped with widely varying particle size, clumped in humid storage, and required sieving to avoid process blockages. Since more manufacturers offer methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate in granule or microprill forms, this isn’t an issue anymore. Handling and metering are smoother. Technicians spend less time managing feed hoppers and cleaning filters, which means fewer interruptions and higher overall productivity.
Storage stability comes from the very design. In high-humidity environments, where other additives clump or degrade, this compound keeps its shape and doesn’t degrade unexpectedly. I’ve helped set up monitoring programs for warehouses and never found evidence of mass loss, odor, or off-spec performance, even after a year in warm coastal climates. Other antioxidants, especially those with lower melting points or hygroscopic tendencies, don’t fare so well.
Plastics processors appreciate a stabilizer that doesn’t interfere with their main jobs. Color retention, mechanical property maintenance, ease of mixing—all add up to fewer headaches and fewer product returns. Process engineers, watching for line downtime and equipment maintenance, know that clogging, volatility, and unplanned shut-downs cost more in staff time than any savings on low-grade stabilizers.
No additive comes without its limitations. The cost of adoption for some firms—especially those deeply invested in legacy antioxidants—can sting. There’s a learning curve in optimizing loadings, checking for compatibility, and qualifying finished product performance. I’ve spent months running side-by-side trials and adjustment phases to fine-tune recipes for new resin grades. But the alternative—declining durability, field failures, increased warranty returns—always costs more over the lifecycle of a product.
In recent years, I’ve seen a shift. Regulators are raising the bar, customers demand more longevity, and brands want to avoid negative headlines connected to failed plastic goods. Choosing a more robust antioxidant like methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate isn’t just technical progress; it is risk mitigation and future-proofing. Engineers, chemists, and procurement folks are playing catch-up as the pace of technical requirements outruns yesterday’s solutions.
Recycling and reuse goals demand stabilizers that outlast multiple melt-process cycles. In secondary material streams, old antioxidants fade and performance crashes. With this compound, recycled plastics show less oxidation, which supports the circular economy push companies face from both consumers and governments. Fewer byproducts, less visible aging, and more reusability mean everyone along the value chain benefits.
My personal experience says the early headaches—qualification, regulatory listing, cost negotiations—fade quickly against the gains in product quality, compliance, and customer trust. Buyers who hesitate at the front end usually come around once field data show fewer complaints, stronger long-term performance, and less maintenance downtime.
Across industry conferences and professional societies, methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate is a regular subject of technical presentations and peer-reviewed papers. Its role in extending polymer lifecycles, while minimizing toxicity and environmental release, gets documented in material science journals, sustainability case studies, and regulatory filings. This isn’t a fleeting trend or a flash-in-the-pan additive; it’s a proven performer with real-world case histories.
Material scientists, process engineers, and regulatory experts recognize the need for transparency and integrity, which is why every serious supplier provides robust safety, environmental, and performance data. The best R&D teams run their own validation and post-market monitoring. In my own work, I saw regulatory staff look for clear proof of stability, compatibility, and low toxicity. The more scrutiny this compound faces, the more it stands out from less-documented competitors.
Companies care about future restrictions. Since this antioxidant avoids many of the persistent, bioaccumulative, or toxic traits regulators spotlight, you can rely on it for future supply security and continued product acceptance in global markets. That’s not something you say about every additive out there.
If you’re setting formulation strategy, start with a clear look at field data. Materials bills and warranty logs tell the truth: less durable plastics hurt reputation and profits. Small investments in high-retention stability agents like this one translate into fewer headaches downstream and stronger relationships up the supply chain.
Process teams benefit from setting up real-world pilot trials before wide adoption. Compare product lifetime, appearance, performance after reprocessing, and complaint ratios. In my teams, results from these in-use pilot phases drowned out initial price objections. I recommend close collaboration with resin and additive suppliers to tweak mixer conditions, dosing routines, and compound blends for each production environment.
Research does not stand still. Scientists are exploring ways to combine the best features of phenolic antioxidants and phosphites, along with sustainable raw material sourcing and improved end-of-life environmental footprint. My own colleagues run life cycle studies and circularity testing, benchmarking every new generation of antioxidant against methyl β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate as the current gold standard.
In the end, product durability and customer confidence build on stable chemistry. This stabilizer marks a decisive step away from short-lived, high-migration additives of the past. I trust it because evidence, not marketing hype, proves its value. From firsthand failures and successes across automotive, packaging, medical, and electronics industries, there’s simply no substitute for rigorous, reliable chemistry that works in the real world.